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Properties and Application of Nanocrystalline Poly (vinyl chloride)

Chuanxi XIONG , Hong YANG , Lijie DONG , Qihong LIU , Qingmin LIU

材料科学技术(英)

The structure and properties of nanocrystalline PVC were investigated. The crystalline region of nanocrystalline PVC was observed by TEM to be 80 nm. The melting point of nanocrystalline PVC was found to be 128ºC which is obviously lower than typical PVC (210ºC). The X-ray diagram indicated that the crystal existed in nanocrystalline PVC. The evident effect of self-plasticizing and reinforcement appeared when nanocrystalline PVC was added. The optimum amount for self-plasticizing is about 10%. The maximal impact strength of 95.1 kJ/m2 was achieved by adding 20% nanocrystalline PVC and tensile strength with 56.2 MPa which was 122% of pure PVC was obtained after adding 5% nanocrystalline PVC.

关键词: Nanocrystalline PVC , null , null , null

碳纤维/环氧复合材料壳体补强新工艺及方法对比研究

王欢 , 刘勇琼 , 廖英强 , 田蔚

宇航材料工艺

为了降低复合材料壳体封头区域的应力集中,提高壳体整体性能,对复合材料壳体薄弱区进行补强以及采用何种方法进行补强是关键问题.本文以碳纤维Ф150 mm复合材料壳体为研究对象,以理论分析和有限元分析为依据,分别采用碳布补强和纤维缠绕补强对壳体前后封头及赤道附近位置进行补强.试验结果表明:纤维缠绕补强效果明显好于碳布补强,壳体特性系数由40.3 km提高到48.5 km,应力平衡系数提高到0.95,纤维发挥强度由3 378.1 MPa提高到4 058.4 MPa.

关键词: 复合材料壳体 , 补强 , 壳体特性系数 , 应力平衡系数 , 纤维发挥强度

耐高低温耐压橡胶弹性材料

余惠琴 , 刘晓红 , 张金明 , 景宽 , 陈雯

宇航材料工艺 doi:10.3969/j.issn.1007-2330.2014.03.010

采用丁异戊橡胶作为主体材料,从补强体系、硫化体系和增塑剂三个方面分析了它们对橡胶高低温性能、耐老化性能和耐压性能的影响.粒径小、结构度高的炭黑和气相白炭黑并用可有效改善橡胶的力学性能;硫磺含量在0.8% ~1.3%使得硫化橡胶既具备较好的高低温性能又兼顾较好的耐老化性能;增塑剂可有效调整橡胶硬度和耐压性能.并对研制的丁异戊橡胶弹性材料及其柔性接头构件耐高低温性能及耐压性能进行分析.结果表明,弹性材料高低温剪切性能及耐压性能表征结果能初步反映柔性接头构件的摆动性能及耐压性能.

关键词: 丁异戊橡胶 , 补强剂 , 硫化体系 , -40 ~ +60℃ , 压缩

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