胡行方
,
快素兰
,
于云
,
TROUNG Vo-Van
无机材料学报
doi:10.3321/j.issn:1000-324X.2005.06.031
介绍了大面积有序反蛋白石结构介孔二氧化钛薄膜光子晶体制备与性能研究的进展.为了保证二氧化钛骨架结构的稳定性和有序度,从而使氧化钛介孔薄膜达到大面积结构均匀,在介孔薄膜制备过程中采用了几种新的工艺方法,其中包括二氧化硅晶体模板的应用和用NaOH溶液代替常用的HF溶液作为模板去除剂.制备的介孔二氧化钛薄膜光子晶体的面积达到厘米尺寸,二氧化钛骨架的填充率达到17.4%,薄膜制备过程中的收缩率＜3%.薄膜透射光谱研究结果表明,这种大面积3D有序的反蛋白石结构介孔二氧化钛薄膜具有非常优良的光子带隙特性,有望成为一类具有非常好的发展和应用前景的光子晶体材料.
关键词:
3D有序结构
,
反蛋白石结构
,
二氧化钛薄膜光子晶体
Physical Review B
The van der Waals (vdW) interactions between carbon nanotubes (CNTs) were studied based on the continuum Lennard-Jones model. It was found that all the vdW potentials between two arbitrary CNTs fall on the same curve when plotted in terms of certain reduced parameters, the well depth, and the equilibrium vdW gap. Based on this observation, an approximate approach is developed to obtain the vdW potential between two CNTs without time-consuming computations. The vdW potential estimated by this approach is close to that obtained from complex integrations. Therefore, the developed approach can greatly simplify the calculation of vdW interactions between CNTs.
关键词:
molecules;clusters;bundles;growth;phase;c-60
Yanwen TIAN
,
Yuchun ZHAI
,
Xin ZHANG
材料科学技术（英文）
The activity of VO in molten ternary CaO-SiO2-VO slag has been determined by chemical equilibrium method, using tin as the solvent metal. The relation between the activity and the content of VO, as well as the effect of slag basicity on activity of VO, are discussed.
关键词:
Chemical Physics Letters
The potential energies of van der Waals (VDW) interactions between two parallel, infinitely long and perfect SWNTs with identical, and different sizes were studied based on the continuum Lennard-Jones model. The conclusion of Girifalco's work on (n, n) SWNTs that the potentials of SWNT-SWNT fell on a single curve, is also applicable to SWNTs with different sizes. We further obtained the corresponding constants of the well depth \phi(0)\ and equilibrium VDW gap g(0) for SWNTs with a radius from 2 to 25 Angstrom. (C) 2005 Elsevier B.V. All rights reserved.
关键词:
carbon nanotubes;graphite;bundles;c-60;moduli;ropes
Journal of Physical Chemistry B
The potential energies of van der Waals interactions between two multiwalled carbon nanotubes (MWNTs) as well as two carbon nanoparticles (CNPs) were calculated and compared on the basis of the continuum Lennard-Jones model. The well depth of the potential is 1 order of magnitude higher for MWNTs than for CNPs, indicating that MWNTs and CNPs can be separated from each other through polymer-induced steric stabilization. On the basis of this prediction, a novel method for the purification of MWNTs was proposed. The method involves a high-temperature annealing ( 2600 degrees C, 1 h) followed by an extraction treatment with a selected dispersing agent. While the annealing process evaporates the metal particles, the extraction treatment removes CNPs. The quality of the nanotubes obtained after purification was examined by laser Raman, thermogravimetric analysis, and electron microscopy observations.
关键词:
decomposition;hydrocarbons;temperature;nanofibers;pyrolysis;monoxide;bundles;purity;gas
张霞
,
苏希玉
,
侯芹英
,
侯艳丽
低温物理学报
doi:10.3969/j.issn.1000-3258.2008.03.011
考虑态密度的Van Hove奇异性和非电声作用,我们在BCS理论框架内研究了HgBa2Cun-1CunO2n+2+δ(n=1,2,3)系统的超导转变温度和同位素效应.结果表明,当同时考虑Van Hove奇异性和非电声作用时,可以更好地解释HgBa2Cun-1CunO2n+2+δ(n=1,2,3)系统的超导性质.
关键词:
Van Hove奇异性
,
非电声作用
,
超导转变温度
,
同位素效应
齐济
,
宁桂玲
,
华瑞年
,
田密霞
材料导报
VO2是一种温感相变材料,68℃左右它从低温半导体相向高温金属相转变,同时其光学和电学性质发生突变.由于V与O之间可以形成任意化学配比的VxOy,,所以纯VO2的制备过程复杂难以控制.采用单一原料NH4VO3,在化学计量反应计算的基础上将其装入刚玉坩埚,置于特制的高压釜中,升温至1000K,反应60min,自然冷却得蓝黑色VO2样品.利用X射线衍射、扫描电镜和差示扫描量热法对样品进行表征与测试.结果表明,所制备的样品为VO2多晶粉末.粒度为几至几十微米,具有相变特性.相变温度为343.53K,相变过程是吸热过程,相变焓为43.75J/g.目前,该方法是合成VO2研究中最简单易行的方法.
关键词:
二氧化钒合成
,
偏钒酸铵分解
,
晶相结构
,
相变性质
张弛
,
刘梅冬
,
曾亦可
,
刘少波
,
黄焱球
材料导报
综述了VO2薄膜的制备工艺,着重探讨了热处理工艺和条件对其性能的影响,并介绍了它的最新应用情况.
关键词:
VO2薄膜
,
制备工艺
,
热处理
,
非制冷红外焦平面
,
光阀
,
激光器反射镜
