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EFFECTIVE-MEDIUM THEORY OF PIEZOELECTRIC COMPOSITES

Journal of Applied Physics

Based on the developed multiple-scattering theory [C.-W. Nan and F. S. Jin, Phys. Rev. B 48, 8578 (1993)], an effective-medium theory (EMT) is proposed to treat coupled electromechanical behavior in composite media. The explicit relations for determining effective behavior of piezoelectric composites are derived. To illustrate the technique, numerical results of piezoelectric ceramic/epoxy composites for various particle shapes are presented over the whole range of concentrations. The EMT estimates are shown to be in good agreement with available experimental results. Porous piezoelectric ceramics are also discussed. The EMT predicts a similar critical behavior for heterogeneous piezoelectric materials to recent experiments.

关键词: electromechanical properties;ceramics

强制对流作用下多晶粒生长的相场模拟

袁训锋 , 丁雨田

材料导报

采用Tong和Beckermann等提出的耦合流场相场模型对纯镍凝固中多晶粒枝晶的生长过程进行模拟,研究了多晶粒枝晶的生长形貌和温度分布.结果表明,熔体流动显著改变凝固前沿的传热,从而影响枝晶生长.受熔体流动和多晶粒之间相互影响的共同作用,枝晶在4个最优生长方向上的形貌呈现不对称;熔体流动还改变了枝晶的水平最优生长方向,使得水平主枝向上游倾斜;此外,二次枝晶出现径向熔化和轴向熔化等粗化方式.

关键词: 相场法 , 强制对流 , 多晶粒 , 凝固

STUDY ON THE THREESTAGE CREEP OF THE DD3SINGLE CRYSTAL SUPERALLOY

Author X.A. Zhang1) , H.Q. Xia1) , Z.T. Wu1) , Y.F. Han1) , R. Shi2) and G.X. Hu2) \= 1) Mechanical Properties Laboratory , Beijing Institute of Aeronautical Materials , Beijing 100095 , China2) The State Education Commission Open Research Laboratory for High Temperature

金属学报(英文版)

Materials and Testing, Shanghai Jiao Tong University, Shanghai 200030, ChinaManuscript received 18 October 1998 The threestage creep behavior of DD3 single crystal superalloy had been studied. The results show that the creeprupture properties of DD3 single crystal satisfy the requirements for high performance turbine blade application. The influence of crystal orientation on the creeprupture property of DD3 single crystal was tested and discussed. An engineering criterion to evaluate the regimes of secondary and tertiary creep is proposed, and this method gives a reasonable result for practical applications. The fractography and TEM micrography of the tested specimens had been studied, and it is determined that the glidecontrolled creep is the basic creep mechanism of DD3 single crystal at intermediate temperature, but the thermally activated processes become dominant at higher temperature.

关键词: threestage creep curve , null , null , null

Crystallographic Tailoring of Graphene by Nonmetal SiO(x) Nanoparticles

Journal of the American Chemical Society

In this communication, we demonstrate nonmetal SiO(x) nanoparticles (NPs) can tailor few-layer graphenes (FLGs) into graphene nanoribbons (GNRs) and regular pieces with smooth edges. The tailoring of graphene is realized by the movements of SiO(x) NPs along the graphene lattice in the atmosphere of H(2), and the tailored trenches exhibit high selectivity of the crystallographic orientation compared to the reported metal. NPs. The low tailoring rate and the tong lifetime provide great potential for accurate control of the trench length or the length of the tailored GNRs. As a result, smooth GNRs with a length of several micrometers and a width narrower than 10 nm are obtained. A catalytic hydrogenation mechanism is proposed for the tailoring of graphene by SiO(x) NPs. These findings open up the possibility for atomically precise graphene device fabrication without metal, contamination and indicate the potential catalytic activity of nonmetal Nips for the hydrogenation of carbon materials.

关键词: nanoribbons;hydrogenation;graphite

Interactions between non-screw lattice dislocations and coherent twin boundaries in face-centered cubic metals

Acta Materialia

In a first report [Jin ZH.. Gumbsch P, Ma E, Albe K, Lu K, Hahn H, et al. Scripta Mater 2006;54:1163], interactions between screw dislocation and coherent twin boundary (CTB) were studied via molecular dynamics simulations for three face-centered cubic (fcc) metals, Cu, Ni and Al. To complement those preliminary results, purely stress-driven interactions between 60 degrees non-screw lattice dislocation and CTB are considered in this paper. Depending on the material and the applied strain, slip has been observed to interact with the boundary in different ways. If a 60 degrees dislocation is forced by an external stress into a CTB, it dissociates into different partial dislocations gliding into the twin as well as along the twin boundary. A sessile dislocation lock may be generated at the CTB if the transited slip is incomplete. The details of the interaction are controlled by the material-dependent energy barriers for the formation of Shockley partial dislocations from the site where the lattice dislocation impinges upon the boundary. (c) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

关键词: dislocation;slip;twinning;twin grain boundary;molecular dynamics;molecular-dynamics simulation;grain-boundaries;nanocrystalline;materials;cross-slip;rate sensitivity;deformation;copper;strength;aluminum;fcc

YBCO薄膜中自旋极化准粒子的注入效应

曹春海 , 杨名 , 张世远 , 杨森祖 , 崔旭高 , 尤立星 , 吉争鸣 , 康琳 , 许伟伟

低温物理学报 doi:10.3969/j.issn.1000-3258.2003.03.002

采用Nd0.7Sr0.3MnO3/SrTiO3/YBa2Cu3O7-δ的异质结构,研究了自旋极化准粒子的注入效应.在56μm宽的YBCO膜条上成功地制备了与超导膜条同样宽度但不同长度的六个注入结区,长度L分别为80μm, 40μm, 20μm, 10μm, 5μm和2μm.80nm厚的YBCO薄膜在16K温度下Jc为2×105A/cm2.Iin=0.5mA的自旋电流注入下,随L从80μm逐渐顺次减小时,注入效率η=ΔJc/ΔJin逐渐增大.而当L≤20μm后,η不再增加,达到几乎相同的值(~6).初步分析认为这与自旋极化准粒子在超导膜内的有效自旋扩散长度有关.异质结构中YBCO薄膜的超导电性以及注入窗口的尺寸对获得大的自旋注入效率十分重要.

关键词: 注入效率 , 自旋准粒子 , 巨磁阻 , 异质材料

桐马环氧玻璃丝粉云母绝缘材料的耐盐雾湿热老化特性

付强 , 孔繁荣 , 陈庆国

复合材料学报

为了研究海洋能电机主绝缘材料耐盐雾湿热老化能力,对电机多胶模压(Resin Rich Molding,RRM)桐马环氧玻璃丝粉云母(Tong ma Epoxy Glass Fiber Power Mica,TEGM)绝缘材料进行模拟海洋气候的盐雾湿热老化试验,测试了不同老化周期下材料的吸水率变化,并结合扫描电子显微镜(Scanning Electron Microscope,SEM)的观测结果分析了材料老化前后微观形貌的变化.利用宽频介电阻抗谱仪测试不同老化周期和不同测试温度下的TEGM绝缘材料的频域介电参数变化,并运用电介质极化理论分析老化前后的微观结构形态变化和宏观介电性能之间的关系.研究结果表明,TEGM绝缘试样老化过程中的吸水性呈现快速吸湿、缓慢吸湿和饱和吸湿3个阶段;随着老化时间的延长,材料相对介电常数和介质损耗因数呈上升趋势,利用频域介电谱(Frequency Domain Spectroscopy,FDS)曲线可较好反映绝缘材料的老化状态;通过对测试数据的拟合,得到老化绝缘材料的介电参数与材料吸水率在低频下存在的二次方程关系.

关键词: 盐雾湿热老化 , 频域介电谱 , 多胶模压 , 桐马环氧玻璃丝粉云母 , 绝缘材料 , 老化 , 吸水率

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