{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用示差扫描量热法(DSC)对5428双马树脂体系的<span style=\"color:red\">动态</span><span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>进行了研究,以自催化<span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>模型为基础方程建立了<span style=\"color:red\">动态</span><span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>方程.并模拟实际<span style=\"color:red\">固化</span>温度历程,采用测定不同<span style=\"color:red\">固化</span>阶段样品残余<span style=\"color:red\">反应</span>热的方法对<span style=\"color:red\">动态</span><span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>方程进行了验证,结果表明<span style=\"color:red\">动态</span><span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>方程能反映体系实际<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>历程.","authors":[{"authorName":"刘天舒","id":"a9b0a1a7-e20f-41bc-9444-1cfa35baf89f","originalAuthorName":"刘天舒"},{"authorName":"张宝艳","id":"2082c216-80d5-4454-9b4a-16a8aac11bb4","originalAuthorName":"张宝艳"}],"doi":"10.3969/j.issn.1001-4381.2005.10.002","fpage":"7","id":"1722c7dc-ec54-4200-a94f-082fe0d84cdb","issue":"10","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"2971b517-9a70-41be-a4a4-441f56c76e08","keyword":"<span style=\"color:red\">动态</span><span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>","originalKeyword":"动态固化反应动力学"},{"id":"fcafbe40-a562-4ee3-a685-86eaa6b2ef2e","keyword":"自催化<span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>模型","originalKeyword":"自催化反应动力学模型"},{"id":"68366b98-aefd-4cc7-9a23-38f359f2be60","keyword":"残余<span style=\"color:red\">反应</span>热","originalKeyword":"残余反应热"}],"language":"zh","publisherId":"clgc200510002","title":"5428双马树脂体系<span style=\"color:red\">动态</span><span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>研究","volume":"","year":"2005"},{"abstractinfo":"采用差示扫描量热法(DSC)在等温和<span style=\"color:red\">动态</span>条件下对3234中温<span style=\"color:red\">固化</span>环氧树脂体系的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>进行了研究,建立了<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>方程;并模拟实际<span style=\"color:red\">固化</span>温度历程,采用测定不同<span style=\"color:red\">固化</span>阶段样品残余<span style=\"color:red\">反应</span>热的方法对<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>方程进行了验证.结果表明,3234中温<span style=\"color:red\">固化</span>环氧树脂体系的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>符合自催化<span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>模型,<span style=\"color:red\">动态</span>实验得到的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>方程与验证结果符合得较好.","authors":[{"authorName":"刘天舒","id":"7c43ea89-32f6-4a02-b103-23eb202d163a","originalAuthorName":"刘天舒"},{"authorName":"张宝艳","id":"202a7482-e05d-4738-831b-e6d07d91852b","originalAuthorName":"张宝艳"},{"authorName":"陈祥宝","id":"660edda2-938d-4f09-90e4-aaa9752329aa","originalAuthorName":"陈祥宝"}],"doi":"10.3969/j.issn.1005-5053.2005.01.010","fpage":"45","id":"2ce57821-4490-4590-8094-142187d177a2","issue":"1","journal":{"abbrevTitle":"HKCLXB","coverImgSrc":"journal/img/cover/HKCLXB.jpg","id":"41","issnPpub":"1005-5053","publisherId":"HKCLXB","title":"航空材料学报"},"keywords":[{"id":"66ae0cfb-d273-463f-8816-0a247b50911c","keyword":"<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>","originalKeyword":"固化反应动力学"},{"id":"2c508e28-16c4-4bf2-8616-d47e14f17551","keyword":"残余<span style=\"color:red\">反应</span>热","originalKeyword":"残余反应热"},{"id":"0bbeb5b8-0ab9-4f37-80f0-eaf986cc66e5","keyword":"自催化<span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>模型","originalKeyword":"自催化反应动力学模型"},{"id":"c7e2c250-b1ed-469c-8a5b-8f7a6d17cefa","keyword":"<span style=\"color:red\">动态</span>","originalKeyword":"动态"}],"language":"zh","publisherId":"hkclxb200501010","title":"3234中温<span style=\"color:red\">固化</span>环氧树脂体系的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>研究","volume":"25","year":"2005"},{"abstractinfo":"采用非等温DSC法研究氰酸酯/环氧树脂<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>,采用Kissinger、Crane和Ozawa法确定<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>参数.结果表明,Kissilager式求得的表现活化能为74.00kJ/mol;Ozawa方法求得的表现活化能为78.87kJ/mol,<span style=\"color:red\">反应</span>级数为0.95,230℃/60min条件下.<span style=\"color:red\">固化</span>度达95%.","authors":[{"authorName":"王浩","id":"bcbaa8f2-6811-437b-9ddc-ae404e948ff1","originalAuthorName":"王浩"},{"authorName":"郑亚萍","id":"f86e1eb3-e225-41fd-9733-e5359315d62a","originalAuthorName":"郑亚萍"},{"authorName":"张娇霞","id":"fb5ecdce-e6e5-42fd-aa93-e7810d30b666","originalAuthorName":"张娇霞"},{"authorName":"郭丽敏","id":"ae66fa2e-d522-4684-8534-18f09a07b076","originalAuthorName":"郭丽敏"},{"authorName":"仙宝君","id":"502dace7-9586-4d0b-8adf-c1404a2764eb","originalAuthorName":"仙宝君"},{"authorName":"王继辉","id":"88225c38-00db-44b2-a34e-d30ec7480d8b","originalAuthorName":"王继辉"}],"doi":"10.3969/j.issn.1003-0999.2008.05.001","fpage":"3","id":"32775316-ce5d-4a5a-a690-584913945eb1","issue":"5","journal":{"abbrevTitle":"BLGFHCL","coverImgSrc":"journal/img/cover/BLGFHCL.jpg","id":"6","issnPpub":"1003-0999","publisherId":"BLGFHCL","title":"玻璃钢/复合材料"},"keywords":[{"id":"63e54511-ca91-4e10-9a39-6c78d1622db3","keyword":"氰酸酯","originalKeyword":"氰酸酯"},{"id":"16aaca11-0cf3-4377-b168-3dbbf7b14465","keyword":"<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>","originalKeyword":"固化动力学"},{"id":"71f063c5-4ba7-4c10-b2c0-b1217ae707c3","keyword":"<span style=\"color:red\">反应</span>级数","originalKeyword":"反应级数"},{"id":"628c586d-255d-4c08-b37e-482423351316","keyword":"环氧树脂","originalKeyword":"环氧树脂"}],"language":"zh","publisherId":"blgfhcl200805001","title":"氰酸酯/环氧树脂<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>研究","volume":"","year":"2008"},{"abstractinfo":"用傅立叶红外光谱(FTIR)跟踪研究了双马来酰亚胺预聚体(BMI)/氰酸酯树脂(BCE)的<span style=\"color:red\">反应</span>,并结合差示热扫描分析(DSC)探讨了<span style=\"color:red\">反应</span>机理.结果表明.BMI/BCE体系的<span style=\"color:red\">反应</span>主要包括BCE自聚<span style=\"color:red\">反应</span>、BMI自聚<span style=\"color:red\">反应</span>以及BCE与BMI之间的共聚<span style=\"color:red\">反应</span>,在<span style=\"color:red\">反应</span>前期主要以BCE自聚为主.到<span style=\"color:red\">反应</span>后期则以BCE与BMI之间的共聚<span style=\"color:red\">反应</span>为主.利用非等温差示扫描量热法研究了二者的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>,求得<span style=\"color:red\">固化</span>工艺参数:凝胶温度为139.06℃,<span style=\"color:red\">固化</span>温度为175.97℃,后处理温度为214.05℃.<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>参数:表观活化能为39.27 kJ/mol,频率因子为499.12 s-1,<span style=\"color:red\">反应</span>级数为0.83.","authors":[{"authorName":"方芬","id":"fb609f36-5acf-4410-831e-bfe4d997cf79","originalAuthorName":"方芬"},{"authorName":"颜红侠","id":"559dcad2-18bf-4ee0-bbfd-3c6c135a04d7","originalAuthorName":"颜红侠"},{"authorName":"李倩","id":"c143717a-e02d-4f14-8073-9b4694b80d90","originalAuthorName":"李倩"},{"authorName":"张军平","id":"bac873d3-26f4-4667-9622-557c68238060","originalAuthorName":"张军平"}],"doi":"10.3969/j.issn.1000-0518.2007.03.011","fpage":"291","id":"55133f3b-04fd-4b23-a314-eecf46e680ff","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"8dc9ea29-0133-4ad5-817d-36aded8a2b59","keyword":"氰酸酯","originalKeyword":"氰酸酯"},{"id":"a4853ee9-1de0-435b-b5cf-0fc9b8862aa7","keyword":"双马来酰亚胺","originalKeyword":"双马来酰亚胺"},{"id":"d4eadb70-f1c1-42aa-8cec-c68f41bf614e","keyword":"<span style=\"color:red\">反应</span>机理","originalKeyword":"反应机理"},{"id":"bc826ef7-7ba2-487e-b853-d8de007e674f","keyword":"<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>","originalKeyword":"固化动力学"}],"language":"zh","publisherId":"yyhx200703011","title":"BMI/BCE树脂体系<span style=\"color:red\">反应</span><span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>研究","volume":"24","year":"2007"},{"abstractinfo":"应用DSC和IR分析技术,研究了含有硼杂环的硼胺络合物与环氧树脂体系的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>机理和<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>.结果表明,<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>主要是硼胺络合物与体系中羟基化合物形成含氢质子的配位络合物,然后由此引发体系的环氧基进行的阳离子开环聚醚<span style=\"color:red\">反应</span>,整个体系的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>过程遵循一级<span style=\"color:red\">动力学</span>方程.","authors":[{"authorName":"陈平","id":"755fd674-6eba-4b7d-82f0-1ea9c293425a","originalAuthorName":"陈平"},{"authorName":"张岩","id":"d8705f23-3ca9-4dcf-8eb6-6cf27df2623a","originalAuthorName":"张岩"}],"doi":"10.3321/j.issn:1000-3851.1999.04.011","fpage":"54","id":"47a48601-62d7-448e-9d1f-527682bb769c","issue":"4","journal":{"abbrevTitle":"FHCLXB","coverImgSrc":"journal/img/cover/FHCLXB.jpg","id":"26","issnPpub":"1000-3851","publisherId":"FHCLXB","title":"复合材料学报"},"keywords":[{"id":"37bb846d-4fd9-42e2-9b14-88599f62b092","keyword":"硼胺络合物","originalKeyword":"硼胺络合物"},{"id":"56c7c4bc-84c9-4a2b-a1a2-e8ec86f398bc","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"633bfca1-c259-4393-bbe0-ce27eb1778fd","keyword":"<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>机理","originalKeyword":"固化反应机理"},{"id":"0170f4b2-0343-40cf-afdb-1c4d0e96d770","keyword":"<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>","originalKeyword":"固化反应动力学"}],"language":"zh","publisherId":"fhclxb199904011","title":"硼胺络合物/环氧树脂体系的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>机理及其<span style=\"color:red\">动力学</span>","volume":"16","year":"1999"},{"abstractinfo":"采用<span style=\"color:red\">动态</span>DSC法对耐高温双马来酰亚胺树脂的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>进行研究,根据Kissinger方程和Crane方程,拟合得到树脂的<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>参数,并建立树脂的唯象模型.此外,采用恒温DSC法,根据DiBenedetto方程,建立树脂的玻璃化转变温度与<span style=\"color:red\">固化</span>度之间的函数关系.采用凝胶盘法,获得树脂在不同温度下的凝胶时间,建立凝胶时间和凝胶温度之间的函数关系,最终得到树脂的TTT图.结果表明:根据TTT图确定合适的加压时机,可以有效排除夹杂于预浸料层内层间的气体,从而制备内部质量完好的复合材料.","authors":[{"authorName":"李伟东","id":"aa4f16ed-647e-40f6-9f62-6655a12ca7fd","originalAuthorName":"李伟东"},{"authorName":"张金栋","id":"e3f060a5-7a6b-44e1-b219-33e49576a888","originalAuthorName":"张金栋"},{"authorName":"李韶亮","id":"596ccb15-d032-4a4a-bfb1-905879af9eeb","originalAuthorName":"李韶亮"},{"authorName":"刘刚","id":"d703a723-ee07-42a8-a2c6-809f20021c41","originalAuthorName":"刘刚"},{"authorName":"钟翔屿","id":"ac27be4f-6001-4f50-8cba-672225a9c31c","originalAuthorName":"钟翔屿"},{"authorName":"包建文","id":"d60fb4e8-79d9-458c-972e-d9481e8af950","originalAuthorName":"包建文"}],"doi":"10.11868/j.issn.1001-4381.2016.09.007","fpage":"44","id":"e914c33a-e8ca-424e-851b-e67ed6495704","issue":"9","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"ca389c35-7edf-4ee3-9a78-cd74efaeabd7","keyword":"双马来酰亚胺树脂","originalKeyword":"双马来酰亚胺树脂"},{"id":"a3161753-f5a3-4d1f-be8c-b0cb52e4a843","keyword":"<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>","originalKeyword":"固化反应动力学"},{"id":"af7853c7-57d5-40b3-a586-aea322f79600","keyword":"TTT图","originalKeyword":"TTT图"},{"id":"18ef9069-2887-42a7-aaf9-c2e3299f8cf7","keyword":"工艺优化","originalKeyword":"工艺优化"}],"language":"zh","publisherId":"clgc201609007","title":"耐高温双马来酰亚胺树脂的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>和TTT图","volume":"44","year":"2016"},{"abstractinfo":"采用非等温DSC技术分析了不同升温速率下硼改性酚醛树脂的<span style=\"color:red\">固化</span>行为,运用Kissinger和Ozawa方法对其<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>进行了研究,得到了<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>活化能.结果表明,硼可以加速酚醛树脂的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>,使酚醛树脂的<span style=\"color:red\">固化</span>峰温度向低温方向移动,降低了酚醛树脂<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>的活化能,使<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>易于进行.","authors":[{"authorName":"宋超","id":"0c2350ea-98df-4ddd-88ce-6d320323bca9","originalAuthorName":"宋超"},{"authorName":"刘胜平","id":"d766333c-a8e2-4c48-b702-60b396ce7ee1","originalAuthorName":"刘胜平"},{"authorName":"徐世爱","id":"07eb38bd-790b-4799-8b76-5026288beb74","originalAuthorName":"徐世爱"}],"doi":"10.3969/j.issn.1003-0999.2010.06.011","fpage":"45","id":"ce16cd52-83d0-4cc9-927c-c5956279d093","issue":"6","journal":{"abbrevTitle":"BLGFHCL","coverImgSrc":"journal/img/cover/BLGFHCL.jpg","id":"6","issnPpub":"1003-0999","publisherId":"BLGFHCL","title":"玻璃钢/复合材料"},"keywords":[{"id":"174369e9-ff8f-46ab-b59e-bf6214034f67","keyword":"酚醛树脂","originalKeyword":"酚醛树脂"},{"id":"4b59d581-aa68-456b-98cb-ee539aef4acd","keyword":"硼","originalKeyword":"硼"},{"id":"cab3dc2c-0b68-4365-b140-cbc5511c34d9","keyword":"<span style=\"color:red\">固化</span>行为","originalKeyword":"固化行为"},{"id":"ce2dfac4-9cfc-438b-97e4-254ec5d909ce","keyword":"活化能","originalKeyword":"活化能"}],"language":"zh","publisherId":"blgfhcl201006011","title":"硼改性酚醛树脂<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>的研究","volume":"","year":"2010"},{"abstractinfo":"含硅芳炔树脂(PSA-R)具有优异的耐高温、优良的介电性能、高温<span style=\"color:red\">力学</span>性能,以及优异的工艺性能,适用于RTM成型工艺,广泛应用于航空航天、电子信息领域.本文采用<span style=\"color:red\">动态</span>差示扫描量热法(DSC)研究了含硅芳炔树脂的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>,试验表明含硅芳炔树脂的<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>符合n-级<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>模型,<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>级数约为2级,<span style=\"color:red\">反应</span>活化能为110kJ·mol~-1.用平板流变仪研究了PSA-R树脂的<span style=\"color:red\">动态</span>粘度及等温粘度变化,研究了凝胶时间与温度的关系,建立了凝胶模型,根据双Arrhenius方程,建立了含硅芳炔树脂的粘度模型,该模型预测粘度与实验结果相吻合.","authors":[{"authorName":"齐会民","id":"a5481936-f5d4-426f-b93a-141bfee54b55","originalAuthorName":"齐会民"},{"authorName":"王春兰","id":"9dcf1f31-c2ce-4eb1-86cb-9a0607380878","originalAuthorName":"王春兰"},{"authorName":"高金淼","id":"ecfc05dc-ad41-4336-9e98-b68decc7de8d","originalAuthorName":"高金淼"},{"authorName":"黄发荣","id":"2e90f718-e00c-40ba-943f-891ff905f455","originalAuthorName":"黄发荣"},{"authorName":"杜磊","id":"95959beb-23ff-419b-87c6-59283497c6ce","originalAuthorName":"杜磊"}],"doi":"10.3969/j.issn.1003-0999.2009.06.017","fpage":"62","id":"80ded637-3b42-4863-aa17-8581a7932158","issue":"6","journal":{"abbrevTitle":"BLGFHCL","coverImgSrc":"journal/img/cover/BLGFHCL.jpg","id":"6","issnPpub":"1003-0999","publisherId":"BLGFHCL","title":"玻璃钢/复合材料"},"keywords":[{"id":"307a343e-5a41-4173-8fca-8a120379448f","keyword":"含硅芳炔","originalKeyword":"含硅芳炔"},{"id":"04bdbfe3-0fee-4d5b-8738-0f647ae311ab","keyword":"RTM成型","originalKeyword":"RTM成型"},{"id":"437988b0-6286-421a-a372-1a3a3a1c061f","keyword":"化学流变","originalKeyword":"化学流变"},{"id":"bd12ec98-af27-49ca-85a4-2ef1842894d1","keyword":"<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>","originalKeyword":"固化动力学"}],"language":"zh","publisherId":"blgfhcl200906017","title":"RTM用含硅芳炔树脂的流变特性与<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>","volume":"","year":"2009"},{"abstractinfo":"为了给环氧树脂(DGEBA)/聚醚胺(T403)的实际<span style=\"color:red\">固化</span>工艺提供指导,在等温条件下采用差示扫描量热法(DSC)对该体系<span style=\"color:red\">固化</span>过程进行了研究.运用Kenny图像分析法得到了<span style=\"color:red\">动力学</span>参数,建立了kamal<span style=\"color:red\">动力学</span>模型;在考虑扩散影响的基础上,多次运用非线性拟合法得到了扩散系数(C)和临界<span style=\"color:red\">固化</span>度(αc),进一步建立了带扩散控制的<span style=\"color:red\">动力学</span>模型.结果表明,总<span style=\"color:red\">反应</span>级数为2.04～2.40,且随<span style=\"color:red\">固化</span>温度升高而下降.<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span>的两个速率常数都随温度升高而增大,对应的表观活化能分别为42.99和54.23kJ/mol.研究发现不带扩散控制的<span style=\"color:red\">动力学</span>模型可以较好地描述<span style=\"color:red\">固化</span>过程的前期阶段,而带扩散控制的<span style=\"color:red\">动力学</span>模型则可以更好地描述<span style=\"color:red\">固化</span>全过程.随着<span style=\"color:red\">固化</span>温度升高,αc增大,扩散影响减小,而带扩散控制的<span style=\"color:red\">动力学</span>模型与实验结果符合得越好.<span style=\"color:red\">固化</span>过程属三分子<span style=\"color:red\">反应</span>,具有明显的自催化特征.","authors":[{"authorName":"孙文兵","id":"e5f7e739-7bb7-46e3-a43d-49755278aa8d","originalAuthorName":"孙文兵"}],"doi":"","fpage":"843","id":"b6a3bcbb-726d-40b7-a603-4f5c6ff5cf71","issue":"6","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"7ef8cf99-a230-46ca-9210-5b320c224233","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"b9412659-1a5a-4366-847d-ca9b922648f3","keyword":"聚醚胺","originalKeyword":"聚醚胺"},{"id":"91b3781c-3755-4782-84ba-8fbb6e16f315","keyword":"<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>","originalKeyword":"固化动力学"},{"id":"a5e177c9-ad7d-4a18-9916-4f2eac5a0950","keyword":"等温","originalKeyword":"等温"},{"id":"02fa77db-3871-4df7-b9e0-5aa0814843df","keyword":"扩散控制","originalKeyword":"扩散控制"}],"language":"zh","publisherId":"clkxygc201006010","title":"等温DSC法研究聚醚胺与环氧树脂<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>","volume":"28","year":"2010"},{"abstractinfo":"采用<span style=\"color:red\">动态</span>DSC法,研究了高韧性双马来酰亚胺树脂的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>。根据Kissinger方程和Crane方程,拟合得到双马来酰亚胺树脂的<span style=\"color:red\">固化</span><span style=\"color:red\">动力学</span>参数,建立了该树脂的唯象模型。采用恒温 DSC 法,根据 DiBene-detto方程,建立了双马来酰亚胺树脂的玻璃化转变温度与<span style=\"color:red\">固化</span>度之间的函数关系。采用凝胶盘法,获得了该树脂在不同温度下的凝胶时间,建立了凝胶时间和凝胶温度之间的函数关系,得到了树脂的时间-温度-转变(TTT)图。根据TTT图对复合材料的<span style=\"color:red\">固化</span>工艺进行优化。结果表明：预浸料在150℃恒温0.5 h后加压0.6 MPa,树脂具有一定的流动性,可制备内部质量完好的复合材料。","authors":[{"authorName":"李伟东","id":"a6cab0ce-4b5b-4cc7-bbcb-749060984cf8","originalAuthorName":"李伟东"},{"authorName":"张金栋","id":"49ba3ae5-595f-492a-9641-36eef049e533","originalAuthorName":"张金栋"},{"authorName":"刘刚","id":"57a43da3-fc11-4a5f-8296-d74f18312d18","originalAuthorName":"刘刚"},{"authorName":"钟翔屿","id":"f765bdda-2171-4a70-8583-c10de4102609","originalAuthorName":"钟翔屿"},{"authorName":"张代军","id":"936b8b94-c64c-4679-93e8-b523580b0059","originalAuthorName":"张代军"},{"authorName":"包建文","id":"ad5ed9b2-4193-462c-a73c-81af9e9be35b","originalAuthorName":"包建文"},{"authorName":"肇研","id":"c7dac31d-9db0-4100-a7bb-09b05c8b02d2","originalAuthorName":"肇研"}],"doi":"10.13801/j.cnki.fhclxb.20151030.001","fpage":"1475","id":"7e5d8b78-22cf-42c0-b07b-85fae36f8332","issue":"7","journal":{"abbrevTitle":"FHCLXB","coverImgSrc":"journal/img/cover/FHCLXB.jpg","id":"26","issnPpub":"1000-3851","publisherId":"FHCLXB","title":"复合材料学报"},"keywords":[{"id":"0c7e2bec-f032-4e76-8a07-323c337b0d2f","keyword":"双马来酰亚胺树脂","originalKeyword":"双马来酰亚胺树脂"},{"id":"223d34a3-6284-47a9-8b96-0c94865182b2","keyword":"<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>","originalKeyword":"固化反应动力学"},{"id":"4d31b984-2fd5-4e2d-b8a8-6f79da995238","keyword":"TTT图","originalKeyword":"TTT图"},{"id":"8e2b193d-dbe9-40d6-8b77-1ca620e3c241","keyword":"成型工艺优化","originalKeyword":"成型工艺优化"},{"id":"90c47191-fa58-49be-9a57-5012a29c1572","keyword":"复合材料","originalKeyword":"复合材料"}],"language":"zh","publisherId":"fhclxb201607018","title":"高韧性双马来酰亚胺树脂的<span style=\"color:red\">固化</span><span style=\"color:red\">反应</span><span style=\"color:red\">动力学</span>和TTT图","volume":"33","year":"2016"}],"totalpage":6172,"totalrecord":61713}