{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"We report on studies of solid state redox reactions induced by mechanical alloying (MA). The displacement reaction in the Fe-CuO system during MA may be completed by two steps: a rapid self-sustaining combustion reaction process, followed by a gradual reaction process. High densities of point and lattice defects, as well as a fine dispersion of reactants, are introduced in the powder mixture during MA. In addition, the displacement reaction in the Fe-CuO system produces a large negative heat. This combination of factors makes the redox reaction occur in the reaction regions, accompanied by self-heating. The self-heating may raise the temperature up to ignition temperature for a combustion reaction; this ignition temperature is greatly decreased by ball-milling. Combustion then takes place. The displacement reaction may be carried out rapidly during combustion. Complete reduction of copper oxides, including the intermediate oxidation state phase, Cu2O, appearing immediately after combustion, is observed after prolonged milling, during which the reduction is gradual; a similar self-sustaining reaction mechanism works in local reaction regions.","authors":[],"categoryName":"|","doi":"","fpage":"189","id":"2a981d9f-4dc1-420b-8cb2-6938000e8f8d","issue":"2","journal":{"abbrevTitle":"MSAEAMPMAP","id":"29fa6a83-07f2-4d3a-af3e-fac686227352","issnPpub":"0921-5093","publisherId":"MSAEAMPMAP","title":"Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing"},"keywords":[{"id":"a5daf094-5fcd-420e-ae9c-ac17654d3e22","keyword":"amorphous-alloys;powders","originalKeyword":"amorphous-alloys;powders"}],"language":"en","publisherId":"0921-5093_1992_2_3","title":"SOLID-STATE DISPLACEMENT REACTION OF FE AND CUO INDUCED BY MECHANICAL ALLOYING","volume":"151","year":"1992"},{"abstractinfo":"Solid state reaction of Mg with Ni was processed under static high pressure and nanocrystalline Mg2Ni was obtained. An unknown phase was also formed at lower temperature. The relation between the mean grain size of Mg2Ni and the synthetizing pressure is given, and its mechanism is discussed.","authors":[],"categoryName":"|","doi":"","fpage":"127","id":"503c4141-cbcb-493d-a003-cf8565d12a46","issue":"2","journal":{"abbrevTitle":"HPR","id":"1b7ee5ff-cc69-4ee1-8282-2a3ead1e7801","issnPpub":"0895-7959","publisherId":"HPR","title":"High Pressure Research"},"keywords":[{"id":"d38ede99-a64c-4dee-83fc-f92808249611","keyword":"solid state reaction;high pressure;nanocrystalline;Mg2Ni;mean grain;size;unknown phase;ab(2)-type intermetallic compounds;crystal-structure","originalKeyword":"solid state reaction;high pressure;nanocrystalline;Mg2Ni;mean grain;size;unknown phase;ab(2)-type intermetallic compounds;crystal-structure"}],"language":"en","publisherId":"0895-7959_1998_2_1","title":"Solid state reaction of Mg with Ni under high pressure","volume":"16","year":"1998"},{"abstractinfo":"Interdiffusion-induced solid-state amorphization reaction (SSAR) in polycrystalline Ni/amorphous Si multilayers has been studied using an in situ x-ray diffraction technique together with transmission electron microscope observations, The amorphization reaction was found to occur both on the Ni/Si interfaces in terms of a planar-layer growth model and along the grain boundaries in the Ni sublayers. Thermodynamic and kinetic interpretations for the SSAR at grain boundaries are presented and an amorphous growth model is also suggested for elucidating the SSAR in polycrystalline Ni/amorphous Si multilayers.","authors":[],"categoryName":"|","doi":"","fpage":"7217","id":"6d6a8873-252d-4c86-aafc-33b02477aa3b","issue":"11","journal":{"abbrevTitle":"JOAP","id":"7dcf8a89-0513-40ee-be2d-759941dcef7e","issnPpub":"0021-8979","publisherId":"JOAP","title":"Journal of Applied Physics"},"keywords":[{"id":"5089a8e5-a017-415f-a8df-4cf1f0472e4e","keyword":"x-ray-diffraction;thin-films;silicon","originalKeyword":"x-ray-diffraction;thin-films;silicon"}],"language":"en","publisherId":"0021-8979_1993_11_1","title":"SOLID-STATE AMORPHIZATION REACTION IN POLYCRYSTALLINE NI AND AMORPHOUS SI MULTILAYER","volume":"73","year":"1993"},{"abstractinfo":"The mixture of 90%W 7wt%Ni and 3wt%Fe elemental powders was milled in a planetary high-enerpy ball mill. The evolution of the structure during milling and the sintering behavior Of the milled powders were tested. The results showed that by mechanical alloying W(Ni, Fe) supersatumted solid solution with nano-meter size formed, which can enhance the sintering process. Ftilly dense alloy from the milled powders was obtained through solid state sintering. The tensile strength of the obtained alloy is over 900MPa which is comparuble to that of the alloy sintered by traditional liquid-phase sintering from un-milled powders of the same composition.","authors":[{"authorName":"X.H.Qu","id":"b9bf1ca0-4652-4c94-be3f-302fd91429d6","originalAuthorName":"X.H.Qu"},{"authorName":" J.L. Fan","id":"56f6e4e2-d70b-4d93-86d9-31f370ba0b27","originalAuthorName":" J.L. Fan"},{"authorName":" Y.M. Li and B. Y Huang(The State Key Laboratory for Powder Metallurgy","id":"3a454bca-1af6-4725-8b8b-560696a568ab","originalAuthorName":" Y.M. Li and B. Y Huang(The State Key Laboratory for Powder Metallurgy"},{"authorName":" Central South University of Technology","id":"001ef607-ead1-4d3e-8667-5e7858550383","originalAuthorName":" Central South University of Technology"},{"authorName":" Changsha410083","id":"df1c5025-2a40-44b6-a24f-ba94406b1ff6","originalAuthorName":" Changsha410083"},{"authorName":" China)","id":"7361dfa4-0c81-4d37-9422-02e7f075fec8","originalAuthorName":" China)"}],"categoryName":"|","doi":"","fpage":"917","id":"c0a494c9-10e8-4c95-9686-3a66f26ed3ee","issue":"3","journal":{"abbrevTitle":"JSXBYWB","coverImgSrc":"journal/img/cover/amse.jpg","id":"49","issnPpub":"1006-7191","publisherId":"JSXBYWB","title":"金属学报(英文版)"},"keywords":[{"id":"60cec4e7-524e-4159-b544-d0d48376867f","keyword":"mechanical alloying","originalKeyword":"mechanical alloying"},{"id":"a77ad431-353c-4a2c-a9e7-98d4fbcbedff","keyword":"null","originalKeyword":"null"},{"id":"10905fff-14a6-44f4-a26f-a77fc6cca074","keyword":"null","originalKeyword":"null"},{"id":"abe19c87-82ce-4af9-a680-bbe9ffff700a","keyword":"null","originalKeyword":"null"}],"language":"en","publisherId":"1006-7191_2000_3_12","title":"SYNTHESIS AND SOLID STATE SINTERING OF W-Ni-Fe NANO-COMPOSITE POWDERS","volume":"13","year":"2000"},{"abstractinfo":"Different solid-state reactions, i.e. Fe + SiC --> Fe3C + Fe(Si), and Fe + SiC --> Fe3Si + Fe2Si + C, were found in mechanically alloyed nanocrystalline Fe/SiC composites induced by prolonged milling or heat treatment, respectively. The solid-state reaction between nanocrystalline iron and SIC upon heating is greatly enhanced when compared with that between bulk iron and SiC. It is believed that the prolonged milling-induced reaction is related to the changed thermodynamics and kinetics while the heat-treatment-induced reaction, completed during a short time, is attributable to the changed reaction kinetics.","authors":[],"categoryName":"|","doi":"","fpage":"3835","id":"ff454209-2ce3-4063-b61c-d6e3944b5d4d","issue":"14","journal":{"abbrevTitle":"JOMS","id":"d451b714-34b6-45ff-beb7-4cb8e1a8bb9d","issnPpub":"0022-2461","publisherId":"JOMS","title":"Journal of Materials Science"},"keywords":[{"id":"08ea07b7-1431-4d60-9d9b-a3fa26b21018","keyword":"thermodynamic properties;silicon-carbide;copper-alloys;metals;system;microstructure;strength;powders;al","originalKeyword":"thermodynamic properties;silicon-carbide;copper-alloys;metals;system;microstructure;strength;powders;al"}],"language":"en","publisherId":"0022-2461_1997_14_1","title":"Solid-state reaction in nanocrystalline Fe/SiC composites prepared by mechanical alloying","volume":"32","year":"1997"},{"abstractinfo":"Size control of BaTiO3 in solid-state reaction between BaCO3 and TiO2 was demonstrated by varying the size of TiO2 and milling conditions of BaCO3. The smaller TiO2 particles had higher surface area, resulting in faster initial reaction. The mechanically milled BaCO3 particles accelerated the diffusion process and decreased the calcinations temperature. It can be deduced from the results that the size control is possible and nano-sized BaTiO3 particles with about 60 nm can be synthesized by using the conventional solid-state reaction between BaCO3 and TiO2","authors":[{"authorName":"U.Manzoor","id":"c405e6fd-8436-4221-ba0c-8b28b1f1a04e","originalAuthorName":"U.Manzoor"},{"authorName":" D.K.Kim","id":"297f666d-ca3d-40c7-a8e3-4a36566a47c6","originalAuthorName":" D.K.Kim"}],"categoryName":"|","doi":"","fpage":"655","id":"e44e7d5d-d9b1-49e1-a021-518b1d4f6f86","issue":"5","journal":{"abbrevTitle":"CLKXJSY","coverImgSrc":"journal/img/cover/JMST.jpg","id":"11","issnPpub":"1005-0302 ","publisherId":"CLKXJSY","title":"材料科学技术(英文)"},"keywords":[{"id":"93db6e6c-ac49-4d4c-920c-9ff853c6e044","keyword":"Barium titanate","originalKeyword":"Barium titanate"},{"id":"ce7c187e-6bee-4e4f-a4e1-4f0ecfc747db","keyword":"null","originalKeyword":"null"},{"id":"d4828638-e2e3-41b0-a075-260a0871fe0b","keyword":"null","originalKeyword":"null"},{"id":"07293622-e145-478f-8338-0e47eb92b201","keyword":"null","originalKeyword":"null"}],"language":"en","publisherId":"1005-0302_2007_5_7","title":"Synthesis of Nano-sized Barium Titanate Powder by Solid-state Reaction between Barium Carbonate and Titania","volume":"23","year":"2007"},{"abstractinfo":"Wollastonite, a mineral of wide industrial applications was synthesised from rice husk ash silica and limestone. A number of raw batches consisting of these starting materials, in 1:1 molar ratio, were heat treated to produce it through solid state reaction from 900℃ to 1300℃. The conducted reaction was monitored by XRD step by step. Amount of Wollastonite formed at every temperature was also studied to some extent. Analyses of the obtained data indicated that the target mineral formation was quite effective and almost proportional to a rise in temperature up to 1200℃. The results from both, XRD and chemical analysis were found in fair agreement with one another.","authors":[{"authorName":"M.S.Nizami","id":"97e4f1c7-5e60-4b63-8dbb-99b04b8209df","originalAuthorName":"M.S.Nizami"},{"authorName":" M.K.Farooq","id":"d9278983-ff5f-49db-a5f4-64466d8c84b6","originalAuthorName":" M.K.Farooq"},{"authorName":" K.Hussain","id":"ed4099f6-9354-4baa-a10b-aa177d27fb78","originalAuthorName":" K.Hussain"},{"authorName":" M.Z.Iqbal","id":"45e98900-391d-4036-a2bd-5458ee566e46","originalAuthorName":" M.Z.Iqbal"}],"categoryName":"|","doi":"","fpage":"276","id":"825a006f-e6e5-4b2e-afe9-75e3be09f73e","issue":"3","journal":{"abbrevTitle":"CLKXJSY","coverImgSrc":"journal/img/cover/JMST.jpg","id":"11","issnPpub":"1005-0302 ","publisherId":"CLKXJSY","title":"材料科学技术(英文)"},"keywords":[],"language":"en","publisherId":"1005-0302_1999_3_17","title":"Solid State Reaction Yielding a Mineral Utilizing Silica Obtained from an Agricultural Waste","volume":"15","year":"1999"},{"abstractinfo":"An industrial mineral wollastonite (CaSiO3) was produced under solid state conditions from rice husk silica and limestone. Reaction was carried out at 900 degreesC to 1300 degreesC for 1 h. The product batches were subjected to XRD and chemical analysis techniques specific for wollastonite. Mole fractions of different product batches were calculated on the basis of accumulated data to study the kinetics. Specific rate constants and reaction rate were also found out. Various probable models of mechanism for reaction were considered and testified with the laid down criterion for suggesting the suitable one. The resulting data were treated with Arrhenius equation as well and activation energy was calculated-therefrom. In addition to finding it's value from the slope of Arrhenius curve, an alternate method was also applied for this purpose. Both of the values were observed to be comparable. The activation energy required for performed reaction was found to be almost one third of that reported for synthesizing CaSiO3 by using quartz. This referred to the economical preparation of wollastonite by using rice husk as a source of silica instead of quartz.","authors":[{"authorName":"M.S.Nizami","id":"989591c3-0a11-418e-8dbe-bc4daa7d1bcb","originalAuthorName":"M.S.Nizami"},{"authorName":" M.Z.Iqbal","id":"c4856d25-3038-4f01-b123-4ff4db67876b","originalAuthorName":" M.Z.Iqbal"}],"categoryName":"|","doi":"","fpage":"243","id":"610b0d5e-81ca-4e63-a049-ee594a4de1e5","issue":"2","journal":{"abbrevTitle":"CLKXJSY","coverImgSrc":"journal/img/cover/JMST.jpg","id":"11","issnPpub":"1005-0302 ","publisherId":"CLKXJSY","title":"材料科学技术(英文)"},"keywords":[],"language":"en","publisherId":"1005-0302_2001_2_18","title":"Chemical kinetic aspects of solid state reaction producing wollastonite from rice husk silica and limestone","volume":"17","year":"2001"},{"abstractinfo":"BaHfO(3):Ce nanoparticles were synthesized by the process of solid-state reaction. Both XRD and SEM were adopted to analyze the phase change and the characteristics of BaHfO(3):Ce nano-powders during calcining process. Excitation and emission spectra were analyzed separately with the fluorescence photometer. The result shows that the average diameter of the BaHfO(3):Ce nano-powders being approximate to spherical morphology is about 30 nm and the powders have good dispersibility after calcining at 1000 degrees C for 2 h. It also shows that there is no change happened on the cubic crystal structure even though a little amount of Ce(3+) ion added to the powders can lead to the lattice distortion of BaHfO(3) matrix material. The excitation spectrum of BaHfO(3): Ce nanoparticles has two excitation peaks separately at 396 nm and 446 nm points. The emission spectrum excited by the 396 nm light consists of two emission bands, peaking at 531 nm and 591 run, respectively, the emission character of which changes from the 5d ->(2)F(5/2) to 5d ->(2)F(7/2) transitions of Ce(3+) cation. When the emission spectrum is excited by the 446 nm light, only one wide emission peak at 591 nm point exists and the other one at around 531 nm becomes flat. When the Ce(3+) dopant content is 0.9%(molar fraction), the figure of the emission peak reaches its highest point. This figure, however, drops when The Ce(3+) dopant content is 1.1%( molar fraction), which is resulted from the concentraction quenching.","authors":[],"categoryName":"|","doi":"","fpage":"1248","id":"e3d4c177-5c01-4f37-8471-ffe67de95e36","issue":"7","journal":{"abbrevTitle":"CJOIC","id":"ebb2aa1b-ce1f-4f04-b1bd-f890ca4f71dd","issnPpub":"1001-4861","publisherId":"CJOIC","title":"Chinese Journal of Inorganic Chemistry"},"keywords":[{"id":"a9be05b1-e174-4b2a-a797-6603ba4585ee","keyword":"scintillant;BaHfO(3):Ce nanoparticles;solid-state reaction process;excitation spectrum;emission spectrum;combustion synthesis;photoluminescence;phosphors;y2o3-eu;ca;sr;ba;nanophosphors;fabrication;ceramics","originalKeyword":"scintillant;BaHfO(3):Ce nanoparticles;solid-state reaction process;excitation spectrum;emission spectrum;combustion synthesis;photoluminescence;phosphors;y2o3-eu;ca;sr;ba;nanophosphors;fabrication;ceramics"}],"language":"en","publisherId":"1001-4861_2009_7_1","title":"Preparation and Luminescence Characteristics of BaHfO(3):Ce Nanoparticles by the Process of Solid-State Reaction","volume":"25","year":"2009"},{"abstractinfo":"The solid-state reaction between crystalline nickel and pulverized melt-spun amorphous Fe78Si12B10 powders during mechanical milling has been investigated. For the powder mixtures with low nickel content (less-than-or-equal-to 30 at%), the reaction results in the production of a new amorphous phase. For the powder mixture with a high nickel content (up to 50 at%), crystalline gamma(Fe, Ni) and new amorphous phases are obtained. During the milling process, nickel atoms can dissolve in the amorphous matrix by diffusion due to severe deformation. The existence of ''free volume'' in the melt-spun amorphous phase may favour the diffusion of nickel atoms. At the same time, the elemental atoms (such as iron) in the amorphous phase may also dissolve into the nickel matrix. The amorphization between the amorphous and crystalline phases is attributed to the asymmetry of interdiffusion of the atoms in different matrices.","authors":[],"categoryName":"|","doi":"","fpage":"6571","id":"387b9fee-4262-479d-8cfc-1d0993fa711d","issue":"24","journal":{"abbrevTitle":"JOMS","id":"d451b714-34b6-45ff-beb7-4cb8e1a8bb9d","issnPpub":"0022-2461","publisherId":"JOMS","title":"Journal of Materials Science"},"keywords":[{"id":"c3d3b47b-2989-41a6-bae2-5086a16d5cd9","keyword":"metallic glasses;amorphization;alloys","originalKeyword":"metallic glasses;amorphization;alloys"}],"language":"en","publisherId":"0022-2461_1993_24_1","title":"SOLID-STATE REACTION BETWEEN CRYSTALLINE NICKEL AND AMORPHOUS FE78SI12B10 POWDERS DURING MECHANICAL MILLING","volume":"28","year":"1993"}],"totalpage":392,"totalrecord":3919}