{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以含有咪唑阳离子的周期性介孔有机硅(PMO-ILs)材料为载体，制备了一类固载化磷钼酸(PMA)多相催化材料(PMA@PMO-ILs)，并采用N2吸附-脱附实验、X射线衍射、原子吸收光谱、差热-热重分析、红外光谱、紫外光谱及固体核磁共振技术研究了材料的结构及物理化学性质。结果表明，磷钼酸通过静电相互作用被成功固载到PMO-ILs载体表面和孔道中，且在制备过程中磷钼酸及载体基本结构均未发生变化。反应结果表明， PMA@PMO-ILs材料在以叔丁基过氧化氢为氧化剂的环辛烯环氧化反应中表现出一定的催化活性和很高的选择性。中断实验结果表明，催化剂的主要活性中心在反应过程中未发生明显流失，且催化剂经多次循环使用后活性及选择性基本保持不变。 PMO-ILs中大量的咪唑阳离子能有效稳定磷钼酸阴离子，使该催化材料表现出良好的稳定性。","authors":[{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"24c86f38-5dae-403c-9c31-43b74a059062","originalAuthorName":"王静"},{"authorName":"邹永存","id":"79cc35b6-6719-46a0-9b99-5da1dc30ac8b","originalAuthorName":"邹永存"},{"authorName":"孙渝","id":"2063940d-ab5c-4b5f-84a4-d48e9c364d48","originalAuthorName":"孙渝"},{"authorName":"Maximilian Hemgesberg","id":"f4ed4265-480b-4caa-ad6b-44257dc42134","originalAuthorName":"Maximilian Hemgesberg"},{"authorName":"Dirk Schaffner","id":"0569c3c3-57c6-4dee-87de-1cb7aebd1edc","originalAuthorName":"Dirk Schaffner"},{"authorName":"高洪成","id":"253501ed-96e4-43c8-88eb-bc17da52e470","originalAuthorName":"高洪成"},{"authorName":"宋晓<span style=\"color:red\">静</span>","id":"58c53565-fe7c-4b13-99c1-e6b5ba71b5f6","originalAuthorName":"宋晓静"},{"authorName":"张文祥","id":"63b53b01-92a5-4450-9491-0fbde3a45037","originalAuthorName":"张文祥"},{"authorName":"贾明君","id":"43249af1-34c8-44f4-8079-4ff751f263cc","originalAuthorName":"贾明君"},{"authorName":"Werner R. Thiel","id":"eb47c2bf-b6a1-48cb-b04d-00aa50a1024d","originalAuthorName":"Werner R. Thiel"}],"doi":"10.1016/S1872-2067(14)60025-5","fpage":"532","id":"5dd8b3d1-30c1-421f-b6fb-4bf35c683ed6","issue":"4","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"ef1fe3be-6c1e-4f2b-9543-28966b86f997","keyword":"多金属氧酸盐","originalKeyword":"多金属氧酸盐"},{"id":"8051f627-2deb-49f5-8817-9b8874bed81e","keyword":"介孔有机硅","originalKeyword":"介孔有机硅"},{"id":"f0eeb6cb-c655-45fb-bb8c-7011eebd42ca","keyword":"咪唑阳离子","originalKeyword":"咪唑阳离子"},{"id":"4466e6f6-7f4d-4521-bdf3-9f33c291d19e","keyword":"静电相互作用","originalKeyword":"静电相互作用"},{"id":"ee93145e-bf5a-4621-8597-9a58b266223e","keyword":"环氧化","originalKeyword":"环氧化"},{"id":"3cb9b1da-ccaa-46e5-b303-a7d8af96052e","keyword":"多相催化","originalKeyword":"多相催化"}],"language":"zh","publisherId":"cuihuaxb201404013","title":"咪唑基介孔有机硅材料固载磷钼酸催化剂的制备及烯烃环氧化性能","volume":"","year":"2014"},{"abstractinfo":"首次将钙钛石 BiMnO3用于低温条件下 NH3选择性催化还原 NO 反应中.结果表明,该催化剂在100~240 oC 范围内表现出较好的催化活性.实验和理论计算显示,相对于 LaMnO3, BiMnO3优异的低温催化活性归因于其较强的 Lewis 酸性和较多的表面吸附氧物种.此外, BiMnO3还具有较好的抗水、抗硫性能.","authors":[{"authorName":"张一波","id":"710aab7e-4df0-44b0-a2cf-19ead2bd68b0","originalAuthorName":"张一波"},{"authorName":"<span style=\"color:red\">王</span>德强","id":"cc93193c-d2b5-4306-902d-8f965553dff8","originalAuthorName":"王德强"},{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"f29f2b2c-7215-4263-87b7-690000695844","originalAuthorName":"王静"},{"authorName":"陈去非","id":"ceba0e26-b472-4c35-904c-221fd2ea9a5e","originalAuthorName":"陈去非"},{"authorName":"张震东","id":"2620eeda-45fc-4a1c-89fb-99d9b727e240","originalAuthorName":"张震东"},{"authorName":"潘喜强","id":"088945c1-3a4f-4d51-b9fa-258af46c577d","originalAuthorName":"潘喜强"},{"authorName":"苗珍珍","id":"05beefeb-049d-4023-8dc6-aab6fac99572","originalAuthorName":"苗珍珍"},{"authorName":"张彬","id":"685a92e3-9bb6-48d9-b2dd-335b5bc7bb2b","originalAuthorName":"张彬"},{"authorName":"武志坚","id":"163732f8-7bcc-4924-b814-51f967d5850e","originalAuthorName":"武志坚"},{"authorName":"杨向光","id":"4ea197f2-b061-40f3-b412-768eb1bda4c2","originalAuthorName":"杨向光"}],"doi":"10.1016/S1872-2067(11)60439-7","fpage":"1448","id":"d98d26eb-c951-4448-93af-329bf070b33c","issue":"9","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"932c36ff-4eea-4b57-945f-2fc9c8bae25d","keyword":"钙钛石","originalKeyword":"钙钛石"},{"id":"60f2b723-34f4-4d45-a8a7-39fc9f936eac","keyword":"锰酸铋","originalKeyword":"锰酸铋"},{"id":"6484faa6-1a77-4ff5-95b4-204acdfb9913","keyword":"酸性","originalKeyword":"酸性"},{"id":"e8f70577-2a37-43a7-bfae-44ee373d6e4d","keyword":"选择催化还原","originalKeyword":"选择催化还原"},{"id":"cffbc95c-fd8d-4f13-8c71-bb9d2f6d7b88","keyword":"低温","originalKeyword":"低温"}],"language":"zh","publisherId":"cuihuaxb201209003","title":"BiMnO3钙钛石上低温NH3选择性催化还原NO","volume":"","year":"2012"},{"abstractinfo":"采用化学共沉淀法制备纳米Fe3O4,油酸包覆,高锰酸钾氧化,修饰得到羧基功能化的亲水性磁性纳米复合粒子.通过XRD、TEM、傅里叶红外光谱仪等方法对纳米复合粒子的形态、结构及磁性能进行了研究.结果显示:修饰前后的纳米粒子粒径基本无变化,粒径20 nm左右.纳米复合粒子的磁性能表现出超顺磁性,矫顽力减小为0,羧基化磁性纳米粒子可在pH=7.4的磷酸缓冲液中形成稳定分散的磁流体.","authors":[{"authorName":"杜鹏飞","id":"51e6b669-0241-44d5-9d2f-129c402e53b7","originalAuthorName":"杜鹏飞"},{"authorName":"许晓曦","id":"ebf7c029-39ca-4d07-a654-44db44d2460b","originalAuthorName":"许晓曦"},{"authorName":"金茂俊","id":"351920f3-6aec-4030-a9e1-08a68d7f6a21","originalAuthorName":"金茂俊"},{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"da87ed23-9e06-4199-8d12-981a53fce2bd","originalAuthorName":"王静"},{"authorName":"金芬","id":"4fe78721-c90f-4424-a726-4f805ef073f6","originalAuthorName":"金芬"},{"authorName":"邵华","id":"a2a33d47-578d-4ab0-aa0d-fb23e25b5aa1","originalAuthorName":"邵华"},{"authorName":"<span style=\"color:red\">王</span>淼","id":"e38819f5-d8ba-4be4-9159-a782d86334eb","originalAuthorName":"王淼"},{"authorName":"杨丽华","id":"8f88dd93-ba9a-471f-83f2-aec8740e873d","originalAuthorName":"杨丽华"}],"doi":"","fpage":"42","id":"01f830aa-5daf-4dba-9163-ee0929251ab4","issue":"4","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"42d8897f-6be1-473d-9535-e04eb5323f14","keyword":"化学共沉淀法","originalKeyword":"化学共沉淀法"},{"id":"26d3b36c-59e3-49f0-856b-8c7221a00d8c","keyword":"磁性Fe3O4微球","originalKeyword":"磁性Fe3O4微球"},{"id":"f76feebc-e184-464c-bf01-8a3d6c4b0d32","keyword":"制备","originalKeyword":"制备"},{"id":"3961870e-22e1-4973-82c9-de2a93bd7c08","keyword":"表征","originalKeyword":"表征"}],"language":"zh","publisherId":"cldb201404012","title":"羧基化Fe3O4磁性纳米微球的制备及表征","volume":"28","year":"2014"},{"abstractinfo":"通过水热法制备了Er3+掺杂的SrTiO3系列光催化剂,对样品进行了X射线衍射、扫描电镜、紫外可见吸收光谱和比表面积分析,并以染料降解考察了样品的光催化活性.研究表明,Er3+的适量掺杂抑制了SrTiO3粒径生长,增加了SrTiO3对太阳光的利用率.在紫外光和可见光辐照下,水热法制备Er3+-SrTiO3的光催化活性优于纯SrTiO3和高温固相反应制备的Er3+-SrTiO3.当掺杂量为1.5％时,SrTiO3的光催化活性达到最大,且在可见光辐照下的光催化活性优于TiO2(P25)光催化剂.","authors":[{"authorName":"许<span style=\"color:red\">静</span>","id":"9bcce77f-991e-49d8-8971-326d048e2240","originalAuthorName":"许静"},{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"8946c30f-9bd4-4b7b-b937-928f8e9d7f5b","originalAuthorName":"王静"},{"authorName":"魏月琳","id":"4844de9f-84e8-4943-9b8f-b43e7619e785","originalAuthorName":"魏月琳"},{"authorName":"孙志贤","id":"7c1a545d-3bf4-425f-b10a-b1301216820c","originalAuthorName":"孙志贤"},{"authorName":"郑宣清","id":"8fe60d0c-4dfc-48bb-8cc2-60571c2c5e11","originalAuthorName":"郑宣清"},{"authorName":"陶鑫灵","id":"1f6f979c-2f34-4b3c-9e26-3024d690dc3d","originalAuthorName":"陶鑫灵"},{"authorName":"范乐庆","id":"37edc139-e5cb-4b8c-9614-dc5b57b15e1a","originalAuthorName":"范乐庆"},{"authorName":"黄妙良","id":"f0f26fae-02d8-4bbe-a7ae-f642322021c0","originalAuthorName":"黄妙良"},{"authorName":"黄昀昉","id":"20f15e3f-ed8d-49b3-a3b5-9e3771b78b45","originalAuthorName":"黄昀昉"}],"doi":"","fpage":"1954","id":"06cd2f44-0f14-4531-a48e-c5a665d95110","issue":"8","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"6e10bad0-c1b7-4a27-b4b0-1335907eb56b","keyword":"SrTiO3","originalKeyword":"SrTiO3"},{"id":"85621d05-7172-4499-906d-d1af970b78b6","keyword":"水热法","originalKeyword":"水热法"},{"id":"5075b588-c0eb-43cd-8ce9-8dc6245bb6cf","keyword":"光催化","originalKeyword":"光催化"}],"language":"zh","publisherId":"rgjtxb98201408013","title":"Er掺杂钛酸锶的制备及可见光催化性能研究","volume":"43","year":"2014"},{"abstractinfo":"设计并合成了一种基于喹诺酮衍生物的双极绿色磷光主体材料1-甲基-3-[4-(9-咔唑基)苯基]-4-苯基喹啉-2(1H)-酮.计算发现,化合物的HOMO轨道的电子云位于咔唑基团,LUMO轨道的电子云位于喹诺酮基团,是一种良好的双极材料.化合物的磷光发射峰为515 nm(2.41 eV),符合绿色磷光主体材料的基本要求(>2.4 eV).热失重和差热分析结果表明,该化合物具有较高的热稳定性,分解温度和玻璃化转变温度分别为312 ℃和105 ℃.研究结果表明:该新型化合物是一种潜在的具有双极特性的绿色磷光主体材料.","authors":[{"authorName":"黄达","id":"0f9bd38b-a13b-4dd5-8a41-5b1bf2a7d66e","originalAuthorName":"黄达"},{"authorName":"叶俊","id":"64ad3271-5eb9-44f1-b29c-abd38fab105f","originalAuthorName":"叶俊"},{"authorName":"赵伟明","id":"1c157616-bb0a-4ccf-822e-ec95c4e27d56","originalAuthorName":"赵伟明"},{"authorName":"郑才俊","id":"1e9f2f3f-3200-489d-9dcf-cdf2da372c21","originalAuthorName":"郑才俊"},{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"8e01d29f-7089-4719-911a-1391e9da1996","originalAuthorName":"王静"},{"authorName":"陶斯禄","id":"23f76484-3acf-4208-aec8-e6778bd58f60","originalAuthorName":"陶斯禄"},{"authorName":"欧雪梅","id":"c1936b49-1271-4023-8a43-b1442979434d","originalAuthorName":"欧雪梅"},{"authorName":"张晓宏","id":"126c2576-864c-4f7f-ae2c-eca913d4a13a","originalAuthorName":"张晓宏"}],"doi":"","fpage":"408","id":"31f49b5f-3126-45d4-b9d6-b340434138ba","issue":"6","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"c43dcf76-f5e1-4bc0-8980-8fdcf3c018b4","keyword":"有机电致发光二极管","originalKeyword":"有机电致发光二极管"},{"id":"bf1be902-2f5f-4f74-9552-125ecaebcc5f","keyword":"双极绿色磷光主体材料","originalKeyword":"双极绿色磷光主体材料"},{"id":"e5a2066c-6684-48ef-8414-ea4613e8521a","keyword":"喹诺酮衍生物","originalKeyword":"喹诺酮衍生物"}],"language":"zh","publisherId":"ggkxyghx201006002","title":"双极绿色磷光主体材料1-甲基-3-[4-(9-咔唑基)苯基]-4-苯基喹啉-2(1H)-酮的合成与性能研究","volume":"28","year":"2010"},{"abstractinfo":"本文以石墨烯氧化物(GO)和硫代钼酸铵((NH4)2MoS4)为前体,曙红(EY)和三乙醇胺(TEOA)为光敏单元和电子牺牲体,通过一种环境友好的光还原方法原位制备了石墨烯-硫化钼(RGO-MoSx)产氢催化剂.RGO-MoS表现出高效的催化产氢活性,石墨烯的引入使其催化产氢效率提高至原来的2.10倍.通过傅里叶红外光谱(FTIR)、拉曼光谱(Raman)、透射电子显微镜(TEM)和X射线光电子能谱(XPS)表征,证实了RGO-MoSx的组成、结构及形貌特征.","authors":[{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"aca3d152-449c-42b0-9c1e-3d3595a99ef7","originalAuthorName":"王静"},{"authorName":"张慧慧","id":"5fa9b09c-c07b-4ee6-948b-05e63d5f72cd","originalAuthorName":"张慧慧"},{"authorName":"高雨季","id":"992a1eec-bd25-44cb-901d-722b7dee46e3","originalAuthorName":"高雨季"},{"authorName":"叶晨","id":"98fb11e6-40d6-4767-b4fa-e5888fcc93bf","originalAuthorName":"叶晨"},{"authorName":"冯科","id":"72e3bc45-3f85-491f-b94a-db65dc30d4e2","originalAuthorName":"冯科"},{"authorName":"陈彬","id":"9457ab30-0503-4c61-9c04-e0a8af076329","originalAuthorName":"陈彬"},{"authorName":"张丽萍","id":"afd54814-485a-401a-8bd7-040e1754c015","originalAuthorName":"张丽萍"},{"authorName":"佟振合","id":"f375e5c9-0198-4b5e-9455-2461f97b1311","originalAuthorName":"佟振合"},{"authorName":"吴骊珠","id":"72daefb4-1617-4bbb-afec-fee7e4b8f85c","originalAuthorName":"吴骊珠"}],"doi":"10.7517/j.issn.1674-0475.2015.06.461","fpage":"461","id":"358634a9-a7ae-4d75-9186-8d08ec231aac","issue":"6","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"cd7ea2f1-838e-4906-b845-f4f2842c926e","keyword":"RGO-MoSx","originalKeyword":"RGO-MoSx"},{"id":"41ec0a10-526b-40ad-bbbd-ca6bdf1f1063","keyword":"原位光还原","originalKeyword":"原位光还原"},{"id":"cb684b8f-d0c1-4a79-93a0-bed70462f31f","keyword":"光催化产氢","originalKeyword":"光催化产氢"}],"language":"zh","publisherId":"ggkxyghx201506002","title":"光还原制备石墨烯-硫化钼RGO-MoSx产氢催化剂","volume":"33","year":"2015"},{"abstractinfo":"设计并合成了一种新型的香豆素衍生物,3,3'-(1,3-苯基)双(7-乙氧基-4-甲基香豆素)(mEMCB),并系统地对该香豆素衍生物进行了结构表征、光物理性能、热物理性能及电化学性能的研究.mEMCB具有较高的三重态能级(2.42eV),可敏化绿色、红色磷光掺杂材料.同时,mEMCB还具有较好的热稳定性(Tg:79.72 ℃,Td:361.49 ℃),其Tg明显高于目前广泛使用的磷光主体材料CBP.研究结果表明,mEMCB是一个潜在的可以用于绿色和红色磷光有机电致发光器件的主体材料.","authors":[{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"5013a28c-d30c-4594-85c0-08f49f2f6fcb","originalAuthorName":"王静"},{"authorName":"郑才俊","id":"b3dc4fa3-c244-44b8-9726-c115a9f2f096","originalAuthorName":"郑才俊"},{"authorName":"黄达","id":"4a4feff8-595e-478c-8b4f-f072610bd2f0","originalAuthorName":"黄达"},{"authorName":"叶俊","id":"ea662d0f-f60b-42b3-8997-b037d432f9a9","originalAuthorName":"叶俊"},{"authorName":"欧雪梅","id":"c6284e70-97e9-4a1e-a75f-bc2437a6fed7","originalAuthorName":"欧雪梅"},{"authorName":"陶斯禄","id":"e23c1676-b29a-4268-aa33-6e7fa79cd2c1","originalAuthorName":"陶斯禄"},{"authorName":"张晓宏","id":"25e3dbe1-03cc-42c9-8ae7-d90f5f7117d9","originalAuthorName":"张晓宏"},{"authorName":"赵伟明","id":"dc467ce4-e542-4964-9c3f-5afc9f7d73ea","originalAuthorName":"赵伟明"}],"doi":"","fpage":"383","id":"38ef933c-83db-4a5c-b0ee-fee01d1f9fcd","issue":"5","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"b8b4309b-2650-44ee-830a-f0a03f98e040","keyword":"主体材料","originalKeyword":"主体材料"},{"id":"4f1197c1-fe00-48e1-afb8-0b398aa1de9d","keyword":"香豆素衍生物","originalKeyword":"香豆素衍生物"},{"id":"f76cb9ec-dd68-4462-967f-a1c82ebd0786","keyword":"磷光","originalKeyword":"磷光"},{"id":"b84fc525-3a29-4c5e-beba-26230ca1256e","keyword":"有机电致发光器件","originalKeyword":"有机电致发光器件"}],"language":"zh","publisherId":"ggkxyghx201005009","title":"基于香豆素衍生物的新型绿色/红色磷光有机电致发光主体材料的设计、合成及性能表征","volume":"28","year":"2010"},{"abstractinfo":"以水玻璃和NaOH为橡胶颗粒表面改性剂,比较了两种改性剂改性增强橡胶颗粒-水泥砂浆强度的效果,并考察了水玻璃的模数和浓度对橡胶颗粒表面改性增强水泥砂浆效果的影响.通过SEM和FT-IR分析了NaOH和水玻璃表面改性橡胶颗粒的机理.实验结果表明:水玻璃表面改性橡胶颗粒增强橡胶颗粒-水泥砂浆的效果优于NaOH.水玻璃改性的橡胶颗粒,表面更加粗糙,覆盖块状凝胶凸起,同时表面存在-OH基团和Si-O基团更利于橡胶颗粒与水泥水化产物的结合.随水玻璃模数、浓度增大,水玻璃改性橡胶颗粒-水泥砂浆试样强度逐渐增大,模数对改性效果的影响更明显.","authors":[{"authorName":"刘志刚","id":"cfca2f57-3b3b-4c15-b6c4-c32b6085cd72","originalAuthorName":"刘志刚"},{"authorName":"霍超","id":"cc4b8aa1-d4bd-46b9-a920-addd6ca38e1e","originalAuthorName":"霍超"},{"authorName":"白瑞英","id":"ba2cf76f-17cf-45ba-9b69-aed3db5e782a","originalAuthorName":"白瑞英"},{"authorName":"杨立荣","id":"d7ea6476-9a01-45a0-9761-e01153df55bf","originalAuthorName":"杨立荣"},{"authorName":"<span style=\"color:red\">王</span>春梅","id":"c58974d0-350d-411f-a5cd-64618e6b6772","originalAuthorName":"王春梅"},{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"5148584b-0e1c-44a8-b5e3-083368d4d290","originalAuthorName":"王静"},{"authorName":"魏庆敏","id":"a6ee1f22-ba0a-4c20-b07d-e19064d98232","originalAuthorName":"魏庆敏"},{"authorName":"封孝信","id":"fb2a7f0a-139d-4235-bd41-3caece77a5a7","originalAuthorName":"封孝信"}],"doi":"","fpage":"2600","id":"55183a06-4238-4537-93bb-85dc72b05508","issue":"9","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"973d86a1-eb7b-4958-b752-8971508ce4cb","keyword":"表面改性","originalKeyword":"表面改性"},{"id":"cb25ad05-0ed3-4cd9-a36b-125e03af68fb","keyword":"橡胶颗粒","originalKeyword":"橡胶颗粒"},{"id":"855831e5-4437-4d74-a35c-4ead93905416","keyword":"水玻璃","originalKeyword":"水玻璃"},{"id":"d5b90277-6feb-4626-bf82-1355fc20bb35","keyword":"水泥砂浆","originalKeyword":"水泥砂浆"}],"language":"zh","publisherId":"gsytb201509033","title":"橡胶颗粒表面改性及对水泥砂浆强度的影响研究","volume":"34","year":"2015"},{"abstractinfo":"通过电导率测试跟踪乙烯基三乙氧基硅烷(A-151)的水解过程,然后将水解完全的A-151水解液添加到基础钝化液中进行复合钝化,研究以替代有毒铬酸盐钝化.采用中性盐雾腐蚀试验(NSS)研究了所得复合钝化膜的耐蚀性;应用SEM/EDS分析了复合钝化膜的形貌及元素组成;极化曲线和电化学阻抗测试研究了钝化膜的耐蚀性及耐蚀机理.结果表明,所得复合钝化膜72 h NSS后腐蚀面积百分比仅为4%;SEM/EDS结果显示在镀锌层表面形成了厚度约为8 μm的保护性膜层,膜的主要组成元素为Si、Mo、P和O等;极化曲线表明复合钝化膜的存在主要抑制锌腐蚀过程中的阳极反应.电化学阻抗表明,低频区复合钝化膜的阻抗值比基体锌板增加了一个数量级.","authors":[{"authorName":"易德莲","id":"50a4619c-6620-4e65-a80e-097f8eac1d08","originalAuthorName":"易德莲"},{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"ec12c474-abfc-4d3f-b63d-d5d7a9ca3f3b","originalAuthorName":"王静"},{"authorName":"李字鹏","id":"d5a97cf7-90cf-465c-8c0c-3a7fe47c7027","originalAuthorName":"李字鹏"},{"authorName":"刘敏","id":"dffa1921-89f7-4aff-9abe-f959f9a20e94","originalAuthorName":"刘敏"},{"authorName":"伍林","id":"15949d66-8f6f-4714-9524-3e565994dd29","originalAuthorName":"伍林"},{"authorName":"庞宽","id":"dee38f6b-988b-429d-9714-59b1e7447d3f","originalAuthorName":"庞宽"},{"authorName":"豆丙乾","id":"ad69a329-0465-41d6-9431-1f0e1fddcfe2","originalAuthorName":"豆丙乾"},{"authorName":"李敏敏","id":"276695ac-a8aa-428a-9e37-2f42fd8aa9e9","originalAuthorName":"李敏敏"}],"doi":"","fpage":"142","id":"8f9fc6bc-1da9-4b2a-8907-c39edd61d2f3","issue":"2","journal":{"abbrevTitle":"FSYFH","coverImgSrc":"journal/img/cover/FSYFH.jpg","id":"25","issnPpub":"1005-748X","publisherId":"FSYFH","title":"腐蚀与防护"},"keywords":[{"id":"4214386e-0766-44bb-b3be-c5a021c6bf4c","keyword":"复合钝化","originalKeyword":"复合钝化"},{"id":"24b838a7-fb32-4350-8e6f-e28a0f7d5b7d","keyword":"硅烷偶联剂","originalKeyword":"硅烷偶联剂"},{"id":"a8e313e0-38fb-41f5-9a87-de63ec95735b","keyword":"耐蚀性","originalKeyword":"耐蚀性"},{"id":"f6394fc8-c4bc-4bd2-8ff3-2b3bdf3c9154","keyword":"极化曲线","originalKeyword":"极化曲线"},{"id":"b62fd568-0c50-48ba-9094-ed4a79590ea8","keyword":"电化学阻抗","originalKeyword":"电化学阻抗"}],"language":"zh","publisherId":"fsyfh201002014","title":"镀锌板的复合钝化","volume":"31","year":"2010"},{"abstractinfo":"本文利用高温原位拉曼光谱技术,测定了非线性光学晶体硼酸铯锂(CsLiB6O10,CLBO)晶体及其熔体的变温拉曼光谱.利用密度泛函理论计算了基本单元为(B3O7)5-六元环的CLBO晶体的拉曼光谱,并对振动模式进行了分析归属.在升温过程中,CLBO晶体的拉曼光谱出现展宽和红移,无相变发生；在熔化过程中,CLBO晶体微结构中(B3O7)5-六元环的[BO4]四面体发生异构化反应,转变为[BO3]三角形,即晶体相中的(B3O7)5-环变为熔体中的(B3O6)3-环.利用量子化学从头计算方法计算分析了熔体中结构基元的拉曼光谱谱学特征,结合熔体实测结果,表明CLBO熔体的阴离子基元为四个(B3O6)3-六元环组成的大四元环超级结构.","authors":[{"authorName":"<span style=\"color:red\">王</span><span style=\"color:red\">静</span>","id":"9d8e9126-1b3f-4e22-ab52-68f3fcb5fa3e","originalAuthorName":"王静"},{"authorName":"尤<span style=\"color:red\">静</span>林","id":"996d1939-caa9-456d-b436-92d16213f3df","originalAuthorName":"尤静林"},{"authorName":"<span style=\"color:red\">王</span>媛媛","id":"f91d3c1d-20c0-4b68-96bf-879a42abdab5","originalAuthorName":"王媛媛"},{"authorName":"张国春","id":"e58059d7-5ccf-4b83-89ac-8aba59dd3cf5","originalAuthorName":"张国春"},{"authorName":"万松明","id":"e331a838-5923-4e4d-8525-a19d5bcce1dc","originalAuthorName":"万松明"},{"authorName":"傅佩珍","id":"92623f5c-69c0-42e8-b92f-3a7f5a5d2702","originalAuthorName":"傅佩珍"},{"authorName":"殷绍唐","id":"9cd74090-f90e-4641-a748-885d14620637","originalAuthorName":"殷绍唐"},{"authorName":"刘钦","id":"adfa1333-8261-41aa-9a86-1dd14447b9d2","originalAuthorName":"刘钦"},{"authorName":"<span style=\"color:red\">王</span>晨阳","id":"b9763540-2928-46de-bee3-af1fe61162bc","originalAuthorName":"王晨阳"}],"doi":"","fpage":"397","id":"9e6e0bb0-87ba-43fd-a90b-1e0fe6538c84","issue":"3","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"d1a094f4-6ca9-49b3-a917-b00ec0f2ebdd","keyword":"CsLiB6O10晶体","originalKeyword":"CsLiB6O10晶体"},{"id":"3a22aa8d-6e54-4851-8b87-ab6ddad1e9ac","keyword":"高温拉曼光谱","originalKeyword":"高温拉曼光谱"},{"id":"8759f491-1225-4112-b858-dbf7bb9beba3","keyword":"熔体结构","originalKeyword":"熔体结构"},{"id":"3a4ac92d-bd8c-4ced-a7b2-aab30df1149c","keyword":"晶体生长","originalKeyword":"晶体生长"}],"language":"zh","publisherId":"rgjtxb98201303004","title":"CsLiB6O10晶体及熔体微结构的高温拉曼光谱研究","volume":"42","year":"2013"}],"totalpage":99,"totalrecord":990}