{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用水热法合成了一种3d-4f<span style=\"color:red\">杂</span><span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>[Fe(phen)3]2[FeSm(H2O) (tiron)3]·6H2O(1,Na2H2tiron=4,5-二羟基苯-1,3-二磺酸钠),利用IR、元素分析、TGA和X射线单晶衍射分析进行了表征.该<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>属立方晶系,P213空间群,a=2.1711(3) nm,V=10.234(2) nm3,Mr=2323.82,Dc=1.508 g/cm3,F (000)=4720,Z=4,R1=0.0482,wR2=0.1345.2～300 K温度范围的变温磁化率测试结果显示,SmⅢ-FeⅢ之间存在反铁磁相互作用.","authors":[{"authorName":"储召华","id":"07335e1d-713f-445d-bd61-8b9569bd90a7","originalAuthorName":"储召华"},{"authorName":"陈延民","id":"ceeecf9f-4523-4d4f-8070-f605e424e6bf","originalAuthorName":"陈延民"},{"authorName":"解庆范","id":"79270803-e321-44f0-ba27-53df178fb4ea","originalAuthorName":"解庆范"}],"doi":"","fpage":"1472","id":"d83d47fc-6cac-408b-8196-64065fff5f00","issue":"5","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"b2592d7e-aab5-4622-bfcb-65f11a40d947","keyword":"<span style=\"color:red\">杂</span><span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>","originalKeyword":"杂核配合物"},{"id":"331218b0-069d-4aa4-95c1-bc24d564960d","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"dcfd05ca-c302-4063-85dd-f1ba17adb2c4","keyword":"水热合成","originalKeyword":"水热合成"},{"id":"371b3a02-14b2-4464-808e-be8ee1962173","keyword":"磁性","originalKeyword":"磁性"}],"language":"zh","publisherId":"rgjtxb98201205060","title":"钛铁试剂桥联的FeⅢ-SmⅢ<span style=\"color:red\">杂</span><span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的合成、结构和磁性","volume":"41","year":"2012"},{"abstractinfo":"合成了不对称双Schiff碱Cu(Ⅱ)单<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>HCuLe(H3Le为N-3-羧基水杨醛-N'-(5-氯水杨醛)缩乙二胺)及三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>Cu(Ⅱ)Co(Ⅱ)Cu(Ⅱ)和Cu(Ⅱ)Cu(Ⅱ)Cu(Ⅱ),用元素分析、红外光谱、电子光谱测试技术对它们进行了表征. 测定了2个三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>在5～300 K范围内的变温磁化率,并通过自旋哈密顿算符H=-2JSM(SCu1 +SCu2)推导出的理论公式对实验值进行最佳拟合,得到了2个三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的磁交换参数J1=-15.1 cm-1,J2=-61.8 cm-1,表明在这2个<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>分子内存在金属离子间反铁磁偶合作用.","authors":[{"authorName":"刘宝林","id":"6da1d5e9-0316-4b5d-9539-d77f333e6024","originalAuthorName":"刘宝林"},{"authorName":"李付安","id":"80b90d31-6450-4706-8c6a-1fee9ccba5e4","originalAuthorName":"李付安"},{"authorName":"陶偌偈","id":"c1e618dd-1465-413b-9297-ef6d49df265d","originalAuthorName":"陶偌偈"},{"authorName":"王庆伦","id":"b02ba6b8-deb8-43ba-93c3-bb21cdf55ead","originalAuthorName":"王庆伦"},{"authorName":"廖代正","id":"cd4549fb-ee95-4411-a782-f2e85856f2b1","originalAuthorName":"廖代正"}],"doi":"10.3969/j.issn.1000-0518.2006.10.009","fpage":"1108","id":"03a0f5fd-d1a7-4293-ab4c-c0848c943841","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"8e5418e8-889b-4f09-87e0-79c0e3b278a3","keyword":"不对称双Schiff碱","originalKeyword":"不对称双Schiff碱"},{"id":"780e3a3b-151e-4492-88d3-806116bf97fe","keyword":"三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>","originalKeyword":"三核配合物"},{"id":"2fd23c51-3329-4d08-a266-d7b629bb602b","keyword":"磁性","originalKeyword":"磁性"}],"language":"zh","publisherId":"yyhx200610009","title":"不对称双Schiff碱三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的合成和磁性","volume":"23","year":"2006"},{"abstractinfo":"合成了三种新的异三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>, 其组成为{Ln2(bpy)4[Cu(opba)](ClO4)2}(ClO4)2. 通过元素分析、红外光谱、紫外光谱、差热-热重及摩尔电导分析等手段表征了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>.","authors":[{"authorName":"范玉华","id":"125b3519-9aa2-4e5d-a4a8-8fe486ec97f5","originalAuthorName":"范玉华"},{"authorName":"毕彩丰","id":"5d404b4e-5bb9-4ccb-b7c9-808455781f68","originalAuthorName":"毕彩丰"},{"authorName":"郑庚修","id":"a207e971-ebec-41f5-bbec-b41ff634e4a9","originalAuthorName":"郑庚修"},{"authorName":"谢英","id":"e53035b0-7c9f-4cc5-878a-b341ffe8f084","originalAuthorName":"谢英"}],"doi":"10.3969/j.issn.0258-7076.1998.02.004","fpage":"93","id":"1d18864b-b38f-46b9-b96a-6f630bea1338","issue":"2","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"60811756-24d0-46e6-b752-358e26fe4e08","keyword":"稀土-铜-稀土三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>","originalKeyword":"稀土-铜-稀土三核配合物"},{"id":"ebf89381-c793-4d23-8bdc-a19b3bfdea9e","keyword":"草胺酸根","originalKeyword":"草胺酸根"},{"id":"73e5646f-7f5a-4380-9afd-f6595a047468","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"xyjs199802004","title":"稀土-铜-稀土异三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的合成与表征","volume":"22","year":"1998"},{"abstractinfo":"合成了2种不对称草酰胺桥联异三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>{[Cu(oxca)]2M(H2O)2}[oxca表示N-(2-羧基苯)*N-(3-氨丙基)草酰胺三价阴离子,M=Co2+,Ni2+]. 用元素分析、红外光谱、电子光谱等对所合成<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>进行了表征. 在DMSO中采用循环伏安法研究了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的电化学性质. 在4～300 K范围内测量了{[Cu(oxca)]2Co(H2O)2}体系的变温磁化率,经拟合得磁参数J=-28.09 cm-1. 结果表明,异三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>分子内金属离子间存在反铁磁交换作用.","authors":[{"authorName":"陶偌偈","id":"7b3b63df-d953-458f-a78b-7b878296d3c7","originalAuthorName":"陶偌偈"},{"authorName":"娄本勇","id":"1c5cb276-3f50-4b94-be1f-d6592204382a","originalAuthorName":"娄本勇"},{"authorName":"臧双全","id":"0a9d2112-d025-4588-9e96-e61b9bfb10e6","originalAuthorName":"臧双全"},{"authorName":"周绪亚","id":"75fe725f-fc35-43ba-abc7-db1434eae115","originalAuthorName":"周绪亚"},{"authorName":"王庆伦","id":"72f0f5e8-1c01-4385-9bb2-251eccbe928a","originalAuthorName":"王庆伦"},{"authorName":"廖代正","id":"e41449ff-6127-4542-8d5a-636d0c01d484","originalAuthorName":"廖代正"}],"doi":"10.3969/j.issn.1000-0518.2002.12.009","fpage":"1158","id":"c475190d-90f6-49fb-92e6-8bf544804f64","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"3aabcf00-fea1-4fc7-835c-cea68f2162a2","keyword":"异三核草酰胺桥联<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"异三核草酰胺桥联配合物"},{"id":"6a8be81b-7291-4848-843d-5de258e4d6cb","keyword":"循环伏安法","originalKeyword":"循环伏安法"},{"id":"3f80f9d5-517d-483b-a6b7-39dc4fe72b52","keyword":"反铁磁作用","originalKeyword":"反铁磁作用"}],"language":"zh","publisherId":"yyhx200212009","title":"草酰胺桥联异三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的电化学及磁学性质","volume":"19","year":"2002"},{"abstractinfo":"合成了不对称双Schiff碱Cu(Ⅱ)单<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>CuHL (H3L为N-3-羧基水杨醛-N′-水杨醛-缩乙二胺)及其Cu(Ⅱ)-Zn(Ⅱ)-Cu(Ⅱ)异三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>.用元素分析、红外光谱、电子光谱对它们进行了表征,用X射线单晶衍射法测定了三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的晶体结构.该三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>属三斜晶系,P1空间群,晶胞参数为a=1.186 2(2) nm,b=1.544 0(3) nm,c=1.948 8(4) nm;α=90.04(3)°,β=97.86(3)°,γ=90.12(3)°;V=3.535 6(12) nm3,Z=1;R1=0.061 4,wR2=0.131 9.","authors":[{"authorName":"陶偌偈","id":"d7af10bc-89b1-4cb5-bd34-b5fc00ed3542","originalAuthorName":"陶偌偈"},{"authorName":"梅崇珍","id":"2de570c2-5ee3-42b3-ba45-87609d1895c1","originalAuthorName":"梅崇珍"},{"authorName":"牛景扬","id":"5645a0b9-61c9-4601-bedf-07f54495a5e5","originalAuthorName":"牛景扬"}],"doi":"10.3969/j.issn.1000-0518.2004.10.011","fpage":"1020","id":"e5c4c24b-6885-4377-a3e9-ac4567f8fa45","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"d1f5f147-e5ee-468f-a2c6-a580b5b92d2e","keyword":"羧基水杨醛,不对称双Schiff碱,Cu(Ⅱ)-Zn(Ⅱ)-Cu(Ⅱ)异三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>,晶体结构","originalKeyword":"羧基水杨醛,不对称双Schiff碱,Cu(Ⅱ)-Zn(Ⅱ)-Cu(Ⅱ)异三核配合物,晶体结构"}],"language":"zh","publisherId":"yyhx200410011","title":"新型不对称双Schiff碱Cu(Ⅱ),Zn(Ⅱ)异三<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的合成和晶体结构","volume":"21","year":"2004"},{"abstractinfo":"合成了4种聚醚桥连二异羟肟酸双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>,并将其用于催化α-吡啶甲酸对硝基苯酯(PNPP)水解反应,研究了聚醚桥连二异羟肟酸双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>催化PNPP水解反应的动力学和机理,提出了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>催化PNPP水解的动力学模型.结果表明,在25℃条件下,随着缓冲溶液pH值的增大,聚醚桥连二异羟肟酸双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>催化PNPP水解速率逐渐提高,表现出很高的催化活性.根据阿累尼乌斯公式和不同温度下的表观一级常数,求出了水解反应的表观活化能.","authors":[{"authorName":"黄生田","id":"40720f75-005b-4678-8e5f-40feae66053f","originalAuthorName":"黄生田"},{"authorName":"李建章","id":"046ac0f9-16b0-4055-8025-c6fa2773e5c2","originalAuthorName":"李建章"},{"authorName":"刘富安","id":"7b594180-e44e-4792-ab24-ee6b9aacd58b","originalAuthorName":"刘富安"},{"authorName":"周波","id":"b2735724-83e9-4c3b-985f-c1cc38e019e8","originalAuthorName":"周波"},{"authorName":"冯发美","id":"6c73c82a-0ed5-4783-bb41-4c7839285bee","originalAuthorName":"冯发美"},{"authorName":"秦圣英","id":"522bfe2e-7ce1-4498-8106-0bdf6e2d7dbf","originalAuthorName":"秦圣英"}],"doi":"","fpage":"43","id":"98267021-0953-4fb3-b316-f5e49f565df5","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"daa7bcac-8c7b-4ccc-aed7-842ae1490544","keyword":"聚醚桥连二异羟肟酸","originalKeyword":"聚醚桥连二异羟肟酸"},{"id":"a1a43246-b393-4e32-bea3-2cfa3ad32d6e","keyword":"过渡金属<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"过渡金属配合物"},{"id":"ed9c6857-2421-494c-b4a3-18e9dca4dfca","keyword":"α-吡啶甲酸对硝基苯酯","originalKeyword":"α-吡啶甲酸对硝基苯酯"},{"id":"ce1518b9-46c9-4cb2-b0ed-b987c0a6005b","keyword":"水解","originalKeyword":"水解"},{"id":"6f90a272-757c-4268-b155-795a14eb5a3c","keyword":"反应动力学","originalKeyword":"反应动力学"}],"language":"zh","publisherId":"cuihuaxb200501010","title":"聚醚桥连二异羟肟酸双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>催化PNPP水解的反应动力学","volume":"26","year":"2005"},{"abstractinfo":"合成和表征了四种含过渡金属离子Cu(Ⅱ)和Ni(Ⅱ)的草酰胺桥联异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>,并将这些<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>与Brij35表面活性剂胶束构成金属胶束作为金属水解酶模拟<span style=\"color:red\">物</span>用于催化对硝基苯酚磷酸单酯(NPP)水解.研究了金属胶束对NPP水解反应的催化机理,建立了异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>催化NPP水解的动力学数学模型.结果表明,四种草酰胺桥联异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>在NPP水解反应中表现出较高的催化活性,随着胶束溶液pH的增大,<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>催化NPP水解的速率提高.<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中的两个金属离子在催化NPP水解过程中表现出较好的协同效应.","authors":[{"authorName":"蒋维东","id":"791fc025-4c25-4db2-9701-804c0032e19a","originalAuthorName":"蒋维东"},{"authorName":"黄忠","id":"22e0468d-43c0-41dd-91c3-fa37ed74a8e2","originalAuthorName":"黄忠"},{"authorName":"刘富安","id":"dea53b10-8e2b-4a89-9b03-deada3e59be1","originalAuthorName":"刘富安"},{"authorName":"谢家庆","id":"d681a237-5d5e-4086-b716-f268f1239c57","originalAuthorName":"谢家庆"},{"authorName":"胡常伟","id":"0a9bdda4-5360-43f7-bda3-607bee37b19e","originalAuthorName":"胡常伟"},{"authorName":"曾宪诚","id":"6943e41b-02fa-4090-8249-e2b07bf23f68","originalAuthorName":"曾宪诚"}],"doi":"","fpage":"819","id":"d21157b8-d564-4e77-b10e-f0eddfe712ba","issue":"10","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"1defb38a-0f4f-44cb-a71a-6ca2cb610f85","keyword":"异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>","originalKeyword":"异双核配合物"},{"id":"b8b62667-5b51-46d2-8454-c0d1c923a27a","keyword":"金属胶束","originalKeyword":"金属胶束"},{"id":"881dd76f-d82a-4a54-b120-59ad1b7eda5c","keyword":"模拟酶","originalKeyword":"模拟酶"},{"id":"2f2f5cf7-7704-4328-ae34-892e686318bc","keyword":"磷酸酯酶","originalKeyword":"磷酸酯酶"},{"id":"d2494d36-6a43-4ab4-9920-3d7a0c101ac0","keyword":"对硝基苯酚磷酸单酯","originalKeyword":"对硝基苯酚磷酸单酯"},{"id":"2c55c9b8-7df7-4382-b0d2-3f9ec845cf25","keyword":"水解","originalKeyword":"水解"},{"id":"2342370d-8307-4efc-a80e-b0e2481b839e","keyword":"反应动力学","originalKeyword":"反应动力学"}],"language":"zh","publisherId":"cuihuaxb200410013","title":"异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>金属胶束模拟磷酸酯酶催化磷酸单酯水解","volume":"25","year":"2004"},{"abstractinfo":"设计合成了一种双核环金属铱，铂<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>二[ N，N-2-（2，4-二氟苯基吡啶） C3，N1]（吡啶甲酸）合铱（Ⅲ）-C6-[苯基吡啶-C3，N1]（吡啶甲酸）合铂（Ⅱ）（FIrPPyPt）。通过核磁共振仪、元素分析仪、紫外-可见吸收光谱仪和光致发光光谱仪对其结构和性能进行了表征。结果表明，<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>FIrPPyPt的紫外-可见吸收位于250～450 nm之间，荧光发射峰位于465和493 nm。将<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>FIrPPyPt以质量分数1％～8％掺杂到主体材料聚乙烯基咔唑（PVK）＋2-（联苯-4-芳基）-5-（4-叔丁基苯）-1，3，4-噁二唑（PBD）（30％）中制作了电致发光器件，在不同电压下电致发光光谱中，显现出铱<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>和铂<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的特征峰，波峰位于400、500和530 nm蓝绿光区发射区。该双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>用于单掺杂有机白光电致发光器件具有制作简单、色稳定性和重复性好等特点，为单掺杂白光发光器件提供了一种好的思路。","authors":[{"authorName":"胡峥勇","id":"207953eb-e23e-422a-810a-5be541653955","originalAuthorName":"胡峥勇"},{"authorName":"李善佳","id":"0756d87b-c72e-4f56-901c-1837816009a6","originalAuthorName":"李善佳"},{"authorName":"董新荣","id":"8d1a6442-bf8a-4a6e-9125-289e78b4c119","originalAuthorName":"董新荣"}],"doi":"10.11944/j.issn.1000-0518.2016.12.160119","fpage":"1428","id":"646325b2-7eab-4414-a569-6bb559a01ad9","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"4f58f013-ba9a-4d40-b313-2359f17a4538","keyword":"铱<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铱配合物"},{"id":"c8bd24ee-97b0-4050-b5d4-9d9407d351e2","keyword":"铂<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铂配合物"},{"id":"2b5376e3-0dbc-496b-9042-8e3417430a3c","keyword":"有机电致发光器件","originalKeyword":"有机电致发光器件"}],"language":"zh","publisherId":"yyhx201612012","title":"一种环金属铱、铂双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的合成及光电性能","volume":"33","year":"2016"},{"abstractinfo":"合成并表征了异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>CuZnTS*CH3OH[TS为二(3-羧基水杨醛)缩-1, 3-丙二胺]. 晶体结构分析表明此<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>属三斜晶系,空间群为P1,晶格参数为a=0.944 03(19) nm,b=1.159 1(2) nm,c=0.913 22(18) nm,α=91.09(3)°,β=97.06(3)°,γ=75.06(3)°,Z=2. 最终一致性因子R1=0.049 9,wR2=0.131 8. 异双核CuZnTS*CH3OH<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中的2个金属原子通过酚氧原子桥联在一起;铜原子与2个氮原子、2个酚氧原子和1个甲醇分子配位形成变形的四方锥结构;锌原子与2个酚氧和2个端基羧氧配位,并与相邻分子中的1个端基羧氧原子存在弱的配位相互作用,锌原子也处于变形四方锥几何构型之中. 结合晶体结构对<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>做了电化学性质研究.","authors":[{"authorName":"陶偌偈","id":"0afe12e1-efde-41b2-933b-3a174e55f6f6","originalAuthorName":"陶偌偈"},{"authorName":"臧双全","id":"e40aa071-21a9-43d8-be5c-222ae5c2c8c7","originalAuthorName":"臧双全"},{"authorName":"赵阁","id":"adef26b7-b6aa-41aa-846c-e0b59294ced5","originalAuthorName":"赵阁"},{"authorName":"于兆文","id":"fccf82fd-2ca9-4994-adbb-dea5d0ceed45","originalAuthorName":"于兆文"},{"authorName":"牛景扬","id":"a39e307f-aee1-41d2-b4f0-ca6f1ec5eebf","originalAuthorName":"牛景扬"},{"authorName":"周绪亚","id":"de7c5f69-83c3-4a69-956e-ea0e948f53a1","originalAuthorName":"周绪亚"}],"doi":"10.3969/j.issn.1000-0518.2002.11.008","fpage":"1059","id":"394a0f41-39bb-438d-8184-6bfa9f3316cc","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"5028d298-dde3-4752-901d-cdc584887a49","keyword":"异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>","originalKeyword":"异双核配合物"},{"id":"26b6c2ae-801b-4297-bd89-b5f737eafa2c","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"3e955ae5-6b69-42ca-80cc-c251ec764b74","keyword":"电化学性质","originalKeyword":"电化学性质"}],"language":"zh","publisherId":"yyhx200211008","title":"异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>CuZnTS·CH3OH的合成和晶体结构","volume":"19","year":"2002"},{"abstractinfo":"以N,N＇-双(3-氨基-2,2-二甲基丙基)草酰胺根阴离子(Me2oxpn)为桥联配体,分别端接N,N,N',N'-四甲基乙二胺(tmen)和2,9-二甲基-1,10-邻菲罗啉(Me2-phen);合成和表征了3种新的异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>[Cu(Me 2oxpn)Fe(tmen)2]SO 4(a),[Cu(Me2oxpn)Zn(tmen)2]SO4(b)和[Cu(Me2oxpn)Zn(Me2-phen)2]SO 4(c).经元素分析、红外光谱、电子光谱、电导及磁性测量等方法推定了这些<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的结构.测定并研究了(a)的变温磁化率(4～300K),求得交换参数J=-12.96 cm-1,表明双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>中Cu(I)-Fe(I)离子间存在反铁磁超交换作用.测试了3个双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的杀菌作用.","authors":[{"authorName":"焉翠蔚","id":"e19786c9-eadd-492a-8de8-75a9e253b70f","originalAuthorName":"焉翠蔚"},{"authorName":"李延团","id":"1eeb239d-a2f2-4f9c-919f-b2937a694e0e","originalAuthorName":"李延团"},{"authorName":"廖代正","id":"b0f99e2b-dcfb-4588-b502-11228312c606","originalAuthorName":"廖代正"}],"doi":"10.3969/j.issn.1000-0518.2001.10.010","fpage":"806","id":"8fdb1a8e-5a39-43fd-8b0e-fcfb7df49c17","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"06a84d9f-623c-46f7-aaf8-4b04f56008f5","keyword":"μ-草酰胺桥,异双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>,Cu(I)-Fe(I),Cu(Ⅱ)-Zn(I),抗菌活性","originalKeyword":"μ-草酰胺桥,异双核配合物,Cu(I)-Fe(I),Cu(Ⅱ)-Zn(I),抗菌活性"}],"language":"zh","publisherId":"yyhx200110010","title":"含草酰胺桥的Cu(Ⅱ)-Fe(Ⅱ)和Cu(Ⅱ)-Zn(Ⅱ)双<span style=\"color:red\">核配合</span><span style=\"color:red\">物</span>的合成、磁性及生物活性","volume":"18","year":"2001"}],"totalpage":4111,"totalrecord":41102}