{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>作为一种重要的芳香<span style=\"color:red\">二</span><span style=\"color:red\">胺</span>类聚合物,因其大分子结构中含有较多的活性自由氨基和亚胺基而具有多功能性.根据国内外最新文献,系统论述了<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>的合成方法和分子链结构.指出<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>具有优异的酶固定功能、离子的高选择透过性、金属防腐性、重金属离子吸附性等多种功能性.","authors":[{"authorName":"黄美荣","id":"be5a64ca-09c7-47fa-9505-b3d770455465","originalAuthorName":"黄美荣"},{"authorName":"马小立","id":"26d0bf95-cad9-470f-882f-1d385388f8b4","originalAuthorName":"马小立"},{"authorName":"李新贵","id":"6cb872c0-d22b-4617-8638-8763fa6ad532","originalAuthorName":"李新贵"}],"doi":"","fpage":"9","id":"1a6306ef-9de5-4a67-945c-1f8ad573a258","issue":"1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"72fe223f-255a-46fc-836b-2caf5f862645","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>","originalKeyword":"聚邻苯二胺"},{"id":"afd0b835-9149-4705-9a96-ba9b7dcef30d","keyword":"电化学聚合","originalKeyword":"电化学聚合"},{"id":"1953a347-623d-40ce-b3d1-439bd964ad8b","keyword":"化学氧化聚合","originalKeyword":"化学氧化聚合"},{"id":"22eb55de-b8f7-4424-89a7-90c869b9f3ef","keyword":"功能性","originalKeyword":"功能性"}],"language":"zh","publisherId":"gncl200801003","title":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>的合成及多功能性","volume":"39","year":"2008"},{"abstractinfo":"在NaOH碱性条件下利用循环伏安法于不锈钢表面上制备了<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>薄膜，并对其在不锈钢表面上的电化学行为进行了研究.结果表明，该膜呈棕色，且表面均匀，与基底附着力强；在3%NaCl 溶液中的极化曲线表明<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>薄膜在一定程度上能有效提高不锈钢表面的耐蚀性能；在碱性介质中制备的<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>膜显示出一定的电活性，且随着NaOH浓度的提高，其电活性也有一定的提高.\n","authors":[{"authorName":"沈艺程","id":"0ad7352b-245d-4ca5-8645-e636cecdc689","originalAuthorName":"沈艺程"},{"authorName":"辜志俊","id":"38e06c8a-f70a-4553-b72a-003b5a010eb1","originalAuthorName":"辜志俊"},{"authorName":"陈衍珍","id":"92026ad1-380f-49bf-ad96-b1c9cae57d3a","originalAuthorName":"陈衍珍"},{"authorName":"郭琦龙","id":"346bb290-19e0-4430-87dc-f9d8c927c24d","originalAuthorName":"郭琦龙"},{"authorName":"赵雄超","id":"fda35f6f-a7a3-488c-9a62-383d6b14ebbf","originalAuthorName":"赵雄超"},{"authorName":"洪艳萍","id":"940297cc-b1a8-40aa-8482-c580702885d9","originalAuthorName":"洪艳萍"}],"categoryName":"|","doi":"","fpage":"460","id":"530c1f67-e076-40c7-8e41-a9af90602261","issue":"增刊","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"69a90a4c-b191-4876-9863-2f854727182e","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>","originalKeyword":"聚邻苯二胺"},{"id":"b5d37850-2cd2-4b16-8cfb-0d8214cf0588","keyword":"null","originalKeyword":"null"},{"id":"297b70ea-bc61-40d4-8a87-3396b4c98568","keyword":"null","originalKeyword":"null"},{"id":"947cfd45-b551-4a25-81b2-4a6998d90b81","keyword":"null","originalKeyword":"null"}],"language":"zh","publisherId":"1002-6495_2005_增刊_9","title":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>膜在不锈钢表面上的电化学行为研究","volume":"17","year":"2005"},{"abstractinfo":"在NaOH碱性条件下利用循环伏安法于不锈钢表面上制备了<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>薄膜,并对其在不锈钢表面上的电化学行为进行了研究.结果表明,该膜呈棕色,且表面均匀,与基底附着力强;在3%NaCl溶液中的极化曲线表明<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>薄膜在一定程度上能有效提高不锈钢表面的耐蚀性能;在碱性介质中制备的<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>膜显示出一定的电活性,且随着NaOH浓度的提高,其电活性也有一定的提高.","authors":[{"authorName":"沈艺程","id":"fe898f51-1e86-4a42-8e5f-b5c8f09829d8","originalAuthorName":"沈艺程"},{"authorName":"辜志俊","id":"db2577cf-3d25-4de1-b67a-47079024739b","originalAuthorName":"辜志俊"},{"authorName":"陈衍珍","id":"3ef8e40d-e0b0-45c8-b78c-5a1b44040090","originalAuthorName":"陈衍珍"},{"authorName":"郭琦龙","id":"1fe558ae-8160-4ab5-a6a6-fe2a832f2953","originalAuthorName":"郭琦龙"},{"authorName":"赵雄超","id":"8b7e5298-553c-47ca-8538-c86c89d38061","originalAuthorName":"赵雄超"},{"authorName":"洪艳萍","id":"12efde5e-5a1f-4d76-8475-47578a18e1be","originalAuthorName":"洪艳萍"}],"doi":"10.3969/j.issn.1002-6495.2005.z1.003","fpage":"460","id":"be4aa736-dae0-40a0-943f-6a7f5cb8c5c7","issue":"z1","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"d50d3ad5-2488-4091-bc35-b8f0cb7bd1b5","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>","originalKeyword":"聚邻苯二胺"},{"id":"a3b5aa20-7b68-46ec-a9b5-58868408b892","keyword":"不锈钢","originalKeyword":"不锈钢"},{"id":"97cb7260-2766-432e-94e4-ee7068032fba","keyword":"耐蚀性","originalKeyword":"耐蚀性"},{"id":"76c671d5-8766-460e-ada2-d7f504da16d7","keyword":"NaOH","originalKeyword":"NaOH"}],"language":"zh","publisherId":"fskxyfhjs2005z1003","title":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>膜在不锈钢表面上的电化学行为研究","volume":"17","year":"2005"},{"abstractinfo":"首次使用固相法制备出<span style=\"color:red\">聚</span>对<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>和<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>纳米粒子.利用红外光谱(FT-IR),电子扫描显微镜(SEM),X射线衍射(XRD)等测试方法,对聚合物进行了表征.结果表明, 固相法合成的<span style=\"color:red\">聚</span>对<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>和<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>粒子直径为30 nm～40 nm,大小均匀,聚合物分子链排列有序,晶化率较好.且采用循环伏安法对<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>电活性进行了测试,结果表明,<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>有较好的电化学活性.","authors":[{"authorName":"吐尔逊·阿布都热依木","id":"addb37bd-90c9-4a4a-9525-8ab8e9c68107","originalAuthorName":"吐尔逊·阿布都热依木"},{"authorName":"张校刚","id":"b47b91c9-7080-43cd-b683-9d5684d011e8","originalAuthorName":"张校刚"}],"doi":"","fpage":"110","id":"4d22d627-993e-4264-80a5-9281790a0797","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"abe52899-4f98-447b-bf96-fb11e4762a5a","keyword":"固相反应法","originalKeyword":"固相反应法"},{"id":"24bb57a0-0898-47c7-8427-2779bd113227","keyword":"导电聚合物","originalKeyword":"导电聚合物"},{"id":"01eb0c9d-63b0-46e0-bf19-d1ea8aa6af1f","keyword":"纳米级","originalKeyword":"纳米级"}],"language":"zh","publisherId":"gfzclkxygc200501026","title":"固相法制备纳米级<span style=\"color:red\">聚</span>对<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>和<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>","volume":"21","year":"2005"},{"abstractinfo":"用乳液共混插层法制备了<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>/蒙脱土纳米复合材料微粒,通过IR、XRD及TEM对其结构进行了表征.结果发现,<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>插入蒙脱土层间聚合后,导致蒙脱土片层之间的剥离,形成纳米复合材料.将其分散在甲基硅油中(体积分数,22%)配制成无水电流变液,该复合材料表现出较大的协同效应,具有较好的电流变行为.实验结果表明在外加电场下,其电流变效应比<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>、蒙脱土均有显著提高.在3 kV/mm(DC,74.5 s-1)时,剪切强度达8.27 kPa;同时抗沉降性极好,静置60 d沉淀率小于3%.介电性能测试表明,<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>/蒙脱土纳米颗粒的介电常数和介电损耗较蒙脱土和<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>均有一定提高,电导率也达到了最佳范围.","authors":[{"authorName":"路军","id":"73d1c187-4d30-48ee-96a8-183837509b91","originalAuthorName":"路军"},{"authorName":"赵晓鹏","id":"82551d2d-3708-4c1b-bd5f-c97abaa0e03f","originalAuthorName":"赵晓鹏"}],"doi":"10.3321/j.issn:1000-3851.2004.04.002","fpage":"8","id":"24092b0f-107d-4b62-8748-88f8616872c7","issue":"4","journal":{"abbrevTitle":"FHCLXB","coverImgSrc":"journal/img/cover/FHCLXB.jpg","id":"26","issnPpub":"1000-3851","publisherId":"FHCLXB","title":"复合材料学报"},"keywords":[{"id":"70d6f932-fb40-4f58-8de0-41f319c8adaa","keyword":"插层法","originalKeyword":"插层法"},{"id":"76de8965-0ee6-4d58-99a0-8850542899ab","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>/蒙脱土","originalKeyword":"聚邻苯二胺/蒙脱土"},{"id":"89134059-b6ac-49df-b513-04e0343332f2","keyword":"纳米复合材料","originalKeyword":"纳米复合材料"},{"id":"6b7ae349-1d10-4bb5-92fc-92ff07acc84e","keyword":"电流变液","originalKeyword":"电流变液"}],"language":"zh","publisherId":"fhclxb200404002","title":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>/蒙脱土纳米复合材料的合成及其电流变效应","volume":"21","year":"2004"},{"abstractinfo":"在磷酸盐缓冲溶液中于玻碳电极表面聚合<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>,再负载纳米铜氧化物,成功制备了<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>负载纳米铜氧化物修饰玻碳电极(CuO/P-oPD/GC).探讨了聚合和负载机理,用电化学交流阻抗谱表征了修饰电极界面的阻抗变化,用扫描电镜表征了<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>膜和负载铜氧化物后的表面形态,发现CuO/P-oPD/GC电极对H2O2有显著的电催化氧化、还原双重活性,并呈现\"协同增敏\"效应.考察了制备条件对CuO/P-oPD/GC电极电催化活性的影响,最佳CoO负载扫描次数为20,Cu2+的质量浓度为1.67mmol/L.对H2O2电催化氧化的线性方程为△ip8(μA)=0.08+5.64c(mmol/L)(R=0.9982),线性范围为2.4×10-2～48mmol/L,检测限为2.8×10-3mmol/L(3S/k);电催化还原的线性方程为△ipc(μA)=0.11-2.45c(mmol/L)(R=0.9820),线性范围为2.4×10-3～38.4mmol/L,检测限为2.0×10-4mmol/L(3S/k).该复合材料修饰电极的灵敏度高、稳定性好,用于实际水样中H2O2测定结果满意.","authors":[{"authorName":"刘有芹","id":"3ea369cb-2b98-4044-8bd5-9443880e93c8","originalAuthorName":"刘有芹"},{"authorName":"乐文志","id":"10d0423a-25f9-4f3f-9fe0-85c00931a271","originalAuthorName":"乐文志"},{"authorName":"薛峰峰","id":"c9f70ecd-4eb7-4ca8-90d0-229139b09b64","originalAuthorName":"薛峰峰"},{"authorName":"颜芸","id":"a207616e-2705-4a21-bcdb-29bfdb12c27c","originalAuthorName":"颜芸"},{"authorName":"徐莉","id":"efab1944-58a2-4d3e-8604-a97c3430d2bf","originalAuthorName":"徐莉"}],"doi":"","fpage":"103","id":"62a23e29-d3d7-45bd-a543-e2acb9e3bec6","issue":"8","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"bb574349-9229-40a2-b648-5938b1bc35c6","keyword":"<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>","originalKeyword":"邻苯二胺"},{"id":"10c25933-7431-4256-b1d5-d422742a5181","keyword":"铜氧化物","originalKeyword":"铜氧化物"},{"id":"abe8aad8-b773-4046-af65-06e1a58a0a86","keyword":"玻碳电极","originalKeyword":"玻碳电极"},{"id":"9e974c73-a301-4048-8b52-6167205715c3","keyword":"过氧化氢","originalKeyword":"过氧化氢"},{"id":"27db642e-024e-4851-bcc9-8b1b449a61e6","keyword":"电催化","originalKeyword":"电催化"}],"language":"zh","publisherId":"cldb201008029","title":"<span style=\"color:red\">聚</span><span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>负载纳米铜氧化物修饰玻碳电极的制备及表征","volume":"24","year":"2010"},{"abstractinfo":"采用低温溶液缩聚的方法,在N-甲基吡咯烷酮(NMP)-氯化锂(LiCl)溶剂体系中引入了<span style=\"color:red\">邻</span>氯对<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>作为第三单体,与对<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>(PPD)和对苯<span style=\"color:red\">二</span>甲酰氯(TPC)反应,得到改性PPTA树脂.考察了第三单体含量对聚合体ηinh的影响,并对合成的芳香酰胺进行了XRD、TG、SEM等分析表征.研究结果表明改性聚合体的结晶度及热性能与PPTA相比略有下降,但仍不失为良好的稳定型树脂.通过表征膜的力学性能,发现加入45mol％第三单体制备的薄膜具有最佳的力学性能,与相同条件下制备的PPTA薄膜相比其拉伸强度有明显的提高,而且加入第三单体能够逐渐提高薄膜的断裂伸长率,改善薄膜的韧性.","authors":[{"authorName":"沈伟波","id":"e06cb631-004e-4322-a9b3-727e5021f644","originalAuthorName":"沈伟波"},{"authorName":"李双江","id":"5bc08544-0e06-4678-b258-5b3994514275","originalAuthorName":"李双江"},{"authorName":"孔海娟","id":"e098b870-59dc-41cd-a5d8-4e93bd737534","originalAuthorName":"孔海娟"},{"authorName":"王涛","id":"86315aa8-47a1-4ab1-92c5-d93dcfa55748","originalAuthorName":"王涛"},{"authorName":"韩克清","id":"ca2b5c5d-dd10-4242-82b2-4f24869c15a8","originalAuthorName":"韩克清"},{"authorName":"滕翠青","id":"1dccc3ed-8a5f-47d6-befa-172af9a3b82a","originalAuthorName":"滕翠青"},{"authorName":"余木火","id":"8eaa89ba-53de-420a-875e-7d1baa6ccdef","originalAuthorName":"余木火"}],"doi":"","fpage":"653","id":"cd7cfee6-f8b7-4167-bb42-38c524e64dc5","issue":"5","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"a7e95fd5-fc05-4ae8-88fd-98cb1edbcfaa","keyword":"第三单体","originalKeyword":"第三单体"},{"id":"a987b3dc-b114-480b-bf22-b6ddae256dd3","keyword":"<span style=\"color:red\">邻</span>氯对<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>","originalKeyword":"邻氯对苯二胺"},{"id":"fefeac1f-0e77-40a0-98bc-529b75f89068","keyword":"力学性能","originalKeyword":"力学性能"},{"id":"ac12e070-c666-4019-8b7c-1add8f9a66bf","keyword":"韧性","originalKeyword":"韧性"}],"language":"zh","publisherId":"clkxygc201405007","title":"<span style=\"color:red\">邻</span>氯对<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>改性PPTA聚合体的合成与性能表征","volume":"32","year":"2014"},{"abstractinfo":"采用界面缩聚法制备了<span style=\"color:red\">聚</span>间<span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲酰间<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>（PMIA），并通过红外、热重和凝胶渗透色谱（GPC）等方法与传统的低温溶液缩聚法制得的聚合物进行了比较。界面缩聚法制得的聚合物与低温溶液缩聚法制得的聚合物结构一致，但是界面缩聚法制得的PMIA聚合物的热稳定性稍好一些，最大分解速率对应的温度（界面缩聚：452℃，低温溶液缩聚：448℃）；且具有分子量分布更窄小的优点（界面缩聚：2．25，低温溶液缩聚：2．87）。通过扫描电镜（SEM）对聚合物制得的纤维表面进行分析，结果表明，采用界面缩聚法制得的PMIA纤维缺陷较少，有利于得到高品质的纤维。","authors":[{"authorName":"敖玉辉","id":"87327685-5ec7-40bc-b9b1-af98b8ad8282","originalAuthorName":"敖玉辉"},{"authorName":"耿杰","id":"9974c785-0400-4d4a-914d-1852bf8bdb2d","originalAuthorName":"耿杰"},{"authorName":"陈刚","id":"05287644-ff42-49be-bc57-c510b6729487","originalAuthorName":"陈刚"}],"doi":"","fpage":"21","id":"69c736ae-d0e4-487a-875e-15933887e566","issue":"12","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"15932aea-989d-4a1f-bf8e-3bbc1254239c","keyword":"界面缩聚","originalKeyword":"界面缩聚"},{"id":"048c1e64-9f26-4d36-943f-563928552771","keyword":"<span style=\"color:red\">聚</span>间<span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲酰间<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>","originalKeyword":"聚间苯二甲酰间苯二胺"},{"id":"b4c6184e-e1e0-4d48-9962-202000986ae4","keyword":"制备","originalKeyword":"制备"}],"language":"zh","publisherId":"gfzclkxygc201212006","title":"界面缩聚法制备<span style=\"color:red\">聚</span>间<span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲酰间<span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>","volume":"28","year":"2012"},{"abstractinfo":"本实验采用\"准一步法\"以<span style=\"color:red\">二</span>乙醇<span style=\"color:red\">胺</span>和<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲酸酐为原料先合成了AB2型中间体Ⅰ,中间体Ⅰ分别以<span style=\"color:red\">苯</span>、甲苯和<span style=\"color:red\">二</span>甲苯为带水剂进行缩聚反应生成端基为羟基的超支化聚酰胺Ⅱ,然后采用不同封端剂(苯甲酸,α-甲基丙烯酸,乙酸)进行端基改性得到最终产物Ⅲ.实验结果表明,较适宜的反应时间为:第一步1小时,第<span style=\"color:red\">二</span>步10小时(甲苯为带水剂),第三步10小时.同时确定出甲苯为带水剂、对甲苯磺酸为催化剂较好,产物收率大于94%,粘度在0.18～0.21dL/g,较易溶于酰胺类物质,并且热重检测产物有较好的热稳定性.","authors":[{"authorName":"封瑞江","id":"a85858df-c666-41e4-9af1-87ec5d6c212e","originalAuthorName":"封瑞江"},{"authorName":"赵崇峰","id":"a1e11ffc-addc-493c-9016-878b1b49aeff","originalAuthorName":"赵崇峰"}],"doi":"10.3969/j.issn.1671-5381.2008.01.002","fpage":"3","id":"ad7ae13e-53f6-4a63-a141-df84e6ee46c5","issue":"1","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"1d420594-de45-4519-8f58-185d366bbcaa","keyword":"超支化聚合物","originalKeyword":"超支化聚合物"},{"id":"197742fa-25c3-464f-8256-94ccfe629840","keyword":"<span style=\"color:red\">二</span>乙醇<span style=\"color:red\">胺</span>","originalKeyword":"二乙醇胺"},{"id":"c7f8b7e0-cb4a-4ccb-addd-9eb761fb0ce5","keyword":"<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲酸酐","originalKeyword":"邻苯二甲酸酐"},{"id":"30952fec-db1b-471a-9fd5-b85b6b6947eb","keyword":"合成","originalKeyword":"合成"},{"id":"72e7d617-b911-4e8d-a870-0185e52fbff1","keyword":"封端剂","originalKeyword":"封端剂"}],"language":"zh","publisherId":"hccllhyyy200801002","title":"<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲酸酐和<span style=\"color:red\">二</span>乙醇<span style=\"color:red\">胺</span>合成超支化聚合物的研究","volume":"37","year":"2008"},{"abstractinfo":"室温条件下,在水-NMPD混合溶液中,以<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>还原硝酸银,通过直接混合的一步反应,实现了球形纳米尺度银颗粒的可控制备.制备的颗粒采用扫描电子显微镜(SEM)和X射线衍射(XRD)技术进行性质表征,反应后的溶液体系采用紫外-可见光谱(UV-Vs)和液相色谱-质谱(LC-MS)技术进行分析.结果表明:制备的纳米银颗粒呈现出良好的球形形态,粒径均匀,平均粒径约70 nm,银纳米颗粒具有面心立方对称结构,其品格参数dhkl,a和V3均略大于标准卡片值,<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>经银离子氧化后的产物为2,3-<span style=\"color:red\">二</span>氨基吩嗪.","authors":[{"authorName":"李涛","id":"1342872a-4b6d-4720-a107-a912b4c095a2","originalAuthorName":"李涛"},{"authorName":"马国华","id":"dca9fd73-2bc7-4bb2-8adb-e81d45959ddd","originalAuthorName":"马国华"},{"authorName":"彭同江","id":"7699caa6-ffe0-438a-a75f-7530c5a2be4f","originalAuthorName":"彭同江"}],"doi":"","fpage":"1071","id":"0fc4e3d1-22a5-4e42-a74a-e2f44d57b304","issue":"5","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"9dfa3994-2558-42ed-870b-3a8050b63580","keyword":"银粒","originalKeyword":"银粒"},{"id":"f7ad4ce7-0c76-4798-85e3-f2c660f8f044","keyword":"纳米尺度","originalKeyword":"纳米尺度"},{"id":"dfe2a462-3e6b-43cd-9481-1cf226ec9056","keyword":"球体","originalKeyword":"球体"},{"id":"add5c9d6-5387-4392-8bd5-3cd860aac989","keyword":"湿化学还原","originalKeyword":"湿化学还原"}],"language":"zh","publisherId":"xyjsclygc201505007","title":"水-NMPD溶液体系<span style=\"color:red\">邻</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span><span style=\"color:red\">胺</span>还原制备球形纳米银反应机理","volume":"44","year":"2015"}],"totalpage":3722,"totalrecord":37213}