{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"聚氯乙烯常用的抑烟剂钼(Ⅳ)化合物系在凝聚相中以Lewis 酸机理抑烟,文中叙述低价过渡金属化合物(包括低价铜的亚磷酸酯络合物及低价过渡金属的草酸盐和甲酸盐等)对PVC的<span style=\"color:red\">还原</span><span style=\"color:red\">偶联</span>抑烟,讨论了<span style=\"color:red\">还原</span><span style=\"color:red\">偶联</span>抑烟机理及其优越性,对<span style=\"color:red\">还原</span><span style=\"color:red\">偶联</span>抑烟剂的要求,并介绍几类可供用于聚氯乙烯的此类抑烟剂及其效果和应用前景.","authors":[{"authorName":"欧育湘","id":"a9c67638-2e52-4bef-a66d-0efb7e35a3ef","originalAuthorName":"欧育湘"},{"authorName":"吴俊浩","id":"c6aafd73-a178-4e81-a241-43dfb6643532","originalAuthorName":"吴俊浩"},{"authorName":"王建荣","id":"a0bf0f46-fdce-4a8c-b10c-233a551e534b","originalAuthorName":"王建荣"}],"doi":"","fpage":"6","id":"3ecdd5e6-98a5-4c88-9d0e-12cbe6ac398f","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"5f2087a1-dc4b-429e-9e9a-84072db648ea","keyword":"抑烟","originalKeyword":"抑烟"},{"id":"f26a5447-13da-45e0-bef4-79298766b62f","keyword":"<span style=\"color:red\">还原</span><span style=\"color:red\">偶联</span>","originalKeyword":"还原偶联"},{"id":"8c2eb2ab-5e6a-42f4-92f8-53dc7c3c6e20","keyword":"过渡金属化合物","originalKeyword":"过渡金属化合物"},{"id":"9a5b1336-3800-42ac-859c-e1e982b32c1f","keyword":"聚氯乙烯","originalKeyword":"聚氯乙烯"}],"language":"zh","publisherId":"gfzclkxygc200304002","title":"聚氯乙烯的<span style=\"color:red\">还原</span><span style=\"color:red\">偶联</span>抑烟剂","volume":"19","year":"2003"},{"abstractinfo":"近十几年来,N-杂环卡宾的配位化学和金属有机化学发展迅速,已成为均相催化反应中研究最为广泛的配体之一.在许多过渡金属催化的有机合成反应中特别是<span style=\"color:red\">偶联</span>反应中,N-杂环卡宾与传统有机膦配体相比具有较高的反应性.镍价格低廉,在很多反应中有望替代贵金属钯催化剂.本文总结了镍N-杂环卡宾化合物在催化交叉<span style=\"color:red\">偶联</span>反应和<span style=\"color:red\">还原</span><span style=\"color:red\">偶联</span>反应中的最新应用进展.","authors":[{"authorName":"顾绍金","id":"01d44030-50db-41be-b019-51a9b40dbf66","originalAuthorName":"顾绍金"},{"authorName":"倪鹏","id":"1807a44e-29d4-4120-8252-d13c0ef66cf8","originalAuthorName":"倪鹏"},{"authorName":"陈万芝","id":"bc31243a-a17a-4719-a52b-f1b04cc280a5","originalAuthorName":"陈万芝"}],"doi":"10.1016/S1872-2067(09)60089-9","fpage":"875","id":"3f9f5420-2cef-48dc-b27e-cb7b6353aadc","issue":"8","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"0f4c1231-39b6-42b3-bafa-6dd91ec8ebde","keyword":"镍","originalKeyword":"镍"},{"id":"2701b5dd-66b3-4908-8d14-fdf93aeae23b","keyword":"N-杂环卡宾","originalKeyword":"N-杂环卡宾"},{"id":"a30698a3-bf3e-424b-965a-3807a6ba2411","keyword":"交叉<span style=\"color:red\">偶联</span>反应","originalKeyword":"交叉偶联反应"},{"id":"1c1271f7-caf6-456d-9f07-d0822ba0b568","keyword":"<span style=\"color:red\">还原</span><span style=\"color:red\">偶联</span>","originalKeyword":"还原偶联"},{"id":"befe24a6-04b8-4315-90e5-c8d05d2de6e4","keyword":"均相催化","originalKeyword":"均相催化"}],"language":"zh","publisherId":"cuihuaxb201008003","title":"镍N-杂环卡宾配合物在均相催化<span style=\"color:red\">偶联</span>反应中的应用","volume":"31","year":"2010"},{"abstractinfo":"","authors":[{"authorName":"刘键","id":"257cd5aa-467d-4db9-8fde-ff246f1f0291","originalAuthorName":"刘键"},{"authorName":"罗志强","id":"7239214d-a6cc-41be-87d0-0bc65f9a91b8","originalAuthorName":"罗志强"},{"authorName":"阳年发","id":"a0352d6d-b1f1-4e8d-880b-9d3b8a0c844c","originalAuthorName":"阳年发"},{"authorName":"林原斌","id":"6ef8be51-4178-469f-bc01-7ca791a0a2e4","originalAuthorName":"林原斌"}],"doi":"10.3969/j.issn.1000-0518.2002.05.021","fpage":"489","id":"f2a537fa-31cb-4fab-8612-d1483c0ba3a1","issue":"5","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"e18f6d5e-23cc-4a45-afc0-572836a2f63b","keyword":"二苯乙烷","originalKeyword":"二苯乙烷"},{"id":"20fae4b1-dac6-4ea7-af74-4f1d55b2506d","keyword":"合成","originalKeyword":"合成"},{"id":"e074a3b0-4c7b-4af8-a196-de2863feb121","keyword":"氯化苄","originalKeyword":"氯化苄"},{"id":"f0f0481f-0647-4140-9cbe-1f5a71cf9937","keyword":"Cu2Cl2","originalKeyword":"Cu2Cl2"},{"id":"54cc3927-7c3e-476e-961b-79ed1a88d786","keyword":"<span style=\"color:red\">还原</span><span style=\"color:red\">偶联</span>","originalKeyword":"还原偶联"}],"language":"zh","publisherId":"yyhx200205021","title":"1,2-二苯乙烷的新合成法","volume":"19","year":"2002"},{"abstractinfo":"综述了钛酸酯<span style=\"color:red\">偶联</span>剂特殊的分子结构和分类特征,重点介绍了各类钛酸酯<span style=\"color:red\">偶联</span>剂的<span style=\"color:red\">偶联</span>机理及其性能,最后简单介绍了钛酸酯<span style=\"color:red\">偶联</span>剂目前的研究现状.","authors":[{"authorName":"李红玲","id":"e04e0ff9-f030-4c2e-886f-ee8e25512879","originalAuthorName":"李红玲"},{"authorName":"董斌","id":"7dafb66b-51ab-4510-8cef-e5d9d515babb","originalAuthorName":"董斌"},{"authorName":"韩延安","id":"e106c578-b4f3-4d7e-b1e1-ea7a5529274f","originalAuthorName":"韩延安"},{"authorName":"娄淑芳","id":"9433b0aa-5112-4ea3-9c30-9efefa04c644","originalAuthorName":"娄淑芳"},{"authorName":"李杰","id":"1dd5ef2e-243a-41c8-9d8d-932190ad75bc","originalAuthorName":"李杰"},{"authorName":"李文静","id":"b5dc4221-cee5-474b-b48e-465021a3bee2","originalAuthorName":"李文静"}],"doi":"","fpage":"99","id":"cb3429f4-ade9-4a9d-9e1e-57065ed4b056","issue":"4","journal":{"abbrevTitle":"BMJS","coverImgSrc":"journal/img/cover/BMJS.jpg","id":"3","issnPpub":"1001-3660","publisherId":"BMJS","title":"表面技术   "},"keywords":[{"id":"311e4548-8b99-42f1-a2d3-06e8d9fc1183","keyword":"钛酸酯<span style=\"color:red\">偶联</span>剂","originalKeyword":"钛酸酯偶联剂"},{"id":"49cbf2c7-54da-4168-8f48-b8ce17c2943a","keyword":"分子结构","originalKeyword":"分子结构"},{"id":"e2fa181d-7507-47c5-97b8-9fd52c45d30d","keyword":"<span style=\"color:red\">偶联</span>机理","originalKeyword":"偶联机理"},{"id":"01617eb2-67be-4dca-8a69-f46a8c13c052","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"bmjs201204030","title":"钛酸酯<span style=\"color:red\">偶联</span>剂的<span style=\"color:red\">偶联</span>机理及研究进展","volume":"41","year":"2012"},{"abstractinfo":"用硅烷<span style=\"color:red\">偶联</span>剂对由部分<span style=\"color:red\">还原</span>沉淀法制备的Fe3O4磁微粒子进行了表面修饰.并利用XRD,TEM,AFM,IR,古埃磁天平等手段对其结构与性能进行了表征.分析了<span style=\"color:red\">偶联</span>剂使用量对磁性纳米复合微球性能的影响.研究结果表明,经硅烷<span style=\"color:red\">偶联</span>剂修饰后的微球表面可带有-OH,-NH2,-C=O,-C=C等多种有机功能基团,随着硅烷<span style=\"color:red\">偶联</span>剂用量的增大,微球表面包覆的有机特征基团也增多,<span style=\"color:red\">偶联</span>反应趋于完全.当硅烷用量较少时,随着用量的增加,磁性能随之提高;而当硅烷用量达到一定值之后,继续增加用量,则会使磁性能降低.磁性纳米复合微球的Zeta电位随着<span style=\"color:red\">偶联</span>剂用量的增加呈现先增加后降低的变化趋势.","authors":[{"authorName":"赵慧君","id":"39eddf13-3497-47d9-a009-7bb4d938d127","originalAuthorName":"赵慧君"},{"authorName":"张中杰","id":"6ad73829-3885-4a71-bacc-924daf847efa","originalAuthorName":"张中杰"},{"authorName":"范积伟","id":"8443661d-379f-4b06-97ce-79636cce0077","originalAuthorName":"范积伟"}],"doi":"","fpage":"733","id":"8b956b6b-45bf-4ac0-996a-0a929121c5c6","issue":"z1","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"d4513eb4-436a-45e5-98fd-7b34d34af620","keyword":"复合材料","originalKeyword":"复合材料"},{"id":"502a219b-55e9-45f6-91f8-93c050ff610d","keyword":"Fe3O4磁性微球","originalKeyword":"Fe3O4磁性微球"},{"id":"df110087-10b5-4f66-afde-9fae1ff4b2ee","keyword":"硅烷<span style=\"color:red\">偶联</span>剂","originalKeyword":"硅烷偶联剂"},{"id":"29760db2-149c-48ae-bfcb-2c84754fb103","keyword":"磁化率","originalKeyword":"磁化率"}],"language":"zh","publisherId":"xyjsclygc2008z1192","title":"硅烷<span style=\"color:red\">偶联</span>剂用量对磁性纳米复合微球性能的影响","volume":"37","year":"2008"},{"abstractinfo":"三价铑在氧化<span style=\"color:red\">还原</span>中性条件下催化硝酮与炔发生<span style=\"color:red\">偶联</span>，经过氮芳环的碳氢键活化和氧转移可以高化学选择性、中等到良好非对映选择性的得到三取代二氢吲哚。","authors":[{"authorName":"孔令恒","id":"a48d1e10-4b8c-4e17-8c5d-dcdefe686f77","originalAuthorName":"孔令恒"},{"authorName":"谢芳","id":"1c92fd2a-2bc3-4a14-8676-9920fb19c37d","originalAuthorName":"谢芳"},{"authorName":"于松杰","id":"d8a08fdb-6074-4502-bbd6-8a41b33fc3b9","originalAuthorName":"于松杰"},{"authorName":"戚自松","id":"f2d5b73b-76cd-4422-8c9f-9d6f67a8da74","originalAuthorName":"戚自松"},{"authorName":"李兴伟","id":"cddb2582-da84-43ff-b045-4a263ac032e6","originalAuthorName":"李兴伟"}],"doi":"10.1016/S1872-2067(15)60866-X","fpage":"925","id":"0f9c9f42-2073-40c2-89ba-12bafd01a3ff","issue":"7","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"58766c2d-ef5c-4bc7-bdce-9b5c80aa914c","keyword":"三价铑","originalKeyword":"三价铑"},{"id":"00d065f5-568b-46b2-8dc2-58875c53f93c","keyword":"碳氢活化","originalKeyword":"碳氢活化"},{"id":"679d35b1-6797-42a6-b8b1-8066611e1a0b","keyword":"氧转移","originalKeyword":"氧转移"},{"id":"7f146fab-0191-433b-b7be-0050e15c4e92","keyword":"氮芳基硝酮","originalKeyword":"氮芳基硝酮"}],"language":"zh","publisherId":"cuihuaxb201507003","title":"三价铑催化硝酮与炔的碳氢活化<span style=\"color:red\">偶联</span>合成二氢吲哚","volume":"","year":"2015"},{"abstractinfo":"三价铑在氧化条件下催化N-烷基苯甲酰胺与醌反应生成芳基醌。在氧化<span style=\"color:red\">还原</span>中性条件下，经过<span style=\"color:red\">偶联</span>和内酯化反应可以得到2-羟基-6H-苯并[c]吡喃-6-酮。","authors":[{"authorName":"戚自松","id":"39692fed-0fbc-4487-8293-bb8cfe03a445","originalAuthorName":"戚自松"},{"authorName":"李兴伟","id":"6e6201cb-6a63-4d9c-9b00-39d2bac8d831","originalAuthorName":"李兴伟"}],"doi":"10.1016/S1872-2067(14)60245-X","fpage":"48","id":"cf61868c-5696-4f02-afe9-6717fa71262e","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"192ac500-2090-477a-ab3a-062300fd2ccb","keyword":"三价铑","originalKeyword":"三价铑"},{"id":"480a3879-b42a-45d0-b9fc-69cb3eb8a935","keyword":"碳氢活化","originalKeyword":"碳氢活化"},{"id":"2e61e05f-6272-44f8-80bf-804d7d19ca28","keyword":"苯甲酰胺","originalKeyword":"苯甲酰胺"},{"id":"62c64ea9-ece2-4e2d-a6ee-693c0a45cb99","keyword":"芳基醌","originalKeyword":"芳基醌"}],"language":"zh","publisherId":"cuihuaxb201501011","title":"三价铑催化苯甲酰胺与醌的C-H活化<span style=\"color:red\">偶联</span>","volume":"","year":"2015"},{"abstractinfo":"非晶合金粉末作为电磁屏蔽涂料的填料应用的还较少.本文分别使用1%～10%的KH-550硅烷<span style=\"color:red\">偶联</span>剂对自制的钴基非晶合金粉末进行了<span style=\"color:red\">偶联</span>处理.通过SEM和TGA对<span style=\"color:red\">偶联</span>处理后的粉末分析后认为,<span style=\"color:red\">偶联</span>剂的较佳用量在2%左右.","authors":[{"authorName":"冯猛","id":"28e8ed4e-519b-4157-8589-77db7899095c","originalAuthorName":"冯猛"},{"authorName":"张羊换","id":"55f0735b-53ae-44a2-91f4-d98680862439","originalAuthorName":"张羊换"},{"authorName":"曾敏","id":"ee995c28-602a-4169-b7e7-69512b5c3639","originalAuthorName":"曾敏"},{"authorName":"王新林","id":"1fa1a932-b7a4-43f5-b923-6af7ac08f48d","originalAuthorName":"王新林"}],"doi":"","fpage":"9","id":"e4d98b27-513d-47b7-9689-2d2988701561","issue":"1","journal":{"abbrevTitle":"JSGNCL","coverImgSrc":"journal/img/cover/JSGNCL.jpg","id":"46","issnPpub":"1005-8192","publisherId":"JSGNCL","title":"金属功能材料"},"keywords":[{"id":"2545a252-c402-409f-ac6e-b1dfa49fe090","keyword":"硅烷<span style=\"color:red\">偶联</span>剂","originalKeyword":"硅烷偶联剂"},{"id":"ff5fdc6b-8660-44c7-81ae-3d532a999f87","keyword":"非晶合金粉末","originalKeyword":"非晶合金粉末"},{"id":"f4580c67-2e42-4a66-8c03-80b6ffeb5028","keyword":"<span style=\"color:red\">偶联</span>处理","originalKeyword":"偶联处理"}],"language":"zh","publisherId":"jsgncl200901003","title":"电磁屏蔽涂料用非晶粉末<span style=\"color:red\">偶联</span>处理研究","volume":"16","year":"2009"},{"abstractinfo":"采用有机金属Pd_2(dba) _3(dba为二亚苄基丙酮)<span style=\"color:red\">还原</span>分解法制得均匀分布的Pd纳米颗粒(粒径为3～6nm)混合液,并用活性炭直接吸附得到了组合型Pd/C纳米催化剂.采用透射电子显微镜、X射线光电子能谱和X射线衍射等手段测定了催化剂表面Pd颗粒大小分布、晶型和化学态等.将该催化剂用于Suzuki碳-碳<span style=\"color:red\">偶联</span>反应,其催化活性比浸渍法制备的Pd/C催化剂高2倍以上.以溴代芳烃为底物时,在80℃下0.5h后<span style=\"color:red\">偶联</span>产物收率可达98%以上.以邻氯硝基苯为底物时,在110°C下1 h后<span style=\"color:red\">偶联</span>产物收率可达64%:延长反应时间,产物收率可达90%以上.","authors":[{"authorName":"黄钟斌","id":"acf450ea-2f46-4c13-816a-7d79e9025892","originalAuthorName":"黄钟斌"},{"authorName":"严新焕","id":"7ba28118-d655-4763-8e5a-472854eaf320","originalAuthorName":"严新焕"},{"authorName":"江玲超","id":"7946268f-670c-4574-a9fa-60567561e9ba","originalAuthorName":"江玲超"},{"authorName":"蒋虹","id":"67c16922-fa32-46fb-94a6-1da14d41bb9d","originalAuthorName":"蒋虹"}],"doi":"10.3724/SP.J.1088.2010.90626","fpage":"90","id":"65a266b9-4ec0-4412-874b-1c749fb1ab6b","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"2a28a2f4-3d5e-4574-a490-7514b2d3d56a","keyword":"钯","originalKeyword":"钯"},{"id":"d4768e24-5c0a-4b76-945e-2cab13022080","keyword":"纳米颗粒","originalKeyword":"纳米颗粒"},{"id":"7807157e-0ad1-4a84-b174-8117d4339e25","keyword":"活性炭","originalKeyword":"活性炭"},{"id":"49854f7b-40be-4240-b5b1-9d0eaa833da4","keyword":"负载型催化剂","originalKeyword":"负载型催化剂"},{"id":"d9989be6-875c-425b-ace4-400223311105","keyword":"溴代芳烃","originalKeyword":"溴代芳烃"},{"id":"918ee9c7-0fde-48fb-aa2a-1503c12aaec2","keyword":"氯代芳烃","originalKeyword":"氯代芳烃"},{"id":"d4dc140d-cdb2-418a-aac8-b5cad9ef1841","keyword":"Suzuki反应","originalKeyword":"Suzuki反应"}],"language":"zh","publisherId":"cuihuaxb201001016","title":"高效组合型Pd/C催化剂用于Suzuki<span style=\"color:red\">偶联</span>反应","volume":"31","year":"2010"},{"abstractinfo":"采用多元醇为溶剂和<span style=\"color:red\">还原</span>剂制备了聚乙烯吡咯烷酮(PVP)保护的纳米银,并将其用于催化正十二烷基硫醇氧化<span style=\"color:red\">偶联</span>反应.质谱、红外光谱、拉曼光谱和核磁共振氢谱表征结果表明所得产物为二硫化物.考察了反应时间、反应温度、催化剂和水的用量等对正十二烷基硫醇氧化<span style=\"color:red\">偶联</span>反应的影响,从而得出优化的反应条件:0.157mmolPVP保护的纳米银,20μl水,100℃下反应3h.此外,进一步将PVP保护的纳米银用于正丁硫醇和正辛硫醇的氧化<span style=\"color:red\">偶联</span>反应,也得到了相应的二硫化物.","authors":[{"authorName":"闫江梅","id":"98715eb4-06a4-4eb2-9166-2c86f07fc526","originalAuthorName":"闫江梅"},{"authorName":"陶辉旺","id":"f13ba81f-0b7c-49ff-9939-24640ea1b3d3","originalAuthorName":"陶辉旺"},{"authorName":"曾牡玲","id":"6eff9de9-8fa0-4c7c-9b36-74daabd40c1b","originalAuthorName":"曾牡玲"},{"authorName":"陶军","id":"732e78dd-e6d5-44e2-9c7f-bba06e12ed87","originalAuthorName":"陶军"},{"authorName":"张世鸿","id":"0c64c47d-8e61-4b05-b891-2cc4c565aee4","originalAuthorName":"张世鸿"},{"authorName":"闫智英","id":"348c5d36-14d9-4601-8405-487b1bf98715","originalAuthorName":"闫智英"},{"authorName":"王伟","id":"24643cfd-d321-4658-94f5-5060f0d8a457","originalAuthorName":"王伟"},{"authorName":"王家强","id":"2d6d20d4-6842-4850-9847-53cc95f269e7","originalAuthorName":"王家强"}],"doi":"","fpage":"856","id":"bf7df85e-0b3e-4288-9ce8-b2474de4fa93","issue":"9","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"8205f29d-7e5b-4125-bf48-046d21505c52","keyword":"聚乙烯吡咯烷酮","originalKeyword":"聚乙烯吡咯烷酮"},{"id":"6e3a04c1-9cd8-4b7b-a69b-e56d4ca43137","keyword":"纳米银","originalKeyword":"纳米银"},{"id":"4bfeb2a7-c143-4160-96c5-307a6b6eb72f","keyword":"氧化<span style=\"color:red\">偶联</span>","originalKeyword":"氧化偶联"},{"id":"994f6cf9-ec00-4c57-b688-f41aff888e2e","keyword":"硫醇","originalKeyword":"硫醇"},{"id":"5d145e3d-263c-43c8-a66b-92eb252c5d56","keyword":"二硫化物","originalKeyword":"二硫化物"}],"language":"zh","publisherId":"cuihuaxb200909002","title":"纳米银催化氧化<span style=\"color:red\">偶联</span>硫醇制二硫化物","volume":"30","year":"2009"}],"totalpage":885,"totalrecord":8842}