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BEHAVIOUR OF Co_5Cr_3Si_2 PHASE IN Cu-RICH ALLOYS CONTAINING Co,Cr AND Si

ZHUANG Yinghong Guangxi University , Nanning , China ZHUANG Yinghong Department of Physics , Guangxi University , Nanning , China

金属学报(英文版)

The major phases in the Cu-rich alloys containing Co,Cr and Si are α-Cu(a solid solution of Co,Cr and Si in Cu),χ-phase(Co_5Cr_3Si_2)and Co_2Si.In comparison with reference sample,it has been detected that the crystal structure of Co_5Cr_3Si_2 is cubic,α-Mn type with a=0.8694 nm.The melting temperature of χ-phase and the alloy are higher than that of the pure Cu,namely,1535 and 1389 K respectively.During ageing treatment,the Co_2Si phase precipitates out from α-Cu and χ-phase simultaneously,but the hardening effect is mainly contributed by the precipitation from α-Cu.

关键词: Cu-rich alloy , null

MgO-Al2O3-ZrO2系相关系辨析

高振昕

耐火材料 doi:10.3969/j.issn.1001-1935.2017.01.020

为了阐述应用相图的局限性,评议了MgO-Al2O3-ZrO2系相图和相关文章.在《Phase Equilibria Dia-grams》相平衡图册中有两份内容不同的MgO-Al2O3-ZrO2系相图,分别为Fig.10087(Zr-306)和Fig.10087(Zr-307).前者认为存在一个组成为MgsAlz 4 Zr1.7 O12或Mg4.68 Al2.64 Zr1.68 O12的三元化合物;而后者认为是MgAl2O4-ZrO2分系.但问题是缺欠表征X相的显微结构鉴定.需要指出的是,在应用任一相图时受反应动力学限制,只有局部能达到相图预示的平衡.

关键词: MgO-Al2O3-ZrO2系相图 , MgAl2O4-ZrO2分系相图 , X相 , 显微结构

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