{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"通过六氯环三<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的热开环聚合得到了线性<span style=\"color:red\">聚</span>二氯<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>（PDCP）,再采用两步亲核<span style=\"color:red\">取代</span>合成了<span style=\"color:red\">聚</span>（苯氧基/乙醇胺基）<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>。运用红外光谱（FT-IR）、核磁共振（1H-NMR）、X射线光电子能谱仪（XPS）、场发射扫描电子显微镜（FE-SEM）、热重分析（TGA和DTA）对聚合物进行结构和性能表征。FE-SEM结果表明,聚合物呈珊瑚状颗粒无规分布,具有较大的比表面积和较短的颗粒间距,材料中存在大量微米级空隙。TGA、DTA测试表明材料具有优异的热稳定性,800℃时残炭量为60%。","authors":[{"authorName":"张新孟","id":"582bea29-d04d-429d-aea4-0655ce89d536","originalAuthorName":"张新孟"},{"authorName":"王秀峰","id":"83d8bbee-2943-487b-acd1-f6e175d24b5d","originalAuthorName":"王秀峰"},{"authorName":"江红涛","id":"55302ff2-c1af-4b27-8cf7-9165f6938ccc","originalAuthorName":"江红涛"},{"authorName":"伍媛婷","id":"b268c407-507b-48d7-9739-6da8c71d8e8d","originalAuthorName":"伍媛婷"}],"doi":"","fpage":"21","id":"ce1141fd-1a4b-4cc5-9103-1aa06ddcf67a","issue":"11","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"46da4910-8b15-43eb-9bfd-db8274fd5fee","keyword":"<span style=\"color:red\">混合取代</span><span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"混合取代聚磷腈"},{"id":"3d3c2363-51cb-4fe9-abe6-7ed6d9f6e99c","keyword":"苯氧基","originalKeyword":"苯氧基"},{"id":"70255f2e-9ab3-4eac-91bd-fac01b78b120","keyword":"乙醇胺基","originalKeyword":"乙醇胺基"},{"id":"6e75d214-933c-41d7-aa6b-166d9c1bf150","keyword":"热性能","originalKeyword":"热性能"}],"language":"zh","publisherId":"gfzclkxygc201111006","title":"<span style=\"color:red\">聚</span>（苯氧基/乙醇胺基）<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的合成及表征","volume":"27","year":"2011"},{"abstractinfo":"基于<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>三<span style=\"color:red\">聚</span>体(HCCP)的开环聚合和亲核<span style=\"color:red\">取代</span>合成了三氟乙氧基<span style=\"color:red\">取代</span><span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>(PTFEP).并对其进行红外光谱(FT-IR)、凝胶渗透光谱(GPC)、核磁共振<span style=\"color:red\">磷</span>谱(31P-NMR)、差示扫描量热(DSC)分析.以高压静电纺丝法制备了PTFEP纳米纤维,通过扫描电镜对其微观结构进行了观测,测定了其接触角.","authors":[{"authorName":"陈大凯","id":"3fbe9405-744a-4a06-bbee-cfc0b5d91c95","originalAuthorName":"陈大凯"},{"authorName":"裘迪红","id":"bd20fe50-6af2-4967-a986-ebeb75dd24ee","originalAuthorName":"裘迪红"},{"authorName":"陆茵","id":"f2208246-270a-4363-9c1d-bf7ca1b349a1","originalAuthorName":"陆茵"},{"authorName":"安全福","id":"c2cade6e-f6e5-4c45-860d-6d4e996ec9b4","originalAuthorName":"安全福"},{"authorName":"戈丹","id":"c0ef3ad1-eca8-40b5-82a5-bc3b65239a53","originalAuthorName":"戈丹"},{"authorName":"梁焕","id":"78636d9d-23be-4441-8717-c67860239c30","originalAuthorName":"梁焕"}],"doi":"","fpage":"58","id":"8c4e5403-d442-480d-a75e-cde6c2735ad9","issue":"12","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"454de037-de98-45d2-9387-adc9d403e247","keyword":"三氟乙氧基<span style=\"color:red\">取代</span><span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"三氟乙氧基取代聚磷腈"},{"id":"85503cdb-d978-43fa-bf8b-ddafba9a5ac8","keyword":"开环聚合","originalKeyword":"开环聚合"},{"id":"d0478630-de1c-4fda-85e9-7fdc299e6ca0","keyword":"亲核<span style=\"color:red\">取代</span>","originalKeyword":"亲核取代"},{"id":"450ab797-ab8f-4939-9e73-62ecbeae3313","keyword":"静电纺丝","originalKeyword":"静电纺丝"},{"id":"1c625f97-db55-4686-84a3-a3ad7fc94696","keyword":"接触角","originalKeyword":"接触角"}],"language":"zh","publisherId":"gfzclkxygc200812014","title":"三氟乙氧基<span style=\"color:red\">取代</span><span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>纳米纤维的合成","volume":"24","year":"2008"},{"abstractinfo":"<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>是一类新型的无机高分子,具有特殊的结构和有机高分子难以比拟的特性,已应用于航天航空、船舶制造、石油化工及生物医学等领域.介绍了<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的制备、结构和性能、应用以及发展前景.","authors":[{"authorName":"任杰","id":"c909cd31-d5fc-448b-875d-1ad6acc3ed72","originalAuthorName":"任杰"},{"authorName":"陈云华","id":"06c92f6a-c959-443c-bfb5-dfcaf4492ec9","originalAuthorName":"陈云华"}],"doi":"","fpage":"58","id":"5f8d6c49-12c1-475a-892e-5e88a992463d","issue":"7","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"7deff5d0-db07-4741-bcf7-8c08ab50ecb9","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"聚磷腈"},{"id":"7235808f-30ab-4266-a0c1-1bb976d244a7","keyword":"生物医用材料","originalKeyword":"生物医用材料"},{"id":"a8019813-be95-472a-964f-f2b9c8d09c6c","keyword":"分离膜","originalKeyword":"分离膜"},{"id":"3b578007-ecf5-4e74-b855-1975f457357b","keyword":"高分子导体","originalKeyword":"高分子导体"},{"id":"50582044-7976-4fa8-8a5c-92b41c4a9016","keyword":"高分子液晶","originalKeyword":"高分子液晶"},{"id":"c1e254a6-c004-450c-a8a8-07527510daf8","keyword":"非线性光学材料","originalKeyword":"非线性光学材料"}],"language":"zh","publisherId":"cldb200407017","title":"<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的研究和应用","volume":"18","year":"2004"},{"abstractinfo":"从分子设计的角度出发,以甘氨酸乙酯、丙氨酸乙酯和苯丙氨酸乙酯为亲核试剂,成功地制备了一系列氨基酸酯单<span style=\"color:red\">取代</span>和<span style=\"color:red\">混合取代</span>的<span style=\"color:red\">聚</span>膦<span style=\"color:red\">腈</span>.研究了<span style=\"color:red\">取代</span>反应条件及亲核试剂的添加顺序对聚合物合成及结构的影响,<span style=\"color:red\">取代</span>反应过程中反应温度、反应时间对氨基酸酯<span style=\"color:red\">取代</span>度的影响,以及亲核试剂的添加顺序对聚合物合成及结构的影响,其结果为控制合成该类可降解聚合物提供了更多依据.","authors":[{"authorName":"张腾","id":"56ed675e-f10d-411c-884d-afc9d71ee58c","originalAuthorName":"张腾"},{"authorName":"洪挺","id":"1cc79603-febc-4e51-81d0-3f130a6420f4","originalAuthorName":"洪挺"},{"authorName":"吴战鹏","id":"5288999b-7e2c-4b50-8b42-21b4774d78d6","originalAuthorName":"吴战鹏"},{"authorName":"崔帆","id":"e9aaf712-488f-4b97-bb89-3dba52519635","originalAuthorName":"崔帆"},{"authorName":"蔡晴","id":"2b496401-9d30-44b7-99f7-b156d8111c88","originalAuthorName":"蔡晴"},{"authorName":"金日光","id":"bf63ce34-9bfd-43d2-9100-29bc418a874a","originalAuthorName":"金日光"}],"doi":"","fpage":"90","id":"1c12ba4c-17d0-4685-8682-e9fd91022793","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"973d75d5-9c9d-4602-a5fe-8ddbd697fd65","keyword":"<span style=\"color:red\">聚</span>膦<span style=\"color:red\">腈</span>","originalKeyword":"聚膦腈"},{"id":"58000a08-b3a7-4138-ab45-9eb87ce37a31","keyword":"氨基酸酯","originalKeyword":"氨基酸酯"},{"id":"3051fe87-ebc8-40f8-ae15-32ac4c6fb2e1","keyword":"亲核<span style=\"color:red\">取代</span>","originalKeyword":"亲核取代"},{"id":"a1cb4f10-8b26-4ac1-ae44-3295bd854d97","keyword":"生物材料","originalKeyword":"生物材料"}],"language":"zh","publisherId":"gfzclkxygc200606023","title":"氨基酸酯<span style=\"color:red\">取代</span><span style=\"color:red\">聚</span>膦<span style=\"color:red\">腈</span>的分子结构和性能关系的研究——(Ⅰ)合成与表征","volume":"22","year":"2006"},{"abstractinfo":"介绍了<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>主要的合成方法,如开环聚合、小分子单体直接聚合和室温可控聚合,综述了<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>在生物医学材料、固体聚合物电解质材料、光学材料、膜材料和防火阻燃材料等主要应用领域的研究进展,并展望了其发展前景.","authors":[{"authorName":"张宏伟","id":"01df6563-b86b-4bb5-bdd9-a92a1e14dd89","originalAuthorName":"张宏伟"},{"authorName":"李爱元","id":"243a3e67-a5cf-4142-868c-6ca08e9e5193","originalAuthorName":"李爱元"},{"authorName":"沈培康","id":"a6ae3246-c11d-4094-bce7-fe3cf9ce054c","originalAuthorName":"沈培康"}],"doi":"","fpage":"133","id":"6e2fc56a-1b1a-4673-814d-b1b39211ddc7","issue":"13","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"d2e9b1ef-fd4b-44f3-880c-146dfcbba0b4","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"聚磷腈"},{"id":"09847f5e-cc6b-4ba4-9822-3783c1c2b6d9","keyword":"合成","originalKeyword":"合成"},{"id":"f6643f3c-7988-4ebf-b421-121fefb2ecf2","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"cldb201013029","title":"<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的研究进展","volume":"24","year":"2010"},{"abstractinfo":"利用<span style=\"color:red\">聚</span>氯<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的亲核<span style=\"color:red\">取代</span>反应合成了2种咔唑全<span style=\"color:red\">取代</span>的有机<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>高分子材料,对其结构进行了表征. IR、1H NMR、31P NMR、UV-vis测试结果表明,<span style=\"color:red\">聚</span>氯<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的氯侧基全部被咔唑基团所<span style=\"color:red\">取代</span>,咔唑<span style=\"color:red\">取代</span>聚合物在紫外-可见区呈现咔唑基团的特征吸收. GPC测得2种<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的重均分子量分别为34 700和11 300. 热分析结果表明, 所合成的<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>为无定型结构,具有较低的玻璃化转变温度(5 ℃),聚合物在300 ℃左右开始分解.","authors":[{"authorName":"张丽","id":"fda2c41e-b771-4961-8751-84e5a1e20f39","originalAuthorName":"张丽"},{"authorName":"杨正","id":"7e0df3f4-8ac6-4474-8f3d-9658a6497eb3","originalAuthorName":"杨正"},{"authorName":"姜治伟","id":"80f69e6d-c53f-4c0f-b17d-b7fc9a01834f","originalAuthorName":"姜治伟"},{"authorName":"石军","id":"c889e28a-3bad-473c-8722-7e5fc3dad740","originalAuthorName":"石军"},{"authorName":"曹少魁","id":"e721b30a-faa7-49e9-9c09-f29349640aa9","originalAuthorName":"曹少魁"}],"doi":"10.3969/j.issn.1000-0518.2005.12.003","fpage":"1287","id":"2380d067-3293-4b2e-a581-083dea21904a","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"71d8e23d-839a-445a-aa81-f787151efffc","keyword":"咔唑","originalKeyword":"咔唑"},{"id":"203cb8f9-eeda-4cec-a2a4-21e9a42df0fe","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"聚磷腈"},{"id":"747217c8-f31e-4efa-96b5-e95f4d5ac4f2","keyword":"亲核<span style=\"color:red\">取代</span>","originalKeyword":"亲核取代"}],"language":"zh","publisherId":"yyhx200512003","title":"含咔唑基团的有机<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的合成与表征","volume":"22","year":"2005"},{"abstractinfo":"合成了3种以<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>为主链,接枝不同官能团的非线性化合物,分别是对硝基苯胺接枝苯酚<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>、2,4-二硝基苯胺接枝苯酚<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>、2,4-二硝基苯胺接枝咔唑<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>,对3种化合物进行光电性能测试,含咔唑<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>接枝2,4-二硝基苯胺的光电导率和电光系数是较大的。通过探索官能团结构与<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>光电性能间的关系,为实验设计合成新的非线性材料提供理论支持。","authors":[{"authorName":"张文龙","id":"4196a784-8503-416c-afdd-9839f10515c9","originalAuthorName":"张文龙"},{"authorName":"赵成龙","id":"4ff91c53-04be-47c7-9ea5-9dea8a5c1517","originalAuthorName":"赵成龙"},{"authorName":"蒋强","id":"067c241c-b9ef-4a8b-9d15-0b5c183e76ed","originalAuthorName":"蒋强"},{"authorName":"乔思怡","id":"72b99154-648e-4de2-a50e-a3746b0d9735","originalAuthorName":"乔思怡"},{"authorName":"姜文影","id":"3150bd8e-a578-499e-8df1-8f848fbb412a","originalAuthorName":"姜文影"},{"authorName":"王暄","id":"2b114e1a-9eed-473f-b811-b67755f7fe67","originalAuthorName":"王暄"}],"doi":"","fpage":"3386","id":"0850e076-1fdf-45b8-827b-b40981292773","issue":"24","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"d483469d-c048-415b-862a-3e7c349f60e9","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"聚磷腈"},{"id":"a0f3478d-b8da-4a67-9388-87c7ac3d6237","keyword":"官能团","originalKeyword":"官能团"},{"id":"f4ad080a-39b2-45dc-a4a5-578a21210728","keyword":"光电系数","originalKeyword":"光电系数"},{"id":"c3b476c3-e6c8-4e1d-a8a8-6a651b9b7788","keyword":"光电导率","originalKeyword":"光电导率"}],"language":"zh","publisherId":"gncl201224013","title":"<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>接枝官能团的光电性能","volume":"43","year":"2012"},{"abstractinfo":"通过六氯环三<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的热开环聚合合成了线性<span style=\"color:red\">聚</span>二氯<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>(PDCP)中间体,探讨了聚合时间、聚合温度单体纯度及空气湿度等对PDCP合成的影响,采用FT-IR、TGA对PDCP进行了表征.TGA结果表明,PDCP呈现明显的二段降解性;通过正丁醇对PDCP进行亲核<span style=\"color:red\">取代</span>合成了<span style=\"color:red\">聚</span>双正丁氧基<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>,采用FT-IR、TGA、SEM对<span style=\"color:red\">聚</span>双正丁氧基<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>进行了表征,TGA结果表明,<span style=\"color:red\">聚</span>双正丁氧基<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>具有优良的热稳定性和较高的残留率,SEM结果表明,材料形貌呈现无定形态分布,而且其表面比较光滑无明显缺陷.","authors":[{"authorName":"张新孟","id":"fec8661b-b3fd-4bda-8f18-86b324c2c8a8","originalAuthorName":"张新孟"},{"authorName":"王秀峰","id":"0cd15538-1abe-4093-931c-0cbf732675b4","originalAuthorName":"王秀峰"},{"authorName":"江红涛","id":"c9bcbaba-b540-42f3-a35f-13aa4be9ef30","originalAuthorName":"江红涛"},{"authorName":"伍媛婷","id":"eff9f3b0-1525-4fea-ba72-2e0aef480b1b","originalAuthorName":"伍媛婷"}],"doi":"","fpage":"100","id":"a49566c4-813e-45ec-9b65-4f77d2f743f6","issue":"20","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"0d9c3106-fa44-4ad6-96b7-9fd302a9d388","keyword":"线性<span style=\"color:red\">聚</span>二氯<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"线性聚二氯磷腈"},{"id":"10165577-0544-4f36-9e62-57e89b2ae89b","keyword":"<span style=\"color:red\">聚</span>双正丁氧基<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"聚双正丁氧基磷腈"},{"id":"5d35b191-b83b-4445-b243-d8e3f0f8657a","keyword":"亲核<span style=\"color:red\">取代</span>","originalKeyword":"亲核取代"},{"id":"658d43d4-725c-485c-bd12-0e27211c05c7","keyword":"热开环聚合","originalKeyword":"热开环聚合"},{"id":"fdc64f0d-fa27-4492-85ef-9e305d0105e8","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"cldb201020029","title":"<span style=\"color:red\">聚</span>双正丁氧基<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>的合成与表征","volume":"24","year":"2010"},{"abstractinfo":"直接利用五配位硅络合物和六氯代环三<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>反应得到耻一种星型含硅的环状<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>,并用FTIR、XRD、EDS、热分析等方法对其结构和热性能进行了表征.结果表明:产物在热分解过程中生成一类含<span style=\"color:red\">磷</span>的无机物,这类无机物具有很好的稳定性,能够在1150℃高温下不分解.并且这类无机物在热分解过程的产率较高,在空气和氮气中分别达到55%和58%以上.","authors":[{"authorName":"张亚峰","id":"fc1a4a11-2209-4206-8953-809bb4bc849a","originalAuthorName":"张亚峰"},{"authorName":"龚克成","id":"b710ec03-da89-4b81-9638-992e999d4c86","originalAuthorName":"龚克成"},{"authorName":"刘安华","id":"953dadc8-430f-409b-a8e4-4ab5ed3de1f6","originalAuthorName":"刘安华"}],"doi":"10.3969/j.issn.1671-5381.2000.04.001","fpage":"1","id":"9780e1bb-5694-4db9-8922-722a48c837f0","issue":"4","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"60a46d58-edb9-47c9-9f40-0b3fefc12e9a","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"聚磷腈"},{"id":"a4eb8229-cf0f-4e0e-9868-ad71826ed12f","keyword":"五配位硅络合物","originalKeyword":"五配位硅络合物"},{"id":"f291e81b-776a-4635-afb9-82a1ee301ea6","keyword":"合成","originalKeyword":"合成"},{"id":"6664c827-eea7-4e13-b16e-5e6e163c7ef7","keyword":"热性能","originalKeyword":"热性能"}],"language":"zh","publisherId":"hccllhyyy200004001","title":"环状含硅<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>制备与热性能","volume":"","year":"2000"},{"abstractinfo":"利用后重氮偶合方法制备了2种含咔唑双功能生色团的三<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>,并用1H NMR、31P NMR、IR、UV-Vis以及DSC等测试技术对<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>小分子的结构进行了分析和表征.31P NMR谱图上的单峰说明,六氯环三<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>上的氯已经全部被咔唑基团<span style=\"color:red\">取代</span>.1H NMR、IR、UV-Vis谱图表明,对硝基偶氮苯基团以不同比例连接在咔唑环上.DSC结果显示,<span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>小分子为完全无定型态,玻璃化转变温度随着生色团含量的增加而升高.","authors":[{"authorName":"张丽","id":"fa757086-a28b-4384-bfab-f767a5331317","originalAuthorName":"张丽"},{"authorName":"杨正","id":"59198596-3461-4408-9a58-eb9d5e87b2c2","originalAuthorName":"杨正"},{"authorName":"姜治伟","id":"ca99740e-6271-484a-949b-58a9851670f0","originalAuthorName":"姜治伟"},{"authorName":"石军","id":"56d74633-eb5d-4f31-a117-9237c3a11ffe","originalAuthorName":"石军"},{"authorName":"曹少魁","id":"df6577f2-ed5e-4a38-9ed1-df794187c47e","originalAuthorName":"曹少魁"}],"doi":"10.3969/j.issn.1000-0518.2006.03.002","fpage":"238","id":"fa386281-2005-4261-9ae4-bdce7b217daa","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"31947210-29b3-4f18-96c2-be599eae3b20","keyword":"三<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>","originalKeyword":"三聚磷腈"},{"id":"709020bc-0c8c-417f-9b3c-b08acb85bbe1","keyword":"后重氮偶合","originalKeyword":"后重氮偶合"},{"id":"5dd4efa5-ef67-435b-bab6-b581d95ef273","keyword":"咔唑","originalKeyword":"咔唑"},{"id":"6f570b7f-2693-4c2f-9547-258c13cae8ed","keyword":"光折变分子玻璃","originalKeyword":"光折变分子玻璃"}],"language":"zh","publisherId":"yyhx200603002","title":"含咔唑生色团的三<span style=\"color:red\">聚</span><span style=\"color:red\">磷</span><span style=\"color:red\">腈</span>分子玻璃的合成","volume":"23","year":"2006"}],"totalpage":2333,"totalrecord":23328}