{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"制备了多壁碳纳米管(MWCNTs)固载的金鸡纳生物碱季铵盐类手性相转移催化剂PTC-1/MWCNTs,并用于催化N-二苯亚甲基-甘氨酸叔丁酯的<span style=\"color:red\">不对称</span><span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>中.采用紫外-可见光谱系统研究了五种有机溶剂对PTC-1在MWCNTs上吸附和脱附的影响.结果表明,在甲苯中,MWCNTs对PTC-1的吸附率最高(53％),而在三氯甲烷中PTC-1的脱附率最低(仅为0.75％).PTC-1/MWCNTs催化剂在催化N-二苯亚甲基-甘氨酸叔丁酯和不同卤代烃的<span style=\"color:red\">不对称</span><span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>中,所得产物的收率和对映体选择性都较高,而且该催化剂可回收循环使用,说明PTC-1经MWCNTs固载后,仍能够有效地催化多种卤代烃的<span style=\"color:red\">不对称</span><span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>.","authors":[{"authorName":"刘健","id":"58ebce82-3d72-42ec-a5d9-cb51dda3d559","originalAuthorName":"刘健"},{"authorName":"刘","id":"e4455eda-faf6-4c90-897b-0e6d355b0a8a","originalAuthorName":"刘"},{"authorName":"石鑫","id":"523fed18-c206-4c01-9983-580e642a247c","originalAuthorName":"石鑫"},{"authorName":"杨启华","id":"67daacf8-1681-455b-b697-7bbd708d4aed","originalAuthorName":"杨启华"}],"doi":"10.3724/SP.J.1088.2012.11213","fpage":"891","id":"3024a93c-aba8-4b2d-9fe8-eb751c8075a8","issue":"5","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"dd89abf7-76a0-4c3e-a5df-3b4817db77f0","keyword":"多壁碳纳米管","originalKeyword":"多壁碳纳米管"},{"id":"e6d2557d-22c0-420a-808a-e9c0e56a5cf1","keyword":"手性相转移催化剂","originalKeyword":"手性相转移催化剂"},{"id":"df1f5ff7-5679-4920-b00d-0130a6725be8","keyword":"金鸡纳生物碱","originalKeyword":"金鸡纳生物碱"},{"id":"37175522-89d4-47e9-bcc1-869a48d1f307","keyword":"吸附","originalKeyword":"吸附"},{"id":"603d35c5-9f3c-469d-a62c-b4b54e63e0e0","keyword":"<span style=\"color:red\">不对称</span><span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>","originalKeyword":"不对称烷基化反应"}],"language":"zh","publisherId":"cuihuaxb201205022","title":"多壁碳纳米管固载金鸡纳生物碱季铵盐类手性相转移催化剂的制备及其催化<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>性能","volume":"33","year":"2012"},{"abstractinfo":"分别用水杨醛铜、β-二酮-铜和希夫碱-铜络合物为催化剂进行β-(-)-蒎烯与重氮乙酸酯的<span style=\"color:red\">不对称</span>环丙烷<span style=\"color:red\">化</span><span style=\"color:red\">反应</span>,研究了催化剂结构与<span style=\"color:red\">反应</span>立体选择性之间的关系,获得了较高的立体选择性.","authors":[{"authorName":"李争宁","id":"c9ca77e9-fc8c-4471-8186-6889c766d442","originalAuthorName":"李争宁"},{"authorName":"姜岚","id":"a6c26933-8f42-4561-b55c-bf4e171dbd3d","originalAuthorName":"姜岚"},{"authorName":"刘改玲","id":"5a07d465-6de3-4f01-8366-f3a7b59ab2ff","originalAuthorName":"刘改玲"},{"authorName":"陈惠麟","id":"d027c4d9-a53d-4d04-9bf3-55ea24bbbfb4","originalAuthorName":"陈惠麟"}],"doi":"","fpage":"934","id":"fba7c2bf-0e6c-4ed9-8b3a-bb05a66b88c8","issue":"11","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"9098f8c9-be70-407f-99a0-bcdb4fe3347e","keyword":"环丙烷<span style=\"color:red\">化</span>","originalKeyword":"环丙烷化"},{"id":"c8576587-e539-4899-9629-a3ce0562824e","keyword":"立体选择性","originalKeyword":"立体选择性"},{"id":"ef23cf17-9811-439b-8d86-cf6641e0bedb","keyword":"铜络合物","originalKeyword":"铜络合物"},{"id":"4559a2af-010c-45d7-8a4f-e8bdfa5d4de6","keyword":"β-(-)-蒎烯","originalKeyword":"β-(-)-蒎烯"},{"id":"89ebc4ec-235b-40de-a195-ac120dfc5962","keyword":"重氮乙酸酯","originalKeyword":"重氮乙酸酯"}],"language":"zh","publisherId":"cuihuaxb200711002","title":"铜络合物催化β-(-)-蒎烯的<span style=\"color:red\">不对称</span>环丙烷<span style=\"color:red\">化</span><span style=\"color:red\">反应</span>","volume":"28","year":"2007"},{"abstractinfo":"研究了聚Salen D-Ti(Ⅳ)配合物对芳香醛<span style=\"color:red\">不对称</span>硅腈<span style=\"color:red\">化</span><span style=\"color:red\">反应</span>的催化作用. 考察了催化剂用量、溶剂和温度对苯甲醛<span style=\"color:red\">不对称</span>硅腈<span style=\"color:red\">化</span><span style=\"color:red\">反应</span>的影响,在-40 ℃和1.0 mol催化剂量下,以4-Cl-C6H4CHO为底物,获得了ee值为82%和收率为98%的加成产物. 探讨了聚Salen D-Ti(Ⅳ)上取代基对芳香醛硅腈<span style=\"color:red\">化</span><span style=\"color:red\">反应</span>产物光学异构体选择性的影响. 在20 ℃下,催化剂可重复使用多次而<span style=\"color:red\">反应</span>活性和对映体选择性保持不变. ","authors":[{"authorName":"江万义","id":"94ef2df6-f9b1-4240-ad1e-4b3529882388","originalAuthorName":"江万义"},{"authorName":"姚小泉","id":"9434da84-e4d7-47c5-b2ed-7d861af5cab9","originalAuthorName":"姚小泉"},{"authorName":"宋玉明","id":"f542a48d-1804-4278-88bd-d38b23a2ca1f","originalAuthorName":"宋玉明"},{"authorName":"胡信全","id":"9f52a305-a35a-4c5e-a393-58d019e2348d","originalAuthorName":"胡信全"},{"authorName":"陈惠麟","id":"d7fad8c6-8bea-4a59-8c0b-9d0522f6f302","originalAuthorName":"陈惠麟"},{"authorName":"白长敏","id":"1e3428c7-6dfa-4aa4-b933-634499ea9099","originalAuthorName":"白长敏"},{"authorName":"郑卓","id":"94cf9d55-60f4-4b42-9440-41b5bc7b376d","originalAuthorName":"郑卓"}],"doi":"","fpage":"57","id":"7c55e239-97c6-4b96-bc63-f86dd1733f18","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"2145c5b0-9fd4-42f7-a94d-34349a182494","keyword":"<span style=\"color:red\">不对称</span>硅腈<span style=\"color:red\">化</span>","originalKeyword":"不对称硅腈化"},{"id":"cf9f1344-6be4-4ab4-8374-576957aab8cf","keyword":"聚Salen-钛配合物","originalKeyword":"聚Salen-钛配合物"},{"id":"dd8ad2f3-9ff8-42e8-b031-1a2b295c5a00","keyword":"苯甲醛","originalKeyword":"苯甲醛"},{"id":"b8d8619f-d739-426c-b6d3-b4348f6b8beb","keyword":"光学异构体选择性","originalKeyword":"光学异构体选择性"},{"id":"041b519f-a34c-4fe1-b746-99582bcab494","keyword":"三甲基硅腈","originalKeyword":"三甲基硅腈"}],"language":"zh","publisherId":"cuihuaxb200301014","title":"聚Salen-Ti(Ⅳ)配合物对芳香醛<span style=\"color:red\">不对称</span>硅腈<span style=\"color:red\">化</span><span style=\"color:red\">反应</span>的催化作用","volume":"24","year":"2003"},{"abstractinfo":"研究了噻吩、2-甲基噻吩、3-甲基噻吩和 2,5-二甲基噻吩等硫化物与己烯进行<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>的性能. 结果发现,它们进行一次<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>的能力都比较强,在实验条件下转化率几乎都达到了100%. 但噻吩衍生物与己烯进行二次以至多次<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>的能力则随着噻吩环上支链的增加逐渐减弱,原因可能来自噻吩衍生物继续进行<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>的热力学条件不利,以及环上已有侧链的空间位阻效应. 噻吩衍生物发生深度<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>能力的减弱导致了另外两个并行竞争<span style=\"color:red\">反应</span>芳烃<span style=\"color:red\">烷基化</span>和烯烃<span style=\"color:red\">烷基化</span>(聚合)的<span style=\"color:red\">反应</span>程度增强,表现为芳烃转化率和己烯聚合量的升高,以及各自二次<span style=\"color:red\">烷基化</span>产物相对含量的增加.","authors":[{"authorName":"张泽凯","id":"c0748784-a8d4-4800-9aa0-45a443f0e7b0","originalAuthorName":"张泽凯"},{"authorName":"蒋晖","id":"e8870465-a46f-487a-a24a-8a16792bcf54","originalAuthorName":"蒋晖"},{"authorName":"刘盛林","id":"ccd274fe-0490-4c24-9446-77a74a834b29","originalAuthorName":"刘盛林"},{"authorName":"王清遐","id":"a2d87bec-20af-4adb-94bb-746b136f3ff6","originalAuthorName":"王清遐"},{"authorName":"徐龙伢","id":"6304331d-1441-4b1e-aa4f-23aabf433dff","originalAuthorName":"徐龙伢"}],"doi":"","fpage":"309","id":"5b204899-aeb5-4ded-a394-4ac14348a43a","issue":"4","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"69e99652-1726-44f2-b841-c9493b18120b","keyword":"噻吩","originalKeyword":"噻吩"},{"id":"61893992-6293-44f5-b947-08eabb698206","keyword":"噻吩衍生物","originalKeyword":"噻吩衍生物"},{"id":"79258bdd-6417-49ed-b80e-94114d3f4f13","keyword":"<span style=\"color:red\">烷基化</span>","originalKeyword":"烷基化"},{"id":"1515766b-bd20-411b-9097-90b8e7d9b3cc","keyword":"汽油","originalKeyword":"汽油"},{"id":"0921652e-b700-4adc-9777-feab2d6e7605","keyword":"脱硫","originalKeyword":"脱硫"}],"language":"zh","publisherId":"cuihuaxb200604007","title":"汽油<span style=\"color:red\">烷基化</span>脱硫<span style=\"color:red\">反应</span>中噻吩及其衍生物的<span style=\"color:red\">烷基化</span>性能","volume":"27","year":"2006"},{"abstractinfo":"尽管含芳香基等较大取代基团的底物能被生物转化为高对映体纯手性有机硅醇,但生物催化其他底物还原<span style=\"color:red\">反应</span>的产物收率及对映体选择性均较低. 作者筛选到一株能高效催化羰基/羟基<span style=\"color:red\">不对称</span>转化的酵母菌株,探讨了用固定<span style=\"color:red\">化</span>酵母细胞高效催化乙酰基三甲基硅烷<span style=\"color:red\">不对称</span>还原制1-三甲基硅乙醇的可能性,系统研究了培养基碳源及其浓度对该<span style=\"color:red\">反应</span>的影响. 发现在水/正己烷两相体系中,固定<span style=\"color:red\">化</span>酵母细胞能催化乙酰基三甲基硅烷<span style=\"color:red\">不对称</span>还原成1-三甲基硅乙醇. 可通过调节培养基碳源的种类及其浓度在一定程度上控制<span style=\"color:red\">反应</span>的产物收率及对映体选择性. 以最适碳源(3.0%麦芽汁)培养的酵母细胞催化该<span style=\"color:red\">反应</span>的产物收率和对映体过量值分别为91.3%和72.8%,远高于文献报道值. ","authors":[{"authorName":"罗涤衡","id":"67886509-5c32-4fec-8dc6-22d3ea8bfd6a","originalAuthorName":"罗涤衡"},{"authorName":"宗敏华","id":"c3436dcc-f986-4db3-bca2-7be879c7bbdf","originalAuthorName":"宗敏华"},{"authorName":"陈晓瑜","id":"4d93c40b-c0df-41b9-b688-3fa45bbc98a6","originalAuthorName":"陈晓瑜"},{"authorName":"袁玉宇","id":"d295b581-e8a1-408d-832d-17938531b806","originalAuthorName":"袁玉宇"},{"authorName":"许建和","id":"d8ca78c9-8d77-4ec3-855e-cb656feb595c","originalAuthorName":"许建和"}],"doi":"","fpage":"219","id":"58d9a25f-046e-44a6-97fe-732d6e4bdc31","issue":"3","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"fbeba296-29f6-4caa-b782-03c7dde2d0b0","keyword":"Rhodotorula sp.AS2.2241,培养基,碳源,乙酰基三甲基硅烷,<span style=\"color:red\">不对称</span>还原,三甲基硅乙醇","originalKeyword":"Rhodotorula sp.AS2.2241,培养基,碳源,乙酰基三甲基硅烷,不对称还原,三甲基硅乙醇"}],"language":"zh","publisherId":"cuihuaxb200403012","title":"培养基碳源对固定<span style=\"color:red\">化</span>酵母细胞催化乙酰基三甲基硅烷<span style=\"color:red\">不对称</span>还原<span style=\"color:red\">反应</span>的影响","volume":"25","year":"2004"},{"abstractinfo":"考察了180 ℃下不同的胺与各类醇在Ni-Sn/Al_2O_3催化作用下的氮<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>. 研究表明,<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>具有普遍的适用性,多数胺与甲醇、乙醇、正丁醇<span style=\"color:red\">反应</span>,具有较高的氮<span style=\"color:red\">烷基化</span>总产率. 一些胺与醇<span style=\"color:red\">反应</span>产率可达99%以上. 该催化剂还具有很高的稳定性,可保持活性达480 h以上. 对<span style=\"color:red\">反应</span>前后的催化剂进行了XRD和TEM表征,结合表征结果对催化剂前期活性增加及后期活性下降给出了初步分析.","authors":[{"authorName":"罗智伟","id":"35a90d5c-60c6-4831-8879-53e5ad2c5ac3","originalAuthorName":"罗智伟"},{"authorName":"顾辉子","id":"59deae7b-47c6-435a-b830-69c93505d0d4","originalAuthorName":"顾辉子"},{"authorName":"周莉","id":"83b7d888-04ca-4393-ba9f-9ba0505595db","originalAuthorName":"周莉"},{"authorName":"严新焕","id":"f6754c0d-4d81-4a91-befe-fe07fee0598d","originalAuthorName":"严新焕"}],"doi":"10.3969/j.issn.1000-0518.2009.10.009","fpage":"1169","id":"5ec22e5e-6d91-4f9e-989b-f63fd616fc9f","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"bc71fa77-ba93-4383-890e-a1679b803c12","keyword":"N-<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>","originalKeyword":"N-烷基化反应"},{"id":"eae0a4d2-bce2-4994-b6d4-8da9ef1a930e","keyword":"原位液相加氢","originalKeyword":"原位液相加氢"},{"id":"693491a8-6ab3-47e8-9b83-947bb73d58fb","keyword":"氮<span style=\"color:red\">烷基</span>胺化合物","originalKeyword":"氮烷基胺化合物"}],"language":"zh","publisherId":"yyhx200910009","title":"原位液相催化氮<span style=\"color:red\">烷基化</span><span style=\"color:red\">反应</span>","volume":"26","year":"2009"},{"abstractinfo":"采用以L-脯氨酸为原料合成的5种手性β-氨基醇作为有机小分子催化剂,用于催化α,β-不饱和酮的<span style=\"color:red\">不对称</span>环氧化<span style=\"color:red\">反应</span>.考察了影响对映选择性的催化剂结构、氧化剂种类、溶剂、<span style=\"color:red\">反应</span>温度等因素.结果表明,催化剂的结构、氧化剂的种类、<span style=\"color:red\">反应</span>的溶剂对对映选择性和化学产率影响较大,而<span style=\"color:red\">反应</span>温度在室温至-20 ℃范围内,对<span style=\"color:red\">反应</span>的对映选择性和化学产率影响不明显.当以叔丁基过氧化氢(TBHP)为氧化剂、正己烷为溶剂、在室温下、以(S)-2-吡咯烷-α,α-二(α-萘基)甲醇(2b)作催化剂时,所得环氧化物的对映体过量最高为84.6%e.e.,产率最高为89.7%.通过1H NMR对所得环氧化物4的结构进行了表征,并利用手性色谱柱通过高效液相色谱法(HPLC)对产物4的对映体过量进行了测定.","authors":[{"authorName":"柳文敏","id":"699e1291-0d50-4977-b3f7-af47c664c8cc","originalAuthorName":"柳文敏"},{"authorName":"王巧峰","id":"e1b69c3f-2c83-409f-bfc2-3e49161e386a","originalAuthorName":"王巧峰"},{"authorName":"刘雪英","id":"85e68a27-31a4-44bc-b86c-6146037f12ac","originalAuthorName":"刘雪英"},{"authorName":"张生勇","id":"e1d9f275-4c38-420a-8a3f-0581bbe6560e","originalAuthorName":"张生勇"}],"doi":"10.3969/j.issn.1000-0518.2007.08.015","fpage":"925","id":"f5b20673-3e4a-40aa-b5e8-289f26aa2099","issue":"8","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"324838ce-228c-46c7-9c1f-3dc4bb2b8e0c","keyword":"环氧化<span style=\"color:red\">反应</span>","originalKeyword":"环氧化反应"},{"id":"945d52c7-0b74-48d0-a99d-523796fcbba7","keyword":"手性β-氨基醇","originalKeyword":"手性β-氨基醇"},{"id":"d6c8d213-3dd8-46ad-ab87-a789a2d04ee1","keyword":"<span style=\"color:red\">不对称</span>催化","originalKeyword":"不对称催化"},{"id":"5a86b015-bb99-476b-9cad-8598873ec330","keyword":"α","originalKeyword":"α"},{"id":"fe949ef4-22a9-49ff-8e58-f5e9ddc7eb14","keyword":"β-不饱和酮","originalKeyword":"β-不饱和酮"},{"id":"71185e1b-34d1-4186-962d-df8112c32658","keyword":"L-脯氨酸衍生物","originalKeyword":"L-脯氨酸衍生物"}],"language":"zh","publisherId":"yyhx200708015","title":"(S)-2-吡咯<span style=\"color:red\">烷基</span>甲醇衍生物催化α,β-不饱和酮的<span style=\"color:red\">不对称</span>环氧化<span style=\"color:red\">反应</span>","volume":"24","year":"2007"},{"abstractinfo":"以商业易得的(-)-麻黄碱、(+)-伪麻黄碱和各种手性氨醇为主要原料,经过简单的两步<span style=\"color:red\">反应</span>,合成了一系列基于甲磺酰基的磺酰胺-氨醇(SAA)配体,并将其用于催化苯乙炔基锌对醛的<span style=\"color:red\">不对称</span>加成<span style=\"color:red\">反应</span>.在没有Ti(OiPr)4等金属试剂的条件下,配体表现出较好的<span style=\"color:red\">不对称</span>诱导能力,取得了高达83%ee.","authors":[{"authorName":"金薇","id":"41f34cce-5961-45e9-824f-e3f3779b5fd0","originalAuthorName":"金薇"},{"authorName":"黄永波","id":"1c3ef9db-0b15-49e6-8ad4-c83d35ee5ae1","originalAuthorName":"黄永波"},{"authorName":"万伯顺","id":"458b85b5-f213-452c-8902-ade18b0b2c9e","originalAuthorName":"万伯顺"}],"doi":"10.1016/S1872-2067(10)60106-4","fpage":"1098","id":"9c8c057e-21c7-4732-a035-e2eff63aa369","issue":"9","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"3a03c7c0-3399-4664-ada9-28b7dd41f906","keyword":"磺酰胺-氨醇配体","originalKeyword":"磺酰胺-氨醇配体"},{"id":"c2139da4-1cc9-427f-a1f9-05bb43b010b2","keyword":"<span style=\"color:red\">不对称</span>加成","originalKeyword":"不对称加成"},{"id":"3f39de37-cf52-4d8d-911a-c9f596a10c6f","keyword":"炔基<span style=\"color:red\">化</span><span style=\"color:red\">反应</span>","originalKeyword":"炔基化反应"},{"id":"91b865c7-efeb-4fff-bf0b-5a358dc8d5f3","keyword":"醛","originalKeyword":"醛"}],"language":"zh","publisherId":"cuihuaxb201009002","title":"基于甲磺酰基的磺酰胺-氨醇作为催化醛的<span style=\"color:red\">不对称</span>炔基<span style=\"color:red\">化</span><span style=\"color:red\">反应</span>新配体","volume":"31","year":"2010"},{"abstractinfo":"以轴手性的BINOL/H8-BINOL(BINOL为联苯酚)和大位阻的金刚烷酰氯为原料,合成了系列新型手性单齿亚磷酸酯配体,并应用于Cu催化的二乙基锌对环烯酮的<span style=\"color:red\">不对称</span>1,4.共轭加成<span style=\"color:red\">反应</span>中.结果表明,配体结构中部分氢化的2,2'-(1,1'-联萘基)亚磷酸酯单元和金刚<span style=\"color:red\">烷基</span>团,有助于改善<span style=\"color:red\">反应</span>的对映选择性,对映选择性最高可达79%.","authors":[{"authorName":"万博","id":"2eb04dfd-3b46-48bf-aea5-dd2aab6441aa","originalAuthorName":"万博"},{"authorName":"邝福儿","id":"942418a5-b91d-41b3-8095-e45376d8ca9a","originalAuthorName":"邝福儿"},{"authorName":"王来来","id":"53a7ca69-5539-44ae-9e5f-f47c472affc4","originalAuthorName":"王来来"},{"authorName":"徐立进","id":"5afb8893-9793-4b7c-af03-1485a142cdbb","originalAuthorName":"徐立进"},{"authorName":"赵庆鲁","id":"48c399db-9634-4fa1-9002-be27593f2c75","originalAuthorName":"赵庆鲁"},{"authorName":"邢爱萍","id":"2f70e946-d125-4dde-8160-ee3f92a70db3","originalAuthorName":"邢爱萍"}],"doi":"10.1016/S1872-2067(10)60164-7","fpage":"80","id":"93787f1a-55bf-4e55-ac0a-97cf55b38229","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"684a038c-a954-4740-8afa-1a0c7c89af82","keyword":"<span style=\"color:red\">不对称</span>1,4-共轭加成","originalKeyword":"不对称1,4-共轭加成"},{"id":"1a65ce9a-89a2-4ee6-a474-69c153ef5942","keyword":"单齿亚磷酸酯配体","originalKeyword":"单齿亚磷酸酯配体"},{"id":"4d777dea-f1ef-471a-a0e9-739cd0c22f56","keyword":"铜盐","originalKeyword":"铜盐"},{"id":"ded74f0e-8010-468b-b93b-e91001614298","keyword":"环烯酮","originalKeyword":"环烯酮"},{"id":"e4f31839-c7a3-41bd-a125-54fa9258aa88","keyword":"金刚烷","originalKeyword":"金刚烷"},{"id":"efb39878-c234-4bb6-bdb7-3bae86063ad1","keyword":"氢八联萘酚单元","originalKeyword":"氢八联萘酚单元"}],"language":"zh","publisherId":"cuihuaxb201101012","title":"含金刚<span style=\"color:red\">烷基</span>团的新型手性单齿亚磷酸酯配体的合成及其在<span style=\"color:red\">不对称</span>1,4-共轭加成<span style=\"color:red\">反应</span>中的应用","volume":"32","year":"2011"},{"abstractinfo":"通过将手性胺和酸基团同时引入到二氧化硅表面制备得到了一种多相双功能催化剂.该催化剂在<span style=\"color:red\">不对称</span>直接Aldol<span style=\"color:red\">反应</span>中表现出中等的催化活性和对映选择性(ee值最高可达60%以上).催化剂中手性胺和酸基团的协同作用对<span style=\"color:red\">反应</span>的活性和手性诱导至关重要.","authors":[{"authorName":"钟琳","id":"51bd87ee-7406-41f9-93f5-189329e78db3","originalAuthorName":"钟琳"},{"authorName":"肖建良","id":"2b0797a0-0bd0-4fd2-a94c-328d3ebd7e1b","originalAuthorName":"肖建良"},{"authorName":"李灿","id":"1daf68eb-d1e4-4a20-8dea-6a9ef9131bd9","originalAuthorName":"李灿"}],"doi":"","fpage":"673","id":"79117075-2234-43f0-96ce-c90b4e69bef6","issue":"8","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"2cad8ae0-2999-4217-ab30-4f607bb2b1ba","keyword":"<span style=\"color:red\">不对称</span>催化","originalKeyword":"不对称催化"},{"id":"b39f728c-b61a-454d-9023-a8ffbcb19010","keyword":"Aldol<span style=\"color:red\">反应</span>","originalKeyword":"Aldol反应"},{"id":"351fc831-e7bc-4e6c-98e6-3bf202d8810c","keyword":"双功能催化剂","originalKeyword":"双功能催化剂"},{"id":"c99c17c9-cc61-4ee5-a318-4623320abec2","keyword":"有机-无机材料","originalKeyword":"有机-无机材料"}],"language":"zh","publisherId":"cuihuaxb200708003","title":"多相双功能催化剂上的<span style=\"color:red\">不对称</span>直接Aldol<span style=\"color:red\">反应</span>","volume":"28","year":"2007"}],"totalpage":5287,"totalrecord":52862}