{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"简述了TiAlN涂层的应用领域、氧化机理以及采用磁控溅射制备该涂层的方法,分析了制备过程中N2分压、Al靶功率以及基体温度对涂层抗氧化性能的影响规律.同时指出了致密、膜基结合力高的涂层具有较高的抗氧化性;加入其他合适<span style=\"color:red\">元素</span>和合理设计<span style=\"color:red\">过渡</span>层不仅可以提高涂层与基体的物理匹配程度,减小内应力,同时也可提高膜基结合力,改善涂层的热力学稳定性及抗氧化性能,将成为今后的研究趋势.","authors":[{"authorName":"张贝贝","id":"7ab8d4ec-d4df-42cf-b2a0-0b90e145057b","originalAuthorName":"张贝贝"},{"authorName":"张程煜","id":"b6c6d13f-bd97-404a-bd0e-d3257fda4a0d","originalAuthorName":"张程煜"},{"authorName":"折洁","id":"9bfd69b3-dae7-4d6b-bc39-7c5a4b3f5dc0","originalAuthorName":"折洁"},{"authorName":"乔生儒","id":"2bf6482c-e965-4504-9e95-acdc461262e0","originalAuthorName":"乔生儒"}],"doi":"","fpage":"14","id":"5892f138-a4cd-47de-a952-d6a1d5471a19","issue":"21","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"7c070c25-f7a5-40cd-9a4d-7c58d670d3cf","keyword":"磁控溅射","originalKeyword":"磁控溅射"},{"id":"ea08802b-0e60-4793-874f-3a3ca3930056","keyword":"TiAlN涂层","originalKeyword":"TiAlN涂层"},{"id":"00592dbd-13a2-4294-9eff-fe206ac62ea1","keyword":"氧化机理","originalKeyword":"氧化机理"},{"id":"6eab39ec-d9a5-4e28-b520-bb44018b16f8","keyword":"工艺参数","originalKeyword":"工艺参数"},{"id":"9b642c4a-ad58-4924-a5eb-33d1f4e3322f","keyword":"抗氧化性","originalKeyword":"抗氧化性"},{"id":"08347ee4-83ae-434b-992f-e543ababf3e7","keyword":"<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span><span style=\"color:red\">元素</span>","originalKeyword":"过渡族元素"},{"id":"c8f51c6c-0d21-4178-9fd6-0057aba6915e","keyword":"多元多层","originalKeyword":"多元多层"}],"language":"zh","publisherId":"cldb201321003","title":"磁控溅射TiAlN涂层抗氧化性能的研究进展","volume":"27","year":"2013"},{"abstractinfo":"在前文的研究基础上,本文研究了<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span><span style=\"color:red\">元素</span>在Ti-Al-Sc,Ti-Al-V,Ti-Al-Nb和Ti-Al-Mo四个三元合金系中Ti,X相形成中的行为。 实验结果表明:在含有<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span><span style=\"color:red\">元素</span>Sc,V,Nb和Mo的Ti-Al固溶体中,Ti_3X相的形成仍然遵守电子浓度规律,且<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span><span style=\"color:red\">元素</span>的价电子数是由它们的d能带结构决定的。对周期表中位于Ti左侧的Sc,N_(sc)=2(s~2);对周期表中位于Ti右侧的V,Nb和Mo,N_v=3(d~3),N_(Nb)=4(d~4),和N_(Mo)=5(d~5)。另外,实验结果还表明:合金中添加任何一种<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span><span style=\"color:red\">元素</span>都不可能对Ti,X相的形成有抑制作用。","authors":[{"authorName":"李东","id":"688d440a-4660-4bc7-af60-8ccc24bcc84e","originalAuthorName":"李东"},{"authorName":"刘羽寅","id":"06a6ecc7-fa74-4506-94a9-cb57462b4edc","originalAuthorName":"刘羽寅"}],"categoryName":"|","doi":"","fpage":"384","id":"1bba5946-6b69-4924-8189-b9c06617f43c","issue":"6","journal":{"abbrevTitle":"JSXB","coverImgSrc":"journal/img/cover/JSXB.jpg","id":"48","issnPpub":"0412-1961","publisherId":"JSXB","title":"金属学报"},"keywords":[],"language":"zh","publisherId":"0412-1961_1984_6_15","title":"钛合金热稳定性研究  Ⅱ.<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span><span style=\"color:red\">元素</span>在Ti_3X相形成中的行为","volume":"20","year":"1984"},{"abstractinfo":"合成了四种含氧<span style=\"color:red\">族</span><span style=\"color:red\">元素</span><span style=\"color:red\">过渡</span>链(醚键及硫醚键)的邻苯二甲腈衍生物,红外光谱(FT-IR)和核磁共振氢谱(1HNMR)证实了它们的结构.氮气氛下的热重分析(TGA)和差示扫描量热分析(DSC)对四种单体的性能进行的表征结果显示,带有氨基的邻苯二甲腈衍生物在高温下出现了自加速热固化现象,不带氨基的邻苯二甲腈衍生物没有出现自加速热固化现象;含硫醚键的邻苯二甲腈衍生物热性能可以优于对应的含醚键衍生物.含硫醚键的邻苯二甲腈衍生物在空气氛中的TGA测试结果显示,由于未发生热氧化交联反应,但热氧化降解明显,其热性能反而更低.","authors":[{"authorName":"刘韬","id":"3808339e-042c-4489-9cc5-a821d1753b0a","originalAuthorName":"刘韬"},{"authorName":"曾科","id":"f2e4eab1-fa86-4129-9c7b-97a2e4f7acdf","originalAuthorName":"曾科"},{"authorName":"缪培凯","id":"7708aa23-666d-4cff-be32-3429b8985a4f","originalAuthorName":"缪培凯"},{"authorName":"杨刚","id":"71d020f9-bf65-463b-9eba-198f1cf25c93","originalAuthorName":"杨刚"}],"doi":"","fpage":"47","id":"1d1124f3-3abb-4121-b4f7-50abb3153a07","issue":"8","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"18b0997b-92ed-40a6-8e2e-0472abe091af","keyword":"邻苯二甲腈","originalKeyword":"邻苯二甲腈"},{"id":"decc0ca2-1761-4ca7-bf01-921284323136","keyword":"氧<span style=\"color:red\">族</span><span style=\"color:red\">元素</span><span style=\"color:red\">过渡</span>链","originalKeyword":"氧族元素过渡链"},{"id":"fe97ba1e-05e5-4dde-949d-160aee0009a9","keyword":"自加速固化","originalKeyword":"自加速固化"},{"id":"3ccc0adb-d9c9-46df-9fa8-383e6e496f61","keyword":"热氧化分解","originalKeyword":"热氧化分解"}],"language":"zh","publisherId":"gfzclkxygc200908014","title":"含氧<span style=\"color:red\">族</span><span style=\"color:red\">元素</span><span style=\"color:red\">过渡</span>链的邻苯二甲腈衍生物的性能","volume":"25","year":"2009"},{"abstractinfo":"本文给出了设计室温磁制冷功能材料的基本原则及具体方法.通过测试、验证得出如下结论:Re2Fe17-xMex型稀土-<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>金属所形成的Ce2Fe16.4Co0.6与Er2Fe15.26Ni1.74化合物具有较好的制冷效果,在外加磁场度H＝2.0特斯拉条件下,它们的退磁制冷温差ΔT均可达4.5K以上,基本与纯金属Gd接近(ΔT＝5.25K),但它们的价格仅为Gd的1/3.","authors":[{"authorName":"王宝珠","id":"4ea5b2bb-64ee-4339-b614-8e1cd3c92582","originalAuthorName":"王宝珠"},{"authorName":"温鸣","id":"cf4e5a6d-921a-4334-994d-a833bc0df186","originalAuthorName":"温鸣"},{"authorName":"曹晓明","id":"95aab8c4-e872-4aca-9e0a-664fd2ead083","originalAuthorName":"曹晓明"}],"doi":"10.3969/j.issn.1005-8192.2000.04.004","fpage":"24","id":"c4289297-de37-4cec-bfda-2b973ac8ff1d","issue":"4","journal":{"abbrevTitle":"JSGNCL","coverImgSrc":"journal/img/cover/JSGNCL.jpg","id":"46","issnPpub":"1005-8192","publisherId":"JSGNCL","title":"金属功能材料"},"keywords":[{"id":"597d88be-8160-4404-83e2-8e694d911612","keyword":"稀土金属","originalKeyword":"稀土金属"},{"id":"07bcdd62-5865-4d67-b92a-04238c850a70","keyword":"磁制冷","originalKeyword":"磁制冷"},{"id":"76e6ebb1-5e3a-44bf-b91a-783f6c940c8e","keyword":"磁制冷材料","originalKeyword":"磁制冷材料"},{"id":"ea3da44b-314b-45e2-b81b-bea354a434f6","keyword":"设计方法","originalKeyword":"设计方法"}],"language":"zh","publisherId":"jsgncl200004004","title":"稀土<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>磁制冷功能材料的研究","volume":"7","year":"2000"},{"abstractinfo":"利用键参数函数和尺寸因数对第四长周期<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>金属<span style=\"color:red\">元素</span>基准晶形成规律进行研究.发现可以用抛物线y=a-bx2将准晶形成区与准晶不能形成区区分开,准晶形成区的准确率达到了93.12%.同时,发现抛物线的参数a,b可以由基体<span style=\"color:red\">元素</span>的相关参数确定,即a∝E,b∝EμR30.","authors":[{"authorName":"桂许春","id":"fd161697-8681-4122-ab37-95ca64eee18e","originalAuthorName":"桂许春"},{"authorName":"廖树帜","id":"acf7910c-4363-487c-b1bc-df21cad7c2f5","originalAuthorName":"廖树帜"},{"authorName":"谢浩文","id":"08b4c624-d86d-4ad8-bc14-7dc5b9e285c7","originalAuthorName":"谢浩文"},{"authorName":"张邦维","id":"335a563d-c9c3-4999-bf65-6c998562f3ec","originalAuthorName":"张邦维"}],"doi":"","fpage":"1080","id":"e4e24c8d-6a22-4d33-8dc3-d40f817f73b5","issue":"7","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"a1582fa6-26d4-44d8-937a-b9f5f6c42f3f","keyword":"准晶","originalKeyword":"准晶"},{"id":"2d53537e-abbe-4d62-8e4e-647aced49f32","keyword":"抛物线模型","originalKeyword":"抛物线模型"},{"id":"e2102983-52aa-45bb-8c50-300d0ec3cc7d","keyword":"键参数函数","originalKeyword":"键参数函数"},{"id":"211ea6e3-9a49-4538-b00e-344f1d8b569e","keyword":"尺寸因素","originalKeyword":"尺寸因素"}],"language":"zh","publisherId":"xyjsclygc200607016","title":"第四<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>金属基准晶形成规律的抛物线模型","volume":"35","year":"2006"},{"abstractinfo":"介绍了各类<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>离子掺杂尖晶石微晶玻璃的制备方法,概述了各类<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>离子掺杂尖晶石微晶玻璃的光学性能及其研究进展,重点分析了该类材料的可饱和吸收、近红外宽带发光和可见发光等性能,并指出改进制备工艺、提高掺杂<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>离子在晶相中的比例、调控晶相与玻璃相的折射率匹配减少光散射作用等将是<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>离子掺杂尖晶石微晶玻璃未来研究的主要方向.","authors":[{"authorName":"李巍","id":"5d1d9ca9-e1ec-401e-8a9f-2c2f072ae5ce","originalAuthorName":"李巍"},{"authorName":"陈文哲","id":"07e43b7a-1e1c-4611-b70c-b0dbe26b3156","originalAuthorName":"陈文哲"},{"authorName":"郑婵","id":"fb77ec62-fd3a-4a97-899e-2d5d7e614a15","originalAuthorName":"郑婵"}],"doi":"","fpage":"15","id":"8d19bf6a-9b49-4a46-ad79-1842fd427666","issue":"4","journal":{"abbrevTitle":"JXGCCL","coverImgSrc":"journal/img/cover/JXGCCL.jpg","id":"45","issnPpub":"1000-3738","publisherId":"JXGCCL","title":"机械工程材料"},"keywords":[{"id":"56d008da-e98e-4d4d-aace-f5c132b31bd4","keyword":"<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>离子","originalKeyword":"过渡族离子"},{"id":"25f27768-7ae8-4c79-b1f9-1773b516edd6","keyword":"尖晶石","originalKeyword":"尖晶石"},{"id":"e4357527-c52f-4e12-8747-22a59ea3b174","keyword":"微晶玻璃","originalKeyword":"微晶玻璃"}],"language":"zh","publisherId":"jxgccl201404003","title":"<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>离子掺杂尖晶石微晶玻璃的研究进展","volume":"38","year":"2014"},{"abstractinfo":"阐述并归纳了近年来痕量及超痕量铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>的分析研究进展,重点介绍了样品的分离富集技术以及检测手段等,并对铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>测试技术未来的研究方向提出建议和展望.","authors":[{"authorName":"王敏芳","id":"712be601-e780-4b3f-839c-86631b67e543","originalAuthorName":"王敏芳"}],"doi":"","fpage":"2255","id":"8e509292-4cbd-4016-bd5b-5e13c949e71e","issue":"12","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"20143cd7-b7d8-436d-acb4-dda08f3a65dd","keyword":"铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>","originalKeyword":"铂族元素"},{"id":"11e5f544-7911-48bd-8f5e-1f96b20fb71d","keyword":"分离与富集","originalKeyword":"分离与富集"},{"id":"ddaff65b-c295-40a4-850b-914d1de715cc","keyword":"检测手段","originalKeyword":"检测手段"},{"id":"df975e1a-679c-4a10-984c-8afe2012232a","keyword":"展望","originalKeyword":"展望"}],"language":"zh","publisherId":"xyjsclygc201012041","title":"铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>分析的研究现状与展望","volume":"39","year":"2010"},{"abstractinfo":"本文从萃淋树脂在单个、2个、3个及以上铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>分离提取中的应用三方面进行了综述.萃淋树脂技术将溶剂萃取的高选择性和离子交换的简便、高效性结合起来,克服了溶剂萃取污染严重、分相困难和离子交换树脂合成困难、成本高等缺点,成为1种新型的简便、高效和环境友好的分离技术.该技术为铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>分离开拓了一条新途径.","authors":[{"authorName":"李华昌","id":"dbf68891-7d6f-46d7-92cc-0c9c2eb0ae9d","originalAuthorName":"李华昌"},{"authorName":"周春山","id":"7170edef-7457-43c5-af55-f85ae43a2af8","originalAuthorName":"周春山"},{"authorName":"符斌","id":"253f8d58-a9f5-49c0-b0d1-b958db45176f","originalAuthorName":"符斌"}],"doi":"10.3969/j.issn.1004-0676.2001.04.010","fpage":"49","id":"d3ec79ca-51e0-407f-a82a-510dc9ea97e2","issue":"4","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"b18b6483-c9c4-4859-8706-00926994aa8e","keyword":"铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>","originalKeyword":"铂族元素"},{"id":"68fe13a7-3600-4ce9-803e-8d04a8dec9f1","keyword":"萃淋树脂","originalKeyword":"萃淋树脂"},{"id":"e1ba6dd5-1b0a-4d03-98c3-b4ee13830ecf","keyword":"分离","originalKeyword":"分离"}],"language":"zh","publisherId":"gjs200104010","title":"铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>分离中的萃淋树脂技术","volume":"22","year":"2001"},{"abstractinfo":"在GPt-1～7标准物质的基础上,新近研制了3个铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>地球化学标准物质,包括1个ng/g级的样品(GPt-8)和2个μg/g级的铂矿石(GPt-9、GPt-10),由7～9个实验室采用锍镍试金-碲共沉淀-等离子体质谱为主的多种分析方法定值,并将超痕量GPt-1、GPt-2标准物质中的Os、Ru、Ir、Rh数据做了补充测定,提高了定值程度,使GPt-1～GPt-10成为从n×10-11～n×10-6均有可靠量值的铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>地球化学标准物质的完整系列.","authors":[{"authorName":"顾铁新","id":"3ba8a1ac-1811-4838-8418-8a3164f85e94","originalAuthorName":"顾铁新"},{"authorName":"汪世联","id":"42eccce8-c190-48ab-abc6-51502ed798d8","originalAuthorName":"汪世联"},{"authorName":"鄢卫东","id":"94bb3375-a6db-4c15-bd82-2c9f993892a7","originalAuthorName":"鄢卫东"}],"doi":"10.3969/j.issn.1001-1277.2006.07.012","fpage":"42","id":"e2574056-f58d-4e6e-af9d-32747a6070e7","issue":"7","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"d0f8ee11-2fac-4bdc-a570-eb315c21e4dc","keyword":"铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>","originalKeyword":"铂族元素"},{"id":"30890961-7d7f-4803-9391-7e07ecf88bb8","keyword":"地球化学标准物质,GPt系列","originalKeyword":"地球化学标准物质,GPt系列"}],"language":"zh","publisherId":"huangj200607012","title":"铂<span style=\"color:red\">族</span><span style=\"color:red\">元素</span>系列地球化学标准物质研制","volume":"27","year":"2006"},{"abstractinfo":"随着碳富勒烯和碳纳米管的发现,具有类似层状结构的纳米颗粒MoS2,由于片层状平面结构的不稳定,易形成封闭多面体笼状结构和管状结构.综述了<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>金属硫化物MS2(M=W,Mo,Nb,Ta,Zr,Ti,Re,Hf)纳米管的合成方法、微观结构、生长机制及其潜在的性能和应用.","authors":[{"authorName":"刘艳清","id":"6de77f03-b2ae-4ddd-a3a3-ad1eade0f40f","originalAuthorName":"刘艳清"},{"authorName":"李长生","id":"991bd8e2-78f4-4cff-b4db-9bc59de9e4b3","originalAuthorName":"李长生"},{"authorName":"华中","id":"ee9fab2f-46d3-4a10-97fc-d980c105d04c","originalAuthorName":"华中"},{"authorName":"李俊茂","id":"23f09875-282a-4ad9-bc0c-447399c4e1f7","originalAuthorName":"李俊茂"},{"authorName":"颜科红","id":"e6e3668b-e5f6-4ce8-bb27-e7ebd90f3ef5","originalAuthorName":"颜科红"}],"doi":"","fpage":"105","id":"e19f1f16-7eb9-4045-bb97-dde2dcdd7eb8","issue":"7","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"b9de5152-5333-42fd-bcd1-4097489a096f","keyword":"<span style=\"color:red\">过渡</span>金属硫化物","originalKeyword":"过渡金属硫化物"},{"id":"1b3a4578-e241-4fde-beb7-c0bb33b0a095","keyword":"纳米管","originalKeyword":"纳米管"},{"id":"94d52bde-2b9b-4e11-8b4c-857e1e7fb4f7","keyword":"微观结构","originalKeyword":"微观结构"}],"language":"zh","publisherId":"cldb200607028","title":"<span style=\"color:red\">过渡</span><span style=\"color:red\">族</span>金属硫化物纳米管结构研发现状","volume":"20","year":"2006"}],"totalpage":1646,"totalrecord":16456}