{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以对羟基苯甲酸、对羟基苯甲醚和<span style=\"color:red\">丙烯</span>酰氯为主要原料,通过逐步酰化反应,合成出了一种具有刚性结构并带有极性基团的乙烯基单体:<span style=\"color:red\">4-</span>(<span style=\"color:red\">4-</span><span style=\"color:red\">甲</span><span style=\"color:red\">氧基</span>)-<span style=\"color:red\">二</span><span style=\"color:red\">酚</span><span style=\"color:red\">氧</span><span style=\"color:red\">羰基</span><span style=\"color:red\">酚</span><span style=\"color:red\">丙烯酸酯</span>(ACDHP),并通过自由基引发合成出相应的聚合物PACDHP.利用1H-NMR和FT-IR对单体和聚合物的化学结构进行了表征.采用DSC、热台偏光显微镜(HS-POM)和TGA对聚合物的相转变温度、液晶态的织构和热稳定性进行了研究.结果表明该热致液晶聚合物的液晶相变温度范围较宽,热稳定性较好.","authors":[{"authorName":"乔文强","id":"7084b1cd-13dd-4689-99a4-4a63aa9194b7","originalAuthorName":"乔文强"},{"authorName":"范晓东","id":"bd8295f9-9c43-4df8-9198-42801e513166","originalAuthorName":"范晓东"},{"authorName":"孔杰","id":"76fbd9f3-d3a2-4fab-a94f-456b622c9b17","originalAuthorName":"孔杰"},{"authorName":"解云川","id":"4dc5dbc3-c230-46ab-a91e-d30c7ce03641","originalAuthorName":"解云川"}],"doi":"","fpage":"94","id":"2c6ce6df-8db1-41c1-898b-6c743cad1c2d","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"3c9c6ccd-c11b-41f1-a9ca-c76e489dddc5","keyword":"成核剂","originalKeyword":"成核剂"},{"id":"5edd4c5e-fe24-4fae-b54d-22793ce88128","keyword":"液晶","originalKeyword":"液晶"},{"id":"e184f3d2-3dd4-4a15-96a6-5efe60839732","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">4-</span>(<span style=\"color:red\">4-</span><span style=\"color:red\">甲</span><span style=\"color:red\">氧基</span>)-<span style=\"color:red\">二</span><span style=\"color:red\">酚</span><span style=\"color:red\">氧</span><span style=\"color:red\">羰基</span><span style=\"color:red\">酚</span><span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"聚4-(4-甲氧基)-二酚氧羰基酚丙烯酸酯"}],"language":"zh","publisherId":"gfzclkxygc200406023","title":"液晶型成核剂的合成及对聚乙烯结晶行为的影响--(Ⅰ)液晶型成核剂的合成与表征","volume":"20","year":"2004"},{"abstractinfo":"以对羟基苯甲酸乙<span style=\"color:red\">酯</span>,<span style=\"color:red\">4-</span>乙酸氯丁<span style=\"color:red\">酯</span>和<span style=\"color:red\">丙烯酸</span>为原料,经醚化,酯化后合成-<span style=\"color:red\">4</span>(ω-<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span><span style=\"color:red\">氧基</span>)苯甲酸,以<span style=\"color:red\">二</span>环已基碳酰亚胺(DCC)为脱水剂,<span style=\"color:red\">4-</span><span style=\"color:red\">二甲</span>氨基吡啶(DMAP)为催化剂进行酯化反应,合成了一系列<span style=\"color:red\">4-</span>(ω-<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span><span style=\"color:red\">氧基</span>)苯甲酸酯类液晶化合物,总收率大于60%,液相色谱测定了其含量均大于99%.研究了合成工艺、反应条件、提纯方法等因素对产率的影响.对合成的分子结构、液晶相转变和液晶态织构采用FTIR、1H NMR、MS、POM和DSC进行了表征.研究表明,该类液晶化合物呈现向列型液晶织态结构,且在较宽的温度范围内有很好的液晶性.","authors":[{"authorName":"谭丹","id":"2a66a1c4-8086-4152-b488-fdf388b8d820","originalAuthorName":"谭丹"},{"authorName":"李启贵","id":"bf766817-bb02-46af-adc4-cad932349290","originalAuthorName":"李启贵"},{"authorName":"李娜","id":"5e9a104f-d775-414b-937d-0b569efa33d5","originalAuthorName":"李娜"},{"authorName":"巨妮娟","id":"15711b0f-301f-40fe-8435-008521e7630a","originalAuthorName":"巨妮娟"},{"authorName":"杨永忠","id":"da0beb03-fae2-49a9-ac7a-b70b7bd7c773","originalAuthorName":"杨永忠"}],"doi":"10.3969/j.issn.1000-0518.2008.06.024","fpage":"726","id":"60308657-8710-4432-9850-f99ba9d1c8b2","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"5c104fa4-abaa-48e1-9a5e-08d2a28efab5","keyword":"液晶","originalKeyword":"液晶"},{"id":"567b56c8-0af0-4b80-925c-51a505a3d43b","keyword":"<span style=\"color:red\">丙烯酸</span>","originalKeyword":"丙烯酸"},{"id":"ac7a10a7-b46a-4e30-b288-a664926d0912","keyword":"(ω-<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span><span style=\"color:red\">氧基</span>)苯甲酸<span style=\"color:red\">酯</span>","originalKeyword":"(ω-丙烯酸丁酯氧基)苯甲酸酯"},{"id":"6c11cf63-869e-4b29-97da-eb2dbab54cbe","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"yyhx200806024","title":"<span style=\"color:red\">4-</span>(ω-<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span><span style=\"color:red\">氧基</span>)苯甲酸酯类液晶的合成","volume":"25","year":"2008"},{"abstractinfo":"以含双官能团的<span style=\"color:red\">4-</span>(氯甲基)苯基三<span style=\"color:red\">甲</span><span style=\"color:red\">氧基</span>硅烷(CMTMS)为引发剂,CuCl/ligand为催化剂体系,<span style=\"color:red\">二</span>甲苯为溶剂,进行甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">甲</span><span style=\"color:red\">酯</span>(MMA)的原子转移自由基聚合(ATRP),重点研究了配体对聚合反应的影响.通过1H-NMR表征,证明PMMA是由CMTMS引发MMA聚合而得.聚合转化率和聚合物分子量及其分布测定结果表明,分别采用具有长链烷基的<span style=\"color:red\">4,4</span>′-<span style=\"color:red\">二</span>壬基-2,2′-联吡啶(dNbpy)和N,N,N′,N′,N″-五甲基<span style=\"color:red\">二</span>乙基三胺(PMDETA)为配体,所得聚合物的数均分子量与转化率之间的线性关系比较好,分子量分布较窄(Mw/Mn分别为1.27和1.30);而采用2,2′-联吡啶(bpy)为配体,所得聚合物数均分子量随转化率变化关系远远偏离理论分子量随转化率变化关系,且分子量分布相对较宽(Mw/Mn为1.41).","authors":[{"authorName":"张娟","id":"7f86cdbd-17b3-40e1-940d-f781a0494e8c","originalAuthorName":"张娟"},{"authorName":"江龙","id":"1d78a44b-b7c6-416a-ad85-e8a74b58e207","originalAuthorName":"江龙"},{"authorName":"潘凯","id":"003d2ce6-74c7-42aa-9eaa-c6ec19f34666","originalAuthorName":"潘凯"},{"authorName":"淡宜","id":"a6d44a85-ac45-4f4c-8028-e122db677580","originalAuthorName":"淡宜"}],"doi":"","fpage":"68","id":"bff9ac86-f9dc-48f9-9544-5cce991987f6","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"ad449d48-ffad-4c49-8dcc-274af7bd053d","keyword":"原子转移自由基聚合","originalKeyword":"原子转移自由基聚合"},{"id":"5675b80e-f35f-4712-9fbd-4edcfd5995f0","keyword":"双官能团引发剂","originalKeyword":"双官能团引发剂"},{"id":"a561da95-2434-403d-8497-22ec1fad08dc","keyword":"<span style=\"color:red\">4-</span>(氯甲基)苯基三<span style=\"color:red\">甲</span><span style=\"color:red\">氧基</span>硅烷","originalKeyword":"4-(氯甲基)苯基三甲氧基硅烷"},{"id":"dc2ca472-2e8e-4ea3-867c-c89398c3776b","keyword":"甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">甲</span><span style=\"color:red\">酯</span>","originalKeyword":"甲基丙烯酸甲酯"}],"language":"zh","publisherId":"gfzclkxygc200604017","title":"<span style=\"color:red\">4-</span>(氯甲基)苯基三<span style=\"color:red\">甲</span><span style=\"color:red\">氧基</span>硅烷引发的甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">甲</span><span style=\"color:red\">酯</span>的原子转移自由基聚合","volume":"22","year":"2006"},{"abstractinfo":"以环氧树脂与<span style=\"color:red\">丙烯酸酯</span>为基本共聚单体,制备了一种无烷基<span style=\"color:red\">酚</span><span style=\"color:red\">聚</span><span style=\"color:red\">氧</span>乙烯醚(APEO)的含磷环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸酯</span>防锈乳液.为改进环氧树脂与<span style=\"color:red\">丙烯酸酯</span>相容性差、接枝难的问题,首先以甲基<span style=\"color:red\">丙烯酸</span>与环氧树脂发生开环酯化反应合成可聚合的甲基<span style=\"color:red\">丙烯酸</span>环<span style=\"color:red\">氧</span>单<span style=\"color:red\">酯</span>.为使水性涂料具有出色的防锈性能,重点研究了无APEO的水性乳化体系,并引入磷酸<span style=\"color:red\">酯</span>乳化剂及单体.研究发现:选用LCA213与DSB复合的无APEO乳化剂体系,m(LCA213):m(DSB)为5∶1,复合乳化剂的用量占单体总量的3％,磷酸<span style=\"color:red\">酯</span>反应型乳化剂UCAN-3的用量为LCA213用量的8％,磷酸<span style=\"color:red\">酯</span>功能性单体APE-2005的用量占单体总量的<span style=\"color:red\">4</span>％,入釜<span style=\"color:red\">丙烯酸</span>预乳液量为1/<span style=\"color:red\">4</span>,滴加时间为3h,反应温度为85℃时,制得的乳液细腻、均匀,涂膜完整.","authors":[{"authorName":"杨亚萍","id":"a6e88456-ef86-4fe7-bbce-c029ba6f5258","originalAuthorName":"杨亚萍"},{"authorName":"孟婷婷","id":"08f496b5-fc2d-40fb-bff1-09fc276b09ab","originalAuthorName":"孟婷婷"},{"authorName":"陈永康","id":"98beeec0-8f03-4675-8c93-be50bf205876","originalAuthorName":"陈永康"},{"authorName":"季永新","id":"c92885c7-05ef-4b4c-96de-9b2a12bfe69c","originalAuthorName":"季永新"}],"doi":"","fpage":"40","id":"894ad8ab-5981-47ba-9d3a-d8ed864918f0","issue":"7","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"0f4935d3-7fe5-49e7-ba49-492fb16267ec","keyword":"环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸</span>乳液","originalKeyword":"环氧丙烯酸乳液"},{"id":"e5387d66-4a58-48c7-9345-f53283f2b5bc","keyword":"乳化体系","originalKeyword":"乳化体系"},{"id":"ef5445af-fa65-4e9c-ad20-83ba65a83551","keyword":"磷酸<span style=\"color:red\">酯</span>","originalKeyword":"磷酸酯"},{"id":"7b86f292-ca6d-41b7-b664-6a0e82ee5d65","keyword":"APEO","originalKeyword":"APEO"}],"language":"zh","publisherId":"tlgy201507009","title":"无烷基<span style=\"color:red\">酚</span><span style=\"color:red\">聚</span><span style=\"color:red\">氧</span>乙烯醚的含磷环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸酯</span>防锈乳液的制备与性能","volume":"45","year":"2015"},{"abstractinfo":"为了解决天然生漆不能喷印和快干固化的问题,用生漆对环氧树脂进行改性,在此基础上合成了一种新型预<span style=\"color:red\">聚</span>物——漆<span style=\"color:red\">酚</span>环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸酯</span>.以该预<span style=\"color:red\">聚</span>物作为主要成膜物质,制备了UV固化漆<span style=\"color:red\">酚</span>改性环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸酯</span>喷印油墨.配制出色浆基墨后,采用正交实验法,以喷头通过性、黏度、固化时间为测试指标,优选出UV喷印油墨的最佳配方.最后通过粒径分析和性能评价验证了优选配方,制备的UV固化漆<span style=\"color:red\">酚</span>改性环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸酯</span>喷印油墨综合性能优异.","authors":[{"authorName":"李慧敏","id":"05906ac1-e98d-4acc-b75f-2081b45d15e7","originalAuthorName":"李慧敏"},{"authorName":"吴智慧","id":"77047c70-a8b7-436f-b22b-0443ad06a801","originalAuthorName":"吴智慧"},{"authorName":"吴燕","id":"a6332c97-db34-4792-886f-6d6327f9ccc7","originalAuthorName":"吴燕"},{"authorName":"闫小星","id":"ee6e82ce-2cad-482d-8622-89c767696cc2","originalAuthorName":"闫小星"}],"doi":"","fpage":"26","id":"d9a3b4df-9ecc-4ec1-baf0-42d985773e33","issue":"9","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"8181dcae-93ba-47db-814d-ec8ae4a9bc34","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"92e63275-139c-49c6-b475-9e6566b050c6","keyword":"漆<span style=\"color:red\">酚</span>改性","originalKeyword":"漆酚改性"},{"id":"e981a84d-6531-4fe2-b2c7-9e4904eade2a","keyword":"<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"丙烯酸酯"},{"id":"341f783a-d86d-46e5-b138-afe8fc5c7cf5","keyword":"喷印油墨","originalKeyword":"喷印油墨"},{"id":"182acae8-73b4-46f6-861c-4c68131f8ede","keyword":"UV固化","originalKeyword":"UV固化"}],"language":"zh","publisherId":"tlgy201609005","title":"UV固化漆<span style=\"color:red\">酚</span>改性环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸酯</span>喷印油墨的研制","volume":"46","year":"2016"},{"abstractinfo":"通过自由基共聚合反应,合成了一系列不同分子量、不同乙烯基吡啶基的<span style=\"color:red\">聚</span>(甲基<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>+(<span style=\"color:red\">4-</span>乙烯基)吡啶)共聚物,并以低真空度法测试了其<span style=\"color:red\">氧</span>氮渗透性能。结果表明,随着共聚物膜中乙烯基吡啶含量的增加,共聚物膜的密度、玻璃化转变温度及<span style=\"color:red\">氧</span>氮选择性都随之增加,但<span style=\"color:red\">氧</span>氮渗透率和扩散系数、溶解度系数却相应下降。","authors":[{"authorName":"杨继萍","id":"ac60d373-d1fa-4d9d-9c4f-ef66f1eaef4a","originalAuthorName":"杨继萍"},{"authorName":"黄鹏程","id":"4efb2981-6584-448e-8162-be2c08627686","originalAuthorName":"黄鹏程"}],"doi":"","fpage":"122","id":"f68f2a0b-deb2-4692-adee-bd137ee6a4f8","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"75e28093-610e-41c2-937b-9b2d8afa0051","keyword":"(甲基<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>+(<span style=\"color:red\">4-</span>乙烯基)吡啶)共聚物","originalKeyword":"(甲基丙烯酸丁酯+(4-乙烯基)吡啶)共聚物"},{"id":"128651fa-8ede-4520-aefa-c96adeacd22d","keyword":"乙烯基吡啶含量","originalKeyword":"乙烯基吡啶含量"},{"id":"945db821-2f02-45e5-8043-2e7aa5928a41","keyword":"富<span style=\"color:red\">氧</span>性能","originalKeyword":"富氧性能"}],"language":"zh","publisherId":"gfzclkxygc200103031","title":"<span style=\"color:red\">聚</span>(甲基<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>+(<span style=\"color:red\">4-</span>乙烯基)吡啶)共聚物膜的富<span style=\"color:red\">氧</span>性能研究","volume":"17","year":"2001"},{"abstractinfo":"由聚醚型<span style=\"color:red\">聚</span>丙<span style=\"color:red\">二</span>醇<span style=\"color:red\">二</span>缩水甘油醚和甲基<span style=\"color:red\">丙烯酸</span>合成了可光固化的<span style=\"color:red\">聚</span>丙<span style=\"color:red\">二</span>醇<span style=\"color:red\">二</span>缩水甘油醚<span style=\"color:red\">二甲基丙烯酸酯</span>(DMA),再按不同质量配比将此合成物与双<span style=\"color:red\">酚</span>A型环<span style=\"color:red\">氧</span>甲基<span style=\"color:red\">丙烯酸酯</span>(BEMA)混合,经紫外光照射得到复合光固化膜,然后对所得固化膜的耐热性、柔韧性、硬度、光泽度、可见光透过率和微观形貌进行表征.研究结果表明,复合膜兼具DMA和BEMA的优点,呈现良好的耐热性、柔韧性、硬度、光泽度和可见光透过率,而且DMA和BEMA相容性好.在所选的固化条件下,DMA和BEMA为5/5时,所得透明膜的T<,5%>和T<,50%>%可分别达291.2℃和433.6℃,并且柔韧性和硬度良好,光泽度达109.6.","authors":[{"authorName":"唐春怡","id":"35b9465d-bfa1-49bc-9c5b-f7740d60063c","originalAuthorName":"唐春怡"},{"authorName":"刘伟区","id":"8e9fdec7-5890-4f02-b961-33a71b6474bf","originalAuthorName":"刘伟区"}],"doi":"","fpage":"68","id":"0c9b4bc7-5434-4a44-b020-0925a52ad271","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"08fd21bb-8150-4122-89f5-f598c4162acb","keyword":"<span style=\"color:red\">聚</span>丙<span style=\"color:red\">二</span>醇<span style=\"color:red\">二</span>缩水甘油醚<span style=\"color:red\">二甲基丙烯酸酯</span>","originalKeyword":"聚丙二醇二缩水甘油醚二甲基丙烯酸酯"},{"id":"c37bdfe2-e05d-49fa-8b43-c89337eccfa3","keyword":"双<span style=\"color:red\">酚</span>A型环<span style=\"color:red\">氧</span>甲基<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"双酚A型环氧甲基丙烯酸酯"},{"id":"9c1b808e-342d-4e4f-a35f-d1385d644656","keyword":"光固化膜","originalKeyword":"光固化膜"}],"language":"zh","publisherId":"gfzclkxygc201102018","title":"聚醚/双<span style=\"color:red\">酚</span>A环<span style=\"color:red\">氧</span>甲基<span style=\"color:red\">丙烯酸酯</span>复合光固化膜的性能","volume":"27","year":"2011"},{"abstractinfo":"制备了阴离子型聚氨酯<span style=\"color:red\">丙烯酸酯</span>,并以此为乳化剂制备了甲基<span style=\"color:red\">丙烯</span>酰<span style=\"color:red\">氧</span>丙基三<span style=\"color:red\">甲</span><span style=\"color:red\">氧基</span>硅烷( MAPTMS)改性的双<span style=\"color:red\">酚</span>S环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸酯</span>(BPSA)/聚氨酯<span style=\"color:red\">丙烯酸酯</span>(PUA)水性涂料.FT - IR研究表明,该涂料可使用紫外光进行固化；差示扫描量热仪( DSC)及动态力学谱仪(DMA)等研究分析表明,自由基引发的非等温固化反应可用自催化(s)esták - Berggren(S-B)动力模型描述,该组分体系具有良好的相容性,MAPTMS的加入可改善涂膜的热性能,当硅烷偶联剂含量为8％时,玻璃化温度Tg达到最大,与纯组分相比提高了11.5℃.光固化涂层有很好的耐酸/碱性、附着力和硬度.","authors":[{"authorName":"朱风利","id":"1727c168-a208-47a3-9518-41a7a96ac8ad","originalAuthorName":"朱风利"},{"authorName":"高俊刚","id":"c9b3477e-afab-47fa-a50e-2404d27e451a","originalAuthorName":"高俊刚"},{"authorName":"杨建波","id":"9491869f-3dda-4c6a-a7a7-ce0f1546a149","originalAuthorName":"杨建波"},{"authorName":"刘孝谦","id":"a3ce8239-d054-415c-8ad0-d92366e0d726","originalAuthorName":"刘孝谦"}],"doi":"10.3969/j.issn.0253-4312.2012.11.003","fpage":"8","id":"0948fa6b-ceba-4943-8680-ebd3134e9c63","issue":"11","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"d564f473-9388-4934-ba3c-4a9b5716e1ec","keyword":"紫外光固化","originalKeyword":"紫外光固化"},{"id":"79d95dc0-47f9-42dc-bb2f-9b41c5bfc1e3","keyword":"聚氨酯<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"聚氨酯丙烯酸酯"},{"id":"2ba60d44-916c-4650-9070-bc6cedbb2d5a","keyword":"双<span style=\"color:red\">酚</span>-S环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"双酚-S环氧丙烯酸酯"},{"id":"0505b289-389b-4574-87ad-fe0f00f49141","keyword":"水性涂料","originalKeyword":"水性涂料"},{"id":"fc7b7701-e423-473d-a1ed-7db418ee268c","keyword":"固化动力学","originalKeyword":"固化动力学"}],"language":"zh","publisherId":"tlgy201211003","title":"硅<span style=\"color:red\">氧</span>烷改性双<span style=\"color:red\">酚</span>S环<span style=\"color:red\">氧</span><span style=\"color:red\">丙烯酸酯</span>/聚氨酯<span style=\"color:red\">丙烯酸酯</span>水性涂料的固化动力学与性能","volume":"42","year":"2012"},{"abstractinfo":"以DMF作溶剂,在四丁基氟化铵 (TBAF)存在下,对甲基苯基三<span style=\"color:red\">甲</span>硅基醚(1)和<span style=\"color:red\">4,4</span>'-<span style=\"color:red\">二</span>氯<span style=\"color:red\">二</span>苯砜(2)于100 ℃反应1 h,合成了<span style=\"color:red\">4,4</span>'-<span style=\"color:red\">二</span>(<span style=\"color:red\">4-</span>甲基苯<span style=\"color:red\">氧基</span>)<span style=\"color:red\">二</span>苯砜(3),产率为92%;加入催化量的N-溴代丁<span style=\"color:red\">二</span>酰亚胺(NBS)并在光照条件下,与氧气反应得到中间体-<span style=\"color:red\">4,4</span>'-<span style=\"color:red\">二</span>(<span style=\"color:red\">4-</span>羧基苯<span style=\"color:red\">氧基</span>)<span style=\"color:red\">二</span>苯砜(<span style=\"color:red\">4</span>),其产率达90%;将化合物<span style=\"color:red\">4</span>与<span style=\"color:red\">二</span>氯亚砜反应合成目标产物<span style=\"color:red\">4,4</span>'-<span style=\"color:red\">二</span>(<span style=\"color:red\">4-</span>氯<span style=\"color:red\">甲</span>酰基苯<span style=\"color:red\">氧基</span>)<span style=\"color:red\">二</span>苯砜(5),总收率为74.5%(以对甲基苯基三<span style=\"color:red\">甲</span>硅基醚为基准计算).","authors":[{"authorName":"黄振钟","id":"2b35d8a7-0015-4415-abc4-44d1cb58d824","originalAuthorName":"黄振钟"},{"authorName":"霍毅","id":"3db00dca-4aca-4f07-a3a3-45bf0b000129","originalAuthorName":"霍毅"},{"authorName":"罗秋燕","id":"9aebb808-e8c0-4b0a-abf0-c1b0be35bb7e","originalAuthorName":"罗秋燕"},{"authorName":"刘卓","id":"b756e243-dc43-4659-8843-452946312584","originalAuthorName":"刘卓"},{"authorName":"盛寿日","id":"1580cc88-d9c5-4bbb-8fbd-e36797a992dc","originalAuthorName":"盛寿日"}],"doi":"10.3969/j.issn.1000-0518.2007.08.013","fpage":"917","id":"ea9c6c7f-4283-4583-b7b0-b2b4bdcbaf39","issue":"8","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"b4803760-369e-4c20-9f98-0f6a6bc3fc58","keyword":"对甲基苯基三<span style=\"color:red\">甲</span>硅基醚","originalKeyword":"对甲基苯基三甲硅基醚"},{"id":"287fc71e-97d1-4124-841e-a7b3396c0c22","keyword":"<span style=\"color:red\">二</span>氯<span style=\"color:red\">二</span>苯砜","originalKeyword":"二氯二苯砜"},{"id":"8e5e150d-e3ac-4338-a550-17ead5aac7b0","keyword":"<span style=\"color:red\">二</span>(氯<span style=\"color:red\">甲</span>酰基苯<span style=\"color:red\">氧基</span>)<span style=\"color:red\">二</span>苯砜","originalKeyword":"二(氯甲酰基苯氧基)二苯砜"},{"id":"ddd952a9-bf50-4dc0-92a1-241cd2e5b990","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"yyhx200708013","title":"<span style=\"color:red\">4,4</span>'-<span style=\"color:red\">二</span>(<span style=\"color:red\">4-</span>氯<span style=\"color:red\">甲</span>酰苯<span style=\"color:red\">氧基</span>)<span style=\"color:red\">二</span>苯砜的合成","volume":"24","year":"2007"},{"abstractinfo":"以<span style=\"color:red\">4-</span>硝基邻苯<span style=\"color:red\">二甲</span>腈和苯酚为原料,DMSO为溶剂,在K2CO3存在下80℃进行硝基亲核取代反应制得了<span style=\"color:red\">4-</span>苯<span style=\"color:red\">氧基</span>邻苯<span style=\"color:red\">二甲</span>腈化合物.反应过程中采取两步法合成,首先使苯酚和K2CO3反应生成<span style=\"color:red\">酚</span>盐,然后再与<span style=\"color:red\">4-</span>硝基邻苯<span style=\"color:red\">二甲</span>腈反应生成目标产物.该反应过程平稳,产物经重结晶提纯后,收率为97.7%,熔点为102～103℃.傅里叶红外光谱和核磁共振氢谱的测定结果证明了产物的分子结构.","authors":[{"authorName":"王海静","id":"f394c625-4294-48ed-9932-a267df4dafd6","originalAuthorName":"王海静"},{"authorName":"雷毅","id":"e5d02bcf-99cd-455c-bc03-3c8d24ba0d88","originalAuthorName":"雷毅"},{"authorName":"杨刚","id":"1a18d0d5-f3a2-4a48-9f9f-31d0b2ccce4f","originalAuthorName":"杨刚"}],"doi":"10.3969/j.issn.1007-2330.2005.02.007","fpage":"25","id":"78c28b74-f207-40ed-b220-18011899e6cd","issue":"2","journal":{"abbrevTitle":"YHCLGY","coverImgSrc":"journal/img/cover/YHCLGY.jpg","id":"77","issnPpub":"1007-2330","publisherId":"YHCLGY","title":"宇航材料工艺   "},"keywords":[{"id":"09bbabfe-f1f0-4aae-8ecd-70d913bb156a","keyword":"硝基亲核取代","originalKeyword":"硝基亲核取代"},{"id":"8e37a0c6-ae18-417c-9b8d-b154d5c3f8b3","keyword":"<span style=\"color:red\">4-</span>硝基邻苯<span style=\"color:red\">二甲</span>腈","originalKeyword":"4-硝基邻苯二甲腈"},{"id":"913b1d8e-2e28-4d5d-8238-51ebf72a9ca6","keyword":"<span style=\"color:red\">4-</span>苯<span style=\"color:red\">氧基</span>邻苯<span style=\"color:red\">二甲</span>腈","originalKeyword":"4-苯氧基邻苯二甲腈"}],"language":"zh","publisherId":"yhclgy200502007","title":"<span style=\"color:red\">4-</span>苯<span style=\"color:red\">氧基</span>邻苯<span style=\"color:red\">二甲</span>腈的合成研究","volume":"35","year":"2005"}],"totalpage":7933,"totalrecord":79328}