材料期刊网

THE INFLUENCE OF Mo DIFFUSION ON THE THERMAL BEHAVIOR OF TBCs ON Ni3Al BASED ALLOY IC-6

D.B.Zhang , S.K.Gong , H.B.Xu

金属学报(英文版)

Conventional two-layered structure thermal barrier coatings (TBCs) were preparedonto γ'-Ni3Al based alloy IC-6 by electron beam physical vapor deposition (EB-PVD).Isothermal oxidation and thermal cycling tests were carried out to investigate theeffect of Mo content at the interface between bond coat and ceramic top coat causedby diffusion. It has been found that the alloy coated with TBCs presented the lowestoxidation weight gain value for the reason that the ceramic top coat in TBC systemcan effectively stop Mo oxides evaporating. The life time of TBCs has close relationwith Mo content at the interface between the bond coat and top coat. Spallation ofceramic top coat occurred during thermal cyclic testing when Mo atoms accumulatedat the interface up to certain amount to decline the combination between the bond coatand top coat.

关键词: EB-PVD , null , null , null

Response to the Comment on 'Conjectures on exact solution of three-dimensional (3D) simple orthorhombic Ising lattices'

Philosophical Magazine

The error of Equation (15b) in my article [Z.D. Zhang, Phil. Mag. 87 (2007) p.5309] in the application of the Jordan-Wigner transformation does not affect the validity of the putative exact solution, since the solution is not derived directly from that equation. Other objections of Perk's comment [J.H.H. Perk, Phil. Mag. 89 (2009) p.761] are the same as those in Wu et al.'s comments [F.Y. Wu et al., Phil. Mag. 88 (2008) p.3093; p.3103], which do not stand on solid ground and which I have sought to refute in my previous response [Z.D. Zhang, Phil. Mag. 88 (2008) p.3097]. The conjectured solution can be utilized to understand critical phenomena in various systems, whereas the conjectures are open to rigorous proof.

关键词: 3D Ising model;exact solution;conjecture;critical phenomena;ferromagnetism;magnetic phase transition;model;analyticity

Mean-field theory on mixed ferro-ferrimagnetic compounds with (A(a)B(b)C(c))(y)D

Physics Letters A

The magnetic properties of the mixed ferro-ferrimagnetic compounds with (A(a)B(b)C(c))(y)D, in which A, B, C and D are four different magnetic ions and form four different sublattices, are studied by using the Ising model. And the Ising model was dealt with standard mean-field approximation. The regions of concentration in which two compensation points or one compensation point exit are given in c-a, b-c and a-b planes. The phase diagrams of the transition temperature T-c and compensation temperature T-comp are obtained. The temperature dependences of the magnetization are also investigated. Some of the result can be used to explain the experimental work of the molecule-based ferro-ferrimagnet ((NiaMnbFecII)-Mn-II-Fe-II)(1.5) [Cr-III (CN)6] - zH(2)O. (C) 2003 Elsevier B.V. All rights reserved.

关键词: mixed ferro-ferrimagnet;Ising model;four sublattices;phase diagram;transition temperature;compensation temperature;magnetic-properties;prussian blue;alloy

Jian ZHANG/Langhong Lou

材料科学技术（英）

关键词:

INVESTIGATION OF THE INTRINSIC PARAMETER ((B)OVER-BAR(2)(R(0))) FOR 3D(5) IONS IN THE CASE OF CHARGE MISFITTING SUBSTITUTION

Radiation Effects and Defects in Solids

The empirical superposition model has been applied to study the zero-field splitting and its stress; dependence for 3d(5) ions in some crystals. In the calculations, the reasonable local lattice relaxation and local compressibility changes have been taken into account in the case of charge misfitting substitution. The calculated intrinsic parameters (b) over bar(2)(R(0)) show good agreement with the normal (b) over bar(2)(R(0)) which is obtained from the 3d(5) ions in many crystals. So, the disparity between the parameter (b) over bar(2)(R(0)) obtained in the case of isocharge substitution and that in the case of charge misfitting substitution shown in the previous literature can be removed and the superposition model is applicable to the case of charge misfitting substitution.

关键词: superposition model;electron paramagnetic resonance;local lattice;relaxation;local compressibility;mn2+;fe3+;zero-field splittings;superposition-model;spinel crystals;mn2+

热压浸渍裂解法制备3D-B Cf/SiC复合材料性能的研究

所俊 , 郑文伟 , 肖加余 , 陈朝辉

材料科学与工程学报 doi:10.3969/j.issn.1673-2812.2002.02.010

本文通过先热压后先驱体浸渍裂解工艺制备3D-B Cf/SiC陶瓷基复合材料,以期达到缩短材料制备周期的目的.着重对热压温度、压力、时间等因素进行了研究,得到了可优化材料性能的工艺参数.

关键词: 热压 , 先驱体浸渍裂解 , 陶瓷基复合材料

固溶处理对AM60B+XRE及AZ91D+XRE 镁合金性能的影响

彭立明 , 曾小勤 , 朱燕萍 , 丁文江

材料研究学报 doi:10.3321/j.issn:1005-3093.2003.01.018

研究了添加少量富铈混合稀土的AM60B+xRE及AZ91D+xRE合金(x=0.4、0.8、1.2、1.6和2.0%,质量分数)固溶处理后的显微组织与机械性能.结果表明,添加混合稀土能显著提高合金的抗拉强度σb和屈服强度σ0.2,固溶处理明显提高AZ91D+xRE合金的强度;AM60B+xRE及AZ91D+xRE合金的铸态组织由α(Mg)固溶体、杆状Al11RE3相、颗粒状Al10Ce2Mn7相以及网状Mg17Al12相组成,经过固溶处理后,网状Mg17Al12相完全溶解,只剩下热稳定性较高的Al11RE3相和Al10Ce2Mn7相,随固溶时间的延长,其形态略有改变.AM60B+xRE合金拉伸试样断口呈带局部韧窝的准解理断裂形式,而AZ91D+xRE合金则呈现沿晶断裂+解理断裂的混合断口形态.

关键词: 金属材料 , 镁合金 , 稀土合金化 , 固溶处理

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

Three-dimensional (3D) Ising universality in magnets and critical indices at fluid-fluid phase transition

Phase Transitions

Experimental data for critical exponents in some magnetic materials are compared with recent theoretical results on the three-dimensional (3D) Ising model, as derived by one of us (ZDZ) based on two conjectures [Z.D. Zhang, Conjectures on the exact solution of three-dimensional (3D) simple orthorhombic Ising lattices, Phil. Mag. 87 (2007), pp. 5309-5419]. It is found that critical exponents in some bulk magnetic materials indeed form a 3D Ising universality. Our attention is then focused on the critical indices at fluid-fluid phase transition. We suggest to use Zhang's exponent = 3/8 to fit the experimental data over the wider asymptotic region near the critical point of a fluid-fluid phase transition. The 3D Ising universality should exist for critical indices in a certain class of magnets and at fluid-fluid phase transition.

关键词: magnetically ordered materials;fluid-fluid;phase transitions;order-disorder effects;ferromagnetic curie temperature;liquid critical phenomena;x-ray-scattering;critical exponents;critical-point;coexistence;curves;binary-solutions;ionic-solutions;behavior;equation

Superposition model parameters (b)over-bar(2) and t(2) for d(5) ion Cr+ in sulfides

Physica B-Condensed Matter

The superposition model has been applied to the studies of the zero-field splitting b(2)(0) for AgGaS2: Cr+ crystal and the uniaxial stress EPR data for ZnS: Cr+ crystal. These studies show that for [CrS4](7-) groups in crystals, the intrinsic parameter (b)over-bar(2)(R-0) approximate to -0.035(8)cm(-1) with the reference distance R-0 approximate to 2.378(20) Angstrom and the power-law exponent t(2) approximate to 14(4). To our knowledge, this is the first time that the superposition model parameters (b)over-bar(2) and t(2) are given for Cr+-S2- combination (or other Crc-X combinations). (C) 1999 Published by Elsevier Science B.V. All rights reserved.

关键词: electron paramagnetic resonance;superposition model;Cr+ ion;AgGaS2;ZnS;zero-field splittings;crystals;transition;mn-2+;fe-3+