{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以六<span style=\"color:red\">氟</span>环氧丙烷低聚物和(甲基)<span style=\"color:red\">丙烯酸</span>-β-羟乙<span style=\"color:red\">酯</span>为起始原料,合成了(甲基)<span style=\"color:red\">丙烯酸</span>-β-(全<span style=\"color:red\">氟</span>炕氧基酰基)乙<span style=\"color:red\">酯</span>四种新型含<span style=\"color:red\">氟</span>单体,其结构经红外光谱(FT-IR)、核磁共振(1H-NMR和19F-NMR)确证.初步考察了上述单体对<span style=\"color:red\">丙烯酸酯</span>类紫外光固化涂料的改性作用,结果表明,提高含<span style=\"color:red\">氟</span>组分比例对固化膜的初始水接触角影响较小,但经过加热后处理可显著增强固化膜的疏水性.由此推断,热处理能有效促进含<span style=\"color:red\">氟</span>侧基向表面迁移,且含<span style=\"color:red\">氟</span>侧链越长,这种向空气界面富集的倾向尤为明显.当含<span style=\"color:red\">氟</span>组分占涂料配方的4%～6%(质量分数,下同)时,固化膜的最大水接触角可达到120°.","authors":[{"authorName":"郦聪","id":"04888057-e797-4617-9bef-3dc75040fa73","originalAuthorName":"郦聪"},{"authorName":"李家才","id":"f3e0946b-e0d2-4d98-857b-2b01034cdc99","originalAuthorName":"李家才"},{"authorName":"刘光烜","id":"c7b92f5b-5e8e-4743-a415-2a19342b5aa7","originalAuthorName":"刘光烜"},{"authorName":"余考明","id":"2c23cb5e-6b87-402e-a3e9-8f022cdc63c7","originalAuthorName":"余考明"},{"authorName":"江黎明","id":"1cbf81e2-edea-47e4-9657-fdcf4d6151f4","originalAuthorName":"江黎明"},{"authorName":"沈之荃","id":"644fd67a-bc27-463e-ac57-d6dd10929fb0","originalAuthorName":"沈之荃"}],"doi":"","fpage":"1","id":"8d1f4f12-46d2-4261-bdc0-1504e13f4d31","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"dc868d42-23ad-41b8-b8eb-cd4a7f7d00b6","keyword":"六<span style=\"color:red\">氟</span>环氧丙烷低聚物","originalKeyword":"六氟环氧丙烷低聚物"},{"id":"0b772f28-b58b-4f41-b3a4-3da3a86ddb7d","keyword":"<span style=\"color:red\">氟</span><span style=\"color:red\">代</span><span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"氟代丙烯酸酯"},{"id":"9a75ab18-78c0-41ec-88c0-cae11920d2a5","keyword":"紫外光固化","originalKeyword":"紫外光固化"},{"id":"ebbddb59-5b75-495c-a310-c0a1e75fb0a2","keyword":"疏水性","originalKeyword":"疏水性"}],"language":"zh","publisherId":"gfzclkxygc201009001","title":"含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>单体的合成及固化膜的性能","volume":"26","year":"2010"},{"abstractinfo":"在阳/非离子表面活性剂及引发剂作用下,将甲基<span style=\"color:red\">丙烯酸</span>十二<span style=\"color:red\">氟</span>庚<span style=\"color:red\">酯</span>、甲基<span style=\"color:red\">丙烯酸</span>十二醇<span style=\"color:red\">酯</span>、<span style=\"color:red\">丙烯酸</span>羟丙<span style=\"color:red\">酯</span>、甲基<span style=\"color:red\">丙烯酸</span>二甲氨乙<span style=\"color:red\">酯</span>、乙烯基三乙氧基硅烷进行乳液共聚,制得了硅烷改性的阳离子<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>乳液(FL-HDV).用红外光谱(FT-IR)和核磁共振氢谱(1H NMR)对FLHDV主组分的结构进行了表征,用X射线光电子能谱仪(XPS)对乳液的成膜表面成分进行分析和表征,并讨论了硅烷改性前后及不同的整理工艺对其在涤纶织物上应用性能的影响.结果表明,与未用硅烷改性的<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>乳液(FLDH)对比,硅烷改性可以提高含<span style=\"color:red\">氟</span>聚合物的交联度,进而增加织物的拒水拒油性.XPS分析和接触角测定结果表明,在涤纶纤维表面明显存在有FLHDV膜,使得纤维与空气的界面上富集着疏水的含<span style=\"color:red\">氟</span>链段,而硅氧基团与纤维表面结合,从而赋予涤纶良好的拒水拒油性.在不同的工艺条件下,一浸一轧工艺处理的织物具有更高的拒水拒油等级,且弯曲刚度略低,柔软度较好.","authors":[{"authorName":"亢玲娟","id":"314fdc71-7159-4d1a-af9e-3c26115e69a4","originalAuthorName":"亢玲娟"},{"authorName":"安秋凤","id":"0b9f799f-316b-48db-8bf6-7b6be513bcdd","originalAuthorName":"安秋凤"},{"authorName":"王前进","id":"29ab5636-bdc3-4f1f-a01c-4bc8965dd72d","originalAuthorName":"王前进"},{"authorName":"袁俊敏","id":"586a9162-560b-48c3-971d-7606f6c9ac3c","originalAuthorName":"袁俊敏"},{"authorName":"刘爽","id":"6ec2cc87-86e4-487c-8089-6c7fe1e54965","originalAuthorName":"刘爽"}],"doi":"10.3969/j.issn.0253-4312.2011.01.002","fpage":"1","id":"cf3c5b65-b703-45d2-8e4b-aaf977f220be","issue":"1","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"b45e372e-0c3e-490d-90e9-6a364510b9ac","keyword":"<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"氟代聚丙烯酸酯"},{"id":"6bf40fe7-98d4-4262-a975-b5f59ffad2d8","keyword":"硅烷改性","originalKeyword":"硅烷改性"},{"id":"694002d7-e1bb-4b0f-ba4b-0b99ac430c8d","keyword":"乳液聚合","originalKeyword":"乳液聚合"},{"id":"2f220b43-5f88-4d51-af08-adc052cb7162","keyword":"拒水拒油","originalKeyword":"拒水拒油"},{"id":"33484163-aedf-44e5-a0b5-63664d2b34bb","keyword":"涤纶","originalKeyword":"涤纶"}],"language":"zh","publisherId":"tlgy201101002","title":"硅烷改性<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>乳液的合成及其应用","volume":"41","year":"2011"},{"abstractinfo":"在过氧化苯甲酰作用下,利用甲基<span style=\"color:red\">丙烯酸</span>十二<span style=\"color:red\">氟</span>庚<span style=\"color:red\">酯</span>与<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>、甲基<span style=\"color:red\">丙烯酸</span>二甲氨乙<span style=\"color:red\">酯</span>、<span style=\"color:red\">丙烯酸</span>羟丙<span style=\"color:red\">酯</span>的溶液聚合反应合成了一种<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>(FBDH),用场发射扫描电镜(FESEM)、原子力显微镜(AFM)等对其结构、成膜性及膜形貌进行了研究.结果表明,在观察尺寸为50 nm、扫描范围为5 μm×5μm条件下,观察所合成的FBDH微观上会表现出一种相分离结构,在其表面有众多凸起峰状物存在.将FBDH附着固化在棉纤维织物表面,可明显改善织物的疏水效果,并使水的静态接触角达到138.5°;而用1%硅溶胶对棉纤维先进行粗糙化处理再附载FBDH,则有助于产生超疏水效果,且能使处理后织物表面的接触角达到153.6°.","authors":[{"authorName":"安秋凤","id":"2df37aac-57ae-4576-9ed1-b9df6cd18b11","originalAuthorName":"安秋凤"},{"authorName":"袁俊敏","id":"17cbfd2f-e4eb-4e62-b57f-30124cb4f25b","originalAuthorName":"袁俊敏"},{"authorName":"王前进","id":"8b2b94eb-0156-44ee-850f-cd6e37fc475d","originalAuthorName":"王前进"},{"authorName":"付永山","id":"646c6278-991d-49f6-aadf-b5d097c5e57d","originalAuthorName":"付永山"},{"authorName":"贾顺田","id":"3b775150-c481-44b2-9202-b697a4441a46","originalAuthorName":"贾顺田"}],"doi":"","fpage":"16","id":"0b86278c-3ec2-49c0-b46b-5288a7e5fe41","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"0ed3a675-eaa4-40d0-a1f4-1f2265461632","keyword":"<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"氟代聚丙烯酸酯"},{"id":"579d4a13-01e5-4488-8a7a-a354185a6d7f","keyword":"防水","originalKeyword":"防水"},{"id":"27f49a5a-10b7-407a-a755-ea81226ab30b","keyword":"棉织物","originalKeyword":"棉织物"},{"id":"f708aa41-eede-42e5-8322-7413db963a16","keyword":"形貌","originalKeyword":"形貌"}],"language":"zh","publisherId":"gfzclkxygc201102005","title":"<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>的合成与膜形貌及疏水性能","volume":"27","year":"2011"},{"abstractinfo":"为了制备一种廉价且具有优异防水性的水性涂料,用<span style=\"color:red\">氟</span>碳乳液,以阴/非离子复合表面活性剂为乳化剂,过硫酸铵为引发剂,通过乳液聚合法制得了全<span style=\"color:red\">氟</span>烷基乙基<span style=\"color:red\">丙烯酸酯</span>(FA)-甲基<span style=\"color:red\">丙烯酸</span>十八醇<span style=\"color:red\">酯</span>(SMA)-<span style=\"color:red\">丙烯酸</span>羟丙<span style=\"color:red\">酯</span>(HPA)-对氯甲基苯乙烯(CMS)四元无规共聚<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>乳液(FSHC),采用红外光谱仪(IR),核磁共振氢谱(1H-NMR),纳米粒度仪及Zeta电位分析仪,光电子能谱仪(XPS)和接触角测定仪分别对FSHC乳液的结构、粒径分布和Zeta电位及膜表面的化学元素组成和疏水性进行了表征.结果表明:FSHC具有预期的结构,其平均粒径为146.2 nm,Zeta电位为-21.2 mV；FSHC膜表面存在较多的F元素,含<span style=\"color:red\">氟</span>基团迁移至表面,发挥优异的防水性能；以FSHC乳液为成膜物质所制备的<span style=\"color:red\">氟</span>碳涂料,表现出良好的拒水效果,水在<span style=\"color:red\">氟</span>碳涂料涂层表面的静态接触角达128.6°.","authors":[{"authorName":"宁姣姣","id":"12ec7314-2e06-4fa9-8ec5-592ecee63c2d","originalAuthorName":"宁姣姣"},{"authorName":"安秋凤","id":"832ec7b2-1976-4418-b574-f0a4e1bd155f","originalAuthorName":"安秋凤"},{"authorName":"吴婧","id":"590900ec-a019-4f1a-9636-9f185c08d371","originalAuthorName":"吴婧"},{"authorName":"雷宁","id":"a04a0c7b-29ea-4593-aacc-74632aa395ed","originalAuthorName":"雷宁"}],"doi":"","fpage":"51","id":"b70f80a2-e60e-4857-b655-93110ff46658","issue":"2","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"4dc43b81-dcb8-42b2-ac3b-7113ab8de6e9","keyword":"<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"氟代聚丙烯酸酯"},{"id":"7215b735-cbec-4f67-bb04-1876dd230a26","keyword":"乳液聚合","originalKeyword":"乳液聚合"},{"id":"a73e5f0a-bc15-4eb9-8d5f-d269bc29f4be","keyword":"<span style=\"color:red\">氟</span>碳涂料","originalKeyword":"氟碳涂料"},{"id":"28af18cd-d20a-4dc8-9898-f24cd36d36f5","keyword":"防水性能","originalKeyword":"防水性能"}],"language":"zh","publisherId":"clbh201302016","title":"<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>乳液的合成及其用于<span style=\"color:red\">氟</span>碳涂料的防水性能","volume":"46","year":"2013"},{"abstractinfo":"通过溶液聚合法,将甲基<span style=\"color:red\">丙烯酸</span>十二<span style=\"color:red\">氟</span>庚<span style=\"color:red\">酯</span>(G04)与烯丙基缩水甘油醚(AGE)、(甲基)<span style=\"color:red\">丙烯酸酯</span>类单体共聚,合成了一种含有环氧基的<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>(FBSA),用红外光谱仪、原子力显微镜、扫描电镜等对其结构及膜形貌进行了研究.结果表明,在观察高度为5 nm,扫描范围为1μm×1 μm条件下,FBSA微观上表现出一种相分离结构,其表面有众多凸起峰状物存在.将其与KH792水解缩聚物上的氨基开环交联,并添加纳米TiO2制得<span style=\"color:red\">氟</span>硅共改性的聚<span style=\"color:red\">丙烯酸酯</span>涂料,涂膜表面的水接触角达到125°.","authors":[{"authorName":"潘家炎","id":"ac434b5b-06e3-4d4b-a02c-dce9d9831cb7","originalAuthorName":"潘家炎"},{"authorName":"安秋凤","id":"3f5de3f6-1b5f-48ac-b3b8-7de420853bdc","originalAuthorName":"安秋凤"},{"authorName":"张艳丽","id":"38d869bb-6fa4-4c51-81ed-1e7649c64b05","originalAuthorName":"张艳丽"}],"doi":"","fpage":"42","id":"c8a93628-d763-4e2c-abde-eec81cf40753","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"0ec43557-591f-4892-af30-dc5b0826602d","keyword":"倍半硅氧烷","originalKeyword":"倍半硅氧烷"},{"id":"81ad4eaa-0e90-4075-8449-9658e033fe2d","keyword":"<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"氟代聚丙烯酸酯"},{"id":"8b660e94-dea3-4b8a-9569-5b729980915e","keyword":"氨基硅烷","originalKeyword":"氨基硅烷"},{"id":"7cfe0989-bc8e-4d49-b188-495bbba2e234","keyword":"疏水性","originalKeyword":"疏水性"}],"language":"zh","publisherId":"gfzclkxygc201509009","title":"倍半硅氧烷改性<span style=\"color:red\">氟</span><span style=\"color:red\">代</span>聚<span style=\"color:red\">丙烯酸酯</span>树脂的合成及疏水性能","volume":"31","year":"2015"},{"abstractinfo":"以甲基<span style=\"color:red\">丙烯酸</span>六<span style=\"color:red\">氟</span>丁<span style=\"color:red\">酯</span>、<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>、甲基<span style=\"color:red\">丙烯酸</span>甲<span style=\"color:red\">酯</span>为原料合成甲基<span style=\"color:red\">丙烯酸</span>六<span style=\"color:red\">氟</span>丁<span style=\"color:red\">酯</span>-<span style=\"color:red\">丙烯酸酯</span>共聚物乳液.研究了不同乳化体系对聚合稳定性的影响.用红外光谱(IR)、19F核磁共振(NMR)、差示扫描量热法(DSC)及热重分析(TGA)表征乳胶膜结构及热稳定性能,用透射电子显微镜(TEM)观察了乳胶粒的微观形态结构,通过接触角和吸水率表征含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>共聚物乳胶膜的表面性能.","authors":[{"authorName":"陈艳军","id":"28671951-80f0-49fe-9bed-54d8497369c8","originalAuthorName":"陈艳军"},{"authorName":"王艺峰","id":"3b13f86f-45f3-4bf8-8f60-c56217cb673f","originalAuthorName":"王艺峰"},{"authorName":"陈沛智","id":"670875e8-6403-42f6-91cc-0f5e45584d81","originalAuthorName":"陈沛智"}],"doi":"10.3969/j.issn.0253-4312.2005.09.008","fpage":"28","id":"7bb6066d-5fda-40a2-9760-092526a767ad","issue":"9","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"46606c18-a9f5-44c5-ba3c-75e17b4ec9e9","keyword":"甲基<span style=\"color:red\">丙烯酸</span>六<span style=\"color:red\">氟</span>丁<span style=\"color:red\">酯</span>","originalKeyword":"甲基丙烯酸六氟丁酯"},{"id":"4e2d360b-2861-46dc-ac1e-6a876856b448","keyword":"共聚物乳液","originalKeyword":"共聚物乳液"},{"id":"3ea6cf55-e55e-4f42-a3ba-d2aabc052912","keyword":"透射电子显微镜","originalKeyword":"透射电子显微镜"},{"id":"05d4dc90-c507-4eab-a251-97f00d5b9600","keyword":"红外光谱","originalKeyword":"红外光谱"},{"id":"3f0ea168-c9ea-4ffc-9e60-4075c150d363","keyword":"差示扫描量热","originalKeyword":"差示扫描量热"},{"id":"6d0c54f7-5e98-47b2-9540-2a60719d872b","keyword":"热重分析","originalKeyword":"热重分析"}],"language":"zh","publisherId":"tlgy200509008","title":"甲基<span style=\"color:red\">丙烯酸</span>六<span style=\"color:red\">氟</span>丁<span style=\"color:red\">酯</span>-<span style=\"color:red\">丙烯酸酯</span>共聚物乳液研究","volume":"35","year":"2005"},{"abstractinfo":"用普通阴离子和非离子表面活性剂复配考察了含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>(FA)和烷基<span style=\"color:red\">丙烯酸酯</span>(AAs)共聚单体在水相中的分散;研究了不同温度和引发剂体系对不同<span style=\"color:red\">氟</span>单体体系的悬浮共聚合的影响;初步表征了FA/AAs共聚物胶乳及其乳胶膜的一些基本性质.实验结果表明,用普通离子型和非离子型乳化剂复合可以制备得到分散稳定的含<span style=\"color:red\">氟</span>单体分散系;无须加入有机溶剂,FA和AAs可以实现有效共聚合,其共聚物乳胶粒子为多相形态结构;线形共聚物乳胶膜可以溶于典型的有机溶剂(如THF)中;而一定交联程度的共聚物乳胶膜则表现出了<span style=\"color:red\">氟</span>材料特有的疏水疏油性质.","authors":[{"authorName":"彭顺金","id":"a16d65f4-3850-411e-94c2-63a783c60d22","originalAuthorName":"彭顺金"},{"authorName":"李建宗","id":"96738daf-4ed3-4133-8984-fe88bd1994d5","originalAuthorName":"李建宗"},{"authorName":"武利民","id":"ad0936e6-e34c-4b10-a1b5-6d53a6acbcc6","originalAuthorName":"武利民"}],"doi":"","fpage":"55","id":"69e1d7e2-65f7-4c83-b4ac-fe44c213fc45","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7cadcb1e-02fe-4104-a733-311e2e9d2457","keyword":"含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"含氟丙烯酸酯"},{"id":"0b0abaa1-857f-4746-854e-2005a8e1f8cd","keyword":"悬浮聚合","originalKeyword":"悬浮聚合"},{"id":"eee3a204-dae4-4de6-9a68-9f6d0f4b512b","keyword":"聚合物胶乳","originalKeyword":"聚合物胶乳"},{"id":"571b250b-32e1-4777-9cb8-08d9ec6fdb45","keyword":"疏水疏油","originalKeyword":"疏水疏油"}],"language":"zh","publisherId":"gfzclkxygc200606014","title":"微悬浮聚合制备含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>/<span style=\"color:red\">丙烯酸酯</span>共聚物胶乳","volume":"22","year":"2006"},{"abstractinfo":"以甲基<span style=\"color:red\">丙烯酸</span>十三<span style=\"color:red\">氟</span>辛<span style=\"color:red\">酯</span>、甲基<span style=\"color:red\">丙烯酸</span>、甲基<span style=\"color:red\">丙烯酸</span>羟乙<span style=\"color:red\">酯</span>、<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>和2,4-甲苯二异氰酸<span style=\"color:red\">酯</span>为原料,通过三步反应合成了一种新型的水性可光固化含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>树脂.利用FT-IR、PCS、TG、TGA等分析测试手段对树脂的结构及热性能进行了研究.PCS分析结果表明:当甲基<span style=\"color:red\">丙烯酸</span>含量达到6％时,乳液可以获得良好的粒径分布及稳定性.TG和DTG分析结果表明:<span style=\"color:red\">氟</span>改性的<span style=\"color:red\">丙烯酸酯</span>树脂的热性能得到显著的提高.","authors":[{"authorName":"何游","id":"a7d98f5b-53e6-4e39-a134-1dd3464d1242","originalAuthorName":"何游"},{"authorName":"张力","id":"27197ca5-5122-4959-ac2b-313a07dfc4a9","originalAuthorName":"张力"},{"authorName":"刘金玲","id":"c5e28b13-3b4e-4391-843a-f438b5110ba9","originalAuthorName":"刘金玲"},{"authorName":"李冠荣","id":"aeca60ce-2155-45f6-a8d8-d9659425b0ff","originalAuthorName":"李冠荣"},{"authorName":"吴业辉","id":"e99eccf1-fa58-4003-92fe-549a1c82fe03","originalAuthorName":"吴业辉"}],"doi":"","fpage":"18","id":"3e1b4426-e93c-47cd-97ef-c7a8f2bc614f","issue":"8","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"8e6b22c9-1801-487c-9911-43cad5da0813","keyword":"含<span style=\"color:red\">氟</span>聚合物","originalKeyword":"含氟聚合物"},{"id":"2f21e28a-baaa-476b-8bd7-4d2ea80cdc76","keyword":"含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"含氟丙烯酸酯"},{"id":"dde46044-3ea5-4d10-9328-21ac5a651c35","keyword":"水性","originalKeyword":"水性"},{"id":"1aa2df14-3469-41c9-9d71-2e467c5e4a30","keyword":"UV固化","originalKeyword":"UV固化"}],"language":"zh","publisherId":"tlgy201308004","title":"水性UV固化含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>涂料的制备及性能研究","volume":"43","year":"2013"},{"abstractinfo":"以四苯基乙二醇、甲苯二异氰酸<span style=\"color:red\">酯</span>和聚四氢呋喃二醇为原料制备了聚氨酯大分子引发转移终止剂,用其引发<span style=\"color:red\">丙烯酸</span>六<span style=\"color:red\">氟</span>丁<span style=\"color:red\">酯</span>聚合,合成了含<span style=\"color:red\">氟</span>聚氨酯<span style=\"color:red\">丙烯酸酯</span>共聚物.用红外、核磁及凝胶渗透色谱对聚合物的结构进行了表征.氟化<span style=\"color:red\">丙烯酸酯</span>的引入使聚氨酯的耐热性得到了提高,<span style=\"color:red\">氟</span>元素又赋予了聚合物膜优异的疏水性,制备的含<span style=\"color:red\">氟</span>聚氨酯<span style=\"color:red\">丙烯酸酯</span>可用作强疏水性涂料.结果表明:引发转移终止剂法是很好的含<span style=\"color:red\">氟</span>聚氨酯合成方法.","authors":[{"authorName":"袁才登","id":"85a22850-45e0-409d-a39a-f7c838bef574","originalAuthorName":"袁才登"},{"authorName":"邢竞男","id":"a2aa1b93-26c5-4b7e-b9ac-639c3450c602","originalAuthorName":"邢竞男"},{"authorName":"郝艳敏","id":"d2876c3f-8707-44aa-b127-1456e85bfa1d","originalAuthorName":"郝艳敏"},{"authorName":"曾海唤","id":"911edca8-f091-453a-9e5a-10c8d1b4ce3e","originalAuthorName":"曾海唤"}],"doi":"","fpage":"13","id":"1cbd80d3-c457-4a19-a2e0-0eea8c02a57e","issue":"8","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"a0a65909-dc40-42e6-8eea-938635aa66a0","keyword":"含<span style=\"color:red\">氟</span>聚氨酯<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"含氟聚氨酯丙烯酸酯"},{"id":"68017f2e-263e-4934-ac7a-c2190061c67d","keyword":"疏水性涂料","originalKeyword":"疏水性涂料"},{"id":"b8b32d6c-978b-4801-82ad-c194329ed630","keyword":"引发转移终止剂","originalKeyword":"引发转移终止剂"},{"id":"85352c30-61f4-49f8-8b04-8a4d6e8284bc","keyword":"<span style=\"color:red\">丙烯酸</span>六<span style=\"color:red\">氟</span>丁<span style=\"color:red\">酯</span>","originalKeyword":"丙烯酸六氟丁酯"}],"language":"zh","publisherId":"tlgy201408003","title":"含<span style=\"color:red\">氟</span>聚氨酯<span style=\"color:red\">丙烯酸酯</span>的合成研究","volume":"44","year":"2014"},{"abstractinfo":"含<span style=\"color:red\">氟</span>聚<span style=\"color:red\">丙烯酸酯</span>除具备<span style=\"color:red\">丙烯酸酯</span>聚合物本身的成膜性好、网络结构疏松特点外,还表现出了<span style=\"color:red\">氟</span>聚合物的特点,有较低的表面能,疏水、疏油、耐腐蚀、耐热、抗氧化性等性能.文中介绍了近年来含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>聚合物的研究进展及与防水防油作用机理相应的结构特点,同时概括介绍了含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>中的碳原子对其性能的影响,并对常用的性能表征方法及应用研究作了简要总结和展望.","authors":[{"authorName":"李俊","id":"f1dbd2cc-398c-4262-9871-faffb1fedad2","originalAuthorName":"李俊"},{"authorName":"陈庆民","id":"0dfda8a7-bf25-48ac-829e-2754015d9edd","originalAuthorName":"陈庆民"}],"doi":"","fpage":"14","id":"54b24c8d-34dd-46ba-a78b-d06f53024546","issue":"5","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"fed25d0d-af91-4927-8b00-0a8d5c910f57","keyword":"含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"含氟丙烯酸酯"},{"id":"66612a30-1860-496f-8dd3-75d36a62a357","keyword":"结构","originalKeyword":"结构"},{"id":"525e46f2-d52c-4bba-a3b6-a23fa39df2e5","keyword":"制备","originalKeyword":"制备"},{"id":"903f35c3-59aa-4139-8da5-a55881b978e2","keyword":"表征","originalKeyword":"表征"},{"id":"1b7a52e7-d97a-438b-b29b-49d836f9ca37","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"gfzclkxygc200505004","title":"含<span style=\"color:red\">氟</span><span style=\"color:red\">丙烯酸酯</span>聚合物研究进展","volume":"21","year":"2005"}],"totalpage":2374,"totalrecord":23732}