Xianting SUN
,
Lianzeng YAO
,
Chimei MO
,
Gang SHI
,
Weili CAI
,
Yimin ZHANG
,
Lide ZHANG
材料科学技术（英）
Alumina aerogels with high porosity of nanometer size were prepared from Al, n-butanol and ethyl acetoacetate by the sol-gel route and the Na supercritical extraction drying technique. Optical experiment results showed that for alumina aerogels after annealing at 500 degrees C for 4 h one intense blue emission band appeared in the wavelength range of 400 to 800 nm, and the optical absorption edge moved from 8.0 eV of coarse grain Al2O3 to 3 similar to 5 eV and with increasing the annealing temperature, this luminescence band presented blue shifts. The reasons of these new optical properties are discussed in detail.
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