{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以<span style=\"color:red\">碘</span>苯、二苯硫醚为主要原料,经Fridel-Crafts酰基化、取代、置换反应得到[4-(对苯甲酰基苯硫基)苯]苯基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span>六氟磷酸盐(Ⅲ). 其结构经UV、1H NMR、IR及MS测试技术分析确证,并通过正交试验确定了合成反应的最佳实验条件:4-苯硫基二苯甲酮2.033 g,羟基对甲苯磺酰氧<span style=\"color:red\">碘</span>苯3.294 g,催化剂乙酐与浓硫酸摩尔比为1∶5,在60 ℃下反应24 h,产率可达47.9%. 并对该产物进行了光引发性能测试.","authors":[{"authorName":"李焱飞","id":"fb6d38df-6a7d-45ce-a119-0cc960c3ba02","originalAuthorName":"李焱飞"},{"authorName":"谢川","id":"1137e8d0-71bb-46aa-954c-255930534ca6","originalAuthorName":"谢川"}],"doi":"10.3969/j.issn.1000-0518.2008.02.027","fpage":"251","id":"c6072edb-a933-46a8-93e0-ef2ed90521da","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"e041c15b-105f-4d0d-bd0e-e23ee02a8c92","keyword":"<span style=\"color:red\">碘</span>(<span style=\"color:red\">鎓</span>)<span style=\"color:red\">盐</span>","originalKeyword":"碘(鎓)盐"},{"id":"12e05977-5c82-413f-9d45-dc0316a63dff","keyword":"光引发剂","originalKeyword":"光引发剂"},{"id":"6d9d8a7d-d79f-44ec-9ca5-dfe1adf4c9f0","keyword":"合成","originalKeyword":"合成"},{"id":"75aef9ac-5b8c-4f75-9a8b-180aa5d833c0","keyword":"正交试验","originalKeyword":"正交试验"},{"id":"f0f2d9e5-6e46-46e5-9a67-7122dc3712ca","keyword":"光引发性能","originalKeyword":"光引发性能"}],"language":"zh","publisherId":"yyhx200802027","title":"[4-(对苯甲酰基苯硫基)苯]苯基<span style=\"color:red\">碘</span>(<span style=\"color:red\">鎓</span>)六氟磷酸盐的合成","volume":"25","year":"2008"},{"abstractinfo":"有机高价<span style=\"color:red\">碘</span>试剂是一类环境友好、制备简单且性质温和的有机合成新试剂。近年来,有机高价<span style=\"color:red\">碘</span>试剂因表现出新颖、独特的反应性能而受到化学工作者广泛关注,成为有机合成重要研究领域之一。二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>是有机高价<span style=\"color:red\">碘</span>试剂的一个重要组成部分,是一类具有较高普适性的芳基化试剂,可用于羰基化合物、烯烃、炔烃和杂原子亲核化合物等的芳基化反应。目前,二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>作为芳基化试剂对具有单一芳基化位点化合物的芳基化已经有了非常广泛而深入的研究。对于具有两个甚至多个芳基化位点的化合物(如同时具有胺基和炔基),其芳基化选择性问题仍缺乏系统研究。特别是在多个芳基化位点共存时如何能够使芳基化发生在某一特定位点仍然是一大难题。这限制了二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>作为芳基化试剂更广泛的应用。因此,我们选用2-炔基苯胺(含有胺基和炔基两个芳基化位点)作为原料,通过溶剂的选择以及溶液酸碱性的调控来改变不同芳基化位点的反应活性,通过催化剂的调变来改变二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>芳基化反应的能力,从而找出最优条件实现底物分子的选择性芳基化反应,并利用剩余活性位点实现分子内的环化反应,从而实现芳基化-环化串联反应合成一系列N-芳基吲哚类化合物。在对模型底物进行条件筛选实验时发现,以2-乙基辛酸铜(Cu(OCOC8H17)2)作催化剂,二异丙基乙基胺(DIPEA)作碱,1,2-二氯乙烷(DCE)为溶剂,反应以最高93%的收率得到1,2-二苯基吲哚。使用该最优反应条件,一系列2-炔基苯胺都能与二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>很好地发生反应并且以良好到优秀的产率(71%–98%)得到目标产物N-芳基吲哚。此外,2-炔基苯胺与非对称的二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>也能发生反应,实验结果证明为位阻较小的芳基对胺基进行了N-芳基化反应。通过空白实验和对比实验,我们提出了可能的反应机理：二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>在铜催化剂作用下转化为亲电性的芳基活性中间体,该中间体与底物的胺基发生芳基化反应,然后芳基化产物在铜催化剂作用下环化生成N-芳基吲哚。该反应很好地解决了同时具有胺基和炔基两个芳基化位点的底物与二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>反应时C-芳基化和N-芳基化的竞争问题,选择合适反应条件使N-芳基化反应优先进行,为二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>的选择性芳基化反应提供了很好的实例,并为其它具有多个芳基化位点化合物的选择性芳基化反应提供了途径。","authors":[{"authorName":"段英","id":"f11dfce3-96fd-491f-a128-1aa9d685c074","originalAuthorName":"段英"},{"authorName":"杨艳良","id":"8eb27307-e5e1-4ca2-a029-9da64d0c6048","originalAuthorName":"杨艳良"},{"authorName":"戴晓玉","id":"47e0f63d-a0fb-49eb-af64-f136d84173a5","originalAuthorName":"戴晓玉"},{"authorName":"李东密","id":"344925fc-262e-4d01-b787-569e04998672","originalAuthorName":"李东密"}],"doi":"10.1016/S1872-2067(16)62522-6","fpage":"1837","id":"5331ab01-f83d-4a3a-8a78-9cefeccbc1bd","issue":"11","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"b581cb6a-82ba-4d1f-8c0f-754b01a24dc1","keyword":"选择性芳基化","originalKeyword":"选择性芳基化"},{"id":"96f90592-d3ea-4e77-99b4-7801ee55d171","keyword":"二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>","originalKeyword":"二芳基碘鎓盐"},{"id":"bdce5ef6-93f6-4a39-8b14-14725cbf192a","keyword":"环化反应","originalKeyword":"环化反应"},{"id":"6124f5a9-9c54-4988-a372-40b7900fdde4","keyword":"2-炔基苯胺","originalKeyword":"2-炔基苯胺"},{"id":"07e9ac92-cd36-4604-b77d-00e918b298bc","keyword":"N-芳基吲哚","originalKeyword":"N-芳基吲哚"},{"id":"c0db67eb-ab93-4f99-87b9-cc0b7796b812","keyword":"串联反应","originalKeyword":"串联反应"}],"language":"zh","publisherId":"cuihuaxb201611004","title":"2-炔基苯胺与二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>的选择性芳基化/环化串联反应","volume":"37","year":"2016"},{"abstractinfo":"采用Photo DSC(光差热扫描)研究了环氧E-51,二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>(CD-1012),光敏剂二异丙基噻唑酮(ITX)组成的阳离子光引发体系的紫外固化动力学.考察了CD-1012和ITX的质量分数、聚合温度、光照强度对其光聚合动力学的影响.利用自加速模型和Arrhenius公式计算了CD-1012/ E-51体系和ITX/CD-1012/ E-51体系的活化能,研究表明光敏剂ITX对CD-1012/ E-51体系具有很好的促进作用.","authors":[{"authorName":"刘宇艳","id":"d8468b4d-33bb-4a22-80fe-e5520ff79cfc","originalAuthorName":"刘宇艳"},{"authorName":"隋微微","id":"81017f3d-ed25-45d7-871f-b5d0e46f66e3","originalAuthorName":"隋微微"},{"authorName":"方佳莹","id":"34d5a488-c719-4f5b-b011-bcb4a29d1b4e","originalAuthorName":"方佳莹"},{"authorName":"谭惠丰","id":"f7b5d009-35c2-49ed-8d5b-55e6ee2057fd","originalAuthorName":"谭惠丰"},{"authorName":"杜星文","id":"f3985bea-171b-462e-bf00-b19a2b05a768","originalAuthorName":"杜星文"}],"doi":"10.3969/j.issn.1001-4381.2008.05.011","fpage":"43","id":"964a66d6-621c-4b47-b5ef-e0f00e59fd34","issue":"5","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"e02f6d4a-71e3-4e5f-a4f4-14880c3c4b7b","keyword":"紫外光阳离子固化动力学","originalKeyword":"紫外光阳离子固化动力学"},{"id":"d7cf7770-b3bc-4ca3-bb32-775084feb134","keyword":"光差热扫描","originalKeyword":"光差热扫描"}],"language":"zh","publisherId":"clgc200805011","title":"二芳基<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>CD-1012/环氧E-51紫外固化动力学研究","volume":"","year":"2008"},{"abstractinfo":"4,4’-二甲苯基三氟甲磺酸<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>可以被染料增感,在365 nm光照时分解产酸.尽管产生的酸与染料的胺基发生作用,依然能在后烘过程中催化缩醛聚合物酸敏基团的分解,但需要稍高的后烘温度和稍长的后烘时间.基于此,本文将酚醛树脂、缩醛聚合物、<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>产酸剂和染料组成了一种新型的化学增幅型i-线正性光致抗蚀剂材料,在曝光量为100 mJ/cm2时可得到分辨率为0.8μm的清晰图形.染料与<span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>光产酸剂组成的感光体系具有很好的漂白性,改善了抗蚀剂材料的透明性.","authors":[{"authorName":"刘娟","id":"c2fb0aee-1f37-4d4a-b9c7-e1c917fe80b3","originalAuthorName":"刘娟"},{"authorName":"孔繁荣","id":"da39c637-63b5-4b7a-8331-249463e9e000","originalAuthorName":"孔繁荣"},{"authorName":"余金星","id":"7b099c7b-d0fa-4fbd-a54b-87a839d0b64e","originalAuthorName":"余金星"},{"authorName":"王力元","id":"36bf3f83-575f-4d47-9280-bcb583fb4beb","originalAuthorName":"王力元"}],"doi":"","fpage":"430","id":"6d0a466f-4483-43ab-8323-54e81f254d0b","issue":"6","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"3f790327-ad7c-44d5-a5ab-5e124cc7e9e7","keyword":"敏化剂","originalKeyword":"敏化剂"},{"id":"51bb87c3-7c32-4d66-8b11-ff867abc1ea6","keyword":"产酸剂","originalKeyword":"产酸剂"},{"id":"1599a983-2a61-43b8-bf1c-13ae304cf3d3","keyword":"染料","originalKeyword":"染料"},{"id":"15a0ed2f-5255-4148-83a8-83ff76c0f3c6","keyword":"正型","originalKeyword":"正型"},{"id":"d930ad7c-bdf6-4dda-848f-2cd871347f24","keyword":"i-线抗蚀剂","originalKeyword":"i-线抗蚀剂"},{"id":"0be779b5-1af4-4520-820c-f5e59417ae95","keyword":"酸解","originalKeyword":"酸解"},{"id":"872a2e14-c3a6-4373-9a7c-e22775d04a77","keyword":"缩醛聚合物","originalKeyword":"缩醛聚合物"}],"language":"zh","publisherId":"ggkxyghx201106003","title":"含<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>光产酸剂和增感染料的化学增幅型i-线正性光致抗蚀剂","volume":"29","year":"2011"},{"abstractinfo":"将二苯二硫醚作为硫源与1-甲基-2-苯基吲哚反应合成了含杂原子环的硫醚类化合物,然后再与二芳基<span style=\"color:red\">碘</span>三氟甲磺酸(<span style=\"color:red\">鎓</span>)<span style=\"color:red\">盐</span>反应,合成了一种新的芳基硫(<span style=\"color:red\">鎓</span>)<span style=\"color:red\">盐</span>.采用1 HNMR、MS等技术对目标化合物进行了表征,并确定了最佳反应条件.在硫醚类化合物与二芳基<span style=\"color:red\">碘</span>三氟甲磺酸(<span style=\"color:red\">鎓</span>)<span style=\"color:red\">盐</span>的摩尔比为1∶1.2,催化剂为CuI/Cu,溶剂为1,1,2,2-四氯乙烷的反应条件下,目标化合物的产率达到了62.0％.同时,对这类结构的芳基硫(<span style=\"color:red\">鎓</span>)<span style=\"color:red\">盐</span>进行了紫外光固化性能测试,发现其能够在紫外光固化体系中作为阳离子光引发剂得到应用.","authors":[{"authorName":"张变香","id":"4124bab7-49a4-445a-bc3d-e7449a4a26f6","originalAuthorName":"张变香"},{"authorName":"郭一力","id":"54286dc6-0884-430e-847c-7fea3d7c9653","originalAuthorName":"郭一力"},{"authorName":"杨丽花","id":"748129b4-fbc5-424b-9dd4-b3a96b4ac619","originalAuthorName":"杨丽花"},{"authorName":"史瑞雪","id":"ce8107e0-dc57-43f4-a569-8d15d644c76c","originalAuthorName":"史瑞雪"}],"doi":"10.7517/j.issn.1674-0475.2015.02.177","fpage":"177","id":"27b4a9a0-7142-45fb-ac3d-67b244555abe","issue":"2","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"01f5079a-8721-44b9-b26e-9f0a9d1ed9ec","keyword":"光引发剂","originalKeyword":"光引发剂"},{"id":"7096b9f7-5c8c-440b-ac88-fa19f003a012","keyword":"芳基硫(<span style=\"color:red\">鎓</span>)<span style=\"color:red\">盐</span>","originalKeyword":"芳基硫(鎓)盐"},{"id":"22b91998-ded5-4db4-9284-01322fe29276","keyword":"二芳基<span style=\"color:red\">碘</span>三氟甲磺酸(<span style=\"color:red\">鎓</span>)<span style=\"color:red\">盐</span>","originalKeyword":"二芳基碘三氟甲磺酸(鎓)盐"}],"language":"zh","publisherId":"ggkxyghx201502010","title":"一种新型芳基硫(<span style=\"color:red\">鎓</span>)<span style=\"color:red\">盐</span>光引发剂的合成及应用","volume":"33","year":"2015"},{"abstractinfo":"以十二烷基苯、碘酸钾为原料,醋酸酐为溶剂,在硫酸的作用下,制备了4,4-双十二烷基苯<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span>盐酸盐.在环己烷溶液中,4,4-双十二烷基苯<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span>盐酸盐与六氟锑酸钾进行离子交换得到目的产物4,4-双十二烷基苯<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span>六氟锑酸盐.通过紫外光谱、红外光谱和核磁共振测定对产物进行了结构确证.","authors":[{"authorName":"刘安昌","id":"0496c472-c255-40d3-afce-6fc657b9ccbc","originalAuthorName":"刘安昌"},{"authorName":"肖庆","id":"a6c62149-0b2c-4d1c-b11e-ff22af105be0","originalAuthorName":"肖庆"},{"authorName":"温玉萍","id":"84a9e2d6-9cba-4065-9155-36ad8256256e","originalAuthorName":"温玉萍"},{"authorName":"谭珍友","id":"7e01047c-6958-4fb8-a437-a3aeeae6f8c1","originalAuthorName":"谭珍友"},{"authorName":"刘芳","id":"b7f87746-4395-45aa-91e8-fc88f7534389","originalAuthorName":"刘芳"}],"doi":"","fpage":"169","id":"985b664c-bfbe-434f-8858-b421562a65e6","issue":"2","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"a09bab4d-e9de-4380-bedd-d1ba2b84d1d9","keyword":"<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>","originalKeyword":"碘鎓盐"},{"id":"d0fca998-1192-48c6-827a-c11a639942c4","keyword":"十二烷基苯","originalKeyword":"十二烷基苯"},{"id":"8802273a-9c4f-4d0c-8adb-321303c6a1eb","keyword":"六氟锑酸钾","originalKeyword":"六氟锑酸钾"}],"language":"zh","publisherId":"ggkxyghx200802012","title":"4,4-双十二烷基苯<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span>六氟锑酸盐的制备","volume":"26","year":"2008"},{"abstractinfo":"本文用羟基对甲苯磺酰氧基<span style=\"color:red\">碘</span>苯与聚苯乙烯进行亲电取代反应,得到大分子阳离子<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>光引发剂聚苯乙烯<span style=\"color:red\">碘</span>锗-六氟锑酸盐(PS-I·SbF6).用核磁共振仪、傅立叶红外光谱仪、凝胶渗透色谱仪、差示扫描量热仪、紫外分光光度仪对其进行了表征.与小分子<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>系光引发剂相比,PS-I·SbF6的紫外最大吸收波长λmax红移,在240-270 nm范围内有较强的吸收;固化成膜后其相对迁移率较小分子光引发剂有显著下降.初步研究了PS-I·SbF6在环氧体系中的光固化性能,结果表明该体系有较好的光固化和后固化特性.","authors":[{"authorName":"夏朝荣","id":"26ae127e-04b5-4975-91ce-95bd7592672f","originalAuthorName":"夏朝荣"},{"authorName":"刘仁","id":"ccbc5302-52b2-476b-9563-8b60f6d7b975","originalAuthorName":"刘仁"},{"authorName":"黄强","id":"9a891f3f-c09d-47b9-adcc-9eac263dba0e","originalAuthorName":"黄强"},{"authorName":"张胜文","id":"f6b1d3fb-d00c-4dcb-a76e-3bab3834fdb2","originalAuthorName":"张胜文"},{"authorName":"江金强","id":"f0a0e796-1b61-4aeb-b434-81b4a61c7a28","originalAuthorName":"江金强"},{"authorName":"刘晓亚","id":"6356e501-093e-4ea2-9bdd-b897aed2e29d","originalAuthorName":"刘晓亚"}],"doi":"","fpage":"438","id":"ad03f41a-8735-4d58-8702-72a44767f003","issue":"6","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"6369ea81-a6ab-4a0c-827e-6f55420afb6d","keyword":"<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>","originalKeyword":"碘鎓盐"},{"id":"3a47c813-77e5-4959-a220-3a8fdf622aa7","keyword":"阳离子大分子光引发剂","originalKeyword":"阳离子大分子光引发剂"},{"id":"0e636a5d-b910-492f-a0f9-01fae9d7a5e2","keyword":"紫外光固化","originalKeyword":"紫外光固化"},{"id":"06760d32-bcc3-4252-8871-1c418ccbe0c5","keyword":"感光性能","originalKeyword":"感光性能"}],"language":"zh","publisherId":"ggkxyghx200806002","title":"大分子阳离子光引发剂聚苯乙烯-<span style=\"color:red\">碘</span>(<span style=\"color:red\">鎓</span>)六氟锑酸盐的合成及其感光性能的研究","volume":"26","year":"2008"},{"abstractinfo":"以对甲苯胺为原料,经重氮化、KI分解得到对-<span style=\"color:red\">碘</span>甲苯.在NH4Cl存在下,对-<span style=\"color:red\">碘</span>甲苯在过硫酸铵的氧化下与异丁苯反应,得到(4-甲苯基)(4-异丁基苯基)<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span>氯.在丙酮溶剂中,(4-甲苯基)(4-异丁基苯基)<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span>氯与六氟磷酸钾进行离子交换,得到目的产物(4-甲苯基)(4-异丁基苯基)<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span>六氟磷酸盐.总收率为46.7%.通过紫外光谱、红外光谱和核磁共振测定,对产物进行了结构确证.","authors":[{"authorName":"刘安昌","id":"6a26aab2-27d7-45cd-851f-7094b5e22612","originalAuthorName":"刘安昌"},{"authorName":"姚珊","id":"9115b9f2-1437-48e1-af64-67f815742b56","originalAuthorName":"姚珊"},{"authorName":"陈涣友","id":"523ef107-c1b2-4a89-bc22-b8c80827f8e4","originalAuthorName":"陈涣友"},{"authorName":"夏强","id":"41607344-a69e-4f22-b9f7-cbd917f867ca","originalAuthorName":"夏强"},{"authorName":"李高峰","id":"b53441d6-8e6c-42ac-9b52-b7381d8c5477","originalAuthorName":"李高峰"}],"doi":"","fpage":"149","id":"e47f858b-2e4f-4e78-bb5f-541d21480bb0","issue":"2","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"cc7c908b-b207-427a-a3af-199fbf2b17cc","keyword":"<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>","originalKeyword":"碘鎓盐"},{"id":"a5644636-d20b-4968-a30d-21deda70a09b","keyword":"阳离子聚合","originalKeyword":"阳离子聚合"},{"id":"c940b9cc-6f77-41d1-9e99-bf6f80f4f84c","keyword":"光引发剂","originalKeyword":"光引发剂"}],"language":"zh","publisherId":"ggkxyghx201102008","title":"光引发剂(4-甲苯基)(4-异T基苯基)<span style=\"color:red\">碘</span><span style=\"color:red\">鎓</span>六氟磷酸盐的合成研究","volume":"29","year":"2011"},{"abstractinfo":"合成了6种适用于248 nm光致抗蚀剂的硫<span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>产酸剂,其中吩噻(噁)体系的产酸剂为自行设计合成. 利用IR、H NMR、UV等测试技术进行了结构表征和紫外吸收测定,各化合物的最大紫外吸收在250～285 nm之间,吸收域较宽,适用性较强.同时,利用酸敏染料罗丹明B遇酸异构变色的特点,使用紫外!可见分光光度计定量检测了6种产酸剂在乙腈溶剂中的产酸效率,其中硫杂蒽酮系列的产酸剂产酸性能最好. 最后使用荧光追踪法研究了溶剂极性对产酸效率的影响,发现产酸剂的产酸性能同溶剂的选取密切相关,随着溶剂极性的减小,产酸效率随之降低. 对6种硫<span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>的产酸效率检测结果可以为产酸剂进一步用于248 nm光致抗蚀剂配方提供详细的参考.","authors":[{"authorName":"杨幸幸","id":"ccbfaef3-82d1-40f6-9c24-5f872ee3b7f1","originalAuthorName":"杨幸幸"},{"authorName":"邹应全","id":"d98b54d7-3302-4f5d-84d6-2c0adff03f89","originalAuthorName":"邹应全"}],"doi":"10.3969/j.issn.1000-0518.2009.10.014","fpage":"1194","id":"09e04948-a818-469c-84cd-8b8b57fd9712","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"deec0541-7747-4053-a903-de9654d021c7","keyword":"硫<span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>","originalKeyword":"硫鎓盐"},{"id":"5a97af8d-97e0-483f-b3b4-77b6d96ab10a","keyword":"产酸剂","originalKeyword":"产酸剂"},{"id":"d2ff951d-5c97-4c09-ae5d-84428e663bd7","keyword":"产酸效率","originalKeyword":"产酸效率"}],"language":"zh","publisherId":"yyhx200910014","title":"硫<span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>产酸剂的合成及其产酸效率","volume":"26","year":"2009"},{"abstractinfo":"采用紫外分光光度分析法,研究了双氧水、高锰酸钾对光亮镀镍体系中添加剂丙烷磺酸吡啶<span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>(PPS)去除的影响情况,并进一步研究了时间和添加量对活性炭吸附光亮镀镍液中PPS的影响.试验结果表明:双氧水、高锰酸钾氧化法对光亮镀镍体系中添加剂PPS的去除影响很小;活性炭吸附法对电镀液中的添加剂PPS的损失有较大影响;当PPS浓度为0.3 g/L时,加入1 g/L粉状活性炭最多可吸附除去0.047 gPPS.","authors":[{"authorName":"毛岩鹏","id":"5ed18946-ef07-47af-bb5c-e2487e217bfb","originalAuthorName":"毛岩鹏"},{"authorName":"高灿柱","id":"49105b97-5791-4b83-bbd2-531e7277ea35","originalAuthorName":"高灿柱"}],"doi":"10.3969/j.issn.1001-1560.2007.01.018","fpage":"53","id":"852a737f-1344-475f-95f5-dbf35e344739","issue":"1","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"cb2ab9cb-683b-43e2-ba8b-400c919378da","keyword":"光亮镀镍","originalKeyword":"光亮镀镍"},{"id":"3665df87-7c30-4add-9ea0-757cbcd6f381","keyword":"镀液","originalKeyword":"镀液"},{"id":"5248b212-353e-4a34-b902-935ebe0ddf58","keyword":"紫外分光光度法","originalKeyword":"紫外分光光度法"},{"id":"74a98d66-73fb-4b5e-abe7-eff40c597c7a","keyword":"丙烷磺酸吡啶<span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>(PPS)","originalKeyword":"丙烷磺酸吡啶鎓盐(PPS)"},{"id":"cd1cdf00-a805-4f70-a845-1b76abd3e2f2","keyword":"活性炭","originalKeyword":"活性炭"},{"id":"e90084d9-b28a-42b0-8139-4616d56c6e50","keyword":"去除","originalKeyword":"去除"}],"language":"zh","publisherId":"clbh200701018","title":"光亮镍电镀液中丙烷磺酸吡啶<span style=\"color:red\">鎓</span><span style=\"color:red\">盐</span>的去除研究","volume":"40","year":"2007"}],"totalpage":542,"totalrecord":5411}