{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>是由一系列规则排列的微<span style=\"color:red\">电极</span><span style=\"color:red\">阵列</span>组成的复合<span style=\"color:red\">电极</span>,可以实现传统电化学测量中对大面积<span style=\"color:red\">电极</span>的统计平均信号的获取,而且可以给出<span style=\"color:red\">电极</span>微区的电位和电流大小和分布信息,从而准确表征<span style=\"color:red\">电极</span>表面的电化学不均匀性.本文就<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>技术在腐蚀领域的应用进展,及其优势与不足进行了总结,并对该技术的发展前景进行了展望.","authors":[{"authorName":"范林","id":"22cdf066-9d3d-47b7-9f86-3afd2d8d13fe","originalAuthorName":"范林"},{"authorName":"邢青","id":"979d4afd-8a91-4407-9f17-9c8cfb0887f1","originalAuthorName":"邢青"},{"authorName":"邱日","id":"82b51ba6-da70-4d04-b7e5-b0c5c425c3e8","originalAuthorName":"邱日"},{"authorName":"张慧霞","id":"62cb9add-6e02-4ef7-8500-30a9652eec40","originalAuthorName":"张慧霞"},{"authorName":"郭为民","id":"b6b3d3eb-40f3-47b9-9f03-b15ab69e0f1b","originalAuthorName":"郭为民"},{"authorName":"侯健","id":"34f69f3a-0a75-462f-b18d-712025e25144","originalAuthorName":"侯健"}],"doi":"10.11903/1002.6495.2014.364","fpage":"509","id":"2fe5cd52-b5a3-4ed6-95f5-7e700bceb5cf","issue":"5","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"d0f4a71a-349a-4766-9868-fb728ec1828f","keyword":"金属材料","originalKeyword":"金属材料"},{"id":"208ff8c8-0947-4a2a-84d2-fa7551d5e993","keyword":"<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>","originalKeyword":"阵列电极"},{"id":"571631c2-1286-4cf1-b0f7-1ef6b937e9b8","keyword":"局部腐蚀","originalKeyword":"局部腐蚀"},{"id":"ea24f0cd-1786-4063-ab9b-ccf65165331b","keyword":"微区电化学","originalKeyword":"微区电化学"}],"language":"zh","publisherId":"fskxyfhjs201505017","title":"<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>技术在腐蚀领域的应用进展","volume":"27","year":"2015"},{"abstractinfo":"在溶胶溶液中通过PAA模板沉积不同时间制备出LiCoO2晶须有序<span style=\"color:red\">阵列</span>.电子显微镜结果显示,沉积较长时间,所得晶须长度较长,分布更均匀,并且结晶程度更好.XRD分析表明得到了层状的LiCoO2结构.电化学测试表明LiCoO2晶须有序<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>具有很好的电化学可逆性和较高的容量.","authors":[{"authorName":"周盈科","id":"a22e2140-ef39-4b45-aeee-39ea1792353b","originalAuthorName":"周盈科"},{"authorName":"贺本林","id":"e73c173d-3b4a-4de8-9e11-e47d98f0dec8","originalAuthorName":"贺本林"},{"authorName":"申承民","id":"941ff3d1-0534-420d-b59d-0ba3a02f2dd0","originalAuthorName":"申承民"},{"authorName":"力虎林","id":"8f71658f-99ec-4c0d-b2b1-6a2258824426","originalAuthorName":"力虎林"}],"doi":"10.3321/j.issn:1000-324X.2004.04.015","fpage":"795","id":"c3f341f8-050e-41ac-9ec1-b8f9a1c21035","issue":"4","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"03bc5135-0312-45bf-9489-19e78ae17d9d","keyword":"LiCoO2晶须","originalKeyword":"LiCoO2晶须"},{"id":"dcacd86d-0141-4ec1-a4ed-ef5a5aa6a358","keyword":"<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>","originalKeyword":"阵列电极"},{"id":"a6643a32-de1a-41dd-9eb9-9a0d1482aa30","keyword":"锂离子电池","originalKeyword":"锂离子电池"},{"id":"c9139c40-add6-47d2-81ab-957a4cc03421","keyword":"PAA模板","originalKeyword":"PAA模板"}],"language":"zh","publisherId":"wjclxb200404015","title":"沉积时间对LiCoO2晶须有序<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>的影响及其电化学性质","volume":"19","year":"2004"},{"abstractinfo":"应用<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>技术研究了Q235碳钢在3.5％NaCl溶液中的电流分布,并根据电流分布变化过程探究了腐蚀机理.结果表明,浸泡起始阶段,自水线向下,阳极电流呈逐渐增大趋势,表现出宏观氧浓差电池的特征,但此时阴极与阳极电流交叉分布.水线腐蚀发展阶段,形成了以水线附近为阴极,水线下为阳极的氧浓差电池.水线上阴极反应速率的不断增加,推动水线下金属腐蚀由水线下逐渐向水线处扩展,加速了整个金属的腐蚀反应速率.水线腐蚀稳定阶段,水线上成为<span style=\"color:red\">电极</span>表面主要的阴极反应区域,腐蚀速率处于稳定状态.<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>测量技术可以提供整个水线区的电流分布及其变化信息,弥补了传统片状<span style=\"color:red\">电极</span>的不足,为水线腐蚀研究提供了有效的技术手段.","authors":[{"authorName":"陈亚林","id":"d9ce3e59-36b5-4b13-837b-ad938150d1ac","originalAuthorName":"陈亚林"},{"authorName":"张伟","id":"98829978-fc00-4fae-ae04-74ce069c01a5","originalAuthorName":"张伟"},{"authorName":"王伟","id":"ca1c4495-900c-4ed2-a8da-f33e03db71b0","originalAuthorName":"王伟"},{"authorName":"王佳","id":"974d1bef-30e9-4289-95e1-2a62f0f845bd","originalAuthorName":"王佳"},{"authorName":"王琦","id":"9207c423-a4b3-4fc8-93f7-1ccf138eaad4","originalAuthorName":"王琦"},{"authorName":"蔡光旭","id":"92282fc1-1472-4466-96d5-6aced6e5a3bb","originalAuthorName":"蔡光旭"}],"doi":"10.11902/1005.4537.2013.247","fpage":"451","id":"90d8f6f6-1eb1-48f0-84ac-387b7687b6db","issue":"5","journal":{"abbrevTitle":"ZGFSYFHXB","coverImgSrc":"journal/img/cover/中国腐蚀封面19-3期-01.jpg","id":"81","issnPpub":"1005-4537","publisherId":"ZGFSYFHXB","title":"中国腐蚀与防护学报"},"keywords":[{"id":"c05428a0-fff0-4e49-9125-e8a6268dadee","keyword":"水线腐蚀","originalKeyword":"水线腐蚀"},{"id":"d03e0347-83af-4b61-9c8f-1b586c111d9b","keyword":"<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>","originalKeyword":"阵列电极"},{"id":"13ca2317-f617-48ff-b3d4-4b94a9c7ada0","keyword":"金属腐蚀","originalKeyword":"金属腐蚀"},{"id":"40fb3c48-a017-4a64-8cb8-b83275e9ca5b","keyword":"电流分布","originalKeyword":"电流分布"}],"language":"zh","publisherId":"zgfsyfhxb201405009","title":"WBE技术研究水线区Q235碳钢腐蚀","volume":"34","year":"2014"},{"abstractinfo":"采用动电位极化(PDS)、电化学阻抗谱(EIS)、电容测量以及<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>等技术研究了Cu的短期贮存对其腐蚀电化学行为的影响.结果表明,金属Cu表面膜呈现p型半导体结构,经过短期贮存后载流子浓度减小,腐蚀电位正移,腐蚀电流密度下降,表面膜对腐蚀阴极过程、阳极过程均有抑制作用.Cu在NaCl液滴下呈现典型的局部腐蚀特征;经过贮存后,<span style=\"color:red\">电极</span>表面润湿性减弱,腐蚀活性降低,总体平均腐蚀强度减弱,但是局部腐蚀强度反而增强.","authors":[{"authorName":"冯林","id":"85e7d819-6a73-40c4-b84e-85cd436bbe19","originalAuthorName":"冯林"},{"authorName":"王燕华","id":"9e6d1b88-7da0-4c19-b887-d20c4afe0f99","originalAuthorName":"王燕华"},{"authorName":"钟莲","id":"425781ea-0887-4e44-b826-9897e6931253","originalAuthorName":"钟莲"},{"authorName":"王佳","id":"7e3c1427-9c3b-426d-8af3-76866c0fba6f","originalAuthorName":"王佳"},{"authorName":"李爱娇","id":"07513e2c-4015-4489-bf07-cd17da41d690","originalAuthorName":"李爱娇"},{"authorName":"金晓晓","id":"47ab83ac-bae9-4c67-9d9c-7496acb2e3ad","originalAuthorName":"金晓晓"}],"doi":"10.11902/1005.4537.2015.162","fpage":"375","id":"411fe6bd-7e19-42d0-a3fa-9804e8ebb771","issue":"4","journal":{"abbrevTitle":"ZGFSYFHXB","coverImgSrc":"journal/img/cover/中国腐蚀封面19-3期-01.jpg","id":"81","issnPpub":"1005-4537","publisherId":"ZGFSYFHXB","title":"中国腐蚀与防护学报"},"keywords":[{"id":"f3293f77-9474-4e51-82b2-a60154de4c48","keyword":"<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>","originalKeyword":"阵列电极"},{"id":"c8c288ad-d3a5-4633-9513-da967a5cfcc3","keyword":"短期贮存","originalKeyword":"短期贮存"},{"id":"d929d916-07b0-45ae-9e67-8d5ff8ab9431","keyword":"Cu","originalKeyword":"Cu"},{"id":"8557cb76-53bf-4233-b02c-cc94418edf3d","keyword":"Mott-Schottky曲线","originalKeyword":"Mott-Schottky曲线"},{"id":"06478bb1-a5a4-452f-bb9c-317311802a3e","keyword":"液滴","originalKeyword":"液滴"},{"id":"068eac3f-3ba5-4d17-bf4a-ab396556ef2d","keyword":"腐蚀","originalKeyword":"腐蚀"}],"language":"zh","publisherId":"zgfsyfhxb201604013","title":"短期贮存对金属铜腐蚀电化学行为的影响","volume":"36","year":"2016"},{"abstractinfo":"利用<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>技术捕获了在不同浸泡时间下每个微<span style=\"color:red\">电极</span>与其它99个微<span style=\"color:red\">电极</span>整体的电偶电流,分析获得了海水/海泥界面附近阴、阳极分布区域的变化规律;利用线性极化和电化学阻抗技术对垂直海水/海泥界面的一行微<span style=\"color:red\">电极</span>进行测试,获得了距海水/海泥界面不同距离的微<span style=\"color:red\">电极</span>的腐蚀电流、腐蚀电位,并观察了腐蚀形貌,探讨了其腐蚀机理.结果表明:平行于海水/海泥界面的海泥区域为电偶腐蚀阳极区、对应的海水区域为电偶腐蚀阴极区域;海水/海泥界面区金属的腐蚀是由电位差、溶解氧浓度、海泥阻抗等多因素控制;腐蚀主要区域是近海水/海泥界面的海泥区域及远海水/海泥界面的海水区域.海水中较高浓度的氧促进了腐蚀产物的致密化,而海泥中缺氧环境及微生物抑制了腐蚀产物的致密化.","authors":[{"authorName":"胡杰珍","id":"ce4c231d-0cc0-4f5d-9de5-26098cc2d663","originalAuthorName":"胡杰珍"},{"authorName":"李晓刚","id":"b1e374a8-f17a-4496-a738-d5646ab61508","originalAuthorName":"李晓刚"},{"authorName":"邓培昌","id":"cbd2ede4-3cfd-4616-8940-41f070266522","originalAuthorName":"邓培昌"},{"authorName":"张际标","id":"1b42094c-026a-45aa-9e54-1e3eaa2bf64a","originalAuthorName":"张际标"},{"authorName":"王贵","id":"267b964f-6f4a-4b11-bc46-7a9311c89188","originalAuthorName":"王贵"},{"authorName":"苏林海","id":"730e6321-db69-4a68-8e7f-839cfb17db1c","originalAuthorName":"苏林海"}],"doi":"10.11903/1002.6495.2015.195","fpage":"551","id":"68a33136-1f48-465a-bcb6-e4d5f1decfd7","issue":"6","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"886b31e3-d12f-487b-a6c1-c038b50861f0","keyword":"海水/海泥界面","originalKeyword":"海水/海泥界面"},{"id":"847d2218-a25b-4093-b9b7-ebeb4d15d74f","keyword":"腐蚀","originalKeyword":"腐蚀"},{"id":"403d9361-917b-48a5-8c0f-af00d07c13fc","keyword":"<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>","originalKeyword":"阵列电极"},{"id":"1f2e8a8f-a460-498a-9c10-5d11579dc8f5","keyword":"电偶腐蚀","originalKeyword":"电偶腐蚀"}],"language":"zh","publisherId":"fskxyfhjs201506004","title":"WBE联合LP技术研究海水/海泥界面碳钢的腐蚀行为","volume":"27","year":"2015"},{"abstractinfo":"采用模拟印刷电路板缝隙腐蚀装置,发展<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>方法测试缝隙内电路板表面铜在NaCl溶液中的腐蚀电位,研究了多种因素对其缝隙腐蚀行为的影响.结果表明,缝隙宽度为20～30μm时,印刷电路板容易发生缝隙腐蚀;在浸泡初期,缝隙内铜的腐蚀电位随浸泡时间延长负移,但浸泡48 h后,变化趋势较小;溶液中NaCl浓度达到1 mol/L时,对促进电路板的缝隙腐蚀作用较为明显;酸性范围内,缝隙内电路板腐蚀电位随缝隙大小、浸泡时间、NaCl溶液浓度、溶液的pH值降低而负移;温度低于45℃后,缝隙内铜的腐蚀电位随温度的升高而降低.","authors":[{"authorName":"曲文娟","id":"50736a1b-cac4-4965-bfc8-881afaac0b02","originalAuthorName":"曲文娟"},{"authorName":"杜荣归","id":"d890906a-e8aa-46ba-b5df-e80b399c326d","originalAuthorName":"杜荣归"},{"authorName":"卓向东","id":"9cb33be3-b862-4e65-b60f-4196c14668fa","originalAuthorName":"卓向东"},{"authorName":"林昌健","id":"7cdfa52b-3508-4fdc-bf3f-18402f7f519d","originalAuthorName":"林昌健"}],"doi":"","fpage":"4","id":"8306186d-e30e-4e86-b0a6-a2d49cdd72cf","issue":"2","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"56b61ced-3c06-4844-a1b7-bffaebc8245b","keyword":"印刷电路板","originalKeyword":"印刷电路板"},{"id":"52035433-aad6-4aed-9490-eba3dca7540b","keyword":"铜","originalKeyword":"铜"},{"id":"c3608204-e01f-4502-a687-c68591eb0d9e","keyword":"缝隙腐蚀","originalKeyword":"缝隙腐蚀"},{"id":"b2b34dd3-9693-4e44-86b0-f1b2b6b91c66","keyword":"<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>","originalKeyword":"阵列电极"}],"language":"zh","publisherId":"clbh200802002","title":"印刷电路板缝隙腐蚀行为研究","volume":"41","year":"2008"},{"abstractinfo":"本文提出了一种简易、低成本的钨丝微<span style=\"color:red\">电极</span><span style=\"color:red\">阵列</span>制作工艺和方法.该方法采用MEMS工艺制作的玻璃模具实现钨丝<span style=\"color:red\">阵列</span>的精密有序排列,同时,在钨丝<span style=\"color:red\">电极</span>表面涂覆一层光敏性的聚酰亚胺作为绝缘层,结合\"双面光刻\"技术和电化学腐蚀技术实现<span style=\"color:red\">电极</span>位点大小和<span style=\"color:red\">电极</span>丝几何尺寸的精确控制.最后,通过注模、光刻制作SU-8固定座体完成钨丝微<span style=\"color:red\">电极</span><span style=\"color:red\">阵列</span>的组装固定.整个制作工艺简单快速,且玻璃模具可重复使用,大大降低了制作成本.此外,本文还测试和评价了所制作微<span style=\"color:red\">电极</span>的表面形貌、电学性能以及生物相容性.","authors":[{"authorName":"姚源","id":"6ff0be43-158d-421f-8d31-23dc0f9f8edc","originalAuthorName":"姚源"},{"authorName":"李刚","id":"a3f5d1fc-7403-498b-b842-b50719b1a655","originalAuthorName":"李刚"},{"authorName":"张华","id":"32f60534-f4a2-45c6-bb33-7417815c2ceb","originalAuthorName":"张华"},{"authorName":"周洪波","id":"3d30a4bd-d59a-48b2-94a4-2716f574e928","originalAuthorName":"周洪波"},{"authorName":"孙晓娜","id":"e50b7190-9547-415e-bf8f-850fcc2ac463","originalAuthorName":"孙晓娜"},{"authorName":"朱壮晖","id":"6b0de3f1-45eb-4cd7-9da6-1f9fcf5cd99f","originalAuthorName":"朱壮晖"},{"authorName":"隋晓红","id":"df5981b4-aede-48d4-9c59-b2b2dc1542dc","originalAuthorName":"隋晓红"},{"authorName":"赵建龙","id":"47956295-0a80-4cca-b56f-eb3b195296aa","originalAuthorName":"赵建龙"}],"doi":"10.3969/j.issn.1007-4252.2009.01.004","fpage":"20","id":"560f4d30-ed25-4bb3-b0fd-44ef5f10de35","issue":"1","journal":{"abbrevTitle":"GNCLYQJXB","coverImgSrc":"journal/img/cover/GNCLYQJXB.jpg","id":"34","issnPpub":"1007-4252","publisherId":"GNCLYQJXB","title":"功能材料与器件学报   "},"keywords":[{"id":"af80953f-63f3-44d7-8839-99187f9f92ab","keyword":"微细加工","originalKeyword":"微细加工"},{"id":"e1e1a70d-197a-41f6-99a7-3c4641f19241","keyword":"钨丝","originalKeyword":"钨丝"},{"id":"ab2f2757-bfa1-487d-a047-b4a8e8cc1df0","keyword":"微<span style=\"color:red\">电极</span><span style=\"color:red\">阵列</span>","originalKeyword":"微电极阵列"},{"id":"8fccc752-4416-4bcb-bcca-c612086d7485","keyword":"神经探针","originalKeyword":"神经探针"},{"id":"dcfe0666-993d-4a1e-bf74-5326c03b112f","keyword":"双面光刻","originalKeyword":"双面光刻"}],"language":"zh","publisherId":"gnclyqjxb200901004","title":"钨丝微<span style=\"color:red\">电极</span><span style=\"color:red\">阵列</span>的简易制备方法","volume":"15","year":"2009"},{"abstractinfo":"采用氧化铝为模板的电化学沉积方法制备锡纳米<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>,用扫描电镜和X射线衍射仪表征<span style=\"color:red\">电极</span>微观形貌结构,并采用循环伏安和交流阻抗研究<span style=\"color:red\">电极</span>嵌锂过程,同时研究纳米晶锡薄膜<span style=\"color:red\">电极</span>和轧制锡箔<span style=\"color:red\">电极</span>.结果表明:纳米<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>与锡薄膜、锡箔<span style=\"color:red\">电极</span>具有不同交流阻抗谱特征,锡纳米<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>在中频区出现双电层阻抗,与其电解液/<span style=\"color:red\">电极</span>接触面积较大有关；不同微观结构形态下锡<span style=\"color:red\">电极</span>的电化学反应表面阻抗相差大于一个数量级,锡纳米<span style=\"color:red\">阵列</span>的表面膜电阻为19.8～14.6 Ω·cm2；锡纳米<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>上的锂离子扩散速率最大,0.2V嵌锂电位下扩散系数为10-10 cm2·s-1；采用纳米<span style=\"color:red\">阵列</span>结构使<span style=\"color:red\">电极</span>具有很高电的化学活性.","authors":[{"authorName":"王宇","id":"27c887f7-6b01-44e6-af20-5247713462cc","originalAuthorName":"王宇"},{"authorName":"刘浪","id":"33c3ecef-9d5c-49b3-8611-40fe51365e95","originalAuthorName":"刘浪"},{"authorName":"吴大平","id":"fddb7d6e-185e-423d-b5eb-f27c82da1e72","originalAuthorName":"吴大平"},{"authorName":"郭玉忠","id":"f751fd63-d9d8-4f34-b26c-362859fac8cd","originalAuthorName":"郭玉忠"},{"authorName":"王剑华","id":"c7acb2c3-876a-48a4-9c25-6021988d3f12","originalAuthorName":"王剑华"}],"doi":"","fpage":"1628","id":"90b7a178-f52d-4dfc-b7a0-df5c8c911a30","issue":"9","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"ac67b14e-b149-452e-ae1c-e211facee68d","keyword":"锡","originalKeyword":"锡"},{"id":"7fa48ecf-c664-4c47-adba-e002e1efd272","keyword":"纳米<span style=\"color:red\">阵列</span>","originalKeyword":"纳米阵列"},{"id":"9fad8748-fc22-4fb2-99b3-a4e1e45fe8e7","keyword":"锂离子电池","originalKeyword":"锂离子电池"},{"id":"7a428164-4aad-410e-94b9-2bc6322ca649","keyword":"循环伏安","originalKeyword":"循环伏安"},{"id":"4467797f-5b9d-42d3-b4c5-58f3b4570e20","keyword":"交流阻抗","originalKeyword":"交流阻抗"}],"language":"zh","publisherId":"xyjsclygc201209026","title":"纳米<span style=\"color:red\">阵列</span>和纳米晶薄膜锡<span style=\"color:red\">电极</span>性质的电化学研究","volume":"41","year":"2012"},{"abstractinfo":"为使TiO2纳米管<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>更好地应用于太阳能电池中,采取恒压阳极氧化法在质量分数0.5%NH4F/甘油电解液中在钛基体上制备出TiO2纳米管<span style=\"color:red\">阵列</span>.采用XRD、SEM、电子顺磁波普仪(EPR)、交流阻抗法(EIS)和循环伏安法(CV)研究TiO2纳米管<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>的电子传输性能及界面性质,确定各<span style=\"color:red\">电极</span>反应过程对应的阻抗曲线,计算得出<span style=\"color:red\">电极</span>的电子传输动力学参数.研究表明,TiO2纳米管<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>表面发生三价钛化合物转化成四价钛氧化物的氧化反应,<span style=\"color:red\">电极</span>电阻明显降低,加速了<span style=\"color:red\">电极</span>-电解液界面电子扩散速度,有利于TiO2<span style=\"color:red\">电极</span>表面自由羟基的产生.","authors":[{"authorName":"田西林","id":"573caa65-cab8-4261-9cb0-3353402ae671","originalAuthorName":"田西林"},{"authorName":"陶杰","id":"d4521f1e-97f7-4133-8747-9bfdf6a6b672","originalAuthorName":"陶杰"},{"authorName":"陶海军","id":"329007df-e5c4-4081-bd83-39f394368cf2","originalAuthorName":"陶海军"},{"authorName":"包祖国","id":"444556cf-b4e7-438b-8870-c3ff277a93d7","originalAuthorName":"包祖国"},{"authorName":"汤育欣","id":"33a65821-f907-455c-a559-8f6e06ccdf36","originalAuthorName":"汤育欣"},{"authorName":"李转利","id":"1640a384-c45f-410f-9f9c-a4a57d7ca125","originalAuthorName":"李转利"},{"authorName":"张焱焱","id":"e698a0fa-6acd-43db-b247-a67c503eeffd","originalAuthorName":"张焱焱"}],"doi":"","fpage":"1066","id":"960f59a9-b5c1-4d55-ae7d-350633c09f6e","issue":"6","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"30471722-9ed0-4d80-a6f6-37504153f77d","keyword":"阳极氧化","originalKeyword":"阳极氧化"},{"id":"5154cd15-9f7d-4711-b5ce-ffe43ad9f490","keyword":"TiO2纳米<span style=\"color:red\">阵列</span>","originalKeyword":"TiO2纳米阵列"},{"id":"91d1c37e-a1bf-4477-a398-383ac976c780","keyword":"循环伏安","originalKeyword":"循环伏安"},{"id":"901cf215-2259-4d4a-9638-fda3a31e841c","keyword":"交流阻抗","originalKeyword":"交流阻抗"}],"language":"zh","publisherId":"xyjsclygc201006029","title":"阳极氧化制备TiO2纳米管<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>反应及阻抗研究","volume":"39","year":"2010"},{"abstractinfo":"利用化学刻蚀法由p型硅片制备了硅纳米线<span style=\"color:red\">阵列</span>,经过表面去氧化层处理后,制备了检测蛋白质细胞色素c的电化学传感器.实验表明,硅纳米线<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>对细胞色素c有良好的电化学响应,并且在低浓度条件下具备线性响应的特点.根据与未经表面处理的硅纳米线<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>的实验结果相对比,提出了细胞色素c所具备的羧基末端与硅纳米线<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>表面的Si-H相互作用从而改善传感性能的检测机理.","authors":[{"authorName":"杨坤","id":"5644ee48-7dce-418e-87a5-a21b255f9d70","originalAuthorName":"杨坤"},{"authorName":"陈欢","id":"7e259b04-851f-46a0-8b0a-2784b3dedcd3","originalAuthorName":"陈欢"},{"authorName":"赵文超","id":"e2fc11ba-a397-4ca2-9382-d897e619787d","originalAuthorName":"赵文超"},{"authorName":"王建涛","id":"9a76c21a-a828-4a42-bb91-9590596ae5bc","originalAuthorName":"王建涛"},{"authorName":"王辉","id":"e689ea1b-9960-4edb-801d-513258827888","originalAuthorName":"王辉"},{"authorName":"张晓宏","id":"cd375c03-5143-4058-be1c-da8f848527a6","originalAuthorName":"张晓宏"}],"doi":"","fpage":"87","id":"bcf79fd1-b41a-4e7b-875b-30236c498c16","issue":"2","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"96277052-0680-4cae-9c1a-73f59788b1cb","keyword":"硅纳米线<span style=\"color:red\">阵列</span>","originalKeyword":"硅纳米线阵列"},{"id":"c3564414-2f47-483e-82c6-c88c67d67bc7","keyword":"电化学传感器","originalKeyword":"电化学传感器"},{"id":"e2de64e9-a8a8-483d-a46b-245cdb7ac417","keyword":"细胞色素c","originalKeyword":"细胞色素c"}],"language":"zh","publisherId":"ggkxyghx200902002","title":"硅纳米线<span style=\"color:red\">阵列</span><span style=\"color:red\">电极</span>作为细胞色素c传感器的研究","volume":"27","year":"2009"}],"totalpage":665,"totalrecord":6643}