{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以甲基丙烯酸甲酯-甲基丙烯酸缩水甘油酯-丙烯酸乙酯三元共聚物(MGE)为增容剂对聚对苯二甲酸丁二醇酯/丙烯腈-丁二烯-苯乙烯共聚物(PBT/ABS)共混体系进行增容.采用扫描电镜(SEM)和旋转流变仪等表征方法,研究了增容剂对PBT/ABS(70/30)共混体系的相形态及动态流变性能的影响.SEM分析结果表明,随着MGE用量的增加,共混体系中分散相的粒径逐渐减小,且分散更均匀.这可能是由于MGE的加入可原位生成PBT-g-MGE共聚物,使共混体系相容性得到显著改善.旋转流变实验结果表明,随着MGE用量的增加,体系黏度不断增加,低频模量随频率的变化趋势逐渐减小,并出现了“第二平台”,这同样说明了体系中两相的界面处生成了对体系具有明显增容作用的第三相(PBT-g-MGE共聚物).","authors":[{"authorName":"刘晶晶","id":"1d6cfc46-73e2-4b9a-b5a4-80a243246add","originalAuthorName":"刘晶晶"},{"authorName":"许兢","id":"c4a39c19-60c4-4bb1-a56a-efc81e1c648e","originalAuthorName":"许兢"},{"authorName":"夏新曙","id":"5d5fb046-b9ab-48ba-b317-f9b41ec7caa8","originalAuthorName":"夏新曙"},{"authorName":"刘欣萍","id":"39d35b68-77c3-48ee-aa46-4c77da8ddf2b","originalAuthorName":"刘欣萍"},{"authorName":"肖荔人","id":"b484a66c-cc05-44d5-94f7-86dce24b6d55","originalAuthorName":"肖荔人"},{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"27e7d73c-82c4-49a7-a534-3e2ea012e0ba","originalAuthorName":"黄宝铨"},{"authorName":"钱庆荣","id":"69b693ab-63e0-4a81-aefb-1d2df46b9a62","originalAuthorName":"钱庆荣"},{"authorName":"陈庆华","id":"31cb9418-a7cc-44c0-b355-d31e094f7d72","originalAuthorName":"陈庆华"}],"doi":"","fpage":"111","id":"1cff4214-cccd-4479-a9c1-bea0d4cf75f3","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"b7340345-09ff-4bea-9106-4597cb1160d2","keyword":"聚对苯二甲酸丁二醇酯","originalKeyword":"聚对苯二甲酸丁二醇酯"},{"id":"32da47c8-baf9-43f3-8831-1cbe4a837904","keyword":"增容","originalKeyword":"增容"},{"id":"91f21205-1e30-4086-ba70-bbc718f9b239","keyword":"形貌","originalKeyword":"形貌"},{"id":"db813cf2-b1ca-4780-8038-cfd0a78cf953","keyword":"动态粘弹特性","originalKeyword":"动态粘弹特性"}],"language":"zh","publisherId":"gfzclkxygc201302028","title":"PBT/ABS反应增容体系的相形态及动态流变行为","volume":"29","year":"2013"},{"abstractinfo":"通过熔融共混法制备CaO含量不同的PE/CaO复合材料,借助熔体流动速率仪和AR2000旋转流变仪,对PE/CaO复合材料熔体的流变行为进行研究.结果表明:PE/CaO复合材料的黏流活化能随CaO含量的增加先上升后逐渐下降;当CaO含量(质量分数,下同)≤20%时,复合材料的线性黏弹性与纯PE相近,零剪切黏度变大的幅度较小;当CaO含量≥25%时,复合材料的时间稳定性下降,零剪切黏度明显增大.","authors":[{"authorName":"游瑞云","id":"2d65ef1a-8c99-4a50-8c19-17eb64105c57","originalAuthorName":"游瑞云"},{"authorName":"肖荔人","id":"ba0189b5-e30a-44f1-9cff-725ec25fb75c","originalAuthorName":"肖荔人"},{"authorName":"刘欣萍","id":"04b6665b-34eb-4f0d-b2f2-bb0c6af45f9f","originalAuthorName":"刘欣萍"},{"authorName":"林葱里","id":"0e5d2b06-ea0e-4ca5-a3fa-41277ee8e3de","originalAuthorName":"林葱里"},{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"d386349e-ef78-4a9e-a34f-e68c58ba44c6","originalAuthorName":"黄宝铨"},{"authorName":"许兢","id":"fddba511-f704-4647-a12b-969408538276","originalAuthorName":"许兢"},{"authorName":"陈宇","id":"80951f44-c253-472e-8200-81ff2470374b","originalAuthorName":"陈宇"},{"authorName":"陈庆华","id":"c8f30e5f-04fe-4faa-87ae-bace62e6defa","originalAuthorName":"陈庆华"}],"doi":"10.3969/j.issn.1001-4381.2010.06.002","fpage":"7","id":"26cc9670-8daa-4cf4-84cc-39597d680a34","issue":"6","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"ba846cdf-9359-4273-b078-683ea3622ba8","keyword":"聚乙烯","originalKeyword":"聚乙烯"},{"id":"3a04c2d1-948b-491d-b3f2-94f4972e3ee9","keyword":"氧化钙","originalKeyword":"氧化钙"},{"id":"95ca4b4d-b499-43ea-bd63-bd980bea1d2f","keyword":"复合材料","originalKeyword":"复合材料"},{"id":"c44fdd9a-d430-4f26-b241-2ee7dac60774","keyword":"流变行为","originalKeyword":"流变行为"}],"language":"zh","publisherId":"clgc201006002","title":"PE/CaO复合材料的流变行为","volume":"","year":"2010"},{"abstractinfo":"以ADR4370S为扩链剂,通过双螺杆挤出机熔融制备扩链改性聚对苯二甲酸丁二醇酯(PBT),采用旋转流变仪、电子万能拉伸试验机和摆锤冲击试验机等测试分析手段,研究扩链改性体系的动态流变行为和力学性能.实验结果表明,随着ADR4370S含量的增加,体系的储能模量、损耗模量、复数黏度和松弛时间均提高;Han图说明ADR4370S的加入有利于提高熔体的强度;当ADR4370S含量为1.25％,体系出现了溶胶凝胶转化,并最终呈现\"类凝胶\"行为;Cole-Cole图显示了PBT支化结构的形成,并且vGP图进一步预测PBT扩链支化产物具有梳型的拓扑结构;静态力学性能分析表明ADR4370S有利于提高扩链体系的缺口冲击强度,在PA1.5体系中缺口冲击强度从6.08 kJ/m2提高到10.46 kJ/m2,相对纯PBT提高72.18％,但体系的拉伸强度因结晶度的减小变化不大.","authors":[{"authorName":"王小君","id":"ca6989a5-350d-4e28-9719-8063fbea7514","originalAuthorName":"王小君"},{"authorName":"陈庆华","id":"9b8c29c6-6a42-4e9b-bb6d-4e5e19145a6b","originalAuthorName":"陈庆华"},{"authorName":"梁聪立","id":"59064758-0e91-4f7f-b340-6ae89c1a5d68","originalAuthorName":"梁聪立"},{"authorName":"曹长林","id":"89e8621e-3a43-46cc-878b-e5960706086c","originalAuthorName":"曹长林"},{"authorName":"夏新曙","id":"2589da44-6214-4d20-b249-2869de9f3ff1","originalAuthorName":"夏新曙"},{"authorName":"钱庆荣","id":"d3260a16-d6b2-494b-9693-86c9988152b6","originalAuthorName":"钱庆荣"},{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"6e90dd61-58d7-40b0-971b-1a8e01a13909","originalAuthorName":"黄宝铨"},{"authorName":"肖荔人","id":"13172321-de4e-4313-ab34-857db7a8f99a","originalAuthorName":"肖荔人"}],"doi":"","fpage":"52","id":"4816d9a0-87f0-4378-8f67-c598d41cc6db","issue":"10","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"da4098cc-74f7-42d6-bfb9-f8f88712c60f","keyword":"聚对苯二甲酸丁二醇酯","originalKeyword":"聚对苯二甲酸丁二醇酯"},{"id":"6e3eaaf3-b731-43b3-8180-04e7ff5c5b14","keyword":"扩链剂","originalKeyword":"扩链剂"},{"id":"a2556431-0419-45eb-9e1f-8a1545fa60e3","keyword":"流变性能","originalKeyword":"流变性能"},{"id":"80871b2c-e299-43c9-8a10-bf0c419eb0cf","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"gfzclkxygc201510011","title":"扩链剂ADR4370S对聚对苯二甲酸丁二醇酯的动态流变行为及力学性能的影响","volume":"31","year":"2015"},{"abstractinfo":"用熔融共混法制备了聚碳酸亚丙酯(PPC)/聚丁二酸丁二醇酯(PBS)共混材料,并采用流变学方法对所制备的共混体系的粘弹特性进行了深入研究.结果表明,PPC/PBS为典型的热力学不相容体系,PBS的加入提高了PPC的加工性能;当PBS的质量分数约为40％～50％时,体系发生相反转,这与Paul模型对相反转点预测的结果一致;在相分离区,动态模量偏离了经典的低频末端标度规则,Han图表现出不同于均相体系的特征,引起时温叠加原理失效;与Gramspacher-Meissner模型相比,Palierne模型可以较好地描述PPC/PBS体系的线性粘弹行为.","authors":[{"authorName":"陈君","id":"6b140a37-cf2c-4b58-a500-87f6bef3ebd8","originalAuthorName":"陈君"},{"authorName":"蒋霞","id":"62269196-546e-4d62-b033-e44f97fa81d2","originalAuthorName":"蒋霞"},{"authorName":"陈庆华","id":"0bd39468-d5a0-401c-9e1f-e84b5f0c6a7c","originalAuthorName":"陈庆华"},{"authorName":"钱庆荣","id":"174dad67-561d-4fb2-8074-2535fa22446d","originalAuthorName":"钱庆荣"},{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"e3b8f697-28f0-4c5b-9fdf-134b9390e024","originalAuthorName":"黄宝铨"},{"authorName":"刘欣萍","id":"15481f39-cbe4-45dd-9bbe-e8b5a80c61a7","originalAuthorName":"刘欣萍"},{"authorName":"许兢","id":"7a565580-2f34-4517-ac79-e88c7672fc85","originalAuthorName":"许兢"},{"authorName":"肖荔人","id":"bdd9697f-ec6d-4b0a-903d-45b82ffc6d88","originalAuthorName":"肖荔人"}],"doi":"","fpage":"43","id":"edcbc4e2-cf2b-46f5-bdad-0e26b09f63cf","issue":"12","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"70db055f-b45c-4a62-ae26-a232b54986e8","keyword":"聚碳酸亚丙酯","originalKeyword":"聚碳酸亚丙酯"},{"id":"aa988a42-da7b-4528-80a2-a793167a9f9f","keyword":"聚丁二酸丁二醇酯","originalKeyword":"聚丁二酸丁二醇酯"},{"id":"cbbff026-4883-4f60-bd6d-fb95ca1cf08f","keyword":"相反转","originalKeyword":"相反转"},{"id":"bf0a3237-c60f-4be9-b3b4-d8b7479368b2","keyword":"粘弹特性","originalKeyword":"粘弹特性"}],"language":"zh","publisherId":"gfzclkxygc201312011","title":"PPC/PBS共混体系的粘弹特性","volume":"29","year":"2013"},{"abstractinfo":"以回收聚四氟乙烯(r-PTFE)为成核剂,对聚对苯二甲酸丁二醇酯(BPT)进行成核结晶改性,采用差示扫描量热仪(DSC)研究了PBT/r-PTFE复合材料的非等温结晶行为,考察了不同降温速率对PBT/r-PTFE共混物结晶行为的影响,并对其DSC扫描数据采用Jeziorny法和Liu-Mo法进行处理,采用Kissiinger法计算体系结晶活化能.结果表明:r-PT-FE对PBT具有异相成核作用,可明显提高PBT的结晶度及其结晶速率,且加入r-PTFE并不会改变PBT的成核和增长方式.由Kissinger法计算得出的结晶活化能结果表明,加入r-PTFE树脂能够明显降低PBT的结晶活化能,进一步验证r-PTFE对PBT具有成核促进作用.","authors":[{"authorName":"林婷惠","id":"308b58f4-2599-4253-834b-312fd0d2b877","originalAuthorName":"林婷惠"},{"authorName":"曹长林","id":"54710a15-9e5f-429f-85ec-b3b3da865031","originalAuthorName":"曹长林"},{"authorName":"陈庆华","id":"3befd6ed-0ab8-41a9-9437-f4c692973af4","originalAuthorName":"陈庆华"},{"authorName":"钱庆荣","id":"2c131726-4f93-4135-9dc6-d4ab3ee1f2b2","originalAuthorName":"钱庆荣"},{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"66102810-38ce-4c59-a13f-e1864fcf3d33","originalAuthorName":"黄宝铨"},{"authorName":"夏新曙","id":"9fa11e08-6ef6-4594-a014-6d2065944cd6","originalAuthorName":"夏新曙"},{"authorName":"林新土","id":"c5ae8aa9-688e-4005-9a07-f0108d8ca2f9","originalAuthorName":"林新土"},{"authorName":"肖荔人","id":"3209585a-86b5-403f-ae65-e3dddb3ac1a0","originalAuthorName":"肖荔人"}],"doi":"10.11868/j.issn.1001-4381.2016.03.015","fpage":"92","id":"70a2826f-ed8f-4581-b85b-35d39e545cf5","issue":"3","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"bc4242e3-3584-4f1a-a340-442c87901dd1","keyword":"聚对苯二甲酸丁二醇酯","originalKeyword":"聚对苯二甲酸丁二醇酯"},{"id":"e763289c-bdd7-4d76-b07c-78c29df33674","keyword":"回收聚四氟乙烯","originalKeyword":"回收聚四氟乙烯"},{"id":"7c573d22-af24-4fbc-b779-af44033d569a","keyword":"非等温结晶动力学","originalKeyword":"非等温结晶动力学"},{"id":"3fd97067-d1f8-403b-899c-0c8c513dd10f","keyword":"活化能","originalKeyword":"活化能"}],"language":"zh","publisherId":"clgc201603015","title":"r-PTFE对PBT非等温结晶动力学的影响","volume":"44","year":"2016"},{"abstractinfo":"采用有机铝型螯合物凝胶剂、松香改性酚醛树脂、亚麻仁油和高沸点煤油制备胶印油墨用连结料,研究了亚麻仁油、高沸点煤油和凝胶剂的用量对连结料流变性能的影响.根据流变实验测定值,准确地拟合出该连结料体系的一系列黏度模型.根据该黏度模型,能够在改变原料配比、温度与剪切速率的条件下,相当精确地描述连结料体系的黏度.因此,若能利用汇编语言设计出连结料的配方计算软件,则可根据连结料体系中各因素变化来直接调节连结料的流变参数,达到快速调整连结料配方、缩短生产工艺时间、稳定连结料质量、适应高速印刷油墨要求的目的.","authors":[{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"f3b4bec5-817e-46b1-8c6a-10b6eadd4ee5","originalAuthorName":"黄宝铨"},{"authorName":"张胜军","id":"8c36e6c6-b6b2-49f4-9a1d-d4df15125270","originalAuthorName":"张胜军"},{"authorName":"陈庆华","id":"6e64f5e2-aedb-49b8-ab3a-1bb2a494848b","originalAuthorName":"陈庆华"},{"authorName":"钱庆荣","id":"7caaed96-e6cc-4fb4-a9f9-0f69f72dd4fb","originalAuthorName":"钱庆荣"},{"authorName":"肖荔人","id":"86d8d9ea-33c8-4438-b746-e419ee530069","originalAuthorName":"肖荔人"},{"authorName":"刘欣萍","id":"f6e9e874-8cbc-4695-922f-8316fadf538f","originalAuthorName":"刘欣萍"},{"authorName":"许兢","id":"e69f33a0-9a79-4e59-a8ee-d8f05ca3b3f3","originalAuthorName":"许兢"}],"doi":"","fpage":"60","id":"bfde8375-92c5-46b5-8fb7-6495fe5fce0d","issue":"5","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰   "},"keywords":[{"id":"a04efe6e-211f-4310-a946-f774aac261ba","keyword":"连结料","originalKeyword":"连结料"},{"id":"7be6d006-f308-4597-9def-75e9a4adf6e3","keyword":"流变性能","originalKeyword":"流变性能"},{"id":"0a61c08f-0c15-4afb-86c6-197674862cf6","keyword":"黏度模型","originalKeyword":"黏度模型"},{"id":"880a4f24-39df-401e-a104-f230ed951b27","keyword":"拟合","originalKeyword":"拟合"}],"language":"zh","publisherId":"ddyts201205016","title":"凝胶型连结料体系黏度模型的参数拟合","volume":"31","year":"2012"},{"abstractinfo":"用熔融插层法制备聚对苯二甲酸丙二醇酯(PTT)/丙烯腈-苯乙烯-丙烯酸酯三元共聚物(ASA)/有机蒙脱土(OMMT)复合材料,研究了OMMT对PTT/ASA体系相形态、结晶性能、流变性能和力学性能的影响.结果表明,OMMT主要以剥离态分布在PTT基体相和界面处,使ASA分散相的尺寸变小,体系的弹性模量和复数黏度得到提高;同时,OMMT是异相成核剂,使体系结晶峰向高温偏移;依据Palieme和Gramspacher-Meissner模型评估,发现OMMT可增大聚合物的界面模量和界面层厚度,在适量范围内使体系的拉伸强度和缺口冲击强度有所提高.","authors":[{"authorName":"陈君","id":"68de43f5-6546-493d-98e8-9a5db60398dc","originalAuthorName":"陈君"},{"authorName":"陈庆华","id":"7dbdcb80-9a71-4724-9244-39941ea770ae","originalAuthorName":"陈庆华"},{"authorName":"钱庆荣","id":"6d1fed06-2e1a-43dc-bd7a-063893f4f180","originalAuthorName":"钱庆荣"},{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"211217a8-87ec-49b3-8656-7f217046b1f3","originalAuthorName":"黄宝铨"},{"authorName":"刘欣萍","id":"b4f5ae69-2396-4530-880a-0a410cfc7502","originalAuthorName":"刘欣萍"},{"authorName":"许兢","id":"c325f260-5e2e-49b2-a6f1-78cf9603eca2","originalAuthorName":"许兢"},{"authorName":"肖荔人","id":"9b3336a2-1bca-4135-ae8c-19a288338e24","originalAuthorName":"肖荔人"}],"doi":"","fpage":"107","id":"ff98afa8-a4f4-4005-ac90-a65ea708cb62","issue":"2","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[{"id":"0ec0b303-21ec-4ffd-94f7-fc0ffc2ff43f","keyword":"有机高分子材料","originalKeyword":"有机高分子材料"},{"id":"683a481e-4140-4229-9b0a-a6085c53a585","keyword":"PTT/ASA体系","originalKeyword":"PTT/ASA体系"},{"id":"9199686b-e2b4-46cd-b815-991f35d87ae1","keyword":"OMMT","originalKeyword":"OMMT"},{"id":"b4c1ddd8-36f5-4e0d-b706-7a5c86768299","keyword":"相形态","originalKeyword":"相形态"},{"id":"143781e0-bb45-43c9-8316-3750400908c8","keyword":"流变性能","originalKeyword":"流变性能"},{"id":"673e14da-2651-4326-9086-7ef23a8a9575","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"clyjxb201402005","title":"OMMT对PTT/ASA体系相形态和性能的影响","volume":"28","year":"2014"},{"abstractinfo":"首先用苄氧羰基赖氨酸和三光气反应合成苄氧羰基赖氨酸酸酐,然后将聚乙二醇中活性较弱的羟基转化为氨基,最后以双端氨基聚乙二醇作为引发剂,采用阴离子开环聚合合成了聚(Nε-苄氧羰基赖氨酸)一聚乙二醇一聚(Nε-苄氧羰基赖氨酸)(PLL(Z)-PEG-PLL(Z)).PLL(Z)-PEGPLL(Z)经去保护后得到带正电荷的聚赖氨酸.聚乙二醇-聚赖氨酸(PLL-PEG-PLL).PLL(Z)-PEG-PLL(Z)在水溶液中自组装形成的聚集体类似于纳米多孔聚集体结构,具有疏松的空洞,原子力显微镜观测其呈球形,其大小为220 nm左右.","authors":[{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"4b35eaf1-4d1d-4562-bfed-beef5f6fb8bf","originalAuthorName":"黄宝铨"}],"doi":"","fpage":"1","id":"0c3ed7ec-7413-45b6-b333-8143bb58c2f9","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"4728dff5-1914-4a5e-a5eb-cbd24c401807","keyword":"两亲嵌段共聚物","originalKeyword":"两亲嵌段共聚物"},{"id":"a1a1905d-6c11-41ad-99a7-1ba1779dfa7f","keyword":"聚合物纳米粒子","originalKeyword":"聚合物纳米粒子"},{"id":"13603d45-0e06-443c-8fde-c2b03c52c6be","keyword":"自组装","originalKeyword":"自组装"}],"language":"zh","publisherId":"gfzclkxygc200901001","title":"两亲嵌段共聚物的合成及纳米自组装","volume":"25","year":"2009"},{"abstractinfo":"分别选用十二烷基苯酚、壬基苯酚、对特辛基苯酚和对叔丁基苯酚四种烷基酚单体为原料,合成了四种不同的松香改性酚醛树脂。通过黏度、溶解性等常规性能分析以及红外光谱（FT-IR）、凝胶渗透色谱（GPC）和流变等表征方法,探讨了不同烷基苯酚对松香改性酚醛树脂结构与性能的影响。结果表明,在相同工艺条件下,不同烷基酚单体对树脂的主体结构及热稳定性影响不大,但对树脂的其它性能影响较大;随着烷基酚碳链长度的增加,树脂在亚麻油中的溶解稳定性提高,但体系的黏度降低;黏度随剪切速率与温度变化的敏感性减弱。可见,选用合适的烷基苯酚能提高树脂的综合性能。","authors":[{"authorName":"肖荔人","id":"2515e3b9-f997-49ac-b47c-1ba127fae8e4","originalAuthorName":"肖荔人"},{"authorName":"张胜军","id":"a2c2572a-95dd-4c4c-ac19-ec1a9ee5a56d","originalAuthorName":"张胜军"},{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"66b919fc-df2c-4ea7-ad8b-fa26d13da18a","originalAuthorName":"黄宝铨"},{"authorName":"陈庆华","id":"d8402c60-ff6d-4823-aa90-9f06d95d3fd1","originalAuthorName":"陈庆华"},{"authorName":"钱庆荣","id":"3581e551-d6ce-4bc4-909b-3ea761e5aaa0","originalAuthorName":"钱庆荣"}],"doi":"","fpage":"76","id":"62c77969-c657-433d-b3bd-ff15c8277cc8","issue":"10","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"483fdb35-a2ad-4e8b-8c2f-b0c5ab2413c0","keyword":"烷基酚","originalKeyword":"烷基酚"},{"id":"2df91896-f6e4-41ca-b947-6d65bce82ff7","keyword":"松香改性酚醛树脂","originalKeyword":"松香改性酚醛树脂"},{"id":"ed8de943-1a38-4011-8d61-f404c4440f83","keyword":"合成","originalKeyword":"合成"},{"id":"be6dbfd6-d756-4011-852b-c6158c7cfcf4","keyword":"表征","originalKeyword":"表征"}],"language":"zh","publisherId":"gfzclkxygc201210019","title":"不同烷基苯酚对松香改性酚醛树脂性能的影响","volume":"28","year":"2012"},{"abstractinfo":"以二氯硅（IV）酞菁（SiPcCl2）为原料,与2-异丙基-6-甲基-4-嘧啶醇（PyO）反应合成轴向取代二-（2-异丙基-6-甲基-4-嘧啶氧基）硅（IV）酞菁配合物SiPc（PyO）2,并采用元素分析、红外光谱（IR）、核磁共振（1H-NMR）和质谱（MS）对其结构进行了表征。以两亲性嵌段共聚物聚赖氨酸-聚乙二醇-聚赖氨酸（PLL-PEG-PLL）为载体,透析法制备负载SiPc（PyO）2的聚合物纳米粒子SiPc（PyO）2/m。SiPc（PyO）2/m呈球形,直径约35 nm。SiPc（PyO）2包裹入聚合物胶束后,SiPc（PyO）2/m的Q带最大吸收峰强度降低,位置蓝移,荧光强度增加,荧光寿命增长。不同孵育时间HUVEC细胞的SiPc（PyO）2和SiPc（PyO）2/m的药代动力学表明,与自由酞菁3相比,SiPc（PyO）2/m摄取率增加,而且提前1 h达到最大浓度。","authors":[{"authorName":"<span style=\"color:red\">黄</span><span style=\"color:red\">宝</span><span style=\"color:red\">铨</span>","id":"33e3e1a2-bb2b-4b60-94e4-abe46374dd48","originalAuthorName":"黄宝铨"},{"authorName":"陈庆华","id":"98fe0510-b1bf-4975-b17f-90978be4efb2","originalAuthorName":"陈庆华"},{"authorName":"肖荔人","id":"745f5621-64c0-48ed-b9d3-d15f1762a8b6","originalAuthorName":"肖荔人"},{"authorName":"张胜军","id":"4722b60b-3d93-40aa-81de-bfaf763e0414","originalAuthorName":"张胜军"},{"authorName":"<span style=\"color:red\">黄</span>静","id":"3f45ed86-95ae-402f-a33b-56a91dce2f1e","originalAuthorName":"黄静"}],"doi":"","fpage":"12","id":"da4900f2-303f-4242-bb3c-539c05d4366e","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"8ce35064-27a4-471b-bea4-d38c24d0f941","keyword":"酞瞢硅","originalKeyword":"酞瞢硅"},{"id":"96cc20fc-8552-433b-86c6-95f0966829e0","keyword":"两亲性嵌段共聚物","originalKeyword":"两亲性嵌段共聚物"},{"id":"e4322f45-d30e-4cc3-9c93-c92a3c2fe572","keyword":"聚合物纳米粒子","originalKeyword":"聚合物纳米粒子"},{"id":"44582813-1a4f-464d-b9d2-f6c80714241a","keyword":"纳米自组装","originalKeyword":"纳米自组装"}],"language":"zh","publisherId":"gfzclkxygc201206004","title":"负载轴向取代硅（IV）酞菁配合物的聚合物纳米粒子的合成与表征","volume":"28","year":"2012"}],"totalpage":59,"totalrecord":586}