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Transport Properties of KxV2O5?nH2O Nanocrystalline Films

A.A. Bahgat

材料科学技术(英文)

Five different compositions of KxV2O5?nH2O (where x=0.00, 0.0017, 0.0049, 0.0064 and 0.0091 mol) were prepared by the sol-gel process. Electrical conductivity and thermoelectric power were measured parallel to the substrate surface in the temperature range of 300-480 K. The electrical conductivity showed that all samples were semiconductors and that conductivity increased with increasing K content. The conductivity of the present system was primarily determined by hopping carrier mobility. The carrier density was evaluated as well. The conduction was confirmed to obey non-adiabatic small polaron hopping. The thermoelectric power or Seebeck effect, increased with increasing K ions content. The results obtained indicated that an n-type
semiconducting behavior within the temperature range was investigated.

关键词: Vanadium pentoxide xerogel

海水中阴极保护用镀铂钛阳极的研究

张玉萍 , 鞠鹤 , 武宏让

表面技术 doi:10.3969/j.issn.1001-3660.2004.06.026

镀铂钛阳极是海水阴极保护中广泛使用的辅助阳极.镀铂钛阳极具有良好的放氯性能,尺寸可变,重量轻,适合海洋中使用.在二亚硝基二氨铂为主盐的酸性镀液中制备了Pt/Ti阳极,测试了Pt/Ti阳极在人造海水中的电化学性能.研制的Pt/Ti电极表面光亮,镀层和基体结合牢固,镀层厚度可达5~10μm,在人造海水中的电化学性能稳定,损耗率为6.0225mg/A.a.

关键词: 阴极保护 , 镀铂钛阳极 , 海水

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