刘鸿鹏
,
乔文明
,
詹亮
,
凌立成
新型炭材料
doi:10.1016/S1872-5805(08)60042-6
采用催化化学气相沉积法在微米硅颗粒表面原位生长纳米炭纤维得到纳米炭纤维/硅复合材料.利用SEM,TEM和XRD表征了复合材料的表面形态和微观结构,并考察了其作为锂离子电池负极材料的循环性能.电化学测试表明:与纳米纤维/硅机械混合物相比,原位生长纳米炭纤维/硅复合材料具有更高的可逆容量(1042mAh/g)和更好的循环稳定性.根据SEM和交流阻抗分析结果,分析了纳米炭纤维/硅复合材料在充放电过程中的结构演变机制,其优异的电化学性能主要来源于原位生长纳米炭纤维与硅颗粒之间良好的接触性能.
关键词:
锂离子电池
,
负极材料
,
纳米炭纤维
,
硅
L.J. Zhu
金属学报(英文版)
Because Si is a noncarbide forming element, a multiphase microstructure consisting of ferrite, bainite, and retained austenite, at room temperature, can be formed by controlling the thermomechanical process strictly. The cooling schedules must be restricted by the formation of pearlite and cementite. In the present article, a new integrated mathematical model for prediction of microstructure evolution during controlled rolling and controlled cooling is developed for a typical kind of low carbon Si-Mn TRIP steel, which consists of temperature simulation, recrystallization, and transformation models. The influence of Si contents has been thoroughly investigated. The calculated results indicate that Si retards recrystallization, restrains austenite grain growth as well as accelerates polygonal ferrite transformation.
关键词:
TRIP steel
,
null
,
null
,
null
,
null
Yu CHEN
材料科学技术（英）
strength of 775 MPa, high elongation of 29% and low ductile-brittle transmission temperature less than -80℃ has been developed in laboratory based on the common silicon and manganese chemical composition. The experimental results showed that the microstructures were featured with ultra fine grain size less than 5 μm, appropriate retained austenite volume fraction around 11.8% and purified ferrite grain, which may result in well balanced mechanical properties for the steel.
关键词:
Ultra fine grain
,
null
,
null
,
null
,
null
Chong TIAN
材料科学技术（英）
Silicon carbide (SiC) foams with a continuously connected open-cell structure were prepared and characterized for their mechanical performance. The apparent densities of SiC foams were controlled between about 0.4 and 1.3 g/cm3, with corresponding compressive strengths ranging from about 13 to 60 MPa and flexural strengths from about 8 to 30 MPa. Compressive testing of the SiC foams yielded stress-strain curves with only one linear-elastic region, which is different from those reported on ceramic foams in literature. This can possibly be attributed to the existence of filaments with fine, dense and high strength microstructures. The SiC and the filaments respond homogeneously to applied loading.
关键词:
Silicon carbide foams
,
carbide
,
foams
,
Apparent
,
density
,
S
