{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"利用二次晶种生长法在α-Al2O3陶瓷管上制备TS-1沸石膜,详细研究了晶化时间对TS-1沸石膜表面形貌、沸石层厚度、沸石生长速率及气体渗透性能的影响.通过扫描电子显微镜(SEM),X-射线衍射仪(XRD),红外光谱(FT-IR)、紫外光谱(UV-Vis)及N2渗透测试对TS-1沸石膜进行了全面表征.研究结果表明:随着晶化时间的延长,TS-1膜层表面沸石粒子互生性增强,且膜层厚度也随之增加.然而,随着沸石层厚度的增加,其气体传输性能下降.当晶化时间为48 h,沸石生长速率最快,为0.087 μm/h,此时TS-1沸石膜厚度为4μm,表面平整,无明显缺陷.","authors":[{"authorName":"郭宇","id":"02b82e2c-3985-4b8a-a37e-f691a76d4d83","originalAuthorName":"郭宇"},{"authorName":"金玉家","id":"0fc64116-1513-4261-bd99-27ea52554343","originalAuthorName":"金玉家"},{"authorName":"吴红梅","id":"d9866b5e-315e-4dd7-a6ad-451d86697995","originalAuthorName":"吴红梅"},{"authorName":"李东昕","id":"5efc72ed-c536-4c3f-8f79-5d01fcfe4a54","originalAuthorName":"李东昕"}],"doi":"","fpage":"2068","id":"154a2440-ff64-4584-85b4-007dfd54d77b","issue":"8","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"b6944661-1f41-457b-b126-d43cba99d8bd","keyword":"TS-1","originalKeyword":"TS-1"},{"id":"4ac29d5d-e9fd-4b67-a333-29f066021d09","keyword":"沸石膜","originalKeyword":"沸石膜"},{"id":"f8673665-b2cb-473f-b8d4-bf5f666b48f8","keyword":"<span style=\"color:red\">氧化铝管</span>","originalKeyword":"氧化铝管"},{"id":"bd437b0d-60fe-4093-8cfc-cfadfb264f65","keyword":"二次晶种生长法","originalKeyword":"二次晶种生长法"}],"language":"zh","publisherId":"gsytb201408039","title":"<span style=\"color:red\">氧化铝</span>陶瓷管负载TS-1沸石膜的制备及表征","volume":"33","year":"2014"},{"abstractinfo":"采用控制<span style=\"color:red\">氧化铝</span>显微结构的方法,通过向<span style=\"color:red\">氧化铝</span>材料中引入不同粒径的板状<span style=\"color:red\">氧化铝</span>颗粒,同时采用超细粉为初始原料来改善<span style=\"color:red\">氧化铝</span>陶瓷的力学性能.<span style=\"color:red\">氧化铝</span>试样于1550℃和1600℃下烧成并加入MgO和Y2O3来抑制晶粒的过分长大.实验结果表明:加入板状<span style=\"color:red\">氧化铝</span>颗粒后,<span style=\"color:red\">氧化铝</span>材料的抗折强度得到明显提高.","authors":[{"authorName":"沈毅","id":"93dab608-4de1-4956-8d6e-df1509704d66","originalAuthorName":"沈毅"},{"authorName":"杨正方","id":"9cb148a2-05a2-4cef-a378-0999cec73dc6","originalAuthorName":"杨正方"}],"doi":"10.3969/j.issn.1001-1625.2001.06.012","fpage":"51","id":"9ef83ca2-c164-4040-88e3-b9e02ef0a378","issue":"6","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"550bcbff-b43b-49f1-a9bf-0d3c98455ac1","keyword":"板状<span style=\"color:red\">氧化铝</span>","originalKeyword":"板状氧化铝"},{"id":"e69b5da2-8878-4dd0-8034-eea98f8450a3","keyword":"增强","originalKeyword":"增强"},{"id":"37635e17-88be-49bb-9a8a-5e477d028f20","keyword":"临界粒径","originalKeyword":"临界粒径"}],"language":"zh","publisherId":"gsytb200106012","title":"板状<span style=\"color:red\">氧化铝</span>增强<span style=\"color:red\">氧化铝</span>陶瓷","volume":"20","year":"2001"},{"abstractinfo":"以片状<span style=\"color:red\">氧化铝</span>晶种作为第二相,采用无压烧结制备了<span style=\"color:red\">氧化铝</span>陶瓷,分析了片状<span style=\"color:red\">氧化铝</span>含量对<span style=\"color:red\">氧化铝</span>陶瓷微观结构的影响,采用扫描电子显微镜（SEM）观察分析试样的断口形貌;采用压痕法计算试样的断裂韧性（KIC）值;研究了不同含量的晶种引入量对<span style=\"color:red\">氧化铝</span>陶瓷断裂韧性的影响。结果表明烧结温度为1575℃时,相对致密度可以达到96.7%;片状<span style=\"color:red\">氧化铝</span>晶种的引入能够显著提高<span style=\"color:red\">氧化铝</span>陶瓷的断裂韧性;其片晶的裂纹偏转、片晶拔出效应等增韧机制发挥了主导作用;随着片状<span style=\"color:red\">氧化铝</span>含量的提高,<span style=\"color:red\">氧化铝</span>陶瓷的力学性能逐渐提高,当掺杂含量达到35%（质量分数）时,KIC达到6.4MPa.m1/2,当含量继续增加,KIC呈现逐渐降低的趋势。","authors":[{"authorName":"于佳伟","id":"9842115f-dd98-4fc1-a959-f3ef887001ae","originalAuthorName":"于佳伟"},{"authorName":"廖其龙","id":"33af89bb-7f67-4f16-88c1-af0a3392f260","originalAuthorName":"廖其龙"}],"doi":"","fpage":"1833","id":"7632341f-3acf-46d1-9f9d-2c53404fabda","issue":"10","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"fbf4a6f7-d72c-4e93-aafa-b19b9bd9c48c","keyword":"片状<span style=\"color:red\">氧化铝</span>","originalKeyword":"片状氧化铝"},{"id":"2cd2ce04-998c-4b21-a7db-733223b45c6b","keyword":"微观结构","originalKeyword":"微观结构"},{"id":"12e07557-072b-4fc3-86bf-feb4f97479dc","keyword":"增韧","originalKeyword":"增韧"},{"id":"6b168c2a-67f3-4de2-bb3e-7faa8be7bed3","keyword":"断裂韧性","originalKeyword":"断裂韧性"}],"language":"zh","publisherId":"gncl201110026","title":"片状<span style=\"color:red\">氧化铝</span>晶种对<span style=\"color:red\">氧化铝</span>陶瓷断裂韧性的影响","volume":"42","year":"2011"},{"abstractinfo":"介绍了3种常用<span style=\"color:red\">氧化铝</span>溶胶的制备方法,探讨了制备过程中温度、酸度、添加剂等几个主要因素的影响情况.","authors":[{"authorName":"刘智信","id":"31669910-5f2d-45b9-979b-08f941814b18","originalAuthorName":"刘智信"},{"authorName":"李东风","id":"3e00dd74-2db5-45f8-b7a5-476a891dee46","originalAuthorName":"李东风"}],"doi":"10.3969/j.issn.1001-1625.2004.04.019","fpage":"73","id":"aa915134-cb54-41f3-b09c-d1cd22f9fb39","issue":"4","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"b66dd13e-4b46-42c2-8db1-724cea483b81","keyword":"<span style=\"color:red\">氧化铝</span>","originalKeyword":"氧化铝"},{"id":"03e62b5f-d7d1-4502-b186-975edfdd738a","keyword":"溶胶","originalKeyword":"溶胶"},{"id":"a058c425-f5cc-4c7f-a447-51051eb2b03d","keyword":"制备","originalKeyword":"制备"}],"language":"zh","publisherId":"gsytb200404019","title":"<span style=\"color:red\">氧化铝</span>溶胶的制备","volume":"23","year":"2004"},{"abstractinfo":"<FONT face=Verdana>利用磷酸溶液浸渍具有独特的六边形结构和组成的多孔型阳极<span style=\"color:red\">氧化铝</span>(PAAO), 获得了带状、棒状、管状等不同形貌的纳米<span style=\"color:red\">氧化铝</span>纤维. 用扫描电镜(SEM)、能谱仪和透射电镜(TEM)等手段对其形貌和组成进行了分析. 结果表明, 纳米<span style=\"color:red\">氧化铝</span>纤维是在阳极<span style=\"color:red\">氧化铝</span>的多孔层形成的, 且在浸渍过程中阻挡层和多孔层表现出完全不同的溶解趋势. PAAO孔壁的特殊结构和组成上的差异造成的择优溶解是不同形貌纳米<span style=\"color:red\">氧化铝</span>纤维形成的主要原因. </FONT>","authors":[{"authorName":"潘金芝","id":"e9d36d53-9c88-44ff-8dd2-25c05f846df9","originalAuthorName":"潘金芝"},{"authorName":"赵红","id":"3b69651a-2120-4b6c-b833-a576b0931419","originalAuthorName":"赵红"},{"authorName":"陈春焕","id":"caa09e1e-5ce0-4604-bd6a-cc54bffac530","originalAuthorName":"陈春焕"},{"authorName":"李国军","id":"bed82aaf-5e8e-4345-94b3-e04153e59a75","originalAuthorName":"李国军"},{"authorName":"任瑞铭","id":"667da14d-6375-407a-9061-035492eac2c5","originalAuthorName":"任瑞铭"}],"categoryName":"|","doi":"10.3724/SP.J.1077.2006.00828","fpage":"828","id":"dcb81bb0-97c1-4c3e-a256-c6268bfa35f5","issue":"4","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"8d98ef9b-a19a-4531-a3d0-93d9a2ba8e61","keyword":"纳米<span style=\"color:red\">氧化铝</span>纤维","originalKeyword":"纳米氧化铝纤维"},{"id":"824e632b-21d8-44cb-bb3d-403ea5312d32","keyword":" anodic alumina","originalKeyword":" anodic alumina"},{"id":"9d66bbcf-90cd-4d5d-ae77-d755aeaa8e90","keyword":" porous layer","originalKeyword":" porous layer"},{"id":"79608453-8f72-4a7a-9e9d-96dbace5365b","keyword":" barrier layer","originalKeyword":" barrier layer"}],"language":"zh","publisherId":"1000-324X_2006_4_8","title":"由多孔型阳极<span style=\"color:red\">氧化铝</span>制备纳米<span style=\"color:red\">氧化铝</span>纤维","volume":"21","year":"2006"},{"abstractinfo":"利用磷酸溶液浸渍具有独特的六边形结构和组成的多孔型阳极<span style=\"color:red\">氧化铝</span>(PAAO),获得了带状、棒状、管状等不同形貌的纳米<span style=\"color:red\">氧化铝</span>纤维.用扫描电镜(SEM)、能谱仪和透射电镜(TEM)等手段对其形貌和组成进行了分析.结果表明,纳米<span style=\"color:red\">氧化铝</span>纤维是在阳极<span style=\"color:red\">氧化铝</span>的多孔层形成的,且在浸渍过程中阻挡层和多孔层表现出完全不同的溶解趋势.PAAO孔壁的特殊结构和组成上的差异造成的择优溶解是不同形貌纳米<span style=\"color:red\">氧化铝</span>纤维形成的主要原因.","authors":[{"authorName":"潘金芝","id":"d41561b5-f3c4-41ac-a3c2-e58a0540b1f9","originalAuthorName":"潘金芝"},{"authorName":"赵红","id":"a94c3a48-eeae-4747-ad3b-d54ae4deaf63","originalAuthorName":"赵红"},{"authorName":"陈春焕","id":"3e47ae78-512e-4810-a94f-df381e9ce5d6","originalAuthorName":"陈春焕"},{"authorName":"李国军","id":"cbcc7b9c-9fd4-4933-a848-ce94bb3dc095","originalAuthorName":"李国军"},{"authorName":"任瑞铭","id":"1e069d83-7512-4836-8d89-6dea0bcff3c1","originalAuthorName":"任瑞铭"}],"doi":"10.3321/j.issn:1000-324X.2006.04.011","fpage":"828","id":"e061cff4-6f5c-447c-af20-884ed320fbb5","issue":"4","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"79206cbd-ceb3-45cd-9eb9-c6a268e57763","keyword":"纳米<span style=\"color:red\">氧化铝</span>纤维","originalKeyword":"纳米氧化铝纤维"},{"id":"ea5e9df9-e863-440e-9b44-87bb408a5882","keyword":"阳极<span style=\"color:red\">氧化铝</span>","originalKeyword":"阳极氧化铝"},{"id":"6e422872-f2ea-42da-bd21-dfd10cfa9574","keyword":"多孔层","originalKeyword":"多孔层"},{"id":"d3793aec-8169-40e5-9ac9-b0944038ddf4","keyword":"阻挡层","originalKeyword":"阻挡层"}],"language":"zh","publisherId":"wjclxb200604011","title":"由多孔型阳极<span style=\"color:red\">氧化铝</span>制备纳米<span style=\"color:red\">氧化铝</span>纤维","volume":"21","year":"2006"},{"abstractinfo":"采用发泡法合成了粒径约为15 nm的<span style=\"color:red\">氧化铝</span>. 考察了发泡剂种类、发泡剂(柠檬酸)/Al3+、蒸发温度、发泡温度等制备条件对粒子形成过程及粒径的影响. 结果表明,发泡剂的稳定性和适度的络合能力是合成纳米<span style=\"color:red\">氧化铝</span>的重要因素,在有机配体(柠檬酸、乙二胺四乙酸)和水溶性高分子(聚乙烯醇、聚乙二醇)中,得到的柠檬酸粒径最小;在制备条件中蒸发温度和发泡温度对得到的<span style=\"color:red\">氧化铝</span>颗粒的影响较大,蒸发温度在70～90 ℃;发泡温度在120～150 ℃时为最佳. 用XRD,IR,DTG-DSC,TEM和NMR等方法进行表征,探讨了发泡剂在合成纳米<span style=\"color:red\">氧化铝</span>过程中的作用.","authors":[{"authorName":"程志林","id":"299d2d51-677d-4102-8f1f-cfea9e764347","originalAuthorName":"程志林"},{"authorName":"晁自胜","id":"f4062c32-8306-4a53-bde4-5da440699841","originalAuthorName":"晁自胜"},{"authorName":"万惠霖","id":"4545d530-838a-41de-acb6-e41a7192bb9d","originalAuthorName":"万惠霖"}],"doi":"10.3969/j.issn.1000-0518.2002.11.003","fpage":"1032","id":"106fe4f3-b1ed-48e9-815d-d697641c396d","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"352803d9-e2f7-456f-aa0b-18da7181a5a9","keyword":"<span style=\"color:red\">氧化铝</span>","originalKeyword":"氧化铝"},{"id":"ecc9541e-1f59-42ba-91df-be0ca132ed08","keyword":"发泡剂","originalKeyword":"发泡剂"},{"id":"399b793f-381a-4ebe-9051-bfaea7728f58","keyword":"纳米","originalKeyword":"纳米"},{"id":"4f2a4ebc-0ae5-4fd6-8672-e7785fa6524f","keyword":"表征","originalKeyword":"表征"}],"language":"zh","publisherId":"yyhx200211003","title":"发泡法合成纳米<span style=\"color:red\">氧化铝</span>","volume":"19","year":"2002"},{"abstractinfo":"运用TG/DSC、XRD、SEM等分析技术,研究了F-对<span style=\"color:red\">氧化铝</span>物相转变及α-<span style=\"color:red\">氧化铝</span>显微结构的影响.实验发现F-可以促进亚稳态<span style=\"color:red\">氧化铝</span>向稳定态α-<span style=\"color:red\">氧化铝</span>的相转变,同时改变α-<span style=\"color:red\">氧化铝</span>的结晶习性,促进α-<span style=\"color:red\">氧化铝</span>向片状微晶结构生长.","authors":[{"authorName":"尹周澜","id":"698c0aa3-0978-4a5c-b99f-8a013aea92e6","originalAuthorName":"尹周澜"},{"authorName":"陈玮","id":"0588f987-b2f7-40cd-8896-b02570fdbabd","originalAuthorName":"陈玮"},{"authorName":"李晋峰","id":"e078e480-8215-40dc-98a8-de32ae174a4a","originalAuthorName":"李晋峰"}],"doi":"10.3969/j.issn.1001-1625.2007.04.005","fpage":"640","id":"a199bf87-4d9a-4b22-b431-2ebb201637cc","issue":"4","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"fe093adb-02cc-4be1-89eb-9fb45d3bf521","keyword":"α-<span style=\"color:red\">氧化铝</span>","originalKeyword":"α-氧化铝"},{"id":"bf784295-debe-459f-acf5-8d89835d8929","keyword":"物相转变","originalKeyword":"物相转变"},{"id":"ccaa59ed-7b10-41ef-9617-5dcb86024be8","keyword":"显微结构","originalKeyword":"显微结构"}],"language":"zh","publisherId":"gsytb200704005","title":"F-对<span style=\"color:red\">氧化铝</span>物相转变及α-<span style=\"color:red\">氧化铝</span>显微结构的影响","volume":"26","year":"2007"},{"abstractinfo":"归纳了<span style=\"color:red\">氧化铝</span>纳米材料的制备方法;阐述了纳米<span style=\"color:red\">氧化铝</span>的性能、应用现状及发展前景.","authors":[{"authorName":"李友凤","id":"1ded5519-1362-4bb3-9f70-ce04e5745c29","originalAuthorName":"李友凤"},{"authorName":"周继承","id":"5d24bb13-7660-4248-a30c-9fbe281023fe","originalAuthorName":"周继承"}],"doi":"10.3969/j.issn.1003-7292.2003.04.013","fpage":"242","id":"1b836b10-d7b5-4335-be9e-847c0e886d8a","issue":"4","journal":{"abbrevTitle":"YZHJ","coverImgSrc":"journal/img/cover/YZHJ.jpg","id":"75","issnPpub":"1003-7292","publisherId":"YZHJ","title":"硬质合金"},"keywords":[{"id":"cdf131c8-ec4c-44bd-88e7-9e02e87e7859","keyword":"纳米<span style=\"color:red\">氧化铝</span>","originalKeyword":"纳米氧化铝"},{"id":"9b4ba9bc-fb35-423e-a661-50e5e419e0f5","keyword":"超重力碳分法","originalKeyword":"超重力碳分法"}],"language":"zh","publisherId":"yzhj200304013","title":"<span style=\"color:red\">氧化铝</span>纳米材料的制备与应用","volume":"20","year":"2003"},{"abstractinfo":"综述了<span style=\"color:red\">氧化铝</span>相变的机制、α相变温度控制的方法及其相关的机理.通过对<span style=\"color:red\">氧化铝</span>前驱体的球磨,在前驱体中引人α<span style=\"color:red\">氧化铝</span>籽晶,或者加入TiO2,MgO,NH4NO3等矿化剂可以降低<span style=\"color:red\">氧化铝</span>前驱体的α相变温度,从而得到粒径细小、无硬团聚的<span style=\"color:red\">氧化铝</span>粉体.相反,在某些具体应用时需要提高<span style=\"color:red\">氧化铝</span>α相变温度,提高<span style=\"color:red\">氧化铝</span>的热稳定性能,使用<span style=\"color:red\">氧化铝</span>热稳定添加剂被认为是一种很有效的方式.","authors":[{"authorName":"吴玉程","id":"1830121f-39d3-4279-9376-d1072b612fbb","originalAuthorName":"吴玉程"},{"authorName":"宋振亚","id":"f111a44e-9492-47d4-9785-8abdcdd1c302","originalAuthorName":"宋振亚"},{"authorName":"杨晔","id":"88bf9858-53f1-4c60-8f2d-a363d65f3ccc","originalAuthorName":"杨晔"},{"authorName":"李勇","id":"22038754-75d0-4b98-95d6-3b5c9e47f0e1","originalAuthorName":"李勇"},{"authorName":"崔平","id":"ea5364df-e941-4ca6-a724-6a5231deb276","originalAuthorName":"崔平"}],"doi":"10.3969/j.issn.0258-7076.2004.06.019","fpage":"1043","id":"2c38ae23-7075-4bd6-adc2-9258c467c905","issue":"6","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"82daa5dd-de9b-440c-aa80-ac09bcd94bc5","keyword":"<span style=\"color:red\">氧化铝</span>","originalKeyword":"氧化铝"},{"id":"f40e014e-9a5c-43cc-aee2-fb110aa0f203","keyword":"α相变","originalKeyword":"α相变"},{"id":"ff045c3f-5887-4960-9a00-248cdb973c2f","keyword":"控制","originalKeyword":"控制"},{"id":"d4d19829-f8b3-4b1b-a65b-07255f1fa91a","keyword":"球磨","originalKeyword":"球磨"},{"id":"edd9c3f9-bd9c-463b-9e57-0d696d5e23ee","keyword":"籽晶","originalKeyword":"籽晶"},{"id":"84857c0a-14b4-47d3-bdb6-2f3f49c187df","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"xyjs200406019","title":"<span style=\"color:red\">氧化铝</span>α相变及其相变控制的研究","volume":"28","year":"2004"}],"totalpage":2965,"totalrecord":29643}