{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以丙烯和CO为原料,Pd(OAc)2/(S)-P-PHOS为<span style=\"color:red\">手性</span>催化剂,在有机溶剂中,经不对称交替共聚反应合成了<span style=\"color:red\">手性</span>功能高分子聚酮.当过量的还原剂LiAlH4和NaBH4分别还原聚酮时,<span style=\"color:red\">手性</span>聚醇产率达90%;当NaBH4/羰基摩尔比分别为0.5,1和2,紫外光谱(200～400am)检测证明,<span style=\"color:red\">手性</span>聚酮中羰基的29%,71%和81%分别被还原;使用过量的还原剂BH3·THF时,<span style=\"color:red\">手性</span>聚酮中羰基只能部分被还原.<span style=\"color:red\">手性</span>聚醇的数均分子量比<span style=\"color:red\">手性</span>聚酮的低,产物<span style=\"color:red\">手性</span>聚醇的摩尔旋光度随还原反应条件而变化.","authors":[{"authorName":"王来来","id":"06a73c84-a0a7-4ed3-a3f4-5d79053c8063","originalAuthorName":"王来来"},{"authorName":"贾小静","id":"fa1d9c0e-5af8-4247-ab4f-b5eb9f6efb7e","originalAuthorName":"贾小静"},{"authorName":"万博","id":"05fc561c-b017-4b0d-b42c-e8e0f1ff137e","originalAuthorName":"万博"}],"doi":"10.1016/S1872-2067(10)60161-1","fpage":"65","id":"9b615c14-3457-41d4-a305-d6b597212a0f","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"8cf2628f-b01b-4ff4-b87e-54d8b5114006","keyword":"醋酸钯","originalKeyword":"醋酸钯"},{"id":"797fc192-fabe-402c-9d9e-a4acc744857d","keyword":"<span style=\"color:red\">手性</span><span style=\"color:red\">双</span><span style=\"color:red\">膦</span><span style=\"color:red\">配体</span>","originalKeyword":"手性双膦配体"},{"id":"0d862f2e-1044-4828-835e-995d7d181aca","keyword":"丙烯","originalKeyword":"丙烯"},{"id":"2f9b9885-ab40-46f2-9726-8eac5eee570d","keyword":"一氧化碳","originalKeyword":"一氧化碳"},{"id":"67b5b633-022d-48fe-8448-efc03412775b","keyword":"<span style=\"color:red\">手性</span>聚酮","originalKeyword":"手性聚酮"},{"id":"96d8affa-80fb-43b9-b5c3-8528cd2e1013","keyword":"还原剂","originalKeyword":"还原剂"},{"id":"7d938df1-c371-442d-b235-f207466dbbe7","keyword":"<span style=\"color:red\">手性</span>聚醇","originalKeyword":"手性聚醇"}],"language":"zh","publisherId":"cuihuaxb201101009","title":"Pd(Oac)2/(S)-P-PHOS催化的丙烯与CO交替共聚合成<span style=\"color:red\">手性</span>功能高分子","volume":"32","year":"2011"},{"abstractinfo":"以联萘酚和大位阻的金刚烷酰氯为原料,经两步合成了系列新型<span style=\"color:red\">手性</span>单齿亚磷酸酯<span style=\"color:red\">配体</span>,并应用于铜催化的二乙基锌对环烯酮的不对称1,4-共轭加成反应.结果表明,产物收率和对映选择<span style=\"color:red\">性</span>最高分别为95%和61%.<span style=\"color:red\">配体</span>(S)-(2-(adamantane-1-carboxylic acid)-1,1'-binapthalen-2'-y1)-((S)-1,1'-binaphthalen-2,2'-y1)phosphite[(S)-3a]的两个(S)-联萘酚构型是匹配的组合,产物的绝对构型主要由<span style=\"color:red\">配体</span>中2,2'-二氧<span style=\"color:red\">膦</span>-1,1,-联萘酚的构型控制.","authors":[{"authorName":"万博","id":"3ff23c03-fac8-466e-a198-28e3804dc30d","originalAuthorName":"万博"},{"authorName":"赵庆鲁","id":"81e3de37-0460-46e0-974d-15479deda777","originalAuthorName":"赵庆鲁"},{"authorName":"王来来","id":"27ef9d52-5d56-440a-8509-48f9db6f4ac4","originalAuthorName":"王来来"}],"doi":"10.1016/S1872-2067(09)60063-2","fpage":"514","id":"e69472c2-1d7b-4800-b968-ab8b786f0759","issue":"5","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"87a91687-ae0b-4e61-8dcc-ef37f4713d6b","keyword":"不对称1,4-共轭加成","originalKeyword":"不对称1,4-共轭加成"},{"id":"6d300ab6-145d-46d9-94f4-b3f7faee987f","keyword":"单齿亚磷酸酯","originalKeyword":"单齿亚磷酸酯"},{"id":"63279fc3-0b15-4f93-9f68-c64dc9675c5f","keyword":"2-环己烯酮","originalKeyword":"2-环己烯酮"},{"id":"eb59aa5d-7705-4f6b-be70-4fa56b67e324","keyword":"二乙基锌","originalKeyword":"二乙基锌"},{"id":"45114ef8-0139-4cf6-b827-25ceaafdbc96","keyword":"对应选择<span style=\"color:red\">性</span>","originalKeyword":"对应选择性"}],"language":"zh","publisherId":"cuihuaxb201005003","title":"新型<span style=\"color:red\">手性</span><span style=\"color:red\">膦</span><span style=\"color:red\">配体</span>的合成及其在1,4-共轭加成反应中的应用","volume":"31","year":"2010"},{"abstractinfo":"合成了四个从葡萄糖及半乳糖衍生的<span style=\"color:red\">手性</span>芳基<span style=\"color:red\">双</span><span style=\"color:red\">膦</span><span style=\"color:red\">配体</span>,制备了<span style=\"color:red\">手性</span><span style=\"color:red\">双</span><span style=\"color:red\">膦</span>-铑(Ⅰ)配合物催化剂,并将其用于苯乙烯不对称氢甲酰化反应中.结果表明,葡萄糖骨架<span style=\"color:red\">手性</span>中心与联萘基之间有协同作用,对映体过量值和转化率受<span style=\"color:red\">配体</span>C-4骨架立体中心的绝对构型影响,而产物的绝对构型则主要由联萘单元控制;<span style=\"color:red\">配体</span>4-<span style=\"color:red\">双</span>{[(S)-1,1'-联萘基-2,2'-双基]-磷}-苯基-3,6-脱水-β-D-葡萄糖的吡喃糖苷基和联萘基的匹配组合,给出41%的对映体选择<span style=\"color:red\">性</span>和74:26(异构/正构)区域选择<span style=\"color:red\">性</span>.","authors":[{"authorName":"贾小静","id":"51d2b17f-5e32-49c9-8e68-4bac332f8f8c","originalAuthorName":"贾小静"},{"authorName":"王来来","id":"c2eab1f9-8a09-4040-afb8-d9962e1dc855","originalAuthorName":"王来来"},{"authorName":"陈新滋","id":"7ae7f976-bcc2-4f8b-9ef7-ce156e24d53e","originalAuthorName":"陈新滋"},{"authorName":"李月明","id":"8e93e722-7792-43d8-8035-cc4918791111","originalAuthorName":"李月明"}],"doi":"","fpage":"492","id":"47c52da9-e4df-4ac0-b338-cec8986e3d92","issue":"6","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"f96a4959-1647-4af7-8022-4555e872b59e","keyword":"葡萄糖","originalKeyword":"葡萄糖"},{"id":"13e94130-dfc8-4121-9c59-8f1a0cf42598","keyword":"半乳糖","originalKeyword":"半乳糖"},{"id":"36a8f97a-2daf-48d5-9a43-be807af2f79b","keyword":"<span style=\"color:red\">手性</span>芳基<span style=\"color:red\">双</span><span style=\"color:red\">膦</span><span style=\"color:red\">配体</span>","originalKeyword":"手性芳基双膦配体"},{"id":"5c772f3b-e520-4ea8-908f-7494dc5c4c50","keyword":"铑配合物","originalKeyword":"铑配合物"},{"id":"bc3353b2-733b-4ff8-8a43-ec6b75c4b1ab","keyword":"苯乙烯","originalKeyword":"苯乙烯"},{"id":"7c9f56ad-e91f-4acc-8f70-669a52fccc8c","keyword":"不对称氢甲酰化","originalKeyword":"不对称氢甲酰化"}],"language":"zh","publisherId":"cuihuaxb200706002","title":"葡萄糖及半乳糖衍生的<span style=\"color:red\">手性</span><span style=\"color:red\">双</span><span style=\"color:red\">膦</span>-铑(Ⅰ)配合物催化苯乙烯不对称氢甲酰化反应","volume":"28","year":"2007"},{"abstractinfo":"以天然金鸡纳生物碱为原料,在温和条件下合成了4个<span style=\"color:red\">手性</span><span style=\"color:red\">膦</span>氮<span style=\"color:red\">配体</span>. 考察了它们与过渡金属Ir、 Rh和 Ru的配合物在不对称氢转移反应中的催化活性和不对称诱导作用. 结果表明,用[Ir(COD)Cl]2提供配位金属,KOH做促进剂,催化效果最佳. 用于对6种潜<span style=\"color:red\">手性</span>酮的不对称氢转移反应中,取得了较高的催化活性(化学产率65%～95%)和中等的对映选择<span style=\"color:red\">性</span>(对映体过量值51.5%～75.3%).","authors":[{"authorName":"何炜","id":"300b0e9c-9c61-4fa6-bc99-fcffee95ad4e","originalAuthorName":"何炜"},{"authorName":"姜茹","id":"dc3c9cc5-4157-4eee-980b-4164444fe6d4","originalAuthorName":"姜茹"},{"authorName":"刘鹏","id":"b85eaf94-661a-4b2d-bf9b-5ff7f8c2f27c","originalAuthorName":"刘鹏"},{"authorName":"柳文敏","id":"3a98fb2f-31cd-4bfc-9c1a-724616afba17","originalAuthorName":"柳文敏"},{"authorName":"张生勇","id":"c3cf73be-ec1b-4ed8-b194-aff4eb4eca3b","originalAuthorName":"张生勇"}],"doi":"10.3969/j.issn.1000-0518.2006.11.003","fpage":"1195","id":"2e5d64d2-4977-4aff-8a80-24505afff84c","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"25499cf8-9f91-460f-8cb7-bbb3a1e9640b","keyword":"金鸡纳生物碱","originalKeyword":"金鸡纳生物碱"},{"id":"d7eb7dee-c964-4e55-a726-7e4dd44d8b37","keyword":"<span style=\"color:red\">手性</span><span style=\"color:red\">膦</span>氮<span style=\"color:red\">配体</span>","originalKeyword":"手性膦氮配体"},{"id":"86d6892e-e5af-4086-a562-f57b979bcbf0","keyword":"不对称氢转移反应","originalKeyword":"不对称氢转移反应"}],"language":"zh","publisherId":"yyhx200611003","title":"<span style=\"color:red\">手性</span><span style=\"color:red\">膦</span>氮<span style=\"color:red\">配体</span>的合成及其过渡金属配合物对不对称氢转移反应的催化作用","volume":"23","year":"2006"},{"abstractinfo":"报道了对烷氧基取代的MeO-BIPHEP型<span style=\"color:red\">手性</span><span style=\"color:red\">双</span><span style=\"color:red\">膦</span><span style=\"color:red\">配体</span>钌配合物催化的β-酮酸酯不对称加氢反应,考察了反应温度、压力、底物/催化剂摩尔比和溶剂对反应的影响.结果表明,在乙醇中该配合物催化3-丁酮酸乙酯加氢反应的对映选择<span style=\"color:red\">性</span>达98.0%,且对含不同取代基的β-酮酸酯均表现出较高的活性和对映选择<span style=\"color:red\">性</span>.","authors":[{"authorName":"彭宗海","id":"cb04768b-9193-49d8-900b-5e1c8f3ef0f5","originalAuthorName":"彭宗海"},{"authorName":"马梦林","id":"aaab2f87-c331-404c-90a8-f772d04c15eb","originalAuthorName":"马梦林"},{"authorName":"付海燕","id":"8323e0c8-b1f9-4469-a350-55c08b46c4ae","originalAuthorName":"付海燕"},{"authorName":"陈华","id":"3bebec81-827c-4b0f-b125-1171974ef4f3","originalAuthorName":"陈华"},{"authorName":"李贤钧","id":"8fa2d267-9ec1-41fe-8e36-4d53587ea748","originalAuthorName":"李贤钧"}],"doi":"10.3724/SP.J.1088.2010.90737","fpage":"191","id":"6d6684df-fdf8-44d4-b0ed-1f56c01d9d4e","issue":"2","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"40f431c2-20c1-4168-b26a-17ccbe371db4","keyword":"β-酮酸酯","originalKeyword":"β-酮酸酯"},{"id":"80b79771-f7d9-4046-8152-6580cc0f4e3e","keyword":"不对称加氧","originalKeyword":"不对称加氧"},{"id":"7026700e-2f06-415c-a95a-3528539c917d","keyword":"联苯类<span style=\"color:red\">配体</span>","originalKeyword":"联苯类配体"},{"id":"0b35770a-cf28-4f57-b684-418c54e29272","keyword":"钌配合物","originalKeyword":"钌配合物"}],"language":"zh","publisherId":"cuihuaxb201002010","title":"对烷氧基取代MeO-BIPHEP型<span style=\"color:red\">手性</span><span style=\"color:red\">双</span><span style=\"color:red\">膦</span>钌配合物催化β-酮酸酯不对称加氢反应","volume":"31","year":"2010"},{"abstractinfo":"以螺环<span style=\"color:red\">膦</span>氧化合物为催化剂及三氯硅氢为还原剂，发展了<span style=\"color:red\">手性</span>Lewis碱催化的烯酮与醛的不对称还原-Aldol反应。该类催化剂在查耳酮以及类似物与各种醛的不对称还原-Aldol反应中表现出较高的反应活性和良好的立体选择<span style=\"color:red\">性</span>，以较好的产率(45%-88%)、中等到优秀的非对映选择<span style=\"color:red\">性</span>(8：92-100：0)以及最高达95%的ee值得到相应的还原Aldol产物。","authors":[{"authorName":"张攀科","id":"0cd55a28-58a7-4ad3-bf04-891a2ab85c73","originalAuthorName":"张攀科"},{"authorName":"刘家旺","id":"62ab75d4-1fdd-4620-a7b8-e14a25cc42d8","originalAuthorName":"刘家旺"},{"authorName":"王正","id":"d0a23dde-fa82-497b-a074-7895942eefe2","originalAuthorName":"王正"},{"authorName":"丁奎岭","id":"d2f10b6f-4c71-41c3-9e5c-2db5f9d4e97b","originalAuthorName":"丁奎岭"}],"doi":"10.1016/S1872-2067(14)60241-2","fpage":"100","id":"91d88622-2ac8-4861-acb2-7c3dfe8165c8","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"20819a35-9350-4a6d-8001-e81df8e31028","keyword":"醛","originalKeyword":"醛"},{"id":"359af4fd-0e90-4f9d-851b-ec326a7cfbf6","keyword":"不对称催化","originalKeyword":"不对称催化"},{"id":"de548627-d904-47ef-8c64-2753faa79f78","keyword":"烯酮","originalKeyword":"烯酮"},{"id":"64a3c72b-fde8-4a13-90b8-4f1575bbcd9c","keyword":"路易斯碱","originalKeyword":"路易斯碱"},{"id":"34630050-cb3a-4606-a67f-bb270e061e85","keyword":"还原Aldol反应","originalKeyword":"还原Aldol反应"},{"id":"00f6d5dc-e4dd-4dac-af9a-f99488573a15","keyword":"螺环<span style=\"color:red\">膦</span>氧化合物","originalKeyword":"螺环膦氧化合物"}],"language":"zh","publisherId":"cuihuaxb201501017","title":"<span style=\"color:red\">手性</span>螺环<span style=\"color:red\">双</span><span style=\"color:red\">膦</span>氧化物催化的不对称还原-Aldol反应","volume":"","year":"2015"},{"abstractinfo":"合成了2-(2-羟基-3-烷氧基)丙基-(S)-1,2,3,4-四氢-3-异喹啉羧酸<span style=\"color:red\">手性</span>选择子,制备了两种新型涂渍<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换色谱固定相 ,拆分了某些DL-氨基酸,比较了DL-氨基酸在两种<span style=\"color:red\">手性</span>相上的色谱分辨.","authors":[{"authorName":"王群标","id":"c6edeaaf-5992-4da7-aa03-73b400ec6fdf","originalAuthorName":"王群标"},{"authorName":"龙远德","id":"334b28ff-10a2-48ad-87d8-9c239cd047d5","originalAuthorName":"龙远德"},{"authorName":"黄天宝","id":"ebe75949-13fd-4c31-9602-5295c75d5f1d","originalAuthorName":"黄天宝"}],"doi":"10.3321/j.issn:1000-8713.2000.02.005","fpage":"112","id":"6caf9732-cf74-40a0-b030-4f87af6831ee","issue":"2","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"3a82bd0a-16aa-4952-bb84-6c5eab1dbd96","keyword":"<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换色谱","originalKeyword":"手性配体交换色谱"},{"id":"6455787d-87d7-48ac-9d23-a5a28958a122","keyword":"<span style=\"color:red\">手性</span>固定相","originalKeyword":"手性固定相"},{"id":"bcf988af-6b0a-4acd-99de-23e907952c68","keyword":"异喹啉衍生物","originalKeyword":"异喹啉衍生物"},{"id":"32a6037b-2096-4c39-bd24-787a4c68b8f2","keyword":"DL-氨基酸","originalKeyword":"DL-氨基酸"}],"language":"zh","publisherId":"sp200002005","title":"新型<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换色谱固定相的制备及应用","volume":"18","year":"2000"},{"abstractinfo":"氨基酸的<span style=\"color:red\">手性</span>分析在生命科学中具有重要的研究意义。<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换毛细管电泳法作为常用的氨基酸的<span style=\"color:red\">手性</span>分析方式之一，具有高效、快速、样品迁移顺序可调等优点，引起了研究者们极大的兴趣。本文主要综述了近年来<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换毛细管电泳法在氨基酸的<span style=\"color:red\">手性</span>分析中的应用研究进展。","authors":[{"authorName":"木肖玉","id":"b3f71581-7b23-445f-8df7-3e7a3c04f96a","originalAuthorName":"木肖玉"},{"authorName":"齐莉","id":"ed2c9303-fb09-4705-912b-202eccce22b8","originalAuthorName":"齐莉"},{"authorName":"苏圆","id":"a4700e63-639b-4f0d-9727-1af09174666a","originalAuthorName":"苏圆"},{"authorName":"乔娟","id":"debe514b-00c0-4e9b-887b-14b3cf15d740","originalAuthorName":"乔娟"},{"authorName":"陈义","id":"ee8eb835-1ab8-4abe-b523-cfadf9483842","originalAuthorName":"陈义"}],"doi":"10.3724/SP.J.1123.2015.05038","fpage":"21","id":"2936786c-fdb5-4546-9a98-848fe8e96a52","issue":"1","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"3d84da62-128a-4331-a943-474d100ca51f","keyword":"<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换毛细管电泳","originalKeyword":"手性配体交换毛细管电泳"},{"id":"a7c59e09-2923-419a-a716-8a5f912e1b10","keyword":"D,L-氨基酸","originalKeyword":"D,L-氨基酸"},{"id":"54e92c26-ec55-49b7-acee-35c04b95d18a","keyword":"<span style=\"color:red\">手性</span>分析","originalKeyword":"手性分析"},{"id":"2bf5b35e-2ce5-4894-9329-878d197d5140","keyword":"综述","originalKeyword":"综述"}],"language":"zh","publisherId":"sp201601006","title":"<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换毛细管电泳在氨基酸<span style=\"color:red\">手性</span>分析中的应用研究进展","volume":"","year":"2016"},{"abstractinfo":"基于<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换机理，研究了以<span style=\"color:red\">手性</span>离子液体1-乙基-3-甲基咪唑 L-乳酸盐（[ EMIM][ L-Lac]）为<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>拆分色氨酸对映体（Trys）、苯丙氨酸对映体（ Phes）和酪氨酸对映体（ Tyrs）的方法。实验考察了背景电解质和中心离子种类、<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>与中心离子的浓度及比例、运行缓冲液 pH 等因素对 Trys、Phes 和 Tyrs <span style=\"color:red\">手性</span>拆分的影响。研究发现，当运行缓冲液为40.0 mmol / L[EMIM][ L-Lac]、20.0 mmol / L 氯化铜（ pH 4.5）时，3对对映体均能得到良好的<span style=\"color:red\">手性</span>拆分。为了验证[EMIM][L-Lac]的良好性能，实验进一步将 L-乳酸（L-Lac）作为<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>用于 Trys的<span style=\"color:red\">手性</span>拆分。对比实验发现，单独使用 L-乳酸，DL-Try 只能得到部分拆分，加入离子液体1-乙基-3-甲基咪唑醋酸盐（EMIM-Ace）后，DL-Try 分离情况得到了很大改善，但出峰时间延长至30 min 以上。而使用[ EMIM][ L-Lac]时，Trys 的出峰时间均在15 min 以内。实验最后还对<span style=\"color:red\">手性</span>拆分机理做了进一步讨论。实验结果表明：在 EMIM-Ace 辅助 L-Lac 体系中，EMIM-Ace 仅被用于抑制电渗流，并未参与<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换反应；而在[ EMIM][ L-Lac]体系中，参与<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换反应的主要是未解离的[EMIM][L-Lac]，而不是解离后的 L-乳酸根离子形成的 L-乳酸。","authors":[{"authorName":"黄露","id":"75c35888-9c2e-47b2-979a-18d1ab4b0f2a","originalAuthorName":"黄露"},{"authorName":"余丽<span style=\"color:red\">双</span>","id":"0cbe3816-ec5d-4332-98fb-0c34be5ab73c","originalAuthorName":"余丽双"},{"authorName":"陈毅挺","id":"6855ec58-90cc-4dac-ad74-a0c659df98fe","originalAuthorName":"陈毅挺"}],"doi":"10.3724/SP.J.1123.2014.06040","fpage":"1225","id":"fc9c8d26-2db8-4f80-b3e1-e79ff74ce9bc","issue":"11","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"3c4bc65a-3198-4593-85ee-e3b827fbaded","keyword":"<span style=\"color:red\">手性</span>离子液体","originalKeyword":"手性离子液体"},{"id":"48ec375f-4eaf-4cae-b1e1-9a0b21b162c9","keyword":"1-乙基-3-甲基咪唑 L-乳酸盐","originalKeyword":"1-乙基-3-甲基咪唑 L-乳酸盐"},{"id":"3931c502-f87d-41bc-8d6d-a15004718fdb","keyword":"<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>交换毛细管电泳","originalKeyword":"手性配体交换毛细管电泳"},{"id":"1113e46e-22a9-475f-a545-8e86436f424b","keyword":"<span style=\"color:red\">手性</span>分离","originalKeyword":"手性分离"}],"language":"zh","publisherId":"sp201411012","title":"1-乙基-3-甲基咪唑 L-乳酸盐作为<span style=\"color:red\">手性</span><span style=\"color:red\">配体</span>用于氨基酸的<span style=\"color:red\">手性</span>拆分","volume":"","year":"2014"},{"abstractinfo":"以价廉易得的天然金鸡纳生物碱奎宁和辛可宁为原料,在温和条件下容易地合成了6种<span style=\"color:red\">手性</span><span style=\"color:red\">双</span>胺<span style=\"color:red\">配体</span>. 考察了它们与过渡金属Ir和Rh形成的配合物在苯乙酮不对称氢转移反应中的催化活性和不对称诱导作用. 结果表明, 9-氨基金鸡纳生物碱<span style=\"color:red\">配体</span>具有良好的不对称催化活性,而当<span style=\"color:red\">配体</span>中的氨基被取代后其对映选择<span style=\"color:red\">性</span>降低. 将9-氨基(9-脱氧)表辛可宁的Ir配合物用于其它芳香酮的不对称氢转移反应时,该<span style=\"color:red\">配体</span>也显示了很高的催化活性(80%～90%收率)和对映选择<span style=\"color:red\">性</span>(除对氯苯乙酮ee值为72%外,其余芳香酮ee值均为95%～97%).","authors":[{"authorName":"何炜","id":"8adca25e-cb19-4079-bc04-5d63170c200c","originalAuthorName":"何炜"},{"authorName":"张邦乐","id":"52b8210b-48a2-4687-8e14-23e7c3cf8732","originalAuthorName":"张邦乐"},{"authorName":"刘鹏","id":"8a186b9d-273f-43d1-b3b6-c7460a2e670e","originalAuthorName":"刘鹏"},{"authorName":"孙晓莉","id":"8623d0e6-bf5a-4165-a1fa-1c0a899b5b37","originalAuthorName":"孙晓莉"},{"authorName":"张生勇","id":"1763411c-ffed-4423-a944-893d02f4e413","originalAuthorName":"张生勇"}],"doi":"","fpage":"527","id":"738839db-6d29-4052-9358-201292b4ae48","issue":"6","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"2387c761-7a12-409d-bc45-5cacb57ba143","keyword":"金鸡纳生物碱","originalKeyword":"金鸡纳生物碱"},{"id":"d5f8dc88-5924-4545-ad2e-0eea8e708562","keyword":"奎宁","originalKeyword":"奎宁"},{"id":"fb1a1a33-1556-44da-a0d1-957719416d06","keyword":"辛可宁","originalKeyword":"辛可宁"},{"id":"41670d41-c972-4d6e-88c0-8d7a23fe1651","keyword":"<span style=\"color:red\">手性</span><span style=\"color:red\">双</span>胺<span style=\"color:red\">配体</span>","originalKeyword":"手性双胺配体"},{"id":"9c59328e-9f30-43a6-b05d-57d29766f1c9","keyword":"<span style=\"color:red\">手性</span>催化剂","originalKeyword":"手性催化剂"},{"id":"66125e9e-40c1-4a7f-ad31-0fc1b4d19069","keyword":"不对称氢转移反应","originalKeyword":"不对称氢转移反应"},{"id":"68165512-20ce-469b-98ba-d4d78429992d","keyword":"苯乙酮","originalKeyword":"苯乙酮"}],"language":"zh","publisherId":"cuihuaxb200606016","title":"金鸡纳生物碱衍生<span style=\"color:red\">手性</span><span style=\"color:red\">双</span>胺<span style=\"color:red\">配体</span>的合成及其在不对称氢转移反应中的催化作用","volume":"27","year":"2006"}],"totalpage":6038,"totalrecord":60376}