Shixun DAI
,
Junjie ZHANG
,
Shunguang LI
,
Jianhu YANG
,
Shiqing XU
,
Guonian WANG
,
Lili HU
材料科学技术（英）
1 wt pct Nd2O3-doped tellurite bulk glass and fiber with the same composition of 75TeO2-15ZnO-5Na2O-5Li2O (mol fraction, %) were fabricated. Judd-Ofelt analysis was carried out for the bulk. The emission from the 4F3/2→4I13/2 transition in fiber is at 1.33μm wavelength with a spectral bandwidth of 55 nm, which is similar to that in bulk. In the case of the fiber, the lifetime of 4F3/2 level is 164μs, and the quantum efficiency is ~100%. The figure-of-merit for gain (σpτ0) for Nd3+-doped tellurite glass is about 2.8×10-24 cm2•s, which is quite comparable with that in Nd3+-doped fluoroaluminate glasses, and is an order of magnitude larger than Pr3+-doped fluoride glasses.
关键词:
Tellurite glass
,
null
,
null
,
null
Junjie ZHANG
,
Shixun DAI
,
Shiqing XU
,
Guonian WANG
,
Liyan ZHANG
,
Lili HU
材料科学技术（英）
In this work, a new TeO2-BaO-BaF2-La2O3-LaF3 oxyfluorotellurite glass system is investigated. Differential thermal analysis (DTA) and structural analysis by Raman scattering spectra are reported on the glasses. The DTA results indicated that an increase of fluoride content in the glasses decreases the glass transition temperature (Tg) and increases the crystallization onset temperature (Tx). As a result the 70TeO2•20BaF2•10LaF3 glass showed a large Hruby's parameter, possessing excellent thermal stability. Changes in glass network structure with fluoride content are discussed based on the Raman scattering spectra of glasses. The glass network structures in the 70TeO2• (20-x)BaO•xBaF2• (10-y)La2O3•yLaF3 glasses are basically composed of both Te(O, F)4 and Te(O, F)3 units, but the Te(O, F)4/Te(O, F)3 ratio in the glass becomes higher with increasing fluoride content. This may be considered one of the reasons why the 70TeO2•20BaF2•10LaF3 glass exhibits excellent thermal stability.
关键词:
Raman spectrum
,
null
,
null
F.T.Cheng
材料科学技术（英）
The present communication addresses an interesting problem related to the indeterminacy in hardness of superelastic NiTi reported by Xu et al. The origin of the indeterminacy is attributed to the inadequacy of the conventional Vickers hardness testing measurement which does not record elastic deformation, and thus the indeterminacy may be removed with suitable techniques. Concepts of hardness in relation to deformation are clarified. Recommendations for measuring the hardness of NiTi and other elastic-plastic materials are suggested, together with comments on the advantages and disadvantages of each of these methods.
关键词:
Hardness
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null
,
null
,
null
,
null
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null
Jingpei XIE
,
Yaomin ZHU
,
Xiaoping WANG
材料科学技术（英）
The M-s temperature, Delta G(gamma-->alpha), Delta G(gamma-->M) and mechanical energy under a non-severe impact loading in a medium manganese steel (Fe-7Mn-1.2C) have been calculated by means of Xu's Fe-X-C model. The relation between the yield strength of austenite and the driving force for martensite transformation has been established. It is proved that the martensite transformation can take place in a medium manganese steel (Fe-7Mn-1.2C alloy) under a non-severe impact loading.
关键词:
李莉
,
李庆芬
,
郑磊
,
徐庭栋
,
杜善义
钢铁研究学报
以工业用12Cr1MoV钢为研究对象,通过俄歇电子能谱分析方法(AES),对磷在恒温过程中的非平衡晶界偏聚浓度进行了测定.获得的磷在钢中的非平衡晶界偏聚动力学曲线直接验证了非平衡晶界偏聚动力学理论中的Xu-Song模型.
关键词:
晶界偏聚
,
临界时间
,
扩散
,
钢
陆樟献
,
龚雁
,
王渊明
,
王正才
,
陈善飞
功能材料与器件学报
doi:10.3969/j.issn.1007-4252.2012.01.005
基于Xu等人的经典振荡磁偶极子模型和Matsumoto等人给出的双折射驰豫理论,研究了磁致双折射和二向色性对磁性液体薄片的光透射率弛豫特性的影响.理论推导了磁性液体的双折射和二向色性函数的偏振光透射率具体表达式,并进行了数值模拟计算.该问题的研究对磁性液体光学各向异性的深入认识以及相关磁性液体光学器件的应用具有一定的指导意义.
关键词:
物理光学
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双折射驰豫
,
二向色性驰豫
,
磁性液体
,
磁偶极子
Journal of Materials Research
Based on the best bulk metallic glass (BMG) forming alloy in the Mg-Cu-Y ternary system, we introduced Ag (or Ni) to partially substitute for Cu to improve the glass-forming ability (GFA). The objective of this paper is twofold. First, we illustrate in detail a recently developed search strategy, which was proposed but only briefly outlined in our previous publication [H. Ma, L.L. Shi, J. Xu, Y. Li, and E. Ma: Discovering inch-diameter metallic glasses in three-dimensional composition space. Appl. Phys. Lett. 87, 181915 (2005)]. The protocol to navigate in three-dimensional composition space to land large BMGs is spelled out step-by-step using the pseudo-ternary Mg-(Cu,Ag)-Y as the model system. Second, our ability to locate the best BMG former in the composition tetrahedron allows us to systematically examine, and conclude on, the effects of a given alloying element. The large improvement in glass-forming ability in the Mg-(Cu,Ag)-Y system relative to the based ternary will be contrasted with the reduced glass-forming ability in the Mg-(Cu,Ni)-Y pseudo ternary system. It is demonstrated that the improvement of glass-forming ability requires judicious choice of substitutional alloying elements and concentrations, rather than simple additions of multiple elements assuming the "confusion principle."
关键词:
bulk metallic-glass;shaped copper mold;amorphous-alloys;thermal-stability;ternary-system;casting method;p system;diameter;zr;mm
