{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用自组装-瓶中造船法在NaY分子筛超笼内,将溴化1-癸基-3-甲基咪唑离子液体和邻菲罗啉钯组合成一体化催化剂,并用于苯胺羰化反应.结果表明,相对于以离子液体为溶剂,邻菲罗啉钯配合物/NaY分子筛为催化剂的体系,该一体化催化剂在离子液体和邻菲罗啉钯配合物用量显著降低的条件下,TOF可达23 000h-1,而相应均相催化剂体系的TOF仅为3 060h-1.","authors":[{"authorName":"马<span style=\"color:red\">昱</span>博","id":"84c8b314-e0df-4218-ac9c-5806c35a3493","originalAuthorName":"马昱博"},{"authorName":"<span style=\"color:red\">何</span><span style=\"color:red\">昱</span><span style=\"color:red\">德</span>","id":"033c4e64-7056-4492-93da-a6c362aa51dc","originalAuthorName":"何昱德"},{"authorName":"张庆华","id":"31705fac-c355-4b22-b0b8-9934f88a10df","originalAuthorName":"张庆华"},{"authorName":"石峰","id":"215e3c12-7820-4fe0-9ce7-3fa92827ff5b","originalAuthorName":"石峰"},{"authorName":"马祥元","id":"38526117-311f-471b-9b3a-2e6fc25f56d4","originalAuthorName":"马祥元"},{"authorName":"卢六斤","id":"a514bf36-1e99-4223-8713-570efda50463","originalAuthorName":"卢六斤"},{"authorName":"邓友全","id":"69c051f7-20a8-4dfc-aeb7-85fddf1c43ed","originalAuthorName":"邓友全"}],"doi":"10.1016/S1872-2067(09)60090-5","fpage":"933","id":"42241d0e-081e-4143-a584-88eeb0df01ed","issue":"8","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"9d13a2e3-d675-44fd-81c1-02f2b327d3f5","keyword":"活性位","originalKeyword":"活性位"},{"id":"b8eecefd-c87b-4884-a345-8a8b3ed5e988","keyword":"离子液体","originalKeyword":"离子液体"},{"id":"5df2b088-803a-496e-9c23-316a421aabdf","keyword":"金属配合物","originalKeyword":"金属配合物"},{"id":"e877bd97-d557-4bd0-8e4f-98a003d3c2fe","keyword":"羰化","originalKeyword":"羰化"},{"id":"5f50f344-ce3f-49de-bc88-4662e5e487ff","keyword":"苯胺","originalKeyword":"苯胺"},{"id":"eae4971e-5df0-4557-820e-30e7bcbbd5f5","keyword":"苯胺基甲酸甲酯","originalKeyword":"苯胺基甲酸甲酯"},{"id":"c91a9103-1f85-40a6-94bd-8d946ee1be28","keyword":"转化频率","originalKeyword":"转化频率"}],"language":"zh","publisherId":"cuihuaxb201008009","title":"NaY分子筛超笼内离子液体和金属配合物自组装制备溶剂分子和金属配合物一体化催化剂","volume":"31","year":"2010"},{"abstractinfo":"2011年8日下午，<span style=\"color:red\">何</span>梁<span style=\"color:red\">何</span>利基金2011年度颁奖大会在京举行。我国高性能计算机领域杰出科学家、国防科技大学杨学军教授荣获“科学与技术成就奖”，丁伟岳等35人获“科学与技术进步奖”，吴朝晖等15人获“科学与技术创新奖”。中共中央政治局委员、国务委员刘延东向大会发来贺信，全国人大常委会副委员长桑国卫、全国政协副主席万钢出席会议并为获奖代表颁奖。<span style=\"color:red\">何</span>梁<span style=\"color:red\">何</span>利基金评选委员会主任朱丽兰向大会作工作报告。","authors":[],"doi":"","fpage":"45","id":"f37cc6ef-fc18-4992-bf12-87f4f2454c06","issue":"11","journal":{"abbrevTitle":"ZGCLJZ","coverImgSrc":"journal/img/cover/中国材料进展.jpg","id":"80","issnPpub":"1674-3962","publisherId":"ZGCLJZ","title":"中国材料进展"},"keywords":[{"id":"fb622aa9-b734-4f1c-b64e-92e6a4a88f1a","keyword":"科学家","originalKeyword":"科学家"},{"id":"6423a5d0-9de7-4a39-88fa-566072fd7e5d","keyword":"基金","originalKeyword":"基金"},{"id":"e733528d-7ae2-4e1f-b51c-af533f427e80","keyword":"中共中央政治局","originalKeyword":"中共中央政治局"},{"id":"8f9e518a-8e11-4218-a7b3-3c4611f804f7","keyword":"全国人大常委会","originalKeyword":"全国人大常委会"},{"id":"cddcb0f8-f641-4940-8dfd-f61da6f88936","keyword":"突出","originalKeyword":"突出"},{"id":"9ec15a38-d48c-406e-bf20-bd087ed406a0","keyword":"国防科技大学","originalKeyword":"国防科技大学"},{"id":"23458c7c-6c4e-4e81-b7cd-71807927d295","keyword":"计算机领域","originalKeyword":"计算机领域"},{"id":"b6a04d71-3662-490c-8d43-bef3fa71c865","keyword":"科学与技术","originalKeyword":"科学与技术"}],"language":"zh","publisherId":"zgcljz201111011","title":"2011年度<span style=\"color:red\">何</span>梁<span style=\"color:red\">何</span>利基金获奖科学家年轻化突出","volume":"30","year":"2011"},{"abstractinfo":"对<span style=\"color:red\">德</span>马克连铸机存在的问题进行分析,并针对存在问题进行技术改造,收到较好的效果,使铸坯质量和产量得到明显的提高.","authors":[{"authorName":"姜振强","id":"09c1d70f-8c55-47ae-ba0f-c0e77f57b958","originalAuthorName":"姜振强"},{"authorName":"郭广文","id":"a17f5c61-3ee8-48b8-a907-1897fc12daaf","originalAuthorName":"郭广文"},{"authorName":"陈树林","id":"6d5932f7-228e-47bd-8e6d-5b42150a9407","originalAuthorName":"陈树林"}],"doi":"10.3969/j.issn.1005-4006.2003.05.005","fpage":"12","id":"5777ebc2-0764-44e5-8805-c7c4c71980c2","issue":"5","journal":{"abbrevTitle":"LZ","coverImgSrc":"journal/img/cover/LZ.jpg","id":"52","issnPpub":"1005-4006","publisherId":"LZ","title":"连铸"},"keywords":[{"id":"21ad4ab9-9ba1-467e-b781-12be7452c174","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"lz200305005","title":"<span style=\"color:red\">德</span>马克连铸机系统改造","volume":"","year":"2003"},{"abstractinfo":"介绍了贝纳<span style=\"color:red\">德</span>效应,胆甾相液晶织构等概念,实验制备出胆甾相液晶平面态样品,用偏光显微镜观察温度场致织构变化,观察到液晶盒在清亮点温度附近出现特殊花纹图案,类似于贝纳<span style=\"color:red\">德</span>效应或者是温度场致方格栅效应.实验现象说明了温度场使液晶分子产生对流,在偏光显微镜下观察双折射干涉,指向矢分布有周期性变化,形成了微观的贝纳<span style=\"color:red\">德</span>花纹.实验现象对于胆甾相液晶基础研究具有一定意义.","authors":[{"authorName":"杨磊","id":"5013b502-d604-4221-9af6-8bbbd1960581","originalAuthorName":"杨磊"},{"authorName":"刘洋","id":"202a3a36-249d-468b-b8da-59e126411cd9","originalAuthorName":"刘洋"},{"authorName":"郑永磊","id":"b3d0d06e-5f02-457a-8669-2d895d24bcfb","originalAuthorName":"郑永磊"},{"authorName":"高攀","id":"d0eac134-2d43-4079-aead-c0198398411b","originalAuthorName":"高攀"},{"authorName":"范志新","id":"c705feda-75b8-4a3e-b8ce-75b233083e88","originalAuthorName":"范志新"}],"doi":"10.3788/YJYXS20122703.0288","fpage":"288","id":"33e8f1ec-a2c9-492e-91eb-0329df32f5d9","issue":"3","journal":{"abbrevTitle":"YJYXS","coverImgSrc":"journal/img/cover/YJYXS.jpg","id":"72","issnPpub":"1007-2780","publisherId":"YJYXS","title":"液晶与显示   "},"keywords":[{"id":"abe8f909-b3b4-46da-8e99-5ae5f2101e23","keyword":"胆甾相液晶","originalKeyword":"胆甾相液晶"},{"id":"3f874625-c7c5-48c7-ab2a-44cf168fb99b","keyword":"平面织构","originalKeyword":"平面织构"},{"id":"c5070beb-0731-49fc-b2c8-2db59f17bc70","keyword":"方格栅效应","originalKeyword":"方格栅效应"},{"id":"0dea2f30-25a1-44cc-b3df-f8245b693b31","keyword":"贝纳<span style=\"color:red\">德</span>效应","originalKeyword":"贝纳德效应"},{"id":"43b474c5-b82e-49a8-8bbe-9a835c9ce411","keyword":"偏光显微镜","originalKeyword":"偏光显微镜"}],"language":"zh","publisherId":"yjyxs201203002","title":"胆甾相液晶盒贝纳<span style=\"color:red\">德</span>效应实验","volume":"27","year":"2012"},{"abstractinfo":"建立了一快速、简单地测定阿<span style=\"color:red\">德</span>福韦酯及其降解产物阿<span style=\"color:red\">德</span>福韦单特戊酸甲基酯、阿<span style=\"color:red\">德</span>福韦的反相高效液相色谱方法.以Inertsil CN-3化学键合硅胶为固定相,以乙腈-25 mmol/L磷酸盐缓冲液(pH 4.0)(体积比为33∶67)为流动相,流速1.0 mL/min,检测波长260 nm.阿<span style=\"color:red\">德</span>福韦酯、阿<span style=\"color:red\">德</span>福韦的质量浓度分别为1.861～181.7 mg/L和2.018～197.2 mg/L时与峰面积呈良好的线性关系(r分别为0.9999和0.9998);阿<span style=\"color:red\">德</span>福韦酯及阿<span style=\"color:red\">德</span>福韦平均加样回收率分别为99.5% ～101.0%和99.1% ～99.6% ,相对标准偏差(RSD)均低于1.0% ,阿<span style=\"color:red\">德</span>福韦的最小检测量(以信噪比为3计)为1 ng.该方法能同时测定阿<span style=\"color:red\">德</span>福韦酯及其降解产物,可用于阿<span style=\"color:red\">德</span>福韦酯降解产物的检测.","authors":[{"authorName":"蒋晔","id":"d81c9556-101e-44ae-8f7d-708558882cea","originalAuthorName":"蒋晔"},{"authorName":"徐智儒","id":"9eef3ed2-ee80-4552-ab3a-268dbcbc9fd9","originalAuthorName":"徐智儒"},{"authorName":"张晓青","id":"a608aa9c-6cca-4251-8a2a-f07c34a05c73","originalAuthorName":"张晓青"}],"doi":"10.3321/j.issn:1000-8713.2004.03.015","fpage":"248","id":"aae1beb3-7cee-4866-ac8c-fd12afe66285","issue":"3","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"b1838086-88c9-409b-a0bb-b040bd650e14","keyword":"高效液相色谱法","originalKeyword":"高效液相色谱法"},{"id":"5511da67-0d84-4304-94fb-d76a67fc0b6b","keyword":"阿<span style=\"color:red\">德</span>福韦酯","originalKeyword":"阿德福韦酯"},{"id":"8b0de6ef-2781-4f9a-a028-670dc773b0c8","keyword":"降解产物","originalKeyword":"降解产物"}],"language":"zh","publisherId":"sp200403015","title":"反相高效液相色谱法测定阿<span style=\"color:red\">德</span>福韦酯及其降解产物","volume":"22","year":"2004"},{"abstractinfo":"主要研究了超声处理对伍<span style=\"color:red\">德</span>合金凝固组织及气孔的作用.结果表明,超声处理可以明显细化伍<span style=\"color:red\">德</span>合金的凝固组织;同时超声处理具有明显的除气效果,随着超声波功率的增强,晶粒尺寸明显减小,除气效果显著.对伍<span style=\"color:red\">德</span>合金凝固过程的超声处理,起主要作用的是声空化和声流作用.","authors":[{"authorName":"陈琳","id":"54889cfe-305a-4f61-9f2e-419640d22cd7","originalAuthorName":"陈琳"},{"authorName":"宗燕兵","id":"36a3e3db-ad71-4ca6-86e4-099f5ba9c418","originalAuthorName":"宗燕兵"},{"authorName":"苍大强","id":"9bf876c9-9046-49df-b187-7f60f1bd0f78","originalAuthorName":"苍大强"},{"authorName":"甄云璞","id":"42c2028d-2527-43ce-be89-437530e16f62","originalAuthorName":"甄云璞"}],"doi":"","fpage":"339","id":"3b4d84ce-753a-4845-a791-57864b34bbf0","issue":"3","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"6ed62144-afc9-4cfe-a445-f47b6ffe7641","keyword":"超声波","originalKeyword":"超声波"},{"id":"483e0482-c2d8-4408-893f-6513a38b54d1","keyword":"伍<span style=\"color:red\">德</span>合金","originalKeyword":"伍德合金"},{"id":"935bb526-03e2-49a9-b36c-483280ee22d8","keyword":"凝固组织","originalKeyword":"凝固组织"},{"id":"e50833e9-d94d-4e2c-ba32-a20b87330cde","keyword":"气孔","originalKeyword":"气孔"},{"id":"d329357a-8598-48fc-ba47-85513da3d2b6","keyword":"声空化","originalKeyword":"声空化"}],"language":"zh","publisherId":"clkxygc200803005","title":"超声处理对伍<span style=\"color:red\">德</span>合金细化及气孔生成的影响","volume":"26","year":"2008"},{"abstractinfo":"对<span style=\"color:red\">德</span>马克型连铸机改造后漏钢事故频繁发生的原因进行分析,提出改进措施,取得了较好的效果.","authors":[{"authorName":"陈树林","id":"0a5c15d2-796f-42c5-8067-e268f4c3b122","originalAuthorName":"陈树林"},{"authorName":"周淑华","id":"b14c49a9-eaa2-4ac0-a656-fb71609a642c","originalAuthorName":"周淑华"},{"authorName":"李勇","id":"5cc05ebf-8679-4abd-b889-6e7d7ea7a890","originalAuthorName":"李勇"},{"authorName":"张道刚","id":"acce4468-79bb-4467-9e3a-bcf505b79d3d","originalAuthorName":"张道刚"},{"authorName":"王鸿飞","id":"c79f5b30-37cf-466a-b84b-965d177d73ba","originalAuthorName":"王鸿飞"},{"authorName":"姜振强","id":"1c74bee1-fa12-42fe-b826-33e14371978f","originalAuthorName":"姜振强"},{"authorName":"史平安","id":"b20ade44-6e35-4305-b82f-c18d8c63473e","originalAuthorName":"史平安"}],"doi":"10.3969/j.issn.1005-4006.2005.02.012","fpage":"32","id":"69b85f5f-d388-49d8-ad87-e16ed5d2fa01","issue":"2","journal":{"abbrevTitle":"LZ","coverImgSrc":"journal/img/cover/LZ.jpg","id":"52","issnPpub":"1005-4006","publisherId":"LZ","title":"连铸"},"keywords":[{"id":"07413991-d5df-4159-8eba-38c875f30f9a","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"lz200502012","title":"<span style=\"color:red\">德</span>马克连铸机检修改造中的问题及分析","volume":"","year":"2005"},{"abstractinfo":"通过非线性变换和特殊设计结点的B样条函数研究计算了囚禁于巴基球内的氢原子里<span style=\"color:red\">德</span>堡能级结构和振子强度. 结果表明, 巴基球等效势阱深度可以有选择的影响和改变里<span style=\"color:red\">德</span>堡原子的特性; 囚禁原子拥有很多自由原子所没有的奇特性质. ","authors":[{"authorName":"张现周","id":"09c4cf95-a682-4549-903b-20409b69ee63","originalAuthorName":"张现周"},{"authorName":"焦照勇","id":"4eee1b4a-5ea3-4de1-a609-c37a010c5edd","originalAuthorName":"焦照勇"},{"authorName":"饶建国","id":"5e3fa3f0-7a8b-4b4c-9e72-048fe3703221","originalAuthorName":"饶建国"}],"doi":"10.3969/j.issn.1007-4627.2002.02.047","fpage":"253","id":"99a0b71a-5dc1-4962-a09f-ffc27bdd7f0f","issue":"2","journal":{"abbrevTitle":"YZHWLPL","coverImgSrc":"journal/img/cover/YZHWLPL.jpg","id":"78","issnPpub":"1007-4627","publisherId":"YZHWLPL","title":"原子核物理评论   "},"keywords":[{"id":"13a4be3a-8168-46ee-a390-7e9c302926b8","keyword":"巴基球","originalKeyword":"巴基球"},{"id":"5de53973-06cf-4c45-9864-36b69c971521","keyword":"里<span style=\"color:red\">德</span>堡原子","originalKeyword":"里德堡原子"},{"id":"00810709-6afd-40e0-9ad3-62e8105d549d","keyword":"非线性变换","originalKeyword":"非线性变换"},{"id":"c131c591-c00c-412b-9b76-c19ed339c8c0","keyword":"B 样条函数方法","originalKeyword":"B 样条函数方法"}],"language":"zh","publisherId":"yzhwlpl200202047","title":"囚禁于巴基球内的原子的里<span style=\"color:red\">德</span>堡特性","volume":"19","year":"2002"},{"abstractinfo":"在<span style=\"color:red\">德</span>马克小方坯连铸机上试用三锥度的结晶器铜管,降低了铸机溢漏率和边裂废品率,为铸机生产的稳定顺行奠定了基础.","authors":[{"authorName":"李勇","id":"0455d165-36ec-433b-8f99-1522b0c8b934","originalAuthorName":"李勇"},{"authorName":"岳峰","id":"eab92547-a62d-47b6-b8af-2ce407821563","originalAuthorName":"岳峰"},{"authorName":"陈树林","id":"1ffbb1e4-d75c-49cd-845e-8090a0d716f1","originalAuthorName":"陈树林"},{"authorName":"张太生","id":"b89078da-f69a-45f3-b97d-19d82ac60537","originalAuthorName":"张太生"},{"authorName":"寿业红","id":"416580fd-c433-43ff-a50c-7c95ca3aadd5","originalAuthorName":"寿业红"}],"doi":"10.3969/j.issn.1005-4006.2006.02.003","fpage":"6","id":"d2b30587-af06-4043-8033-5ec47da0c961","issue":"2","journal":{"abbrevTitle":"LZ","coverImgSrc":"journal/img/cover/LZ.jpg","id":"52","issnPpub":"1005-4006","publisherId":"LZ","title":"连铸"},"keywords":[{"id":"a5295f02-3281-462d-9586-b01d2b7bec4b","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"lz200602003","title":"三锥度小方坯结晶器铜管在<span style=\"color:red\">德</span>马克连铸机上的应用","volume":"","year":"2006"},{"abstractinfo":"采用基于第一性原理的密度泛函理论,计算了3种碳化铬的晶格常数、电子结构、弹性模量、理论硬度和<span style=\"color:red\">德</span>拜温度等.结果表明,Cr3C2,Cr7C3和Cr23C6的化学键均为共价键、离子键和金属键组成的混合键；Cr3C2的热力学和力学稳定性均最高；Cr3C2,Cr7C3和Cr23C6的理论硬度值分别为20.9,18.3和13.2 GPa,这与近期的实验研究结果十分相近.此外,本研究预测了3种碳化铬的<span style=\"color:red\">德</span>拜温度.","authors":[{"authorName":"闵婷","id":"3563fab4-aa36-4f54-a870-6f70ca315fb0","originalAuthorName":"闵婷"},{"authorName":"高义民","id":"72c60e03-6e91-4ff6-ac87-484a9061d3ad","originalAuthorName":"高义民"},{"authorName":"李烨飞","id":"0615fa6e-8616-4ebd-914e-66e290a1073b","originalAuthorName":"李烨飞"},{"authorName":"杨莹","id":"d10e419e-320d-458a-afc2-fec6fbf6009b","originalAuthorName":"杨莹"},{"authorName":"李瑞涛","id":"2144fcfb-d031-4678-913e-f4482a022724","originalAuthorName":"李瑞涛"},{"authorName":"谢小军","id":"32fbc0a0-e9b6-4596-a280-92646b94b50d","originalAuthorName":"谢小军"}],"doi":"","fpage":"271","id":"188bee2b-1837-45d8-98db-1f6312abaa09","issue":"2","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"733d7bbe-0df3-45d7-b250-bc311b91546a","keyword":"第一性原理","originalKeyword":"第一性原理"},{"id":"3fd7162a-24d7-4f19-bb63-8b9e326f8089","keyword":"力学性能","originalKeyword":"力学性能"},{"id":"0d3f270f-2c5d-4736-a8bd-bf544f4c410b","keyword":"<span style=\"color:red\">德</span>拜温度","originalKeyword":"德拜温度"},{"id":"82868585-25c9-4bed-8e2d-946b5886cb7c","keyword":"电子结构","originalKeyword":"电子结构"}],"language":"zh","publisherId":"xyjsclygc201202018","title":"第一性原理研究碳化铬的电子结构、硬度和<span style=\"color:red\">德</span>拜温度","volume":"41","year":"2012"}],"totalpage":28,"totalrecord":276}