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用固相反应合成Mg2Si1-xGex热电固溶体

姜洪义 , 张联盟

硅酸盐通报 doi:10.3969/j.issn.1001-1625.2002.02.003

利用二次固相反应合成的方法,在低温下首次合成了Mg2Si1-xGex系连续固溶体;所制得的产品呈单相特征,不含任何氧化物或碳化物,且颗粒粒径大幅度细化.对产物相组成以及固相反应过程中热量的变化,掺Ge对Mg2Si1-xGex晶胞参数的影响都进行了讨论.

关键词: 固相反应 , Mg2Si1-xGex , 热电化合物

Solid State Synthesis and Thermoelectric Properties of Mg-Si-Ge System

Renbo SONG , Yazheng LIU , Tatsuhiko AIZAWA

材料科学技术(英)

Thermoelectric materials, Mg2Si1-xGex(x=0, 0.2, 0.4, 0.6, 0.8, 1), have been prepared by bulk mechanical alloying (BMA) and hot pressing (HP). The electrical conductivity, Seebeck coefficient and thermal conductivity were measured from room temperature up to about 700 K. The electrical conductivity of all the samples increases with increasing temperature, while the Seebeck coefficient and thermal conductivity decrease with increasing temperature. Mg2Si and Mg2Si0.8Ge0.2 possess negative type of conductivity, while for other compounds it is positive. At the same time, the effect of hot processing condition on thermoelectric properties was also investigated. The maximum figure of merit of Mg2Si0.6Ge0.4 was obtained with the processing parameter of BMA at 600 cycles and hot pressing at 773 K and 1 GPa for 1 h.

关键词: Solid-state synthesis , null , null , null , null

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