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Gammasphere上裂变丰中子核核结构若干前沿领域的新进展(Ⅰ:第一和第二部分)

罗亦孝 , J.H.Hamilton , J.O.Rasmussen , A.V.Ramayya , C.Goodin , A.V.Daniel , N.J.Stone , 朱胜江 , J.K.Hwang , 刘少华 , C.J.Beyer , 李科 , H.L.Crowell , D.Almehed , S.Frauendorf , A.Covello , V.Dimitrov , 张敬业 , 车兴来 , 姜卓 , D.Fong , A.Gelberg , I.Stefanescu , A.Gargano , E.F.Jones , P.M.Gore , I.Y.Lee , G.M.Ter-Akopian , Yu.Ts.Oganessian , M.A.Stoyer , R.Donangelo , 马文超 , J.D.Cole , J.Kormicki , 张学谦 , S.C.Wu , J.Gilat , T.N.Ginter , S.J.Asztalos

原子核物理评论

使用Gammasphere多探测器系统对252Cf裂变源瞬发γ射线进行γ-γ-γ和γ-γ(θ)符合测量,裂变丰中子原子核核结构若干前沿领域的深入研究获得了新的进展.高达5.7×1011以上的三重和更高重符合事件的数据统计,以及更少压缩的三维数据为宽广未知丰中子核区的寻找和研究提供了有利的条件.在具有重要物理意义的若干丰中子核区首次建立,或显著扩展了一批包括转晕态和转晕附近能态的高自旋能级纲图.在偶-偶丰中子核110,112Ru和108Mo中鉴别出了手征对称破缺结构.丰中子110,112Ru附近核的三轴形变基态具有最低的能量,在它们之中已确认了接近最大值的三轴形变.在这些Ru和Mo同位素中观察到的手征双线能带展示出手征破缺的一切特征,特别是其理想的能量简并,表明它们在迄今已报道的手征破缺结构中,具有最好的手征特性.研究了手征结构从具有γ软度的108Ru到具有大三轴形变的110,112Ru的过渡.斜轴推转(TAC)和随机相近似(RPA)理论计算成功地拟合了在这些偶-偶丰中子核中观察到的手征双线能带的特性,并指定其为软手征振动态.在这些偶-偶核中观察到的手征破缺不可能归纳为奇-奇核中那样的简化的几何图像.前者来自闭壳外所有中子的相互作用.对双幻核132Sn附近N=83同中素链的系统研究为这个极富吸引力的核区提供了大量新的谱学信息.N=83同中素135Te(Z=52),134I(Z=53),137Xe(Z=54),138Cs(Z=55)和139Ba(Z=56)的最新能级信息,特别是首次建立的138Cs高自旋能级纲图和壳模型理论计算表明,Z=50质子闭壳外少数g7/2价质子激发同N=82中子闭壳外之唯一F7/2价中子的耦合对该核区能级结构具有关键作用.观察到了132Sn和208Pb附近核区谱学信息的相似性和相对应的三粒子和五粒子态.在135Te中观察到了磁转动,这是在双幻核132Sn附近观察到的首例磁转动.

关键词: 丰中子核 , 高自旋 , 转晕态 , 裂变 , 252Cf , γ射线三重符合 , 角关联 , Gammas-phere多探测器系统 , 手征对称破缺 , 三轴形变 , 斜轴推转(TAC)计算 , 软手征振动 , N=83同中数链 , 双幻核132Sn , 壳模型计算 , 磁转动 , 谱学相似性

Gammasphere上裂变丰中子核核结构若干前沿领域的新进展(II:第三和第四部分)

罗亦孝 , J.H.Hamilton , J.O.Rasmussen , A.V.Ramayya , C.Goodin , A.V.Daniel , N.J.Stone , 朱胜江 , J.K.Hwang , 刘少华 , C.J.Beyer , 李科 , H.L.Crowell , D.Almehed , S.Frauendorf , A.Covello , V.Dimitrov , 张敬业 , 车兴来 , 姜卓 , D.Fong , A.Gelberg , I.Stefanescu , A.Gargano , E.F.Jones , P.M.Gore , I.Y.Lee , G.M.Ter-Akopian , Yu.Ts.Oganessian , M.A.Stoyer , R.Donangelo , 马文超 , J.D.Cole , J.Kormicki , 张学谦 , S.C.Wu , J.Gilat , T.N.Ginter , S.J.Asztalos

原子核物理评论

使用Gammasphere多探测器系统对252Cf裂变源瞬发7射线进行γ-γ-γ和γ-γ(θ)符合测量,A~100(Z~40,N>56)丰中子核区关于形状过渡、形状共存和形状突变的深入研究获得了新的进展.奇-Z核的系统研究揭示了从Z=39(Y)同位素的轴对称大四极形变到Z=43(Tc),44(Ru)和45(Rh)同位素中具有中等四极形变之大三轴形变的过渡.Nb(Z=41)同位素具有过渡核的特征.根据邻近同位素和同中素带交叉信息的系统性及推转壳模型(CSM)计算,Tc和Rh偶-N同位素中观察到的带交叉产生于一对h11/2中子的转动顺排.首次观察到100Nb(Z=41,N=59)的高自旋能级纲图和形变态,从而证实了100Nb中的形状共存,并确认,在Nb同位素链上,基态形状突变发生于N=58(球形)到N=59(大形变);而在Sr(Z=38),Y(Z=39)和Zr(Z=40)各同位素链上,基态形状突变均发生于N=59(球形)到N=60(大形变).100Nb具有大形变基态,同现有理论预言相矛盾,其大形变的基态及转动带所具有的很大的和不规则的转动惯量具有重要的理论意义. 对奇-质子Cs(Z=55)和La(Z=57)丰中子同位素八极激发的详细研究,发现了141,143,144Cs同位素链上电二极矩D.随中子数增加而减小的急剧变化,此前在145,147La中观察到的电二极矩Do的较缓和的减小似乎亦很陡地下延至148La.在Cs和La同位素中观察到的电二极矩D.的急剧下降很可能同偶-质子核146Ba和224Ra中观察到的电二极矩D.的急剧下降相类似,后者已获反射非对称平均场壳修正理论的成功解释.实验证明,141Cs具有很大电二极矩D.141Cs和142Xe中观测到的很大的电二极矩D.和仅在141Cs中观察到的电二极矩D.的simplex量子数相关性需要进一步的理论研究.根据转动频率比值ω-(I)/ω+(I)的检定,同Xe同位素一样,认定Cs同位素中包括号143Cs的八极激发为八极振动,而在La同位素中存在八极形变.

关键词: 形状过渡 , 轴对称形状 , 三轴形变 , 形状突变 , 带交叉 , 奇-质子 , 八极激发 , B(E1)/B(E2)比值 , 电二极矩D0 , 二极矩的下降 , 八极振动 , Cs,La同位素

mM)/mP)比值对磷酸镁水泥干燥收缩的影响及机理研究?

戴丰乐 , 齐召庆 , 汪宏涛 , 姜自超 , 张时豪 , 丁建华

功能材料 doi:10.3969/j.issn.1001-9731.2016.12.022

研究了m(M)/m(P)比值对磷酸镁水泥干燥收缩行为的影响,采用温度记录仪、压汞仪、X 射线衍射仪、扫描电镜及能谱仪等分析手段探讨了m(M)/m(P)比值对磷酸镁水泥干燥收缩的作用机理。结果表明,随着m(M)/m(P)比值的增大,磷酸镁水泥水化初期的膨胀量以及干燥收缩减小;水化8 h左右水泥开始收缩,龄期达到20 d左右收缩趋于稳定;磷酸镁水泥收缩量的减少,是由于m(M)/m(P)比值的增大导致磷酸镁水泥水化温度降低,孔隙率增大,水化产物MgKPO4?6 H2 O 减少,水化产物结构趋于疏松。

关键词: 磷酸镁水泥 , 干燥收缩 , m(M)/m(P)比值

m(M)/m(P)比值对磷酸镁水泥石自收缩的影响及机理研究

齐召庆 , 汪宏涛 , 薛明

功能材料 doi:10.3969/j.issn.1001-9731.2016.02.010

采用改进的非接触式混凝土收缩测定仪及标靶,研究了m(M)/m(P)比值(MgO与KH2PO4的质量比)对磷酸镁水泥石自收缩行为的影响,运用八通道微量量热仪、压汞仪、X射线衍射仪、扫描电子显微镜及能谱仪等分析手段,分析了m(M)/m(P)比值对磷酸镁水泥石自收缩的作用机理.结果表明,磷酸镁水泥石的自收缩呈现出3个阶段的特征,即早期的迅速收缩阶段、微膨胀阶段、收缩缓慢发展阶段.随着m(M)/m(P)比值的增大,由于磷酸镁水泥石的水化放热量降低,水泥石内部孔隙率增大,水化产物结晶度降低,水泥石结构疏松,所以,自收缩率减小.

关键词: 磷酸镁水泥 , 自收缩 , m(M)/m(P)比值

High Temperature Oxidation of FGH96 P/M Superalloy

F.J. Liu , M.C. Zhang , J.X. Dong , Y.W. Zhang

金属学报(英文版)

High temperature oxidation behaviors of FGH96 P / M superalloy have been studied in air at temperatures ranging from 600 to 1000℃. By means of isothermal oxidation testing, X-ray diffraction, SEM (scanning electron microscopy) and EDS (energy dispersive X-ray spectroscopy) analyses, the oxidation kinetics as well as the composition and morphology of scales were investigated. Thermodynamic calculations were used to explain the oxidation mechanism. The results showed that as the oxidation temperature increased, the oxidation rate, the scale thickness and scale spallation increased. FGH96 P / M superalloy exhibits good oxidation resistance at temperature below 800℃. The oxidation kinetics follows an approximately parabolic rate law, and the oxide layer was mainly composed of Cr2O3, TiO2, and a little amount of NiCr2O4. The oxidation is controlled by the transmission of chromium, titanium, and oxygen through the oxide scale.

关键词: FGH96 P/M superalloy , null , null

A Novel near Net-Shape Technique for P/M Parts with Large H/D Ratio

Yong LIU , Baiyun HUANG , Kechao ZHOU , Hongwu OUYANG , Yuehui HE

材料科学技术(英)

In order to overcome the shortcomings of conventional hot pressing, a novel near net-shape technique, called radial hot pressing, for P/M parts with large height-to-diameter (H/D) ratio was introduced. Effects of processing parameters on the microstructures and density of P/M TiAl base alloy valves were studied. Results show that the radial hot pressing is an effective technique for manufacturing valves with a H/D ratio of about 10:1, and the perfect joint interface between the Mo sheet and the parts is helpful for subsequent HIPing.

关键词: Near net-shape technique , null , null

FeMoB Enhanced Sintering of P/M 316L Stainless Steel

YANG Xia , GUO Shiju

钢铁研究学报(英文版)

Liquidphase enhanced sintering of powder metallurgy (P/M) 316L stainless steel by addition of sintering aids was studied. 2%-8% of prealloyed FeMoB powder with two different particle sizes was added as sintering aids, and the specimens were sintered in vacuum at 1 200-1 350 ℃. The results show that the fine FeMoB powder (5-10 μm) has stronger activated effect. The sintered density increases with the increase in sintering aid content or sintering temperature. Warm compaction has a better effect on the control of dimensional precision of compacts. The prealloyed FeMoB powder deviated from Mo2FeB2 component can also be sintering aid of P/M 316L stainless steel.

关键词: P/M 316L stainless steel;liquidphase sintering;activated sintering;FeMoB;sintering aid

Li1+xV3-yMyO8(M=Mo,P)高温阴极放电性能的研究

曹笃盟 , 李志友 , 周科朝

稀有金属材料与工程

采用固相反应法制备了Li1+xV3-yMyO8(M=Mo,P;0≤y≤0.4),研究了不同Mo和P含量对Li1+xV3O8相的影响,并首次对其进行了高温阴极放电性能的研究.结果表明:Mo和P掺杂量分别为y≤0.2和y<0.2时可获得纯Li1+xV3O8相;Mo掺杂使Li1+xV3O8峰值电压提高0.3 V,比容量提高25%,嵌入的Li+量最高可达x=3.8;P掺杂(y≤0.20)对Li1+xV3O8的峰值电压和比容量影响较小.化学嵌锂实验也证实掺杂后的材料具有更快的Li+嵌入速度.

关键词: Li1+xV3O8 , 热电池 , 掺杂 , 比容量

Microstructure and Tensile Properties of ZK60 Alloy Fabricated by Simplified Rapid Solidification Powder Metallurgy (S-RS P/M) Process

Zhenya Zhang

材料科学技术(英)

This study investigated the microstructures and mechanical properties of ZK60 alloy prepared by a simplified rapid solidification powder metallurgy (RS P/M) processing system (S-RS P/M), which consists of warm press in dry air and hot extrusion. Microstructure characterizations showed that S-RS P/M alloy consisted of magnesium matrix and oxide stringers of ~1 μm in width. TEM (transmission electron microscopy) observations illustrated nano-size magnesia particles (10{30 nm) constituted oxide stringer in detail. Due to a relatively higher volume of nano-size magnesia particle produced during S-RS P/M process, 0.2% yield strength of S-RS P/M ZK60 alloy was found to be as high as 382 MPa, which is 10% higher than that of RS P/M alloy. The improvement in mechanical properties is mainly attributed to the combination effects of Orowan mechanism and coe±cient of thermal expansion (CTE) mismatch because of the approximately same average grain size.

关键词: Microstructure

Chemical bonding and mechanical properties of M(2)AC (M = Ti, V, Cr, A = Al, Si, P, S) ceramics from first-principles investigations

Journal of Materials Research

MAX-phase carbides (M is an early transition metal, A is an A-group element) exhibit an interesting bonding characteristic of alternative stacking of strong M-C bonds and relatively weak M-A bonds in one direction. In the present first-principles total energy calculations, we establish the relationship between mechanical properties and electronic structure for ternary M(2)AC (M = Ti, V, Cr. A = Al, Si, P, S) carbides. By systematically tuning elements on the M and A sites, pronounced enhancements of bulk modulus, elastic stiffness, and ideal shear strength are achieved in V-containing V(2)AC (A = Al, Si, P, and S) carbides. It is suggested that tailoring on the A site is more efficient than on the M site in strengthening the mechanical properties of studied serial carbides. The results highlight a general trend for tailor-made mechanical properties of ternary M(2)AC carbides by control of chemical bonding.

关键词: strength;solids;shear;dislocations;ti3sic2

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