{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用溶胶-凝胶法制备一系列环境友好型绿色近红外反射纳米颜料,结构通式为Y2Ba(2.x)CuxO5(x=0、0.25、0.50、0.75和1.0),通过X射线衍射(XRD)、扫描电子显微镜(SEM)、UV-vis-NIR分光光度仪和高精度分光测色仪对制备颜料的结构、形貌和光学性能进行了表征.研究结果表明,铜离子掺杂进入Y2Ba2O5晶格中,Y2Ba2O5晶粒尺寸由62.1 nm降低至54.7 nm.Cu2+取代Y2Ba2O5中的部分Ba2+,粉末颜色由白色变为绿色(a*-21.61),禁带宽度由2.30 eV减少到2.04 eV;粉末呈现不规则球形结构,粒径分布在150～300 nm范围内.掺杂Cu2+使粉末的近红外反射率降低,但Cu2+掺杂量为x=0.50时仍然表现出较高的近红外反射率(68.80％)和太阳光反射率(45.95％).因此,Y2Ba(2-x) CuxO5系列<span style=\"color:red\">高</span>近红外反射绿色粉末作为“冷”颜料在建筑涂料方面具有巨大的应用潜能.","authors":[{"authorName":"姜峻","id":"d09c9476-aaf1-447d-9338-109b4d20e80b","originalAuthorName":"姜峻"},{"authorName":"姚伯龙","id":"379185ae-cfe7-491c-9a14-0b574dba56c9","originalAuthorName":"姚伯龙"},{"authorName":"<span style=\"color:red\">高</span><span style=\"color:red\">旭</span><span style=\"color:red\">瑞</span>","id":"a1063757-7789-4491-9e6b-a65b44086f2c","originalAuthorName":"高旭瑞"},{"authorName":"王利魁","id":"7e5ff1c3-d7ec-4cbb-b85a-fda023db0082","originalAuthorName":"王利魁"},{"authorName":"李洪萍","id":"a11938c7-7674-42ba-85cc-0fc8e17f65b6","originalAuthorName":"李洪萍"},{"authorName":"邓丽朵","id":"8a5dc7c0-4510-4e3c-93e7-06bd661ee867","originalAuthorName":"邓丽朵"}],"doi":"10.15541/jim20150562","fpage":"641","id":"e11dd197-2c60-41fd-a560-aee7f8d45c46","issue":"6","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"4bdb7c00-d40e-476d-a723-0c9ca834c46c","keyword":"溶胶-凝胶","originalKeyword":"溶胶-凝胶"},{"id":"8eee2fb0-1001-4a86-bca1-59be88ba577f","keyword":"绿色颜料","originalKeyword":"绿色颜料"},{"id":"e9ff11fb-284e-4217-9d42-bc1193f05ab9","keyword":"近红外反射率","originalKeyword":"近红外反射率"},{"id":"5ec26cbd-f341-4ba8-b41a-53dc8b8d4b65","keyword":"禁带宽度","originalKeyword":"禁带宽度"}],"language":"zh","publisherId":"wjclxb201606013","title":"铜离子掺杂Y2Ba2O5<span style=\"color:red\">高</span>近红外反射颜料的制备和光学性能研究","volume":"31","year":"2016"},{"abstractinfo":"以异佛尔酮二异氰酸酯(IPDI)、聚碳酸酯二元醇(PCDL)、端羟基聚醚改性硅油(THPDMS)、二羟甲基丙酸(DMPA)、六亚甲基二异氰酸酯(HDI)三聚体和丙烯酸羟乙酯(HEA)为主要原料，制备了有机硅改性多臂型水性聚氨酯(TWPU-Si)。采用纳米粒度仪、光学接触角仪、电子拉力机等对膜的结构与性能进行了测试。研究了THPDMS用量对TWPU-Si膜的耐水性、力学性能、硬度、水接触角、热稳定性的影响。结果表明，随着有机硅含量增加乳液粒径逐渐增大、分布变宽，胶膜耐水性和热稳定性增强。拉伸强度先减小再增大后降低。","authors":[{"authorName":"<span style=\"color:red\">高</span><span style=\"color:red\">旭</span><span style=\"color:red\">瑞</span>","id":"c087d504-1cc9-41df-a80a-9fc9f917a0b7","originalAuthorName":"高旭瑞"},{"authorName":"姚伯龙","id":"a25d86cd-ebba-48f9-9898-2efefaa434e8","originalAuthorName":"姚伯龙"},{"authorName":"姜峻","id":"d61072f6-721c-449b-bfe6-31df8006dd21","originalAuthorName":"姜峻"},{"authorName":"王利魁","id":"ca9ed4a6-d8cb-40f2-9e44-384b399c4d8b","originalAuthorName":"王利魁"},{"authorName":"邓丽朵","id":"6d9ad137-4013-44e8-9272-27576bdda2fb","originalAuthorName":"邓丽朵"}],"doi":"10.3969/j.issn.1001-9731.2016.增刊(Ⅰ).044","fpage":"238","id":"e468d1fa-b652-4d59-a30e-e3111fba4584","issue":"z1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"41e228ea-52b1-42b9-9339-9f441b835b4e","keyword":"端羟基聚醚改性硅油","originalKeyword":"端羟基聚醚改性硅油"},{"id":"f6983503-8893-4e0e-bcfa-56330d23664d","keyword":"UV固化","originalKeyword":"UV固化"},{"id":"916e40a5-c8d3-4a2b-b931-a240c4b3b7b9","keyword":"水性聚氨酯","originalKeyword":"水性聚氨酯"},{"id":"4b40fc8b-e468-4632-9c61-e10ae02e5a54","keyword":"HDI三聚体","originalKeyword":"HDI三聚体"},{"id":"75644f85-2ca1-4adc-8c8f-9e3d84a08fcd","keyword":"多臂","originalKeyword":"多臂"}],"language":"zh","publisherId":"gncl2016z1044","title":"有机硅改性多臂型水性聚氨酯的制备及性能研究?","volume":"47","year":"2016"},{"abstractinfo":"采用HDI三聚体(HDT)和二乙醇胺(DEOA)自制六羟基多元醇;采用异佛尔酮二异氰酸酯(IPDI)、全氟己基乙基醇(TEOH-6)和三羟甲基丙烷(TMP)自制含氟二元醇;以IPDI、聚碳酸酯二元醇(PCDL)、含氟二元醇、二羟甲基丁酸(DMBA)、季戊四醇三丙烯酸酯(PETA)为主要原料合成-NCO半封端的聚氨酯,将六羟基多元醇加入到聚氨酯中,制备了氟改性UV固化超支化水性聚氨酯(FWPU).采用光学接触角、纳米粒度仪、电子拉力机、原子力显微镜等对涂膜的结构与性能进行了测试.研究了含氟二元醇添加量对涂膜疏水性、力学性能、硬度、热稳定性等的影响.结果表明:随着含氟二元醇的加入,乳液粒径逐渐增大、分布变宽,涂膜接触角增加、吸水率大幅降低、热稳定性增强、拉伸强度大幅度增大、硬度达到4H.当含氟二元醇含量为8％时,涂膜的综合性能最佳.","authors":[{"authorName":"孙常青","id":"35f321ba-2bc1-4852-980b-77800ec85869","originalAuthorName":"孙常青"},{"authorName":"姚伯龙","id":"b7081d83-5404-4cc9-906b-dec2ed51922b","originalAuthorName":"姚伯龙"},{"authorName":"<span style=\"color:red\">高</span><span style=\"color:red\">旭</span><span style=\"color:red\">瑞</span>","id":"3b1a758b-fe59-4264-a4cb-b9f43c241fcb","originalAuthorName":"高旭瑞"},{"authorName":"王利魁","id":"32d49474-5be0-4cfb-87aa-952de1b2f5a9","originalAuthorName":"王利魁"},{"authorName":"郑春森","id":"c47ee978-5864-4fdd-ab51-948662c0f3fe","originalAuthorName":"郑春森"},{"authorName":"李洪萍","id":"37589b7a-a0d8-4750-8d8c-069b345ef37e","originalAuthorName":"李洪萍"}],"doi":"","fpage":"34","id":"a35f18a0-852c-42ed-beca-78923f1be5f8","issue":"6","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"7fcf143c-eff7-4b40-a03e-91a714cf4aee","keyword":"含氟二元醇","originalKeyword":"含氟二元醇"},{"id":"508b8289-e364-472b-a955-7efc752ac167","keyword":"UV固化","originalKeyword":"UV固化"},{"id":"65c7d1e0-6d01-4fea-9bc7-80ccd0225434","keyword":"超支化","originalKeyword":"超支化"},{"id":"658b3e0b-9cfc-432d-a98e-c61ca1e372a0","keyword":"水性聚氨酯","originalKeyword":"水性聚氨酯"},{"id":"0a210f4c-5651-43e7-b384-bc1d4a74cd31","keyword":"改性","originalKeyword":"改性"}],"language":"zh","publisherId":"tlgy201606007","title":"氟改性UV固化超支化水性聚氨酯的制备与性能研究","volume":"46","year":"2016"},{"abstractinfo":"用甲基丙烯酸羟乙酯(HEMA)与一水合柠檬酸反应生成柠檬酸酯,然后将其与环氧树脂E-51或者甲基丙烯酸缩水甘油酯(GMA)反应,利用环氧开环形成的仲羟基将环氧树脂引入到聚氨酯的主链中,制备了基于柠檬酸架构的水性光固化环氧-聚氨酯.采用纳米粒度仪、光学接触角仪、电子拉力机等对胶膜的结构与性能进行了测试.研究了环氧树脂E-51或GMA的加人对聚氨酯胶膜的耐水性、力学性能、硬度、水接触角、热稳定性的影响.结果表明:随着E-51和GMA的加人,乳液粒径逐渐增大、分布变宽,胶膜热稳定性增强、吸水率大幅度降低、接触角增加;胶膜的拉伸强度和断裂伸长率大幅度增大.","authors":[{"authorName":"<span style=\"color:red\">高</span><span style=\"color:red\">旭</span><span style=\"color:red\">瑞</span>","id":"3b0d757f-5090-4598-a70f-d919e07f537f","originalAuthorName":"高旭瑞"},{"authorName":"姚伯龙","id":"d5e5502e-3cd1-43a6-9d6c-a31529eea7cb","originalAuthorName":"姚伯龙"},{"authorName":"王利魁","id":"c93547ae-a4e9-4811-a451-c6fac5f9498e","originalAuthorName":"王利魁"},{"authorName":"李洪萍","id":"06abba0f-1b94-4e49-a823-4e940b167ed2","originalAuthorName":"李洪萍"},{"authorName":"赵海平","id":"7426ade8-d930-414f-84da-b2edadd5aa0f","originalAuthorName":"赵海平"},{"authorName":"姜峻","id":"e0a39017-0b8d-46ad-bb84-2213ee3f425c","originalAuthorName":"姜峻"}],"doi":"","fpage":"45","id":"96651fc4-7901-416b-9a5b-41ca977bc78f","issue":"4","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"79cf2845-1300-41cc-90d9-8ce97656fbee","keyword":"UV固化","originalKeyword":"UV固化"},{"id":"b40978a8-642b-4750-a98b-476c3af91266","keyword":"水性聚氨酯","originalKeyword":"水性聚氨酯"},{"id":"9869b631-7f79-4b00-8a68-44f04262da0d","keyword":"乳液","originalKeyword":"乳液"},{"id":"3e41f5f1-8523-43b0-bf79-403762c97c4e","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"f51df02e-95f5-4ff7-bf79-b4d71002b140","keyword":"柠檬酸","originalKeyword":"柠檬酸"},{"id":"241c9b04-7c8d-42a8-b640-bfb47ea2a367","keyword":"改性","originalKeyword":"改性"}],"language":"zh","publisherId":"tlgy201604009","title":"基于柠檬酸架构的水性光固化环氧-聚氨酯的制备与性能研究","volume":"46","year":"2016"},{"abstractinfo":"为了提高光固化水性聚氨酯(WPU)涂层的导热性能,采用硅烷偶联剂和半封端聚氨酯来改性纳米氧化铝(Al2O3),将改性后的纳米Al2O3加入水性聚氨酯中制备了Al2O3/光固化水性聚氨酯导热复合涂层.利用光学接触角仪、电子拉力机、热重分析仪等对涂层的性能进行了研究,探讨不同Al2O3的改性方法对涂层耐水性、力学性能、水接触角、热稳定性和导热性能的影响,并用扫描电子显微镜(SEM)对材料断面的形貌进行了观察.结果表明:不同的Al2O3改性方法对光固化涂层的导热性能有较大的提高,热性能和接触角提高,拉伸强度和断裂伸长率也有一定增加.","authors":[{"authorName":"<span style=\"color:red\">高</span><span style=\"color:red\">旭</span><span style=\"color:red\">瑞</span>","id":"d4b28101-3068-4972-a34d-8b4304fda825","originalAuthorName":"高旭瑞"},{"authorName":"王利魁","id":"3a3ae59f-fc06-4347-a0b1-36dcb9371533","originalAuthorName":"王利魁"},{"authorName":"姚伯龙","id":"a97dc502-9994-4acf-8657-4e49bce39857","originalAuthorName":"姚伯龙"}],"doi":"","fpage":"26","id":"206d5505-93ac-4334-8b45-b8967a7250a1","issue":"11","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"0b2fb6a1-7cca-4a3f-90a2-11eab766d2e2","keyword":"水性聚氨酯","originalKeyword":"水性聚氨酯"},{"id":"d144f233-3659-4280-ab69-038baa5d9cbb","keyword":"导热涂层","originalKeyword":"导热涂层"},{"id":"a8e1f253-8e8d-4955-8bcf-8af3a253c1ba","keyword":"改性纳米Al2O3","originalKeyword":"改性纳米Al2O3"},{"id":"97b547c7-24fd-47c2-aaa1-f740b3fdb55d","keyword":"光固化","originalKeyword":"光固化"},{"id":"d7cd5070-b8f7-4210-a397-e8518a207809","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"clbh201611007","title":"光固化水性聚氨酯导热涂层的制备及性能","volume":"49","year":"2016"},{"abstractinfo":"以具有22个不同种类手性中心的新型大环抗生素伊<span style=\"color:red\">瑞</span>霉素为手性选择器,基于环氧基团<span style=\"color:red\">高</span>反应活性的特征,将伊<span style=\"color:red\">瑞</span>霉素用一步法键合到甲基丙烯酸酯整体柱表面制备伊<span style=\"color:red\">瑞</span>霉素键合手性毛细管整体柱.通过对制备条件进行优化,证实该制备方法可在较宽的pH范围(6.0～9.0)内进行,方法简单易行,反应条件温和.应用制备的手性毛细管整体柱在毛细管电色谱模式下,对5种手性氨基酸对映体和手性药物罗格列酮对映体进行拆分,均得到了基线分离,说明伊<span style=\"color:red\">瑞</span>霉素手性固定相具有较强的手性拆分能力.在优化的色谱条件下,6种对映体的分析时间均小于4 min,分析速度快.通过对有机调节剂、缓冲液pH值和缓冲盐浓度等分离条件进行系统考察,初步探讨了该手性毛细管整体柱对不同溶质的手性识别机理.","authors":[{"authorName":"雷雯","id":"f3112f13-31b3-48d4-8a3d-24941a9b5feb","originalAuthorName":"雷雯"},{"authorName":"张凌怡","id":"e0071825-4b94-4a3f-ba04-ba62050f2187","originalAuthorName":"张凌怡"},{"authorName":"万莉","id":"75b5c03d-49e1-4f6e-a59e-e4904e4e2b5f","originalAuthorName":"万莉"},{"authorName":"朱亚仙","id":"4f006e92-817c-4597-842f-7f801bd9dcb9","originalAuthorName":"朱亚仙"},{"authorName":"覃飒飒","id":"954f8ad8-ce48-40e5-bda6-e494c7fc375b","originalAuthorName":"覃飒飒"},{"authorName":"张维冰","id":"62dc267b-d4f0-467d-81ef-ecdbb1d66fda","originalAuthorName":"张维冰"}],"doi":"10.3724/SP.J.1123.2010.00977","fpage":"977","id":"8b0818de-0a05-43be-89a8-9aae5bf1adf3","issue":"10","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"ebde9186-14bb-48bb-a7b9-c54bb9bbfd44","keyword":"伊<span style=\"color:red\">瑞</span>霉素","originalKeyword":"伊瑞霉素"},{"id":"1f065bbb-c191-4889-88ec-8826a836e5d8","keyword":"大环抗生素","originalKeyword":"大环抗生素"},{"id":"f6bb8cb7-1144-4376-85ef-a81fdb8986f4","keyword":"手性整体固定相","originalKeyword":"手性整体固定相"},{"id":"303d37f9-7cd6-4218-8d88-b02ce6b5b5d8","keyword":"毛细管电色谱","originalKeyword":"毛细管电色谱"},{"id":"b90b4039-836a-4782-8b57-34e66b7c89e1","keyword":"对映体","originalKeyword":"对映体"}],"language":"zh","publisherId":"sp201010013","title":"伊<span style=\"color:red\">瑞</span>霉素键合手性毛细管整体柱的制备与对映体分离","volume":"28","year":"2010"},{"abstractinfo":"班公湖-怒江成矿带跨班公湖-怒江缝合带两侧，是近年来发现的一条重要的多金属成矿带。商<span style=\"color:red\">旭</span>金矿床位于班公湖-怒江缝合带中段，主要矿体呈透镜状或脉状产于中-下侏罗统木嘎岗日群浅变质海相复理石建造中，受近东西向断裂构造控制。矿石类型以石英脉型为主，其次为蚀变岩型，近矿围岩蚀变较弱，蚀变类型包括硅化、绢云母化、绿泥石化、碳酸盐化等。矿石中金属矿物主要为自然金、黄铁矿及方铅矿；脉石矿物以石英、方解石以及黏土矿物为主。初步研究表明，该矿床主要受地层及构造因素控制，成因类型为造山型金矿床。在此基础上，初步总结了矿区的主要找矿标志，包括岩性及构造标志、蚀变标志、硫化物标志、化探异常及古采矿遗迹标志等，并认为区域上存在找到商<span style=\"color:red\">旭</span>式金矿床的可能。","authors":[{"authorName":"肖万峰","id":"1d451ac3-887c-4617-a0ca-158b639eee34","originalAuthorName":"肖万峰"},{"authorName":"李光明","id":"a43a9f64-db4e-4ae7-a4db-ad6b5c6fdf01","originalAuthorName":"李光明"},{"authorName":"黄瀚霄","id":"4bd70593-6e2d-4a4a-a476-a8499e8e8141","originalAuthorName":"黄瀚霄"},{"authorName":"马东","id":"62242f64-8b3e-453d-90b4-3cdd52646587","originalAuthorName":"马东"},{"authorName":"张智林","id":"4e3ebf94-f1d0-409d-a4e6-f99d952597d4","originalAuthorName":"张智林"},{"authorName":"曲扎","id":"e0763d49-69d4-429c-ba6a-eba9484badf0","originalAuthorName":"曲扎"}],"doi":"10.11792/hj20131005","fpage":"17","id":"64eb054f-8d90-414b-8571-cdbe479e8b5b","issue":"10","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"e38f1f96-a61b-4a64-b5d5-cf076ed042d1","keyword":"商<span style=\"color:red\">旭</span>金矿床","originalKeyword":"商旭金矿床"},{"id":"222c536e-17cf-4583-ac2e-eb9910f27ce7","keyword":"地质特征","originalKeyword":"地质特征"},{"id":"84cc3253-435b-48e9-8036-2a247c1b10b7","keyword":"控矿因素","originalKeyword":"控矿因素"},{"id":"e472e283-83a4-4b15-bdbe-041026cc787a","keyword":"矿床成因","originalKeyword":"矿床成因"},{"id":"55fa1374-bf4f-4361-8758-6b26fa5c71d1","keyword":"找矿标志","originalKeyword":"找矿标志"},{"id":"b817b4f3-ad9b-4e53-b2d3-2fafe0695a73","keyword":"藏北","originalKeyword":"藏北"}],"language":"zh","publisherId":"huangj201310007","title":"藏北商<span style=\"color:red\">旭</span>金矿床控矿因素及其找矿标志","volume":"","year":"2013"},{"abstractinfo":"本研究采用静电喷雾法,以壳聚糖为基质材料,康普<span style=\"color:red\">瑞</span>丁为模型药物制备微球.实验中采用AcOH/H2O和AcOH/H2O/EtOH两种溶剂,分析了微球形貌和粒径分布的影响因素,并且对CS-CA4微球的缓释性能进行了测定.结果表明,壳聚糖浓度、溶剂配比及乙醇和康普<span style=\"color:red\">瑞</span>丁的加入会使壳聚糖微球呈球状、中间塌陷的类球状、棒状等不同形貌,微球粒径存在较大差异;通过AcOH/H2O/EtOH复合溶剂将疏水性药物康普<span style=\"color:red\">瑞</span>丁载入壳聚糖微球,制备出的壳聚糖/康普<span style=\"color:red\">瑞</span>丁载药微球分散性好,粒径分布均匀,平均粒径仅为0.27μm;使用戊二醛蒸汽交联48h的微球缓释效果明显.","authors":[{"authorName":"马骊娜","id":"1199ac48-a9e3-4a3e-bb00-419a65ff9d7c","originalAuthorName":"马骊娜"},{"authorName":"方大为","id":"75d9368e-192b-4a88-9bec-9695b9fa8044","originalAuthorName":"方大为"},{"authorName":"王克敏","id":"c738f1c1-d104-410d-9f54-55b3dca5dc2e","originalAuthorName":"王克敏"},{"authorName":"聂俊","id":"a11a1f53-3fd7-45b4-9dec-4aff409c0f7b","originalAuthorName":"聂俊"},{"authorName":"马贵平","id":"ccd2cd48-646b-4ffd-95c6-9d59f1efb92a","originalAuthorName":"马贵平"}],"doi":"10.14136/j.cnki.issn 1673-2812.2015.06.023","fpage":"889","id":"e2dd295a-8366-4fe2-816d-1bd9aea9ed57","issue":"6","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"c0915753-d339-4bb7-84b4-fb27eec6936d","keyword":"静电喷雾","originalKeyword":"静电喷雾"},{"id":"84fb1809-9c50-47b3-b2b4-73df58a6cf63","keyword":"壳聚糖","originalKeyword":"壳聚糖"},{"id":"242c9cf4-d5d8-4798-86a4-712f75491661","keyword":"康普<span style=\"color:red\">瑞</span>丁","originalKeyword":"康普瑞丁"},{"id":"7bcabc05-f355-4742-9b0c-d0599dbafa0a","keyword":"微球","originalKeyword":"微球"}],"language":"zh","publisherId":"clkxygc201506023","title":"静电喷雾法制备壳聚糖/康普<span style=\"color:red\">瑞</span>丁载药微球","volume":"33","year":"2015"},{"abstractinfo":"在模拟人体生理条件下(pH=7.40),采用荧光光谱法研究双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白的相互作用.采用2种方法计算不同温度下其结合常数K<,A>、结合位点数n,同时对2种计算方法进行了比较;并根据热力学参数确定了双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白之间的作用力类型.根据Forster非辐射能量转移原理,确定了双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白相互结合时供能体-受能体间的作用距离和能量转移效率,并用同步荧光光谱研究了双醋<span style=\"color:red\">瑞</span>因对人血清白蛋白构象的影响.结果表明,双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白之间主要是以静态猝灭为主;结合距离r=2.88 nm,能量转移效率E=0.273 8,二者主要凭借氢键和范德华力进行结合.","authors":[{"authorName":"吕茜茜","id":"f12bfcef-2194-44f2-af18-bffaf338c1f1","originalAuthorName":"吕茜茜"},{"authorName":"<span style=\"color:red\">高</span>苏亚","id":"a30644da-e49a-4d36-afc7-e716115ce091","originalAuthorName":"高苏亚"},{"authorName":"夏冬辉","id":"d73ff043-6fa7-4f8d-a484-08e90b5cb087","originalAuthorName":"夏冬辉"},{"authorName":"李华","id":"64609acd-7353-4cf0-9b35-d68a7b42f516","originalAuthorName":"李华"}],"doi":"10.3724/SP.J.1095.2011.00497","fpage":"836","id":"c91df298-e5b8-4f97-a2e9-feb360f7f935","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"28c96fc8-c4c6-4273-a94a-5ba9464e0eba","keyword":"双醋<span style=\"color:red\">瑞</span>因","originalKeyword":"双醋瑞因"},{"id":"f2d384ae-ff9a-425a-840a-8f406b7729eb","keyword":"人血清白蛋白","originalKeyword":"人血清白蛋白"},{"id":"316e2743-ed10-4b2a-8872-69ab0668a364","keyword":"荧光光谱法","originalKeyword":"荧光光谱法"},{"id":"5a82aeaa-fe8e-49cc-972a-8fca5dd7381e","keyword":"相互作用","originalKeyword":"相互作用"}],"language":"zh","publisherId":"yyhx201107018","title":"荧光光谱法研究双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白的相互作用","volume":"28","year":"2011"},{"abstractinfo":"","authors":[],"doi":"","fpage":"50","id":"da8d0d99-d439-4c64-b0b8-27fab9a0bf79","issue":"3","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"e329d5ec-a75e-4b3f-8683-b409a831b945","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"hccllhyyy200303016","title":"<span style=\"color:red\">旭</span>化成推出大型薄壁机架用改性PPO","volume":"32","year":"2003"}],"totalpage":2231,"totalrecord":22307}