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Microstructure of the Ductile Phase in Intermetallic Compound Ni_(50)Al_(20)Fe_(30)

Lianlong HE , Shuhe WANG , Jianting GUO , and Hengqiang YE (Lab. of Atomic Imaging of Solids , Institute of Metal Research , Academia Sinica , Shenyang , 110015 , China)(To whom correspondence should be addressed)

材料科学技术(英)

The microstructure of the single hot extruded and annealed Ni50Al20Fe30Y0.003 intermetallic compound alloys has been examined by means of high resolution electron microscopy (HREM). In these extruded and annealed alloys. the ductile phase is of a mixture of the disordered fcc γ matrix and or dered γ' precipitates. This fact well interprets the reason why the degree of annealing treatment can influence the strength and ductility of these alloys. The HREM observation revealed directly that there was some strain concentration at γ'-γ interfaces, due to the presence of more iron atoms in these two phases. The fixed orientation relationship between the γ phase and γ' precipitates was identified to be {001}γ{00 }γ' and <100 >γ < 100 > γ'

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FRACTAL NATURE OF A FRACTURE SURFACE IN LAYERED SOLIDS

Chinese Physics Letters

We study the crack propagation in layered solids and find that when there exists an easy-fractured layer, the fractal surface becomes more rough, which is characterized by larger fractal dimensions.

关键词: dimension

Melting and superheating of crystalline solids: From bulk to nanocrystals

Progress in Materials Science

Melting of solids is a common phenomenon in nature. It is also one of the most important phase transformations in materials science and engineering. In recent years, extensive experimental and theoretical investigations in conjunction with computer simulations on melting of solids, with various geometries ranging from bulk forms to nanometer-sized clusters, have greatly enhanced our understanding of the nature of melting. This paper reviewed the up-to-date research results on this classical and cutting-edge topic. Emphasis was made on melting and superheating of nano-sized particles and thin films including thermodynamic and kinetic analyses of the size effect and the interfacial structure effect on melting processes. (C) 2007 Elsevier Ltd. All rights reserved.

关键词: isolated tin nanoparticles;embedded pb nanoparticles;kinetic stability;limit;energy ion-scattering;equation-of-state;small particles;electron-microscopy;molecular-dynamics;al(110) surface;al matrix

Synthesis of nanocrystalline materials from amorphous solids

Advanced Materials

The key to the formation of nanocrystallites from amorphous solids lies in the annealing temperature. This aspect of the preparation of nanocrystalline materials is covered, as are other attractive features of this method, for example, that it can be applied to most alloy and pure element systems, large quantities of nanocrystalline samples can be produced, and the grain size can be controlled. The properties of these materials are also described and it is concluded that more studies on 3D bulk: porosity-free, and clean samples are needed.

关键词: ultrafine grain-structure;alloys;selenium;sizes

Crystallization kinetics of amorphous solids under pressure

Physical Review B

The pressure effect on crystallization kinetics of amorphous solids was investigated by means of thermodynamic analysis. A model was developed to describe the nucleation process under pressure by considering the crystalline/amorphous (c/a) interface that plays a dominant role in the nucleation process. Applying the model to three types of crystallization process, polymorphous (a-Se), primary (Al89La6Ni5), and eutectic (Ni80P20), we found the calculated results can give reasonable explanations for the experimental observations. The calculation suggests that for a-Se and Ni80P20 amorphous alloy, the initial stage of nucleation is a volume expansion process due to the c/a interface formation, resulting in an increase in the nucleation work with an increment of pressure. Hence the crystallization temperature of the amorphous phase rises when a pressure is applied, while for the Al-La-Ni amorphous alloy, the nucleation barrier decreases at higher pressures. The coincidence between the calculation and the experimental results illustrates that the cia interface formation is the governing factor in the crystallization kinetics of the amorphous solids. [S0163-1829(99)03534-1].

关键词: activation volume;nanocrystalline state;metallic glasses;diffusion;alloy;selenium;phase;se;transformations;microstructure

LaB6功能陶瓷材料的研究现状

郑树起 , 闵光辉 , 于化顺 , 韩建德 , 王维倜 , 张树玉

材料导报

综述了目前国内外LaB6功能陶瓷材料的研究概况及应用,综合了制备LaB6粉末、多晶、单晶的各种工艺.

关键词: LaB6 , 功能陶瓷 , 制备工艺

Quantitative Analysis of Non-Crystalline and Crystalline Solids in Blast Furnace Slag

WANG Haifeng , ZHANG Chunxia , QI Yuanhong

钢铁研究学报(英文版)

China is short of water seriously. But granulation of blast furnace slag (BFS) with water has many disadvantages, such as high water consumption and difficulty in heat recycling. So developing a new dry granulation technique to treat BFS is very important. The applicability of BFS directly depends on the content of non-crystalline solids in the slag after treatment. So it is of theoretical and practical significance to analyze the content of non-crystalline solids in the slag quantitatively and simply. Metallographical test is mainly adopted to quantify the non-crystalline in BFS now with the shortages such as making sample complexly, determining difficultly and personally. For the diffraction intensity of non-crystalline is proportionate to the content of non-crystalline in BFS, X-ray diffraction method was adopted to quantify the non-crystalline and the crystalline solids in BFS. The quantificational coefficient between the crystalline and the non-crystalline solids of BFS is 0.70 whose main composition is: w(CaO)38.2%,w(SiO2)35.7%,w(Al2O3)16.3%,w(MgO)8.3%. The relatively error of using X-ray diffraction instrument to quantitative analyse non-crystalline content of BFS is less than 1%.

关键词: Blast Furnace Slag;Non-Crystalline;Crystalline;Quantificational Analysis

PREPARATION AND REACTIVITIES OF COMPOSITE NANOCRYSTALLINE SOLIDS PREPARED BY MECHANICAL ALLOYING

Journal of Non-Crystalline Solids

The formation of Fe-SiC composite, nanocrystalline solids through ball milling is reported. The effects of mechanical deformation, crystallite size and gaseous elements on the solid state reaction between Fe and SiC are also investigated. The formation of Fe3C after a long milling time is attributed to the kinetics of the reaction between nanocrystalline Fe and SiC.

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