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Fatigue Behavior of HDPE Composite Reinforced with Silane Modified TiO2

C.X. Dong

材料科学技术(英)

The composite of high density polyethylene reinforced with silane-modified TiO2 particles (silane-TiO2/HDPE) is a potential bone substitute biomaterial. The structure, bioactivity, and mechanical properties of silane-TiO2/HDPE are analogous to those of natural bone, correspondingly. In order to investigate the effect of silane connection and saline solution on fatigue behaviors, flexural fatigue tests with this composite were carried out in both air and saline solution. Saline solution was found to have different effect on fatigue life. In saline solution, the fatigue life could be improved at stress levels lower than 30 MPa, while the fatigue life could be reduced at stress levels higher than 30 MPa. After analyzing the fracture morphologies, different failure mechanisms were proposed, and the important role of silane connection in the composite during the fatigue process was discussed. Silane connection cannot only support the loading stress but also hinder the failure process under loading effectively. For dry specimens, no interfacial failure between the filler and matrix was found. For wet specimens, it is inferred that the synergetic effect of saline solution and high concentrated stress at high stress level could easily destroy the silane connection, which accelerated the fracture process, whereas the synergetic effect of saline solution and silane connection at low stress level could promote the formation of more microcracks on sample surface, which hindered the final fracture.

关键词: Fatigue

Fatigue Behavior of HDPE Composite Reinforced with Silane Modified TiO2

C.X. Dong

材料科学技术(英)

The composite of high density polyethylene reinforced with silane-modified TiO2 particles (silane-TiO2/HDPE) is a potential bone substitute biomaterial. The structure, bioactivity, and mechanical properties of silane-TiO2/HDPE are analogous to those of natural bone, correspondingly. In order to investigate the effect of silane connection and saline solution on fatigue behaviors, flexural fatigue tests with this composite were carried out in both air and saline solution. Saline solution was found to have different effect on fatigue life. In saline solution, the fatigue life could be improved at stress levels lower than 30 MPa, while the fatigue life could be reduced at stress levels higher than 30 MPa. After analyzing the fracture morphologies, different failure mechanisms were proposed, and the important role of silane connection in the composite during the fatigue process was discussed. Silane connection cannot only support the loading stress but also hinder the failure process under loading effectively. For dry specimens, no interfacial failure between the filler and matrix was found. For wet specimens, it is inferred that the synergetic effect of saline solution and high concentrated stress at high stress level could easily destroy the silane connection, which accelerated the fracture process, whereas the synergetic effect of saline solution and silane connection at low stress level could promote the formation of more microcracks on sample surface, which hindered the final fracture.

关键词: Fatigue

Dynamic Viscoelasticity of Polyester/Rubber Composites under Cyclic Loading

Yuyan LIU

材料科学技术(英)

This paper focuses on the influence of dynamic viscoelasticity and surface temperature on the fatigue mechanism and fatigue lifetime of polyester/rubber composites. Rubber composites show significant viscoelasticity during fatigue process. The variations of dynamic elastic modulus, mechanical loss angle, loss energy per cycle exhibit different trend in fatigue initial stage and final stage. Due to high viscoelasticity high heat generation occurs under cyclic loading, which leads to a high surface temperature. It is found that the variation of specimen surface temperature depends strongly on cycling frequency and stress amplitude. SEM (scanning electron microscopy) observation and static residual stiffness studies reveal that the surface temperature affects fracture morphology and fatigue lifetime of rubber composites strongly because of heat aging.

关键词: Rubber composites , null , null , null

Density Evolution of the Surface Short Fatigue Cracks of 1Cr18Ni9Ti Pipe-Weld Metal

Yongxiang ZHAO , Jinnuo WANG , Qing GAO

材料科学技术(英)

The evolutionary density and the scatter of densities of the short fatigue cracks on the surface of 1Cr18Ni9Ti pipe-weld metal were observed by local and overall viewpoints, respectively. The local viewpoint, which is in accordance with a so-called ``effectively short fatigue crack criterion", paid attention to the dominant effective short fatigue crack (DESFC) initiation zone and the zones ahead of the DESFC tips. The overall viewpoint focused on the whole test piece of specimen. The results revealed that the density and scatter evolution exhibited a significant character of microstructural short crack and physical short crack stages. The evolutionary behavior by the local viewpoint was sensitive to the increase of DESFC size and tip location. The mechanism of the short crack growth associated with the general test observations that the DESFC acted gradually as a long crack and the scatter of DESFC growth rates tended gradually to that of a long crack was well revealed. Intrinsic causes of the random cyclic strain-life relations and stress-strain responses are appropriately given. In contrast, the evolutionary behavior by the overall viewpoint was non-sensitive and violated the general test observations. Therefore, the intrinsic localization and randomization of material evolutionary fatigue damage should be more appropriately revealed from the observations by the local viewpoint.

关键词: 1Cr18Ni9Ti , null , null

弯曲疲劳后4D-C/C复合材料的抗弯强度及热膨胀性能

李克智 , 李伟 ,

新型炭材料 doi:10.1016/S1872-5805(14)60132-3

采用液相浸渍炭化技术,在压力为75 MPa下制备出4D-C/C复合材料,并进行高温热处理。研究静态和动态加载条件下,材料沿厚度方向的弯曲性能及断裂行为。结果表明,循环次数达到10×105次、频率为10 Hz时,材料的临界弯曲疲劳极限是静态弯曲强度的80%。静态弯曲加载情况下,C/C复合材料失效机制取决于试样底层炭纤维的取向。循环疲劳载荷作用下,其失效机制包括基体开裂、纤维-基体界面弱化及纤维断裂。复合材料在循环加载过程中界面结合强度降低,并释放内应力,故增强了纤维拔出以及复合材料的假塑性,疲劳加载后其剩余弯曲强度增加10%左右,而模量降低。疲劳载荷引起材料基体缺陷和裂纹数量的增加及纤维断裂,削弱了长度方向上的热膨胀,使材料热膨胀系数降低。

关键词: C/C复合材料 , 疲劳 , 抗弯强度 , 微观结构 , 热膨胀

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