{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"将自制咪唑啉磷酸酯盐与KI复配,采用失重法、极化曲线和交流阻抗法研究了该缓蚀剂在1mol/L HCl水溶液中对Q235钢的缓蚀行为,探讨了其在Q235钢表面的吸附行为.结果表明:该缓蚀剂在1mol/L HCl水溶液中对Q235钢为混合偏阴极型缓蚀剂;缓蚀率随缓蚀剂浓度的增大而增加;该缓蚀剂在Q235钢表面的吸附模式遵循Langmuir吸附.","authors":[{"authorName":"于会华","id":"9de5bc7e-22e2-4565-9de4-2610ed0f3cc1","originalAuthorName":"于会华"},{"authorName":"张静","id":"54ae7c65-d272-4f51-a404-5726aa9505ea","originalAuthorName":"张静"},{"authorName":"杜敏","id":"34dcae54-d2f4-4ed6-8bf4-2be4f5bd2c49","originalAuthorName":"杜敏"}],"doi":"10.3969/j.issn.1001-3660.2010.03.014","fpage":"48","id":"42ea3944-bd4f-47ab-bd5c-c66b49c0c8c1","issue":"3","journal":{"abbrevTitle":"BMJS","coverImgSrc":"journal/img/cover/BMJS.jpg","id":"3","issnPpub":"1001-3660","publisherId":"BMJS","title":"表面技术 "},"keywords":[{"id":"4703ea99-3074-4309-85f2-d8ed7e4e0412","keyword":"咪唑啉磷酸酯","originalKeyword":"咪唑啉磷酸酯"},{"id":"f6fa3a34-a1c5-422a-bd57-6b7055092dbe","keyword":"极化曲线","originalKeyword":"极化曲线"},{"id":"1cae577b-4d57-4971-8ecd-bdb8844dc487","keyword":"交流阻抗","originalKeyword":"交流阻抗"},{"id":"c213a806-f7d2-42c8-a81d-5b460c2e4339","keyword":"缓蚀机理","originalKeyword":"缓蚀机理"},{"id":"978bfee7-0169-4fef-96c0-8e3f7ce2b2f1","keyword":"Langmuir吸附","originalKeyword":"Langmuir吸附"}],"language":"zh","publisherId":"bmjs201003014","title":"含咪唑啉磷酸酯的复配缓蚀剂对Q235钢的缓蚀行为研究","volume":"39","year":"2010"},{"abstractinfo":"为了增强咪唑啉磷酸酯类缓蚀剂的水溶性和缓蚀性能,用油酸和二乙烯三胺反应,制备了咪唑啉中间体,分别用氯乙醇与五氧化二磷、磷酸三丁酯与环氧氯丙烷在低温下合成了2种氯化磷酸酯A和B,将其分别作为季铵化试剂与咪唑啉中间体反应,制备了2种改性的咪唑啉磷酸酯缓蚀剂A和B.用傅里叶红外光谱仪对咪唑啉中间体的结构进行了表征,用静态失重法和极化曲线法就2种缓蚀剂在1 mol/L HCl盐酸中对Q235钢的缓蚀性能进行了研究.结果表明:咪唑啉中间体具有预期的结构；2种缓蚀剂在HCl溶液中对Q235钢的缓蚀性能均较好,为控制阳极反应为主的混合型缓蚀剂,其中缓蚀剂B的缓蚀性能更优；缓蚀剂B与无机阴离子E复配后,缓蚀效率在低浓度(20 mg/L)时高达91％,缓蚀性能优异.","authors":[{"authorName":"赵彬","id":"6a1e4dda-d8a7-4fc5-bc73-a7a2341bd978","originalAuthorName":"赵彬"},{"authorName":"谢斌","id":"1af4dd6c-c567-4afd-b9de-036d852eb7c7","originalAuthorName":"谢斌"},{"authorName":"邹立科","id":"11a7de02-bdb6-4a1f-9d43-ca3a946cbd23","originalAuthorName":"邹立科"}],"doi":"","fpage":"26","id":"b637d046-e5c1-447d-926b-dde6572a24a7","issue":"4","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"8cd7478a-5cdc-4109-9255-97d1a9091331","keyword":"咪唑啉中间体","originalKeyword":"咪唑啉中间体"},{"id":"df7aa856-fbf0-4caf-bf97-a3e2777eefe6","keyword":"氯化磷酸酯","originalKeyword":"氯化磷酸酯"},{"id":"18734bdb-4837-4207-921e-f677388f0ab7","keyword":"咪唑啉磷酸酯","originalKeyword":"咪唑啉磷酸酯"},{"id":"529f161d-8ccc-4594-8ea7-7f63e96e5e51","keyword":"缓蚀剂","originalKeyword":"缓蚀剂"},{"id":"29d25a16-a0c3-48e7-a886-8c4580151b47","keyword":"缓蚀性能","originalKeyword":"缓蚀性能"},{"id":"594a4637-7e42-4e84-83a8-1220d0035319","keyword":"季铵化","originalKeyword":"季铵化"}],"language":"zh","publisherId":"clbh201304009","title":"咪唑啉磷酸酯类缓蚀剂的合成及其缓蚀性能","volume":"46","year":"2013"},{"abstractinfo":" 应用电化学方法评价了在饱和CO2模拟盐水中对咪唑啉季铵盐和烷基磷酸酯抑制 A3碳钢腐蚀的效果,并考察了二者复配使用时的协同效应.结果表明,当二者比例为 1∶〖KG-*2〗1时,缓蚀率比单独使用时提高了20%以上.咪唑啉季铵盐主要抑制由于阴极反应引起的腐蚀,烷基磷酸酯主要抑制阳极反应引起的腐蚀,复配使用可同时抑制阴、阳极反应引起的腐蚀,缓蚀效果更好.","authors":[{"authorName":"李倩","id":"0c856f11-70f4-429c-a2f8-245268071527","originalAuthorName":"李倩"},{"authorName":"赵杉林","id":"38530c06-dc1d-493f-8cc8-68959bcf61d2","originalAuthorName":"赵杉林"},{"authorName":"吕振波","id":"8fdad401-5d1d-414d-974a-ad5ea04628b7","originalAuthorName":"吕振波"}],"categoryName":"|","doi":"","fpage":"571","id":"bf8cb528-6c96-47fd-9200-84c839dbae27","issue":"6","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"47198e56-7589-466b-a1ab-ae005bc0879a","keyword":"缓蚀剂","originalKeyword":"缓蚀剂"},{"id":"bc82752c-c461-4d4d-b5d5-1071b96b3cbc","keyword":"imidazoline quaternary-ammonium-salt","originalKeyword":"imidazoline quaternary-ammonium-salt"},{"id":"767ad570-39e8-485f-bac4-625b9f76a8cb","keyword":"alkyl-phosphate ester","originalKeyword":"alkyl-phosphate ester"},{"id":"bd75d2b1-5ab9-431b-a134-ba7d0beb119a","keyword":"synergistic effect","originalKeyword":"synergistic effect"}],"language":"zh","publisherId":"1002-6495_2009_6_9","title":"缓蚀剂咪唑啉季铵盐与烷基磷酸酯用作在饱和CO2模拟盐水体系中的协同效应","volume":"21","year":"2009"},{"abstractinfo":"应用电化学方法评价了在饱和CO_2模拟盐水中对咪唑啉季铵盐和烷基磷酸酯抑制A3碳钢腐蚀的效果,并考察了二者复配使用时的协同效应.结果表明,当二者比例为1:1时,缓蚀率比单独使用时提高了20%以上.咪唑啉季铵盐主要抑制由于阴极反应引起的腐蚀,烷基磷酸酯主要抑制阳极反应引起的腐蚀,复配使用可同时抑制阴、阳极反应引起的腐蚀,缓蚀效果更好.","authors":[{"authorName":"李倩","id":"403ad37a-89a9-4163-8981-3f9a8afe1384","originalAuthorName":"李倩"},{"authorName":"吕振波","id":"abaf4c70-8a2c-46f6-8a4b-d5d1182e247f","originalAuthorName":"吕振波"},{"authorName":"赵杉林","id":"a296821c-d053-45da-81f9-e129a59a42a7","originalAuthorName":"赵杉林"}],"doi":"","fpage":"571","id":"27b31252-e552-46d6-8058-1ce179510636","issue":"6","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"ae64e4b5-acbd-4d31-b104-1fc5e1094b21","keyword":"缓蚀剂","originalKeyword":"缓蚀剂"},{"id":"c7b97f42-2c80-4d0c-b72d-7c501841fa55","keyword":"咪唑啉季铵盐","originalKeyword":"咪唑啉季铵盐"},{"id":"49edbbb5-c5d6-466d-ad84-94a843530d35","keyword":"烷基磷酸酯","originalKeyword":"烷基磷酸酯"},{"id":"a37576b1-daa0-4b77-9be1-59b780177011","keyword":"协同效应","originalKeyword":"协同效应"}],"language":"zh","publisherId":"fskxyfhjs200906017","title":"缓蚀剂咪唑啉季铵盐与烷基磷酸酯在饱和CO_2模拟盐水体系中的协同效应","volume":"21","year":"2009"},{"abstractinfo":"稠油中的环烷酸时常减压装置有较强的腐蚀,必须进行防护,加注缓蚀剂是较为理想的办法.将咪唑啉和亚磷酸二乙酯进行复配,研究其在高温(280℃)下对常减压装置的缓蚀性能.结果表明:280℃,咪唑啉和亚磷酸二乙酯质量比为2:1,复配缓蚀剂的加入量为质量分数0.1%时缓蚀效率最大,达到91.55%.咪唑啉和亚磷酸二乙酯都是吸附膜型缓蚀剂,其质量比2:1时咪唑啉分子在金属表面形成疏松网状的有机吸附膜,高温下亚磷酸二乙酯在这层膜的基础上又生成一层坚韧的吸附覆盖膜,具有较好的缓蚀效果.","authors":[{"authorName":"桑东恒","id":"2812370a-47e4-4e59-9e9b-1dfeb8872683","originalAuthorName":"桑东恒"},{"authorName":"黄本生","id":"ff8e7328-3e86-484f-b6aa-5d278f35dac7","originalAuthorName":"黄本生"},{"authorName":"刘清友","id":"45d6b8a4-18f9-46cb-a148-d46fa909fbbb","originalAuthorName":"刘清友"},{"authorName":"马欣","id":"bb833de2-1edb-4a4e-8048-fc4449733b3a","originalAuthorName":"马欣"},{"authorName":"杨阳","id":"8f6feb0f-9d0f-4c48-a993-80fe05efa582","originalAuthorName":"杨阳"}],"doi":"","fpage":"17","id":"6a0981f3-9440-4393-a065-397445e14776","issue":"5","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"17118d0f-d60a-4aa2-a805-6484899035c5","keyword":"缓蚀剂","originalKeyword":"缓蚀剂"},{"id":"41e7818b-39b1-42da-b146-1e96d27e350a","keyword":"缓蚀机理","originalKeyword":"缓蚀机理"},{"id":"5f7463f3-2ccb-4550-bc5d-71d2c8e0cb3e","keyword":"环烷酸","originalKeyword":"环烷酸"},{"id":"e33caa11-b5b9-4507-adb1-0e2d2f6a55e4","keyword":"咪唑啉","originalKeyword":"咪唑啉"},{"id":"62c16d10-42d3-446e-8cf1-b48262dc65e4","keyword":"亚磷酸二乙酯","originalKeyword":"亚磷酸二乙酯"},{"id":"8321fcc3-003a-4f79-b809-a154e337c684","keyword":"吸附膜","originalKeyword":"吸附膜"}],"language":"zh","publisherId":"clbh201005005","title":"咪唑啉与亚磷酸二乙酯复配对环烷酸腐蚀的缓蚀机理","volume":"43","year":"2010"},{"abstractinfo":"以甲基丙烯酸缩水甘油酯(GMA)与浓磷酸为原料,制备了一种含羟基可交联聚合的磷酸酯功能单体.通过酸值测试跟踪反应进程,确定了GMA中的环氧基团发生开环酯化反应的最佳时间,分析了羟基磷酸酯(HPAM)合成反应机理,确定了最佳的合成工艺.将实验制得的5组HPAM与丙烯酸酯聚合,制备了羟基磷酸酯改性丙烯酸酯乳液,并研究了乳液和涂膜的性能.结果表明,HPAM功能单体的最佳合成工艺为:GMA和浓磷酸按摩尔比为2∶1同步滴加到(0±5)℃的反应釜中进行开环酯化反应,然后升温至(65±2)℃,保温3.5～4.0h.将此工艺下制备的HPAM单体与丙烯酸酯共聚得到的羟基磷酸酯改性丙烯酸酯乳液,具有较好的稳定性,乳液涂膜的附着力为1级,硬度H,冲击强度为50 kg·cm.","authors":[{"authorName":"姚煌","id":"72b91cee-1602-4414-bf88-00f5690f62a5","originalAuthorName":"姚煌"},{"authorName":"许振阳","id":"2eeb0b47-91b3-4a75-b92d-3d65adf8035a","originalAuthorName":"许振阳"},{"authorName":"成晓玲","id":"420b85c1-89c4-4ea3-95a2-534f2165a2c3","originalAuthorName":"成晓玲"},{"authorName":"余倩","id":"c029cbb1-b9a6-4824-9116-308f1916e3b1","originalAuthorName":"余倩"},{"authorName":"张红","id":"d1cf77d7-c28d-4076-9682-cc54acdc1595","originalAuthorName":"张红"},{"authorName":"许奕祥","id":"3248e789-645a-482a-b8a1-e9ce7a90df20","originalAuthorName":"许奕祥"}],"doi":"","fpage":"61","id":"a023e4b0-ffb0-42f6-a476-c93e0ab661fc","issue":"7","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"476cfcf5-0734-4595-8cf6-ed15f6e6cb7f","keyword":"丙烯酸酯乳液","originalKeyword":"丙烯酸酯乳液"},{"id":"7858793b-8d94-472d-8fd4-cf1d881acb07","keyword":"磷酸","originalKeyword":"磷酸"},{"id":"2e9614c3-806d-48b8-91d1-0090f0e92a21","keyword":"羟基磷酸酯","originalKeyword":"羟基磷酸酯"},{"id":"cdb469af-3cfb-4187-82f0-fa915420471e","keyword":"改性","originalKeyword":"改性"},{"id":"a50c749d-4288-4fd8-a6b2-52687cb166f0","keyword":"开环酯化","originalKeyword":"开环酯化"}],"language":"zh","publisherId":"ddyts201307016","title":"羟基磷酸酯功能单体的合成研究","volume":"32","year":"2013"},{"abstractinfo":"在硼酸酯润滑油添加剂中引入氮原子可以改善其水解稳定性和减摩耐磨性能.合成了3种油酸咪唑啉硼酸酯润滑油添加剂,考察了添加剂含量、载荷对试样在液体石蜡基础油中摩擦学性能的影响,用XPS对磨斑表面进行了分析.结果表明,以羟乙基油酸咪唑啉与硼酸摩尔比为3:1合成的硼酸三元酯添加剂以2.0%(质量分数)加入到液体石蜡中具有优良的减摩抗磨效果,但其极压性能不理想;磨斑表面主要形成有机边界润滑膜,没有生成B2O3和BN,在高载荷下油膜脱落或破裂,磨斑表面B的含量很低;添加剂没有和金属表面发生摩擦化学反应,推测添加剂的摩擦学性能可能与其分子极性和分子量有关.","authors":[{"authorName":"王正","id":"4c27683d-9884-41dd-8b89-62a99b471987","originalAuthorName":"王正"},{"authorName":"胡丽天","id":"b6e16fac-6cba-466f-8bfa-2b1acd8d6fc4","originalAuthorName":"胡丽天"}],"doi":"","fpage":"30","id":"ab7a0a43-f11b-480e-8b1b-8cd710732348","issue":"8","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"47770336-f167-4a5f-b68c-d1f3bfb09b97","keyword":"摩擦学性能","originalKeyword":"摩擦学性能"},{"id":"b01a192d-e2e2-41eb-8e87-6bbaaa59097d","keyword":"咪唑啉","originalKeyword":"咪唑啉"},{"id":"5d7349fa-d99b-4c67-a951-af2631b15583","keyword":"硼酸酯","originalKeyword":"硼酸酯"},{"id":"7360dd7e-29bf-47d8-bf82-0bd1d784f7d3","keyword":"润滑","originalKeyword":"润滑"},{"id":"7b6850b0-76f2-447f-804c-f11bb3485642","keyword":"添加剂","originalKeyword":"添加剂"}],"language":"zh","publisherId":"clbh200908009","title":"油酸咪唑啉硼酸酯的摩擦学性能","volume":"42","year":"2009"},{"abstractinfo":"以往,壳聚糖磷酸酯在海水中的缓蚀性能少有研究,为此,在酸性条件下制备了水溶性壳聚糖磷酸酯,采用失重法和电化学测试的方法研究了壳聚糖磷酸酯在海水体系中对Q235碳钢的缓蚀性能.结果表明:壳聚糖磷酸酯在浓度为400 mg/L时缓蚀效率达到最高为73.05%,在较长时间内仍保持较高的缓蚀效率,在常温和高温下都能很好地抑制海水对碳钢的腐蚀,是一种高效的海水缓蚀剂.","authors":[{"authorName":"吴茂涛","id":"9fa0d63b-5ac5-43a3-8726-5a4a200ff253","originalAuthorName":"吴茂涛"},{"authorName":"李再峰","id":"e87f1221-05ef-4655-ad8f-9d65af997db0","originalAuthorName":"李再峰"}],"doi":"","fpage":"21","id":"452969b0-b849-4535-b0b3-a271a0191d44","issue":"11","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"b2e0b815-8154-43c9-b415-d678450fd582","keyword":"海水","originalKeyword":"海水"},{"id":"5bed6698-0ce0-4a03-80d1-479f4bc612ca","keyword":"壳聚糖","originalKeyword":"壳聚糖"},{"id":"2e094867-0054-4996-aa13-46a07a6565e7","keyword":"壳聚糖磷酸酯","originalKeyword":"壳聚糖磷酸酯"},{"id":"999f623f-e1bf-4e71-ba0a-a27cfd4f4669","keyword":"失重法","originalKeyword":"失重法"},{"id":"26d7e4e3-475f-4401-9a29-1e7042787d8d","keyword":"缓蚀性能","originalKeyword":"缓蚀性能"}],"language":"zh","publisherId":"clbh200911007","title":"壳聚糖磷酸酯在海水中的缓蚀性能","volume":"42","year":"2009"},{"abstractinfo":"以多聚磷酸与聚醚多元醇反应制备得到聚醚多元醇磷酸酯,利用聚醚多元醇磷酸酯对环氧基团的反应活性,研究其对环氧树脂-酸酐体系的增韧效果.通过力学性能、热性能以及扫描电镜等研究发现,聚醚多元醇磷酸酯可将与环氧树脂相容性差的聚环氧丙烷链段强制引入到环氧网络中,增强界面性能,具有较好的增韧效果.聚醚在环氧固化网络结构中析出,形成“海岛”结构,SEM测试显示随着磷酸酯化程度的不同,聚醚分相的“海岛”结构的程度和尺寸可以调控;当分散相保持一定的密度和尺寸时,才能达到最佳的增韧效果.同时结果显示,聚醚多元醇磷酸酯的加入基本不影响环氧树脂的力学性能和耐热性能.","authors":[{"authorName":"严慧积","id":"3c7205c8-387b-4003-b28e-623e561fd374","originalAuthorName":"严慧积"},{"authorName":"李文彬","id":"1e79457a-250e-4ca4-badc-a0721730c387","originalAuthorName":"李文彬"},{"authorName":"李欣欣","id":"67d007f3-f132-42cf-af15-52f10d922a18","originalAuthorName":"李欣欣"}],"doi":"10.3969/j.issn.0253-4312.2012.09.002","fpage":"6","id":"36414716-1af3-42e7-b7bd-29ef69955dd7","issue":"9","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"ad396a6a-8d10-49ac-829a-c834ee842244","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"4ad72e88-d3b9-4e6b-a9dd-a8a77fdf5876","keyword":"聚醚多元醇磷酸酯","originalKeyword":"聚醚多元醇磷酸酯"},{"id":"73991de3-bb1c-4d57-a579-80d1cfdb03b2","keyword":"增韧","originalKeyword":"增韧"},{"id":"36ebbde7-5650-4418-80f8-76bf673053cf","keyword":"相分离","originalKeyword":"相分离"},{"id":"c6cfc11b-e479-45e1-a2fe-2baea2159f0c","keyword":"耐冲击性","originalKeyword":"耐冲击性"}],"language":"zh","publisherId":"tlgy201209002","title":"聚醚多元醇磷酸酯增韧改性环氧树脂的研究","volume":"42","year":"2012"},{"abstractinfo":"为了提高淀粉基阻燃剂的稳定性和阻燃效果,以淀粉、多聚磷酸、三聚氰胺等为原料合成了淀粉磷酸酯蜜胺盐.研究结果表明:在120℃下,当PPA用量为淀粉的60%,反应时间为6 h时,可以得到高产率的淀粉磷酸酯,其结合磷最高可达到4.2%.","authors":[{"authorName":"董延茂","id":"1d7e738b-c930-45f1-afc4-c1fa815cbf67","originalAuthorName":"董延茂"},{"authorName":"鲍治宇","id":"fc22dfad-039c-4e99-be87-452f24de40a5","originalAuthorName":"鲍治宇"}],"doi":"10.3969/j.issn.1005-0299.2005.03.010","fpage":"258","id":"9ef5d527-9c6f-4de1-9fbd-3164029f318e","issue":"3","journal":{"abbrevTitle":"CLKXYGY","coverImgSrc":"journal/img/cover/CLKXYGY.jpg","id":"14","issnPpub":"1005-0299","publisherId":"CLKXYGY","title":"材料科学与工艺"},"keywords":[{"id":"e68471e2-5e05-414a-9540-2b34ff4735fc","keyword":"淀粉","originalKeyword":"淀粉"},{"id":"271af09c-de79-4918-b0a9-e8077663f99e","keyword":"多聚磷酸","originalKeyword":"多聚磷酸"},{"id":"d5a9aa0b-a730-4221-88f0-b6575b1d371e","keyword":"磷酸酯","originalKeyword":"磷酸酯"},{"id":"d4535c54-8236-460d-afdd-57253624ab08","keyword":"三聚氰胺","originalKeyword":"三聚氰胺"},{"id":"7772b629-81db-40c1-9dee-79503a8b8bb2","keyword":"膨胀型阻燃剂","originalKeyword":"膨胀型阻燃剂"}],"language":"zh","publisherId":"clkxygy200503010","title":"淀粉磷酸酯蜜胺盐膨胀型阻燃剂的合成","volume":"13","year":"2005"}],"totalpage":1289,"totalrecord":12885}