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稀土钇改性离子镀Ti(Y)N膜与A3钢基材界面的结构特性

刘长清 , 于力 , 于志明 , 金柱京 , 吴维(?)

金属学报

采用透射电子显微镜及微衍射技术,研究了稀土钇改性的离子镀Ti(Y)N膜与A3钢基材之间的界面精细结构。结果表明:Ti(Y)N/A3系统界面是由三个亚层构成,由于Y的添加导致了界面三个亚层中形成了Y_6Fe_(23),Y和YN相,其中Y_6Fe_(23)和Y与α-Fe,FeTi及Ti_2N相之间存在一定的位向关系。本文还讨论了该界面形成机理。

关键词: 离子镀 , interface , sublayer , Y-modification

MICROSTRUCTURE OF INTERFACE BETWEEN Y-MODIFIED REACTIVE ION PLATED Ti(Y)N COATING AND SUBSTRATE STEEL A3

LIU Changqing YU Li YU Zhiming JIN Zhujing WU Weitao Corrosion Science Laboratory , Institute of Corrosion and Protection of Metals , Academia Sinica , Shenyang , China

金属学报(英文版)

The fine rnicrostrueture of the Y-modified ion plated Ti(Y)N coating/substrate steel A3 system has been examined by means of TEM and microdiffraction technique.It was revealed that the interface consists of 3 sublayers,i.e.α-Fe+Y_6Fe_(23),Ti+Y+FeTi and Ti_2N+YN +Ti_xN_y.The thicknesses of them are about 200,50 and 120 nm respectively.The phases in the transition area seem to have certain orientation relations.The mechanism of interface formation has also been discussed.

关键词: Ti(Y)N coating , null , null , null

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