Ying Zhang Jun Lin Dijiang Wen
材料科学技术（英文）
Ferrite compound Co0:6Zn0:4NixFe2-xO4 was synthesized by solid state reaction. The structure and performance of Co0:6Zn0:4NixFe2-xO4 compounds were studied by MÄossbauer spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and infrared radiant tester. MÄossbauer spectroscopy and XPS analysis show the valence states and distribution of cations in Co0:6Zn0:4NixFe2-xO4. Zn2+ has invariably shown preference for the tetrahedral sites, and Ni2+ has the preference for the octahedral sites. The occupancy of Fe3+ linearly increases on the tetrahedral sites, and sharply decreases on the octahedral sites with increasing x, owing to its gradual replacement by Ni2+ on the octahedral sites. It indicates that due to the occupation of octahedral sites by the majority of Ni2+, Fe3+ decreasingly migrated from the octahedral sites to the tetrahedral sites and substituted Co3+ sites, which made the number of Co3+ in the tetrahedral sites decreasing. According to the measurement results of XRD and the infrared radiant tester analysis, the lattice parameter and infrared radiance have shown a nonlinear variation, exhibiting the infrared average radiance of 0.92 in the 8-14 μm waveband, and the results demonstrate that these Co-Zn-Ni spinel ferrites have potential for application in a wide range of infrared heating and drying materials.
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Infrared radiance
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刘欣艳
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赵煜娟
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夏定国
功能材料
LiNi0.8Co0.2O2是锂离子电池界公认的最有希望取代商业化正极材料LiCoO2的新型正极材料之一.本文所研究的复合正极材料LiNi0.8Co0.2O2是由细小的晶粒构成的球形颗粒,单一相,属于R3m空间群.对复合材料LiNi0.8Co0.2O2的Co-K和Ni-K的XANES分析可知,在600～850℃范围温度对于钴元素的影响不明显,而对于镍元素的影响比较显著,随着Ni-K边位置向高能量移动LiNi0.8Co0.2O2正极材料的放电容量升高.复合材料LiNi0.8Co0.2O2和LiNiO2的Ni-K边XANES相似,表明少量钴的引入对晶体结构的改变不是太多,但是峰的强度较高和峰的位置向高能量移动,表明钴Co对Ni的局域结构进行了调制.
关键词:
LiNi0.8Co0.2O2
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XANES
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正极材料
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局域结构
Journal of Materials Research
The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.
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room-temperature
Philosophical Magazine
The error of Equation (15b) in my article [Z.D. Zhang, Phil. Mag. 87 (2007) p.5309] in the application of the Jordan-Wigner transformation does not affect the validity of the putative exact solution, since the solution is not derived directly from that equation. Other objections of Perk's comment [J.H.H. Perk, Phil. Mag. 89 (2009) p.761] are the same as those in Wu et al.'s comments [F.Y. Wu et al., Phil. Mag. 88 (2008) p.3093; p.3103], which do not stand on solid ground and which I have sought to refute in my previous response [Z.D. Zhang, Phil. Mag. 88 (2008) p.3097]. The conjectured solution can be utilized to understand critical phenomena in various systems, whereas the conjectures are open to rigorous proof.
关键词:
3D Ising model;exact solution;conjecture;critical phenomena;ferromagnetism;magnetic phase transition;model;analyticity
中国腐蚀与防护学报
N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat（6）Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac（13）SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch＆tllsth Of ThlollY68 Oil ITOll ID H....
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Physics Letters A
In a magnetic system, consistent with Griffiths analyticity requirements one can parameterize the equation of state near criticality by writing H = r(beta delta)h(theta), T = rt(theta) and the magnetization M = r(beta)m(theta), where T is measured from the critical temperature. For the insulating ferromagnet CrBr(3), the experimental data of Ho and Litster [J.T. Ho, J.D. Litster, Phys. Rev. Lett. 22 (1969) 6031 is well fitted by m(theta) as a linear function of theta [P. Schofield, J.D. Litster, J.T Ho, Phys. Rev. Lett. 23 (1969) 1098]. Also Ho and Litster give beta = 0.368, gamma = 1.215 and delta = 4.3. Those critical experiments are very close to the recent 31) king results of Zhang [Z.D. Zhang, Philos. Mag. 87 (2007) 5309], namely beta = 3/8, gamma = 5/4 and delta = 13/3. We therefore predict that m(theta) will be proportional to theta as a fingerprint of the 3D Ising Hamiltonian. (C) 2009 Elsevier B.V. All rights reserved.
关键词:
Critical-point effects;Critical exponents;Ising model;Criticality;Ferromagnet;Magnetic equation of state;critical exponents
