{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用共沉淀法合成了不同摩尔比的碳酸根型<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>.用X-射线粉末衍射、红外光谱、BET法对它们进行了表征,还测定了四元CuCoMgAl<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>和二元MgAl<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>对氮氧化物(NOx)的吸附性能.结果表明,成功合成的n(Cu):n(Co):n(Mg):n(Al)摩尔比分别为1:1:1:1、1:3:2:2、3:1:2:2的复合氧化物都具有<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>结构,且晶相完整、结晶度高;随着Co含量增加,<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>层间高度略有增加.红外光谱分析结果表明羟基和碳酸根被插入到<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>层间结构.四元CuCOMgAl-HTlcs对NOx吸附性能明显优于二元的Mg3Al-HTlcs,而Cu1.13Co1.07Mg0.94Al-HTlcs对NOx的吸附性能优于其它四元的CuCOMgAl-HTlcs.Cu0.5Co1.55Mg0.95Al-HTlcs和Cu1.57Co0.56MgAl-HTlcs的吸附容量分别为2400、1770 mg/g.","authors":[{"authorName":"曹根庭","id":"afa78afc-6589-4045-8d42-ef4c02e75c98","originalAuthorName":"曹根庭"},{"authorName":"邢方方","id":"3492f081-5a98-4892-ac9e-295d41c366fc","originalAuthorName":"邢方方"},{"authorName":"方彩萍","id":"49bba474-f43b-4541-97da-65b7acce71eb","originalAuthorName":"方彩萍"},{"authorName":"倪哲明","id":"30d7b2a7-dfd6-48c2-977a-f7b8a2984982","originalAuthorName":"倪哲明"}],"doi":"","fpage":"406","id":"eba635a0-76ab-4ca2-9d83-cb157e29ca99","issue":"z2","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"3160696a-c817-4f3d-9816-2d5f33a5b951","keyword":"<span style=\"color:red\">铜</span><span style=\"color:red\">钴</span><span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"铜钴镁铝类水滑石"},{"id":"6084d012-c38e-41ba-aa2f-382037e6be8e","keyword":"制备","originalKeyword":"制备"},{"id":"6a4214e6-c880-4be4-9cfc-edb2e5536680","keyword":"表征","originalKeyword":"表征"},{"id":"be59e2ae-5bff-4785-b2f8-4773890d104b","keyword":"吸附","originalKeyword":"吸附"}],"language":"zh","publisherId":"xyjsclygc2008z2107","title":"<span style=\"color:red\">铜</span><span style=\"color:red\">钴</span><span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>的合成、表征及对NOx吸附性能的研究","volume":"37","year":"2008"},{"abstractinfo":"采用共沉淀法制备了不同Co2AlMgx(x=0.5、1、1.5和2)原子比的<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>,用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)、表面孔吸附(BET)及电感耦合等离子光谱(ICP)等技术手段表征了催化剂的结构、组成和比表面积,并考察了其催化苯甲醇选择氧化制苯甲醛的性能.结果表明,随着Mg含量的增加,催化剂的碱性增强,苯甲醛的选择性提高.在优化条件:苯甲醇0.02 mol,催化剂Co2AlMg1<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>100 mg,过氧化氢叔丁醇0.04 mol,溶剂乙腈8 mL,反应温度60℃,反应时间9h下,苯甲醇的转化率为39.5％,苯甲醛的选择性达到89.2％.催化剂重复使用5次后其活性与选择性未见明显降低,表明催化剂具有较好的稳定性.","authors":[{"authorName":"刘杰","id":"5c043502-7d85-4d39-b377-3bed3f364f00","originalAuthorName":"刘杰"},{"authorName":"周维友","id":"60869af5-2096-4b82-8d54-8ee1ca0388b5","originalAuthorName":"周维友"},{"authorName":"吴中","id":"cb602468-a483-4037-975b-f799a0b4d9ab","originalAuthorName":"吴中"},{"authorName":"孙富安","id":"b7d710e7-b542-4125-add5-9d74e5c8e46a","originalAuthorName":"孙富安"},{"authorName":"何明阳","id":"a8645ab8-bb7e-4654-9ac4-d37c6fab6e14","originalAuthorName":"何明阳"},{"authorName":"陈群","id":"2e672a67-e754-43b7-a380-a208f2a815bd","originalAuthorName":"陈群"}],"doi":"10.11944/j.issn.1000-0518.2015.09.150028","fpage":"1033","id":"75511291-a7a6-4e86-9baa-9d6893f57731","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"ffe7164d-f2a2-4db3-a965-d26e8279c7c9","keyword":"<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"类水滑石"},{"id":"a36e9a5c-b9e0-430a-95c1-591d9f9583a4","keyword":"碱性","originalKeyword":"碱性"},{"id":"4b9af945-ddd8-41c5-88cf-0bb3159e0394","keyword":"苯甲醇","originalKeyword":"苯甲醇"},{"id":"4bc4709e-4638-4f3d-8ad8-7554ce2966ce","keyword":"选择性氧化","originalKeyword":"选择性氧化"},{"id":"5a17abb3-9c19-494d-86fc-81e64b229421","keyword":"苯甲醛","originalKeyword":"苯甲醛"}],"language":"zh","publisherId":"yyhx201509009","title":"<span style=\"color:red\">钴</span><span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>液相选择性催化苯甲醇氧化合成苯甲醛","volume":"32","year":"2015"},{"abstractinfo":"采用氧化吸附法制备了硝酸根型<span style=\"color:red\">铜</span>铁<span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>,借助XRD、FTIR、SEM等分析手段研究了样品的结构、形貌及形成机理.结果表明:存在水蒸气的条件下,以碳酸根型<span style=\"color:red\">铜</span>铁<span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>为前驱体经过500℃焙烧得到的<span style=\"color:red\">铜</span>铁<span style=\"color:red\">铝</span>复合氧化物可以氧化吸附NO2,生成Cu(NO3)2.上述样品在干燥器中放置9 d后转化成直径约为5 μm的硝酸根型<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>.此外,<span style=\"color:red\">铜</span>铁<span style=\"color:red\">铝</span>复合氧化物吸附NO2、H2O和O2后也可直接转化成硝酸根型<span style=\"color:red\">铜</span>铁<span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>,不存在中间相Cu(NO3)2.本文提出的氧化吸附法为制备<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>提供了一种新途径.","authors":[{"authorName":"郭亚平","id":"c2c076d6-83ce-4c21-9d9b-d8af98611bc0","originalAuthorName":"郭亚平"},{"authorName":"吕君英","id":"ff67d5d9-dab3-43a1-a05d-6b341741df59","originalAuthorName":"吕君英"},{"authorName":"龚凡","id":"a5ffa2bd-eac2-4371-93b4-4c16eaf63669","originalAuthorName":"龚凡"}],"doi":"","fpage":"821","id":"ec37bb46-1bb5-43ba-9cf6-8ac0af9ca5c8","issue":"6","journal":{"abbrevTitle":"CLKXYGY","coverImgSrc":"journal/img/cover/CLKXYGY.jpg","id":"14","issnPpub":"1005-0299","publisherId":"CLKXYGY","title":"材料科学与工艺"},"keywords":[{"id":"5c6ee54f-49f0-40b3-9e7f-1d31170b1d9a","keyword":"<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"类水滑石"},{"id":"1bc10771-c777-466d-938e-3a3f39b799fb","keyword":"复合金属氧化物","originalKeyword":"复合金属氧化物"},{"id":"6a5f8508-e473-4691-8a6d-4a569cbbcfa9","keyword":"氧化吸附","originalKeyword":"氧化吸附"},{"id":"9b7cbe5c-2c38-4c61-9085-8dda8d19905e","keyword":"机理","originalKeyword":"机理"},{"id":"1a6d5438-5730-467d-a5f0-d1c5fe03409e","keyword":"NO2","originalKeyword":"NO2"}],"language":"zh","publisherId":"clkxygy200806021","title":"氧化吸附法合成硝酸根型<span style=\"color:red\">铜</span>铁<span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","volume":"16","year":"2008"},{"abstractinfo":"以锌、<span style=\"color:red\">镁</span>、<span style=\"color:red\">铝</span>的水合硝酸盐及尿素等为主要原料,通过水热合成法制备具有层状结构的锌<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>(ZnMgAl-HTLCs).采用XRD、SEM、FT-IR及MP-AES等对样品的晶体结构、微观形貌、元素组成及材料表面性质等进行了表征分析.考察了锌的掺杂量、尿素浓度、二价三价金属离子比和溶剂等因素对<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>结构及形貌的影响.结果表明,M2 +/M3为4.5∶1 ～6∶1,锌的掺入比例在10％～30％之间,尿素的浓度为0.54 ～0.61 mol/L,时间为24h,可以得到结构单一和形貌较好的锌<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>.","authors":[{"authorName":"袁东","id":"dac8ba26-657c-403e-a6bd-0b6f7114ba50","originalAuthorName":"袁东"},{"authorName":"周良芹","id":"c8175866-b2e2-4ac6-bccf-86e38b4e0e16","originalAuthorName":"周良芹"}],"doi":"","fpage":"748","id":"a907f5c4-6e7e-41b0-9cb6-88f98b8ae730","issue":"3","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"a0dd8e20-1858-438b-abd4-d7a7d34acb75","keyword":"<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"类水滑石"},{"id":"104cce33-79d4-4833-8615-527e99f6f248","keyword":"<span style=\"color:red\">水</span>热合成法","originalKeyword":"水热合成法"},{"id":"3a39fafd-ccfc-4e1b-a2f1-3837140b26e7","keyword":"锌<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span>复合物","originalKeyword":"锌镁铝复合物"},{"id":"08a01433-12b0-479d-9935-2604f7f5a341","keyword":"层状双氢氧化物","originalKeyword":"层状双氢氧化物"}],"language":"zh","publisherId":"gsytb201603015","title":"锌<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>的制备与表征研究","volume":"35","year":"2016"},{"abstractinfo":"通过共沉淀法制备了Mg/Al物质的量比为3∶1的<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>,并将其作为载体负载磺化酞菁<span style=\"color:red\">钴</span>制得新型功能材料酞菁<span style=\"color:red\">钴</span>负载<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>(CoPcTs-LDH).通过红外和热重分析表征了CoPcTs-LDH,研究了CoPcTs-LDH/H2O2对100mL 10mg/L甲基橙的氧化脱色.实验结果表明,在25～37℃、pH值为3～9、反应7h后甲基橙的剩余率均低于30％；反应过程符合一级动力学模型,阿伦尼乌斯活化能Ea =57.64kJ/mol；反应过程中羟基自由基发挥了重要作用；CoPcTs-LDH在重复使用5次后对甲基橙仍有很好的氧化脱色能力,具有较高的重复使用性能.","authors":[{"authorName":"徐敏虹","id":"52169d33-e20b-4c5c-9909-44efca775fcd","originalAuthorName":"徐敏虹"},{"authorName":"潘国祥","id":"8a7cbd40-6404-4b3c-a06e-b274cf44bb28","originalAuthorName":"潘国祥"},{"authorName":"陈海锋","id":"0647f16a-13f4-4a60-9901-2b9a8e102fdb","originalAuthorName":"陈海锋"},{"authorName":"曹枫","id":"d595ab25-8b1a-49a6-aa13-7e542d0312e2","originalAuthorName":"曹枫"},{"authorName":"唐培松","id":"137d9fad-8577-4101-a208-e9bbe214fe1f","originalAuthorName":"唐培松"},{"authorName":"陈文兴","id":"ab2018ea-688b-43b9-ba0c-26fa97138b04","originalAuthorName":"陈文兴"}],"doi":"","fpage":"82","id":"3a4b2f65-94bc-4aee-af8d-3181a946badc","issue":"16","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"ad4ea652-7fe9-4867-b8f2-411a3acb0d7e","keyword":"酞菁<span style=\"color:red\">钴</span>","originalKeyword":"酞菁钴"},{"id":"e0c3f1a7-953b-4f09-b6ba-42f3e578f3b1","keyword":"<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"镁铝水滑石"},{"id":"90dafa8a-eb71-48cd-af08-762b3a3cc607","keyword":"甲基橙","originalKeyword":"甲基橙"},{"id":"79ee0caa-ddf2-47cd-b24a-e446ccf8b1de","keyword":"氧化脱色","originalKeyword":"氧化脱色"}],"language":"zh","publisherId":"cldb201116022","title":"酞菁<span style=\"color:red\">钴</span>负载<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>对甲基橙的氧化脱色","volume":"25","year":"2011"},{"abstractinfo":"采用液相非稳态共沉淀法制备了<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>(Mg-Al HTlc),并研究了邻、间和对甲基苯酚在Mg-Al HTlc上的吸附行为.结果表明,邻、间和对甲基苯酚在Mg-Al HTlc上的吸附等温方程均符合Freundlich 吸附等温式；吸附动力学均符合准二级动力学方程；在实验范围内,Mg-Al HTlc对三者的吸附量为:对甲基苯酚＞邻甲基苯酚＞间甲基苯酚；在pH值5.00～13.00范围内,三者的吸附量均随pH值的增加先增大后减小、随温度升高和电解质(NaCl)浓度的增大而增大.探讨了吸附机理和苯环上甲基取代基位置对吸附的影响.","authors":[{"authorName":"李燕","id":"357a3b2a-211b-4bf5-a072-c48210aa1727","originalAuthorName":"李燕"},{"authorName":"沈建强","id":"ea2b9b36-42c0-4ae0-acce-f0d99772a773","originalAuthorName":"沈建强"},{"authorName":"杨国庆","id":"cb600102-c1ae-4989-bfc9-f4ca9258a845","originalAuthorName":"杨国庆"}],"doi":"10.3724/SP.J.1095.2012.00343","fpage":"788","id":"0fc132f4-8584-4b64-8910-11850332d5f7","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"9e4f1362-053f-482a-89d3-1ab59de13407","keyword":"<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"类水滑石"},{"id":"6febce53-6978-4193-b793-c36a6edb78ef","keyword":"甲基苯酚","originalKeyword":"甲基苯酚"},{"id":"3b0a6c77-447c-43da-bc73-019eb8dfb144","keyword":"吸附","originalKeyword":"吸附"},{"id":"40bd7296-b3e5-43b5-8bd2-9faeeae049ee","keyword":"甲基位置","originalKeyword":"甲基位置"}],"language":"zh","publisherId":"yyhx201207011","title":"<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>对邻、间、对甲基苯酚的吸附","volume":"29","year":"2012"},{"abstractinfo":"以Cr(Ⅵ)、对甲基苯酚为代表污染物,用实验室模拟法研究了<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>(Mg-Al HTlc)对Cr(Ⅵ)的吸附行为.结果表明,在Mg-Al HTlc/Cr(Ⅵ)/对甲基苯酚体系中,吸附动力学和热力学分别符合准二级动力学方程和Langmuir吸附等温式；溶液中共存的对甲基苯酚会延缓Mg-Al HTlc对Cr(Ⅵ)的吸附速率,但会增加其对Cr(Ⅵ)的吸附量.一方面,Cr(Ⅵ)与对甲基苯酚产生竞争吸附,竞争作用的大小和溶液中对甲基苯酚与Cr(Ⅵ)的浓度比有关；另一方面,Mg-Al HTlc对对甲基苯酚的吸附可降低体系pH值,增加Cr(Ⅵ)的吸附量,随Cr(Ⅵ)初始浓度的增加,酚离子的竞争能力相对减弱,当Cr(Ⅵ)与对甲基苯酚的质量浓度比大于3时,Cr(Ⅵ)的吸附量增加显著,去除率增强.体系温度升高使Cr(Ⅵ)的吸附量降低.","authors":[{"authorName":"李燕","id":"562d9b26-5ea1-4611-9461-cfa883c5130c","originalAuthorName":"李燕"},{"authorName":"冀勇","id":"f4a7cc5b-ecce-46c2-aa17-e1167f310204","originalAuthorName":"冀勇"}],"doi":"10.3724/SP.J.1095.2013.20361","fpage":"932","id":"fee6bdf3-07ea-4bbe-9985-25fb700a85e7","issue":"8","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"ba1c20e8-3f63-473b-91b1-56801efa5bf2","keyword":"<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"类水滑石"},{"id":"75a53373-8cbd-4900-aad9-16238f433e2f","keyword":"Cr(Ⅵ)","originalKeyword":"Cr(Ⅵ)"},{"id":"f6393021-577a-46a8-99f9-45301b811238","keyword":"对甲基苯酚","originalKeyword":"对甲基苯酚"},{"id":"723d3868-5db5-41d5-acd8-7eeea8a5b9fb","keyword":"吸附","originalKeyword":"吸附"}],"language":"zh","publisherId":"yyhx201308014","title":"<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>在Cr(Ⅵ)和对甲基苯酚复合污染中的吸附","volume":"30","year":"2013"},{"abstractinfo":"采用水热合成法制备了锌<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>（ ZnMgAl-HTLC），利用 X 射线衍射仪（ XRD）对 ZnMgAl-HTLC 的晶体结构进行了表征，并以一系列非极性和极性分子为探针分子，采用反气相色谱法（ IGC）研究了 ZnMgAl-HTLC 的表面性能。结果表明：XRD特征衍射峰窄、尖、高，<span style=\"color:red\">水</span>热合成法能够制得纯度较高的 ZnMgAl-HTLC；ZnMgAl-HTLC表面吸附自由能小于零，表面色散自由能最大为6.02 mJ／m2，酸碱作用自由能最大为5.33 kJ／mol，吸附焓为43.6 kJ／mol，吸附熵为0.15 kJ／mol。本文的反气相色谱方法对研究锌<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>的表面性能具有重要的指导意义。","authors":[{"authorName":"周良芹","id":"d9ed3a13-3df5-4ce5-ae0b-b5969c7dc03f","originalAuthorName":"周良芹"},{"authorName":"付大友","id":"2ce6f67a-e19d-4684-89e0-23a3e34aee8c","originalAuthorName":"付大友"},{"authorName":"袁东","id":"0d004f45-c386-4bc3-abd6-677e3ac79820","originalAuthorName":"袁东"},{"authorName":"范金龙","id":"7e22fa8b-b746-4ed8-9694-778e65d1686b","originalAuthorName":"范金龙"},{"authorName":"谭文渊","id":"dcc0239d-30f5-4dd2-b466-7b1949042db2","originalAuthorName":"谭文渊"}],"doi":"10.3724/SP.J.1123.2014.07032","fpage":"96","id":"323dd819-e7e7-42ca-a164-b5d05d34a9c2","issue":"1","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"0e44ee9d-53be-4bb7-9d1e-6cb176e2f6f8","keyword":"反气相色谱","originalKeyword":"反气相色谱"},{"id":"d736cb1e-c25a-4bc6-b170-91a745f661f7","keyword":"锌<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"锌镁铝类水滑石"},{"id":"097a2e3d-df66-46f1-9ccf-a7da77555672","keyword":"表面性能","originalKeyword":"表面性能"}],"language":"zh","publisherId":"sp201501018","title":"反气相色谱法测定锌<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>的表面性能","volume":"","year":"2015"},{"abstractinfo":"采用共沉淀法制备了硬脂酸柱撑<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span>镧三元<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>,采用X射线衍射(XRD)分析、红外光谱(FT-IR)分析及热重分析(TGA)对其进行表征.利用刚果红法、转矩流变仪研究了其对PVC热稳定性能的影响及与其他热稳定助剂的协同效果,并通过紫外光谱初步分析了热稳定机理.结果表明,硬脂酸柱撑<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span>镧<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>的长期热稳定性较好,与季戊四醇存在明显的协同效应.当上述两者等质量比复配后可使PVC静态稳定时间达到73 min,动态热稳定时间达到2411 s,扭矩适中,能够提高PVC的热稳定性能和加工性能.","authors":[{"authorName":"李先铭","id":"5b65ce35-fbe4-40f7-88af-b44ad4750c73","originalAuthorName":"李先铭"},{"authorName":"张宁","id":"c5e3c9ed-f7c3-46ab-9e9a-f2271bf68045","originalAuthorName":"张宁"}],"doi":"","fpage":"1690","id":"9cd1f9c5-3f8c-45e0-9ed6-0e814aec6332","issue":"6","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"7c7e3e0d-d2ad-4c57-8601-e3a3c16cb981","keyword":"聚氯乙烯","originalKeyword":"聚氯乙烯"},{"id":"db34f56a-0e46-4ed5-a217-d71a36ed95b4","keyword":"柱撑<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"柱撑水滑石"},{"id":"ed085c1c-6a12-4871-99c5-7c57f043af5f","keyword":"稀土","originalKeyword":"稀土"},{"id":"7cdd9b5f-63fd-4bb8-bdc1-e0801bc7d993","keyword":"热稳定剂","originalKeyword":"热稳定剂"},{"id":"30c529d7-cff1-479e-a97c-ccbabe38e068","keyword":"硬脂酸","originalKeyword":"硬脂酸"}],"language":"zh","publisherId":"gsytb201506044","title":"硬脂酸柱撑<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span>镧<span style=\"color:red\">类</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>的制备及其在PVC中的应用","volume":"34","year":"2015"},{"abstractinfo":"采用共沉淀法合成了不同摩尔投料比(Mg/Al/Cu)的碳酸根型<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>,用X-射线、红外光谱、热重-差热分析对<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>进行了表征,测定对NOx的吸附性能.结果表明,Mg/Al/Cu摩尔比为2.5∶1∶0.5,2∶1∶1,1∶1∶2时合成的复合氧化物中都具有\"feitknecht\"结构.热重-差热分析结果显示合成样品的分解均有两个过程,掺入<span style=\"color:red\">铜</span>量少,热稳定性高.Mg/Al/Cu为2.5∶1∶0.5的<span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>对氮氧化物的吸附容量为1484.4mg/g.","authors":[{"authorName":"俞卫华","id":"082c7b04-e7dd-4024-b759-816e80fef2b3","originalAuthorName":"俞卫华"},{"authorName":"倪哲明","id":"dc33c480-9339-4e8d-bd30-9845bb7a6525","originalAuthorName":"倪哲明"},{"authorName":"王力耕","id":"b8815b58-c903-4286-86ab-f2a4bfd3355a","originalAuthorName":"王力耕"},{"authorName":"王海滨","id":"69db2c32-622f-4e73-a51e-63f1a30f2d62","originalAuthorName":"王海滨"},{"authorName":"周春晖","id":"2eb43d78-da92-4258-8bd4-9b897c7b8044","originalAuthorName":"周春晖"},{"authorName":"葛忠华","id":"b5594957-6e6f-434a-bab8-d7a9bcfd6f25","originalAuthorName":"葛忠华"}],"doi":"10.3969/j.issn.1673-2812.2003.05.024","fpage":"717","id":"80611ef4-a68b-4699-ba55-42f53ae09c4e","issue":"5","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"813db5ce-9325-4371-97f5-59e545f9c1a4","keyword":"<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">铜</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>","originalKeyword":"镁铝铜水滑石"},{"id":"4045afdf-ee2d-4e9b-87ae-ab14fc903e23","keyword":"表征","originalKeyword":"表征"},{"id":"7abb83b6-6135-4d71-8979-4d5b942a0f9c","keyword":"吸附","originalKeyword":"吸附"}],"language":"zh","publisherId":"clkxygc200305024","title":"<span style=\"color:red\">镁</span><span style=\"color:red\">铝</span><span style=\"color:red\">铜</span><span style=\"color:red\">水</span><span style=\"color:red\">滑石</span>的合成、表征及性能研究","volume":"21","year":"2003"}],"totalpage":3342,"totalrecord":33414}