材料期刊网

Sodium Activity in Molten Aluminum Measured with a Solid Electrolyte

Gang XIE Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , 200050 , ChinaShiyin SHEN Northeast University of Technology , Shenyang , 110006 , China

材料科学技术（英）

The sodium activities in aluminium in equilibrium with cryolite-alumina melt and during electrolysis were determined by EMF with Naβ-Al_2O_3 solid electrolyte.With this sodium activities,we calculate the activities of NaF and AIF_3 in the cryolite-alumina melt.The potential difference of discharge be- tween sodium ions and aluminum ions at cathode of Hall-Heroult cell was also obtained from the sodium activity in aluminum.

关键词: activity , null , null

Coercivity Mechanism of Melt-spun Nd-Fe-B Bonded Magnet

HUANG Gangxiang XU Qingzhen GAO Huimin YU Shanfu HUA Hongci WANG Geya Shanghai Iron and Steel Research Institute , Shanghai , 200940 , China.Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , 200050 , China.

材料科学技术（英）

The microstructures of melt-spun Nd_135- Fe_81.74B4.76 ribbons have been investigated by means of X-ray diffraction,Mossbauer spectroscopy and HREM.Experimental results show that optimal magnetic properties of the bond- ed magnet can be obtained by melt-spun alloys at wheel velocity of 24m/s,the microstructure of which was single phase Nd_2Fe_(14)B crystallites,and no other phases,such as Nd-rich,B-rich or x-Fe phase,were present.It is considered that the high intrinsic coercivity ~iH_c can be attributed to the sin- gle-domain behaviour of Nd_2Fe_(14)B crystallite phase.

关键词: coercivity , null

PATTERN RECOGNITION APLLIED TO STABILITY OF FILLED Ti_2Ni PHASES

ZHOU Diangen CHEN Nianyi Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , China professor , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , 200050 , China

金属学报(英文版)

Pattern recognition method is used for the investigation of stability,region of filled Ti_2Ni phases in multi-dimensional bond-parameter space.The filling of C,N and O atoms into T_6 octahedra consisting of atoms of earhy-transition elements makes the expansion of the stability region of Ti_2Ni phase,and the relative stability of AI_2Cu and MoSi_2 type com- pounds decreases after the introduction of non-metallic elements such as C,N and O.

关键词: filledTi_2Ni phase , null

Influence of the Preparative History on Physico-chemical Properties of Sodium Aluminate Solutions

CHEN Nianyi LIU Miaoxiu YANG Jinxiu ** Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , 200050 , China*** Laboratory of Theoretical Chemistry , Shanghai University of Science and Technology , Shanghai , 200180 , China+ To whom correspondence should be addr

材料科学技术（英）

关键词: sodium aluminate solution , null , null

Microstructure of the Ionic Discharge of Oxygen on Graphite Anode in Aluminium Electrolysis

By ZHANG Mingjie ZHAI Yuchun OIU Zhuxian LIU Honglin CHEN Nianyi Northeast University of Technology , Shenyang , 110006.China.Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , 200050 , China.To whom correspondence should be addressed.

材料科学技术（英）

With the SCF-ab initio and EHMO method used in quantum chemistry, the total energy and charge distribution are calculated for O ions which are adsorbed on the different positions of various C lattices. Furthermore, the microstructure is dis- cussed for O ions discharging on the graphite anode.

关键词: ionic discharge , null , null

Activity of NaOH in Sodium Aluminate Solutions

CHEN Nianyi LIU Miaoxiu Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , 200050 , China

材料科学技术（英）

关键词: sodium aluminate , null , null

Computerized Simulation of Structure of NaAIO_2 Melt

Chi XU Ming LI Nianyi CHEN Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , 200050 , China

材料科学技术（英）

The structure of NaAlO_2 melt has been studied by computerized simulation using Monte Carlo method.The radial distribution functions and Local structure of this melt are calculated.It has been found that NaAlO_2 melt contains ionic clusters formed by corner-sharing AlO_4 tetrahedra,sodium ions and xNa~+.yO~(2-) ionic clusters.

关键词: computerized simulation , null , null

关于多相材料的研究

材料导报

多相材料是材料研究发展的必然结果。提出多相材料的研究，目的是要拓宽材料研究的视野，主张模糊各类材料的界限，运用纳米材料制备技术，博采各类材料制备工艺之所长，以使用上的要求为材料研究的准则，制作出低成本和高性能稳定性的材料。还强调在考虑材料研究中的问题时，始终以满足使用要求为目标，并不一味地追求材料的高性能，务求创新。提倡用逆向思维来考虑多相材料的研完，研究对象则针对于信息、能源、生物和环保领域的应用。多相材料材料研究About the Research of Multi-phase MaterialsGuo Jingkun (Shanghai Institute of Ceramics,Chinese Academy of Sciences ,Shanghai 200050, China)

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SYNTHESIS OF TiN FILM WITH ION BEAM ENHANCED DEPOSITION AND ITS PROPERTIES

ZHOU Jiankun LIU Xianghuai CHEN Youshan WANG Xi ZHENG Zhihong HUANG Wei ZOU Shichang Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , China

金属学报(英文版)

The TiN films were synthesized with an alternate process of depositing titanium from a E-gun evaporation source and 40 keV N~+ bombarding onto the target.It is shown from the composi- tion analysis and structure investigations using RBS,AES,TEM,XPS and X-ray diffraction spectrum that the formed fihns are mainly composed of TiN phase with grain size of 30—40 nm and without preferred orientation,the nitrogen content in the film is much less than that in case without N~+ bombarding,and an intermixed region about 40 nm thick exists between the film and the substrate.The films exhibt high microhardness and low friction. ZHOU Jiankun,Ion Beam Laboratory,Shanghai Institute of Metallurgy,Academia Sinica, Shanghai 200050,China

关键词: TiN film , null

电化学阴极保护系统中的电位和电流分布

邱枫

腐蚀科学与防护技术

电化学阴极保护系统中的电位和电流分布邱枫(中国科学院上海冶金研究所九五届硕士研究生,上海200050)受电化学阴极保护的金属结构物表面的电位只有在一定的范围内才能受到有效的保护。因而,了解电位分布的规律是合理地设计阴极保护系统的必要条件。本文作者首先探讨了适用于阴极保护系统中电位和电流分布计算的有限元算法的应用范围,并提出了改善迭代收敛性的一种特殊的网格划分方法:在沿第二类边界面法向方向上适当细密地划分,....

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