{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"PPV类电致发光聚合物以其优良的光电性能在微电子及显示领域中得到了广泛的应用,是当今材料科学研究的热点之一.综述了PPV类聚合物的主要合成方法,并对此类材料进行了分子结构设计,同时简要地介绍了相关器件的性能.","authors":[{"authorName":"凌味未","id":"34cf6b62-e3c7-43e1-aecd-0bff72e2e1cf","originalAuthorName":"凌味未"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"2f3698ab-038b-42c8-9fdf-9ee53381fdc6","originalAuthorName":"唐先忠"},{"authorName":"李元勋","id":"764f6711-a89e-4f17-b631-8ee7574950fd","originalAuthorName":"李元勋"},{"authorName":"聂海","id":"5c6eb958-7ddf-4528-90c8-4caa7bc00b7d","originalAuthorName":"聂海"}],"doi":"","fpage":"36","id":"0461f438-c54a-4d89-9496-78867135280c","issue":"9","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"c0fab36e-0d1e-484c-ad2a-9b76173bff4c","keyword":"PPV","originalKeyword":"PPV"},{"id":"c7e85230-0c87-4fff-916e-b7ec710cca28","keyword":"电致发光","originalKeyword":"电致发光"},{"id":"9f2bd283-bc12-4a46-86f8-2ee067cfb3a2","keyword":"合成","originalKeyword":"合成"},{"id":"fd64b645-b057-489b-bc05-60cc6a7f7687","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"cldb200509011","title":"PPV类电致发光聚合物的合成及分子设计研究","volume":"19","year":"2005"},{"abstractinfo":"神经毒剂由于呈现氢键碱性,因此以氢键酸性物质作敏感材料可以提高传感器的灵敏度、增强选择性、缩短响应时间.综述了氢键酸性敏感材料的研究现状,结果表明超支碳硅聚合物与线形、超支碳硅氧烷聚合物相比具有响应幅度大、工作温度高、抗干扰性强等优点.","authors":[{"authorName":"王志东","id":"3cb6af7a-1048-4d7d-970e-453fe65fc435","originalAuthorName":"王志东"},{"authorName":"杜晓松","id":"cfbcd9e7-eb91-4043-9fcf-4569dc4ddefa","originalAuthorName":"杜晓松"},{"authorName":"黄嘉","id":"e9483cdf-c7bf-46ea-9800-ebfef52e3ca9","originalAuthorName":"黄嘉"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"447ee6ea-c051-466b-a4d6-bc950f9092da","originalAuthorName":"唐先忠"},{"authorName":"蒋亚东","id":"00d4a79a-186b-469c-b722-dd8432f99806","originalAuthorName":"蒋亚东"}],"doi":"","fpage":"81","id":"3f065fdf-ef1e-43fd-8d82-8fb38b6f5d11","issue":"11","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"13641e94-86b8-4a3f-bc2b-5e07d9da5d9e","keyword":"神经毒剂","originalKeyword":"神经毒剂"},{"id":"925eb994-670b-493b-8655-501682318c96","keyword":"敏感材料","originalKeyword":"敏感材料"},{"id":"0885dd06-66a8-4273-8042-01e86e9f1d73","keyword":"氢键酸性聚合物","originalKeyword":"氢键酸性聚合物"},{"id":"41085434-b65d-4efa-b8d6-4f513d2c985e","keyword":"超支化聚合物","originalKeyword":"超支化聚合物"}],"language":"zh","publisherId":"cldb200911018","title":"氢键酸性聚合物神经毒剂敏感材料的研究进展","volume":"23","year":"2009"},{"abstractinfo":"光敏聚酰亚胺(PSPI)具有高耐热性、良好的电绝缘性、优异的机械和感光性能等,被认为是极具应用前景的光电功能材料,已成为新型功能高分子材料的研究热点.从已得到商品化的PSPI材料出发,通过材料的分子结构设计,提出了合成新型PSPI的新思路,并根据有机合成的原理,简要论述了这几种新型PSPI的制备方法及提高PSPI性能的几条途径.","authors":[{"authorName":"李元勋","id":"76873a10-80ac-426b-b534-56e080d33d4a","originalAuthorName":"李元勋"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"0e64a45d-db0a-4847-8ce2-7199fcb475ee","originalAuthorName":"唐先忠"},{"authorName":"何为","id":"c844805e-817b-4668-b1b7-ac59388e1aac","originalAuthorName":"何为"},{"authorName":"韩莉坤","id":"145ec7f4-5575-4cac-82bd-6037fb160b1c","originalAuthorName":"韩莉坤"}],"doi":"","fpage":"44","id":"5c9645d4-3d4b-47ca-8d99-5a520847272e","issue":"12","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"4da96fa3-5c2d-418d-ab56-458e78bc3188","keyword":"光敏聚酰亚胺","originalKeyword":"光敏聚酰亚胺"},{"id":"f13b7dfb-67f3-4285-881c-e0242d3a93aa","keyword":"光敏性二胺","originalKeyword":"光敏性二胺"},{"id":"267e582b-44bd-4a83-a8ad-9ca5a87e5dc8","keyword":"羟醛缩合","originalKeyword":"羟醛缩合"}],"language":"zh","publisherId":"cldb200412013","title":"微电子用光敏聚酰亚胺材料的分子设计研究","volume":"18","year":"2004"},{"abstractinfo":"采用未见文献报道的NaCl/AlCl3熔盐法合成多省并醌聚合物,并与常规硝基苯溶剂法进行对比,分析了聚合物的结构与热稳定性,测试了样品的介电常数与介电损耗。研究结果表明多省并醌聚合物热稳定性很好,5%质量损失温度〉380℃。20Hz下熔盐法合成的聚合物介电常数达10471;在硝基苯中所得聚合物的介电常数为9.55。多省并醌聚合物的介电常数随外加电场频率升高而降低。","authors":[{"authorName":"郑华靖","id":"55100aac-fb9d-4b09-bd64-efb8b953d6e6","originalAuthorName":"郑华靖"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"47836bb8-6724-42d5-84b6-613699518110","originalAuthorName":"唐先忠"},{"authorName":"蒋亚东","id":"3144f4ac-0f8b-485e-acd1-a00bb4c7bb80","originalAuthorName":"蒋亚东"},{"authorName":"阮政","id":"8dcf5e12-4d23-46ad-b7aa-fd201e34c00d","originalAuthorName":"阮政"}],"doi":"","fpage":"1855","id":"5d248a3b-8437-49cd-a699-6ca19dd774b8","issue":"10","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"76e36de8-0276-45b8-adfe-151ebf01e609","keyword":"多省并醌聚合物","originalKeyword":"多省并醌聚合物"},{"id":"c7c2dd22-63aa-49f5-9f3c-1c12c5b50006","keyword":"熔盐法","originalKeyword":"熔盐法"},{"id":"fd6f84c6-aba2-426d-bb4c-e53a88f5fdbd","keyword":"高介电常数","originalKeyword":"高介电常数"},{"id":"8879bba0-b0e7-495c-9106-9f429c672de5","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"gncl201110032","title":"多省并醌高介电聚合物的结构与特性的研究","volume":"42","year":"2011"},{"abstractinfo":"含多氰基的有机非线性光学材料是近年来有机非线性光学材料研究的热点.这类材料的合成研究呈现出共轭链由短到长,分子由简单到复杂,由一维到多维的趋势.随着研究技术的成熟,其在器件应用方面的改性也受到重视,目前,很多有机非线性光学材料都已被制作成器件而得到应用.综述了这类材料的合成研究情况,探讨了具有高电光活性和低光损耗的非线性光学材料的合成技术,展望了今后有机非线性光学材料分子设计合成可能的发展方向.","authors":[{"authorName":"<span style=\"color:red\">唐</span>翔","id":"c13cda25-6509-4f50-b057-eaa2afcf0a14","originalAuthorName":"唐翔"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"ddbe92d7-a37a-440d-a602-514f989554cb","originalAuthorName":"唐先忠"},{"authorName":"赵波","id":"d3114a75-efe3-42e4-ba2c-5ae069e55149","originalAuthorName":"赵波"},{"authorName":"闫裔超","id":"4b2de29e-5422-4433-9426-805e66ae9b29","originalAuthorName":"闫裔超"}],"doi":"","fpage":"19","id":"74472d73-98bc-4128-97be-a66d70c931e8","issue":"17","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"f6f8807e-28c5-4c28-8553-fffe16c15d02","keyword":"有机非线性光学材料","originalKeyword":"有机非线性光学材料"},{"id":"db4e7a35-741a-484e-aca0-694524172426","keyword":"合成","originalKeyword":"合成"},{"id":"ffa6c402-a49d-4325-ac3d-2357de6f4c7b","keyword":"多氰基","originalKeyword":"多氰基"},{"id":"351dab9a-3de3-49fb-8895-bcab499c4599","keyword":"共轭链","originalKeyword":"共轭链"}],"language":"zh","publisherId":"cldb200917004","title":"含多氰基的有机非线性光学材料合成研究进展","volume":"23","year":"2009"},{"abstractinfo":"以对乙酰氨基苯甲醛、间乙酰氨基苯乙酮为原料经两步反应合成具有光敏性能的1-(3-氨基苯基)-3-(4-氨基苯基)-2-丙烯-1-酮.采用溶液缩聚及化学亚胺化法制备了相应的光敏聚酰亚胺.光敏性二胺经液相色谱分析其纯度分别为99.92%,紫外可见最大吸收波长为349nm.光敏聚酰亚胺的耐热温度超过400℃,紫外可见最大吸收波长为365nm.所得方法操作简便,收率较高,原料易得.并用元素分析、核磁共振、红外光谱等手段对产物的结构进行了表征.","authors":[{"authorName":"李元勋","id":"23b08b76-818c-49e4-926d-489e69ef8df3","originalAuthorName":"李元勋"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"dc87d8d5-38d1-4f62-9f32-3d3adf12e96e","originalAuthorName":"唐先忠"},{"authorName":"何为","id":"097720f1-e443-490e-9b5f-d384b6ccc4d3","originalAuthorName":"何为"},{"authorName":"韩丽坤","id":"c04387f4-b005-4f7e-a966-c70beb0b7be7","originalAuthorName":"韩丽坤"}],"doi":"10.3969/j.issn.1005-0299.2006.01.020","fpage":"66","id":"8257de10-8617-4426-8d48-66eb2459fcfb","issue":"1","journal":{"abbrevTitle":"CLKXYGY","coverImgSrc":"journal/img/cover/CLKXYGY.jpg","id":"14","issnPpub":"1005-0299","publisherId":"CLKXYGY","title":"材料科学与工艺"},"keywords":[{"id":"92f76dfe-d3bb-47a5-96a0-343c7ce3c777","keyword":"1-(3-氨基苯基)-3-(4-氨基苯基)-2-丙烯-1-酮","originalKeyword":"1-(3-氨基苯基)-3-(4-氨基苯基)-2-丙烯-1-酮"},{"id":"651add84-4396-4f9b-aec4-26d0c7d06c84","keyword":"光敏聚酰亚胺","originalKeyword":"光敏聚酰亚胺"},{"id":"a9724657-015b-4a88-a3d8-24a712447767","keyword":"羟醛缩合","originalKeyword":"羟醛缩合"},{"id":"c7640d51-7e47-4e9d-9e87-15ed7ecb2253","keyword":"光敏性二胺","originalKeyword":"光敏性二胺"},{"id":"024f9046-2443-47d3-a154-6674f2dff23f","keyword":"聚合","originalKeyword":"聚合"}],"language":"zh","publisherId":"clkxygy200601020","title":"结构型光敏聚酰亚胺的合成研究","volume":"14","year":"2006"},{"abstractinfo":"光敏苯并环丁烯(BCB)以其优良的电特性、极低的吸水率以及能够大大简化器件制造工艺等优点成为微电子领域特别是用于多芯片组件(MCM)最理想的绝缘介质材料.介绍了目前光敏BCB的研究现状及应用情况,分析了两种常用的光敏BCB的结构和合成方法,并提出了一种新型光敏BCB的设计思路.","authors":[{"authorName":"王姣","id":"687a121e-f3f2-4d67-9422-663ef4b901bc","originalAuthorName":"王姣"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"447f4881-b886-4c71-b324-6ac697785048","originalAuthorName":"唐先忠"},{"authorName":"赵松楠","id":"7837235c-47ca-464d-8ee5-8ab525b0c78b","originalAuthorName":"赵松楠"},{"authorName":"李元勋","id":"aa5ee314-9a3b-4573-bf3d-2e007bd620f7","originalAuthorName":"李元勋"}],"doi":"","fpage":"56","id":"8c0c371c-875c-48dd-b33f-6604d827df4f","issue":"8","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"82e9b87b-00e0-4d9c-a5d3-a5c9ccefa261","keyword":"光敏","originalKeyword":"光敏"},{"id":"30777d47-924f-40c6-a97e-d6e533dac20b","keyword":"BCB","originalKeyword":"BCB"},{"id":"01086ff2-9099-42a4-aa45-2676bebfef9c","keyword":"合成","originalKeyword":"合成"},{"id":"d27913bf-735a-4ca4-9f2d-5717e247796a","keyword":"分子设计","originalKeyword":"分子设计"}],"language":"zh","publisherId":"cldb200708015","title":"光敏苯并环丁烯的合成研究","volume":"21","year":"2007"},{"abstractinfo":"聚对苯乙炔及其衍生物由于具有独特的导电性和荧光特性,目前广泛应用于有机光致器件、激光器件以及光探测器等领域.Gilch法合成聚对苯乙炔材料中往往存在缺陷,这些缺陷对材料及器件的光电性能产生影响.综述了控制PPV凝胶及苄基-二苯乙炔缺陷的方法,介绍了PPV分子量的影响因素.","authors":[{"authorName":"闫裔超","id":"15438406-81ba-40f7-836c-977d6c3daa53","originalAuthorName":"闫裔超"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"583f4348-10bd-4632-9743-f3173a34cc94","originalAuthorName":"唐先忠"},{"authorName":"王姣","id":"3997a905-0e86-4a61-b056-6f379c2587e4","originalAuthorName":"王姣"},{"authorName":"黄嘉","id":"08ed9d97-5d78-4e28-b079-387884fa0f33","originalAuthorName":"黄嘉"}],"doi":"","fpage":"108","id":"a8c79173-c021-48ce-9381-dda69d6018b8","issue":"6","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"e0d9ec37-16c5-43c3-a2da-a431d239b00f","keyword":"聚对苯乙炔","originalKeyword":"聚对苯乙炔"},{"id":"074c8b30-8ac0-443e-ad15-80384ae66696","keyword":"凝胶","originalKeyword":"凝胶"},{"id":"caf29a76-85e7-4abd-bbc2-bfedac969660","keyword":"苄基-二苯乙炔","originalKeyword":"苄基-二苯乙炔"},{"id":"72b71644-59a7-49d7-b8a5-69c1e19f0a6e","keyword":"分子量","originalKeyword":"分子量"}],"language":"zh","publisherId":"cldb200806026","title":"Gilch法合成聚对苯乙炔缺陷及分子量的控制","volume":"22","year":"2008"},{"abstractinfo":"合成了2种含三氰基呋喃受体的新型非线性光学(NLO)生色团分子.利用元素分析、1H-NMR和FT-IR对这些分子的结构进行了表征.TGA测试结果表明这两种材料具有较好的热稳定性,其热分解温度(Td)最高达311℃.UV-Vis光谱表明材料具有较好的透光性.用DFT-B3LYP方法在6-31G基组下对分子的结构进行了优化并计算出其静态二阶极化率β值最高达5.9×10-28esu.","authors":[{"authorName":"<span style=\"color:red\">唐</span>翔","id":"2c928713-eecd-457b-ae3e-6401dbf58022","originalAuthorName":"唐翔"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"5a21b14a-1ee9-4cc1-b533-2a7118876eaa","originalAuthorName":"唐先忠"},{"authorName":"赵波","id":"15c01d94-0384-4bf1-8a30-53b5216edf70","originalAuthorName":"赵波"},{"authorName":"王洋","id":"abd03138-5cc7-4e43-ad81-3f9ec2e9b8ad","originalAuthorName":"王洋"}],"doi":"","fpage":"1340","id":"bfb7154b-48fe-413b-898f-02e6c949edc5","issue":"8","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"8375f372-5153-4b17-b616-8554fa32da72","keyword":"非线性光学材料","originalKeyword":"非线性光学材料"},{"id":"f9bb70e9-f274-46de-8b48-00c1013046eb","keyword":"三氰基呋喃","originalKeyword":"三氰基呋喃"},{"id":"88ceb91a-399a-49b9-96e5-00068032b4f9","keyword":"热性能","originalKeyword":"热性能"},{"id":"f4cd3a6a-e8cf-4cd0-a438-3697053c8783","keyword":"DFT","originalKeyword":"DFT"}],"language":"zh","publisherId":"gncl201008012","title":"新型含三氰基呋喃受体的非线性光学材料合成及性能研究","volume":"41","year":"2010"},{"abstractinfo":"合成了两种新型蒽醌单体：1,4-二（辛氧基）蒽-9,10-二酮和1,4-二（丁氧基）蒽-9,10-二酮。通过红外、核磁和元素分析确证了单体的结构。DSC、TG结果显示两种新型单体的5%质量损失温度最高可达266.4℃。将新型蒽醌单体与均苯四甲酸酐在硝基苯中预聚,再将预聚产物在NaCl/AlCl3熔盐中继续反应得到改性多省并醌聚合物。通过红外光谱、热分析等方法表征改性聚合物的结构并研究了改性聚合物的介电性能。研究结果表明改性聚合物仍有较好的热稳定性,5%质量损失温度〉387℃;20Hz下改性聚合物的最大介电常数值为100,比改性前低。同时合成了乙醇可溶的改性多省并醌聚合物,20Hz下最大介电常数为19997。","authors":[{"authorName":"姚子君","id":"18ecc4cd-e68a-490e-80e5-0a4ebf4a9807","originalAuthorName":"姚子君"},{"authorName":"郑华靖","id":"43c69133-6c72-4eb4-99c2-88514d1760df","originalAuthorName":"郑华靖"},{"authorName":"<span style=\"color:red\">唐</span><span style=\"color:red\">先</span><span style=\"color:red\">忠</span>","id":"42c166e1-2c2c-456b-a7d7-251243d8743e","originalAuthorName":"唐先忠"},{"authorName":"阮政","id":"043cdc68-5627-4577-b472-28ab55f9f337","originalAuthorName":"阮政"}],"doi":"","fpage":"2588","id":"c9606ec3-bdcb-4c1c-b0ec-79fed9dd5166","issue":"19","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"1d806cd9-781c-4aa5-896d-f6285f553b26","keyword":"多省并醌聚合物","originalKeyword":"多省并醌聚合物"},{"id":"d8cb8b0f-5bbf-4d92-a4bd-4f291656438b","keyword":"熔盐法","originalKeyword":"熔盐法"},{"id":"4a9b99a4-c044-4fba-82d3-094d0584e0ce","keyword":"高介电常数","originalKeyword":"高介电常数"},{"id":"0c9a2983-f694-4d9a-bdc2-2b0093d4ddd4","keyword":"改性聚合物","originalKeyword":"改性聚合物"}],"language":"zh","publisherId":"gncl201219003","title":"改性多省并醌的合成与性能研究","volume":"43","year":"2012"}],"totalpage":514,"totalrecord":5132}