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用于烯烃复分解反应的钌茚基催化剂的合成研究进展

开铖 , Francis Verpoort

材料导报 doi:10.11896/j.issn.1005-023X.2016.015.007

基于钌金属的烯烃复分解反应现今已成为一种至关重要且快速有效的催化反应类型,在聚合领域以及现代有机合成的应用方面起着改革性的推进作用。作为烯烃复分解反应催化剂的一种,钌茚基催化剂在该领域得到成功应用。结合近年来钌茚基催化剂在烯烃复分解反应中的合成研究进展,简述了其发展过程,介绍了该领域创新性的研究成果,重点论述了一些新型钌茚基催化剂的合成方法,并且探讨了辅助配体的结构对催化剂稳定性和活性的影响,最后对其发展方向以及应用前景进行了展望。

关键词: 钌茚基催化剂 , 烯烃复分解反应 , 催化活性 , 合成方法 , 聚合反应

E®ect of Welding Technologies on Decreasing Welding Residual Stress of Francis Turbine Runner

Shude Ji Liguo Zhang Xuesong Liu Jianguo Yang

材料科学技术(英文)

On basis of the subsection welding and the local heating´s reasonable technological parameters obtained by plane experiment, the welding residual stress field of some Francis turbine runner is regulated and controlled. For the experimental plane with a thickness of 16 mm, the effect of subsection welding on decreasing welding residual stress of the prior welding section is obvious when the distance is less than 50 mm away from the end of latter welding section. For the local heating, the best position, where the effect on decreasing the welding residual stress of plane is best, is 60 mm or so away from the edge of heating area. The experimental results of runner show that the subsection welding can make the residual compressive stress engender in the blade dangerous area while the stress value is greatly influenced by the length of the welding section of  blade outlet. The local heating can further decrease the value of residual stress near blade outlet, while the local heating processed after heat treatment is better than that processed before heat treatment.

关键词: Blade

重制汉代司南模型记

戴礼智

金属学报

<正> 1974年,李约瑟教授赞誉《古代中国科学对世界的影响》时,引用17世纪培根(Francis Bacon)曾指出印刷术、火药和指南针的发明,改变了全世界事物的面貌和状态,又从而产生了无数的变化。但据考古学者考证,我国在指南针发明之前,早已有一种指南器,名曰司南。下列文献均有记载: 《韩非子,有度篇》:“故先王立司南以端朝夕”。 《鬼谷子》:“郑人取玉,必载司南,为其不惑也”。

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