{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用反相高效液相色谱(RP-HPLC)-脉冲电<span style=\"color:red\">化学</span>检测(PED)法测定了重组人生长激素(rhGH)中的诱导剂异丙基-β-D-硫代半乳糖苷(IPTG).rhGH样品经超滤离心后,用超纯水提取,经C18色谱柱分离,用脉冲电<span style=\"color:red\">化学</span>器检测.结果表明,样品中添加0.02~0.10 mg/L 的IPTG,其回收率为100%~102%,相对标准偏差(n=3)小于10%.在优化的条件下,IPTG的检出限可达1 μg/L(0.1 pmol, 25 μL).该方法简便高效,具有良好的灵敏度、回收率和重复性.","authors":[{"authorName":"王荔","id":"e05d722f-2430-4757-8547-e4e7dea46acb","originalAuthorName":"王荔"},{"authorName":"林碧蓉","id":"01c2e41e-fd3b-435d-80bc-474039be04b9","originalAuthorName":"林碧蓉"}],"doi":"10.3724/SP.J.1123.2016.10037","fpage":"308","id":"a229ade4-f717-42fb-b014-cc77470dad89","issue":"3","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"0fd7e79c-458a-4e17-9332-8e2e80e4d5e2","keyword":"反相高效液相色谱法","originalKeyword":"反相高效液相色谱法"},{"id":"0745b5e3-aa4d-4131-b76a-c6cf867f0838","keyword":"脉冲电<span style=\"color:red\">化学</span>检测","originalKeyword":"脉冲电化学检测"},{"id":"d0efb953-bf49-40fd-b510-928c5438c8cd","keyword":"巯基","originalKeyword":"巯基"},{"id":"18a3e7a3-e084-4c4e-80da-8170534fc4ac","keyword":"<span style=\"color:red\">含</span><span style=\"color:red\">硫化学</span><span style=\"color:red\">物</span>","originalKeyword":"含硫化学物"},{"id":"8ee36d97-47e9-4820-8d84-d142179d0887","keyword":"异丙基-β-D-硫代半乳糖苷","originalKeyword":"异丙基-β-D-硫代半乳糖苷"},{"id":"296d6612-3e6b-4b27-b1d0-f77e63c40c72","keyword":"重组人生长激素","originalKeyword":"重组人生长激素"}],"language":"zh","publisherId":"sp201703016","title":"反相高效液相色谱-脉冲电<span style=\"color:red\">化学</span>检测法测定重组人生长激素中异丙基-β-D-硫代半乳糖苷","volume":"35","year":"2017"},{"abstractinfo":"用电<span style=\"color:red\">化学</span>方法研究了碱性溶液中<span style=\"color:red\">硫化物</span>在Pt电极上的氧化过程。结果表明，硫离子在-600～+750mV(vs.SCE)存在两个电<span style=\"color:red\">化学</span>氧化过程。经热力学、动力学和<span style=\"color:red\">化学</span>分析证实，在约-400mV时硫离子首先氧化为单质硫及多<span style=\"color:red\">硫化物</span>，沉积在电极表面；约250 mV处，单质硫及多<span style=\"color:red\">硫化物</span>进一步氧化为硫酸根离子而进入溶液。低电位下的氧化反应是可逆反应，硫离子扩散为控制步骤；高电位下，单质硫进一步氧化为硫酸根离子的反应是不可逆反应。而两反应过程密切相关。","authors":[{"authorName":"刘秀玲","id":"7948f269-d02f-4b99-af38-c48789959d74","originalAuthorName":"刘秀玲"},{"authorName":"王佳","id":"ceae5d6c-f349-4c84-98ad-dfdcc7c1439b","originalAuthorName":"王佳"}],"doi":"10.3969/j.issn.1001-1560.2001.03.001","fpage":"1","id":"44c9958d-1b04-4142-b8f1-4ba13e7d6f78","issue":"3","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"7f432994-690d-4e9e-8c26-0d24d07fd235","keyword":"电<span style=\"color:red\">化学</span>氧化","originalKeyword":"电化学氧化"},{"id":"1ebfdaf8-ff11-44a7-babd-eec8f8a8209e","keyword":"<span style=\"color:red\">硫化物</span>","originalKeyword":"硫化物"},{"id":"9eca216a-e7ea-413f-b73c-41423daaae38","keyword":"硫","originalKeyword":"硫"},{"id":"f7b770d1-fded-4240-b5fc-b44dabd7a08d","keyword":"硫酸根离子","originalKeyword":"硫酸根离子"}],"language":"zh","publisherId":"clbh200103001","title":"<span style=\"color:red\">硫化物</span>电<span style=\"color:red\">化学</span>氧化过程研究","volume":"34","year":"2001"},{"abstractinfo":"在实验室对<span style=\"color:red\">含</span>硫非调质钢进行了冶炼和锻压实验,结果表明:随钢凝固速率的增加,钢中<span style=\"color:red\">硫化物</span>夹杂的尺寸减小而数量增多;随锻压压缩比的增加,<span style=\"color:red\">硫化物</span>夹杂碎裂而变得细小;在950℃锻压时<span style=\"color:red\">硫化物</span>的塑性最好,在1 250℃时<span style=\"color:red\">硫化物</span>的塑性较好,在1 050～1 150℃之间<span style=\"color:red\">硫化物</span>的塑性较差;随着加热时保温时间的延长,<span style=\"color:red\">硫化物</span>夹杂的数量减少而尺寸增大.","authors":[{"authorName":"简龙","id":"1a5d9c65-f9a7-4fb3-b00a-cdeee1e258c0","originalAuthorName":"简龙"},{"authorName":"陈伟庆","id":"c3e1ffc1-72a6-4705-917a-1a4229ff2f9c","originalAuthorName":"陈伟庆"},{"authorName":"孟金霞","id":"419f64ab-1e22-4df1-ad5a-6417fb12bf5b","originalAuthorName":"孟金霞"},{"authorName":"惠荣","id":"86924e37-cd66-4259-8001-5d72aaa1fb0f","originalAuthorName":"惠荣"},{"authorName":"李国忠","id":"7cc555d8-3563-4273-9f43-5f9bc7b34f5b","originalAuthorName":"李国忠"}],"doi":"","fpage":"74","id":"22360d67-3723-4806-a3e5-499c3393a513","issue":"10","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"bd353273-009c-4ec9-8039-13b85905305d","keyword":"非调质钢","originalKeyword":"非调质钢"},{"id":"c9370682-dc56-4f09-a13a-41a571fa8882","keyword":"<span style=\"color:red\">硫化物</span>","originalKeyword":"硫化物"},{"id":"f76381dc-a107-4e1f-af22-8e066e518def","keyword":"压缩比","originalKeyword":"压缩比"},{"id":"f12d9919-93db-47a9-a466-37e144df8017","keyword":"轧制温度","originalKeyword":"轧制温度"}],"language":"zh","publisherId":"gt200610018","title":"<span style=\"color:red\">含</span>硫非调质钢中<span style=\"color:red\">硫化物</span>形态的控制","volume":"41","year":"2006"},{"abstractinfo":"在实验室对<span style=\"color:red\">含</span>硫非调质钢进行了冶炼和锻压实验，结果表明：随钢凝固速率的增加，钢中<span style=\"color:red\">硫化物</span>夹杂的尺寸减小而数量增多；随锻压压缩比的增加，<span style=\"color:red\">硫化物</span>夹杂碎裂而变得细小；在950 ℃锻压时<span style=\"color:red\">硫化物</span>的塑性最好，在1250 ℃时<span style=\"color:red\">硫化物</span>的塑性较好，在1050~1150 ℃之间<span style=\"color:red\">硫化物</span>的塑性较差；随着加热时保温时间的延长，<span style=\"color:red\">硫化物</span>夹杂的数量减少而尺寸增大。","authors":[{"authorName":"简龙","id":"871ca1f0-0885-489e-a660-0d5ae5cb3ca4","originalAuthorName":"简龙"},{"authorName":"陈伟庆","id":"7290ca3b-d7d6-45b0-85ff-283a19b9afe5","originalAuthorName":"陈伟庆"},{"authorName":"孟金霞","id":"4393667f-1ff1-404b-a98c-b714ed26bf20","originalAuthorName":"孟金霞"},{"authorName":"惠荣","id":"654c6950-fa12-4db0-8e70-c718c728e3f7","originalAuthorName":"惠荣"},{"authorName":"李国忠","id":"48aeb11b-3323-4717-b540-7d99bd23b11e","originalAuthorName":"李国忠"}],"categoryName":"|","doi":"","fpage":"74","id":"6076add3-85ef-4389-b454-4124c34fced3","issue":"10","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"de943d6b-19ff-4fdd-b43d-9c1160112d71","keyword":"非调质钢;<span style=\"color:red\">硫化物</span>;压缩比;轧制温度","originalKeyword":"非调质钢;硫化物;压缩比;轧制温度"}],"language":"zh","publisherId":"0449-749X_2006_10_2","title":"<span style=\"color:red\">含</span>硫非调质钢中<span style=\"color:red\">硫化物</span>形态的控制","volume":"41","year":"2006"},{"abstractinfo":"根据<span style=\"color:red\">含</span><span style=\"color:red\">硫化物</span>的难选金矿石或金精矿细菌氧化的主要反应和副反应,按照<span style=\"color:red\">化学</span>热力学的基本原理,设计了<span style=\"color:red\">含</span><span style=\"color:red\">硫化物</span>的难选金矿石或金精矿细菌氧化反应热效应--(ΔH 318) 总的计算方法.","authors":[{"authorName":"郭继光","id":"69cf293c-0c8e-4e1a-ac20-29198a174de6","originalAuthorName":"郭继光"},{"authorName":"权新军","id":"af2e4d61-94cb-47b4-9f16-914f3520f1d9","originalAuthorName":"权新军"},{"authorName":"满文慧","id":"62025407-245f-47d9-9eea-90817e6e2f1f","originalAuthorName":"满文慧"}],"doi":"10.3969/j.issn.1001-1277.2005.10.011","fpage":"35","id":"e7051e94-b28d-4924-9bbd-d272008eb63c","issue":"10","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"aa95fb7c-9ffc-4fbf-9d01-d47301e12c23","keyword":"难选金矿石","originalKeyword":"难选金矿石"},{"id":"befc2f4f-13d7-4067-82e2-a662fecbbb24","keyword":"金精矿","originalKeyword":"金精矿"},{"id":"13186c7b-b5de-4206-8183-5928e5808b12","keyword":"细菌氧化","originalKeyword":"细菌氧化"},{"id":"c2b3efda-ca97-4bef-8658-e85f86aab485","keyword":"热效应","originalKeyword":"热效应"},{"id":"9aad1e2a-2fb3-422a-aa34-e5b20dfbb205","keyword":"计算","originalKeyword":"计算"}],"language":"zh","publisherId":"huangj200510011","title":"<span style=\"color:red\">含</span><span style=\"color:red\">硫化物</span>的难选金矿石或金精矿细菌氧化反应热效应的计算","volume":"26","year":"2005"},{"abstractinfo":"通过实验室小炉试验研究钙处理对中硫非调质钢中<span style=\"color:red\">硫化物</span>形态的影响.结果表明,钙处理后铸坯中<span style=\"color:red\">硫化物</span>由纯<span style=\"color:red\">硫化</span>锰转化为含钙铝的复合<span style=\"color:red\">硫化物</span>,长宽比在1~2区间内的<span style=\"color:red\">硫化物</span>比例明显提高;在轧制后,经过钙处理的试样中<span style=\"color:red\">硫化物</span>的长宽比也更多地集中在1~3区间内,这说明钙处理有效改善了钢中<span style=\"color:red\">硫化物</span>的形态特征,使得更多的<span style=\"color:red\">硫化物</span>呈纺锤状,提高了钢材性能.","authors":[{"authorName":"姚登元","id":"bd3c424a-d06e-419a-b2c3-2f9506c65695","originalAuthorName":"姚登元"},{"authorName":"吴华杰","id":"e233de6e-faf6-4b14-a618-70cc629629f9","originalAuthorName":"吴华杰"},{"authorName":"陆鹏雁","id":"f1a87793-b2b1-4428-a6f0-fa2ee945f8dd","originalAuthorName":"陆鹏雁"},{"authorName":"岳峰","id":"f0fc0589-941b-4570-b222-c5ac189f0ef4","originalAuthorName":"岳峰"},{"authorName":"张永超","id":"dc0dcb5a-0b90-437c-ac94-db285a62410f","originalAuthorName":"张永超"}],"doi":"10.13228/j.boyuan.issn1006-9356.20160217","fpage":"11","id":"44868e8a-a13b-4a1e-8c83-89bfeea7ad81","issue":"4","journal":{"abbrevTitle":"ZGYJ","coverImgSrc":"journal/img/cover/ZGYJ.jpg","id":"87","issnPpub":"1006-9356","publisherId":"ZGYJ","title":"中国冶金"},"keywords":[{"id":"fed5689a-e342-4d98-804f-6bd5e0924707","keyword":"<span style=\"color:red\">含</span>硫非调质钢","originalKeyword":"含硫非调质钢"},{"id":"e16f6224-0cd3-48e8-b138-2c089a3f027e","keyword":"<span style=\"color:red\">硫化物</span>","originalKeyword":"硫化物"},{"id":"1e4eaede-1d7c-4af1-a982-5de71c2085cd","keyword":"钙处理","originalKeyword":"钙处理"},{"id":"654d06fa-6f7f-4669-8a36-16edc2e3fc3a","keyword":"长度分布","originalKeyword":"长度分布"},{"id":"1b359ab1-8cf9-4bb6-abe7-07be535cec14","keyword":"长宽比分布","originalKeyword":"长宽比分布"}],"language":"zh","publisherId":"zgyj201704003","title":"钙处理对<span style=\"color:red\">含</span>硫非调质钢中<span style=\"color:red\">硫化物</span>形态的影响","volume":"27","year":"2017"},{"abstractinfo":"金凤金矿矿石的工艺类型为贫<span style=\"color:red\">硫化物</span><span style=\"color:red\">含</span>砷碳微细粒浸染型金矿石.通过对该矿石进行系统的浮选试验研究,确定浮选的最佳工艺条件,为企业取得良好的选矿技术指标提供了有力的技术支持,也为该地区同类型矿石资源的开发利用提供了技术资料.","authors":[{"authorName":"薛忱","id":"d4e36f9d-7ffb-431c-abed-c023f74714a4","originalAuthorName":"薛忱"},{"authorName":"梁泽来","id":"232a1ab0-bbaf-42be-af8b-10c0861a92b0","originalAuthorName":"梁泽来"}],"doi":"10.3969/j.issn.1001-1277.2011.12.011","fpage":"42","id":"9026d929-03ce-44b5-b7fc-2417fa72d81c","issue":"12","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"6501c951-ef53-44c8-8527-ff3988a240ee","keyword":"浸染型金矿石","originalKeyword":"浸染型金矿石"},{"id":"31d2dbb8-cf69-4f2d-9b9e-4ab2a10e6139","keyword":"浮选","originalKeyword":"浮选"},{"id":"4bf15b7b-aa2b-4c53-b239-686c3f8749ad","keyword":"精矿品位","originalKeyword":"精矿品位"},{"id":"62a43647-db35-4bd0-8953-84be8187d2e7","keyword":"回收率","originalKeyword":"回收率"}],"language":"zh","publisherId":"huangj201112011","title":"贫<span style=\"color:red\">硫化物</span><span style=\"color:red\">含</span>砷碳微细浸染型金矿石浮选试验研究","volume":"32","year":"2011"},{"abstractinfo":"采用气相色谱法,分别利用火焰光度检测器(FPD)和原子发射检测器(AED)对中国石化北京燕山石油化工公司(简称燕化)炼油厂和石家庄炼油厂生产的重油催化裂化(RFCC)汽油中的<span style=\"color:red\">硫化物</span>进行了分析.燕化炼油厂RFCC汽油中总硫只有29.5 mg/L,采用FPD无法检测;石家庄炼油厂的RFCC汽油中总硫为720.1 mg/L.用标样和气相色谱-质谱法(GC-MS)定性,FPD分离检测出19种<span style=\"color:red\">硫化物</span>,主要是硫醇、噻吩类<span style=\"color:red\">硫化物</span>,硫醚类<span style=\"color:red\">硫化物</span>和二<span style=\"color:red\">硫化物</span>均未检出.用AED鉴定出燕化炼油厂RFCC汽油中的<span style=\"color:red\">硫化物</span>12种,主要是噻吩和四氢噻吩类、低碳硫醇和二<span style=\"color:red\">硫化物</span>;石家庄炼油厂的RFCC汽油中的<span style=\"color:red\">硫化物</span>26种,也主要以噻吩类为主,另有少量的低碳硫醇、硫醚和二<span style=\"color:red\">硫化物</span>.结果表明,用AED检测RFCC汽油中的<span style=\"color:red\">硫化物</span>,其灵敏度和选择性都高于目前使用最普遍的FPD.","authors":[{"authorName":"梁咏梅","id":"12507858-cc45-405c-9737-85a797f790dc","originalAuthorName":"梁咏梅"},{"authorName":"刘文惠","id":"d5902941-8a40-436e-83fb-1a4eedab7a80","originalAuthorName":"刘文惠"},{"authorName":"刘耀芳","id":"9e4c4380-eae9-4247-acbb-fd8140c1212b","originalAuthorName":"刘耀芳"}],"doi":"10.3321/j.issn:1000-8713.2002.03.026","fpage":"283","id":"c3b47a33-758f-4826-909f-548b2f7e47a0","issue":"3","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"d89833e9-d078-4ed5-aee3-de8caab45561","keyword":"重油催化裂化","originalKeyword":"重油催化裂化"},{"id":"b8d31df0-5edd-4cc3-9cf2-8d1fe669a919","keyword":"汽油","originalKeyword":"汽油"},{"id":"48d56bbe-f9a5-4de6-a62f-2394f4db6a69","keyword":"<span style=\"color:red\">硫化物</span>","originalKeyword":"硫化物"},{"id":"269e9bfc-a87f-4623-a371-2c85b380f1d5","keyword":"火焰光度检测","originalKeyword":"火焰光度检测"},{"id":"6d6b7ec2-09cd-4e15-8551-74f601957b54","keyword":"原子发射检测","originalKeyword":"原子发射检测"}],"language":"zh","publisherId":"sp200203026","title":"重油催化裂化汽油中<span style=\"color:red\">含</span><span style=\"color:red\">硫化合物</span>的分析","volume":"20","year":"2002"},{"abstractinfo":"针对目前无氰镀银层外观差、附着力不良、镀液稳定性差等问题,采用横向划痕法、直角阴极法、赫尔楷8点法、阴极极化曲线及称重法对无氰电镀银的基础液和<span style=\"color:red\">含</span>添加剂SGD-DY1(芳香醛、<span style=\"color:red\">含</span><span style=\"color:red\">硫化合物</span>和表面活性剂)的镀液进行了测试;用扫描电镜和XRD对镀层表面形貌和晶体结构进行了表征,用盐雾试验、耐3.0mg/L H2S和0.1mol/L K2SO4试验测试了镀层耐蚀性能和抗<span style=\"color:red\">硫化</span>变色性能.结果表明:由于SGD-DY1的加入,横向划痕完全消失,整平能力提高;深镀能力由原来的96%提高到100%,均镀能力由60%提高到80%;阴极极化曲线明显负移,阴极极化能力提高,阴极电流效率由96%下降到92%,镀层的沉积速度由12um/h下降到10um/h;镀层由(111)和(110)晶面择优取向向(111)晶面转变且镀层平整、晶粒细致;镀层的耐蚀性和杭变色性明显提高.","authors":[{"authorName":"单颖会","id":"69dd52a7-b364-4c7b-8f38-7e21d8eb31d0","originalAuthorName":"单颖会"},{"authorName":"于锦","id":"e5246b8e-968f-40e2-a8bd-e084cd755ea1","originalAuthorName":"于锦"},{"authorName":"谭宏宇","id":"94ecea64-0b7e-49b2-9d03-2c3bef691132","originalAuthorName":"谭宏宇"},{"authorName":"王丽丽","id":"1dd0cc95-a9b0-455a-911f-3db14cc99a0c","originalAuthorName":"王丽丽"}],"doi":"","fpage":"36","id":"709270ad-2dee-498a-872b-d68f3f44f461","issue":"3","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"5fa76db5-fef5-4feb-8643-f263b6c29d6f","keyword":"无氰电镀银","originalKeyword":"无氰电镀银"},{"id":"37246208-1beb-49c9-82fe-76608a3f60e4","keyword":"添加剂","originalKeyword":"添加剂"},{"id":"2358bdbf-a991-4a98-be63-bbb23f38f370","keyword":"抗变色性","originalKeyword":"抗变色性"},{"id":"db40e7b0-8364-4c5a-ae28-8934d6179309","keyword":"耐蚀性","originalKeyword":"耐蚀性"}],"language":"zh","publisherId":"clbh201103011","title":"<span style=\"color:red\">含</span>芳香醛和<span style=\"color:red\">含</span><span style=\"color:red\">硫化合物</span>的添加剂对无氰电镀银的影响","volume":"44","year":"2011"},{"abstractinfo":"介绍了无机类富勒烯(Inorganic fullerene-like,简称IF)与过渡金属<span style=\"color:red\">硫化物</span>(WS2和MoS2)纳米材料的常用合成技术--固-气与气相反应合成方法; 以及用<span style=\"color:red\">化学</span>复合镀法制备含有IF-WS2纳米颗粒的Ni-P复合镀层的方法.","authors":[{"authorName":"马晓春","id":"1f97d76c-366b-43d7-a36a-33d907998a5b","originalAuthorName":"马晓春"}],"doi":"10.3969/j.issn.1001-3660.2005.06.004","fpage":"11","id":"1b2918f8-64ac-4f60-9618-76c6c91d400c","issue":"6","journal":{"abbrevTitle":"BMJS","coverImgSrc":"journal/img/cover/BMJS.jpg","id":"3","issnPpub":"1001-3660","publisherId":"BMJS","title":"表面技术   "},"keywords":[{"id":"dccddc9d-435d-426f-8223-6a0521678663","keyword":"无机类富勒烯","originalKeyword":"无机类富勒烯"},{"id":"fbaeb079-8ddd-4d90-b8e3-371622c76c33","keyword":"纳米颗粒","originalKeyword":"纳米颗粒"},{"id":"f8989387-d152-4794-bf08-cff5634ed347","keyword":"过渡金属<span style=\"color:red\">硫化物</span>","originalKeyword":"过渡金属硫化物"},{"id":"8b82aa1f-f91b-4051-9341-172f9802adc0","keyword":"纳米复合<span style=\"color:red\">化学</span>镀","originalKeyword":"纳米复合化学镀"}],"language":"zh","publisherId":"bmjs200506004","title":"过渡金属<span style=\"color:red\">硫化物</span>纳米材料<span style=\"color:red\">化学</span>复合镀层制备方法","volume":"34","year":"2005"}],"totalpage":7019,"totalrecord":70181}