王海鸣
,
A.Dax
,
G.Ewald
,
I.Katayama
,
R.Kirchner
,
W.Nortershauser
,
H.J.Kluge
,
T.Kühl
,
R.Sanchez
,
I.Tanihata
,
M.Tomaselli
,
C.Zimmermann
原子核物理评论
doi:10.3969/j.issn.1007-4627.2002.02.055
对丰中子晕核11Li的核电荷均方根半径的实验确定, 特别是其与9Li的半径的差值, 将对各种核模型进行灵敏的检验. 选择锂的合适跃迁, 利用激光光谱技术高精度测量该跃迁的同位素移位, 并扣除精确理论计算的质量移位贡献值, 可以用来确定有关同位素的核电荷均方根半径. 就目前能够提供的实验设备和手段, 对于不稳定锂的同位素8,9Li和短寿命丰中子晕核11Li而言, 这是能够得到与核模型相独立的电荷半径值的唯一可行的方法. 这类实验正在德国重离子研究中心(GSI)和欧洲核子中心的ISOLDE/CERN 上计划实施.描述了锂原子的激光激发共振电离途径和进行锂的同位素移位测量的实验装置, 并讨论了采用这种方法测量到的6,7Li的初步结果及其精度, 以及使用该方法研究不稳定核的灵敏性.
关键词:
晕核
,
同位素移位
,
电荷半径
Physics Letters A
Except for a Peierls transition at T(p) = 180 K, a new transition around T = 270 K in K0.3MoO3 single crystals has been found as evidenced by the anomalies in electrical, magnetic and thermodynamic properties. This transition may be caused by the variation of carrier characteristics or of the charge transfer between cations and anions.
关键词:
Journal of Physics and Chemistry of Solids
Two different potential models to the molecular dynamics (MD) simulations have been applied to investigate the thermoelastic parameter alpha K-T of sodium chloride (NaCl) under high pressure and high temperature. The first one is the shell model (SM) potential that due to the short-range interaction when pairs of ions are moved together as is the case in that polarization of a crystal due to the motion of the positive and negative ions, and the second one is the two-body rigid-ion Born-Mayer-Huggins-Fumi-Tosi (BMHFT) potential with full treatment of long-range Coulomb forces. Particular attention is paid to the comparison of the SM- and BMHFT-MD simulations with the Debye model for the first time, and this model combines with ab initio calculations within local density approximation (LDA) and generalized gradient approximation (GGA) using ultrasoft pseudopotentials and a plane-wave basis in the framework of density functional theory (DFT), and it takes into account the phononic effects within the quasi-harmonic approximation. Note that the MD calculated volumes using SM model is somewhat larger than both the DFT and experimental volumes despite not considering the temperature effect. Compared with SM potential, the MD simulated 300 K isotherm of NaCl with BMHFT potential is very successful in reproducing accurately the measured volumes and the GGA calculated volumes. Generally, it is found that there exist minor differences between the LDA and GGA computed the thermoelastic parameter alpha K-T of NaCI, with both average results giving good agreement with SM-MD simulations. At an extended pressure and temperature ranges, the variation of thermoelastic parameter alpha K-T which play a central role in the formulation of approximate equations of state has also been predicted. The properties of NaCl are summarized in the pressure range of 0-300 kbar and the temperature up to 2000 K. (C) 2012 Elsevier Ltd. All rights reserved.
关键词:
Inorganic compounds;ab initio calculations;High pressure;Thermodynamic properties;molecular-dynamics simulation;density-functional theory;equation-of-state;alkali-halides;thermodynamic properties;elevated-temperatures;thermal expansivity;bulk modulus;ionic solids;nacl
B.H. Kim N.H. Kang W.T. Oh C.H. Kim J.H. Kim Y.S. Kim Y.H. Park
材料科学技术（英）
For Al 6k21-T4 overlap weld joint, the shear-tensile strength by using the weaving laser was improved as compared to the case of linear laser. For the specimen of low strength, the porosity was distributed continuously along the intersection between the plates and fusion line. However, for the optimized welding condition, large oval-shaped porosities were located only in the advancing track of the concave part. Therefore, the continuity of cracks and porosities played a key role to determine the strength. And, the weaving width was also the important parameter to control the strength. Furthermore, the concave part had more significant hot and cold cracking in the weld and heat-affected zone (HAZ), respectively, than the convex part.
关键词:
Weaving laser
,
Weld microstructure
,
Void
,
Al alloy
B.H. Kim N.H. Kang W.T. Oh C.H. Kim J.H. Kim Y.S. Kim Y.H. Park
材料科学技术（英）
For Al 6k21-T4 overlap weld joint, the shear-tensile strength by using the weaving laser was improved as compared to the case of linear laser. For the specimen of low strength, the porosity was distributed continuously along the intersection between the plates and fusion line. However, for the optimized welding condition, large oval-shaped porosities were located only in the advancing track of the concave part. Therefore, the continuity of cracks and porosities played a key role to determine the strength. And, the weaving width was also the important parameter to control the strength. Furthermore, the concave part had more significant hot and cold cracking in the weld and heat-affected zone (HAZ), respectively, than the convex part.
关键词:
Weaving laser
,
Weld microstructure
,
Void
,
Al alloy
Physica C-Superconductivity and Its Applications
Superconducting cuprate fluorides Nd0.7Sr1.3Cu(O,F)(4-delta) with T-c = 44 K were obtained by solid phase fluorination of the T-structure Nd0.7Sr1.3CuO4-gamma at low temperature (200-300 degrees C) using CuF2 as fluorinating reagent. The oxyfluoride has K2NiF4 structure with S.G. I4/mmm as its precursors, but the evident lattice expansions were observed. The a-axis expands from 3.7257(2) Angstrom to 3.9288(5) Angstrom and c-axis from 12.8240(3) Angstrom to 12.9630(2) Angstrom. No trace of SrF2 was detected in these fluorinated products. XRD and magnetic measurement revealed that the superconductivity in the fluorinated products originated from the oxyfluorides with reduced CuO2 plane and in the presence of the apical anion.
关键词:
hole concentration;copper;route;a=ca;tc
柳泽民
连铸
针对718HL中板边部裂纹的形成机制进行研究，认为微裂纹不是轧制时产生的新裂纹，而是由于铸坯内弧横裂纹扩展形成。造成横裂缺陷的主要原因是铸坯玲却不均匀。通过保证连铸关键设备功能精度、优化二冷配水工艺以及加强保护浇铸，能够有效降低中板边裂缺陷。
关键词:
中板
,
边部裂纹
,
铸坯
,
横裂
刘兴玉
,
丁淑芳
,
潘惠芳
催化学报
采用离子交换和浸渍相结合的方法制备了La/HL沸石.将不同La含量的La/HL沸石与REUSY沸石按不同比例复配后作为催化裂化催化剂的活性组分,用标准轻油微反方法(MAT)对催化剂样品进行了评价,考察了La/HL沸石添加量和La/HL沸石中的La含量对催化剂活性、反应产物分布、汽油产品辛烷值及催化剂上积炭的影响.结果表明,在裂化催化剂中分子筛总量保持不变的条件下,当La/HL沸石加入量为催化剂总量的1%～5%时,随着La/HL沸石加入量的增加,MAT活性和汽油收率增大,比积炭下降; 当La/HL沸石加入量大于10%时,MAT活性及汽油收率随La/HL沸石加入量的增加而降低,比积炭增加.当加入5%不同La含量的La/HL沸石时,产物中异丁烷含量增加; La/HL中的La含量低于3.5%时,产物异戊烷含量低于参比样品,但随着La含量的增加,异戊烷含量增大.当La/HL沸石中的La含量为0.2%～0.5%时,汽油中的芳烃含量显著增加,汽油产品的辛烷值提高了1.24～2.06.
关键词:
镧
,
HL沸石
,
改性
,
裂化催化剂
,
积炭
,
辛烷值
张健
,
张罡
,
毕鉴智
,
李玉海
,
姚俊
腐蚀科学与防护技术
TIA－450自绝缘二极管碳离子加速器对T5K10刀具进行了强流脉冲离子束辐照表面处理，加速器的加速电压为250 keV,束流密度为60 A/cm2～150 A/cm2, 脉冲时间为80纳秒，脉冲次数为2次.XRD、SEM、EDS以及显微硬度分析研究结果表明：当束流密度达到100 A/cm2，材料表面为完全熔化凝固组织；当束流密度达到150 A/cm2时，表面层下也出现熔化凝固组织；熔化凝固组织没有明显相变.在100 A/cm2～150 A/cm2内，同未辐照表面相比，显微硬度提高1.25倍.硬度增加的主要原因是表面快速凝固组织产生硬化相和基体相中化学成分的重新分布、碳元素的烧损以及晶界的强化.
关键词:
离子束
,
null
,
null
