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Hafnium in Aluminum Alloys: A Review

Zhi-Hong Jia , Hui-Lan Huang , Xue-Li Wang , Yuan Xing , Qing Liu

金属学报(英文版) doi:10.1007/s40195-016-0379-0

Lots of the available literatures on hafnium in aluminum alloys are reviewed. The new binary Al-Hf phase diagram is simply assessed. Two ternary phase diagrams including Al-Hf-Zr and Al-Hf-Sc are accounted for, with emphasis on the aluminum rich part of the diagrams. The relationship between different structure Al3Hf and several different formation mechanisms including the probable phase transformation mechanisms is described. The continuous Al3Hf phase particles can serve as a grain refiner in the Al melt and a precipitate for controlling the grain structure of the alloy and a strengthening precipitate. A series of effects of Fe, Si, Zr, Sc and Li addition on the behavior of Al3Hf and Al alloys are given. Moreover, the effects of Hf on the microstructure and properties of Al alloys, such as hardness and creep, are reviewed. Finally, some views of Hf-containing Al alloys are summarized.

关键词:

Al-Hf , Phase , diagram , Al3Hf , precipitate , Microstructure , Properties

材料在高温高压水溶液中的电化学行为研究现状与进展

黄军波吴欣强韩恩厚柯伟

中国腐蚀与防护学报

综述了高温高压电化学池和电极的应用研究现状及存在的问题。介绍了高温水化学对材料腐蚀的影响。阐述了高温高压电化学技术应用在高温高压水溶液中的最新研究成果,包括高温E-pH图、极化曲线、电化学阻抗谱和电化学噪声,并提出了需要进一步研究的方向。

关键词: 高温 , high pressure , electrochemistry , aqueous electrolyte , potential-pH , diagram

环烷酸和硫化氢腐蚀体系的热力学分析

高延敏 , 陈家坚 , 柯克

中国腐蚀与防护学报

从热力学角度探讨了环烷酸-铁-硫化氢腐蚀体系的热力学性质,结果表明:在该体系中,腐蚀产物受硫化氢和环烷酸分压影响;钝化区为硫化氢腐蚀,硫化物在膜中的扩散为速率控制步骤;在腐蚀区这环烷酸腐蚀,环烷酸与金属表面的反应为速率控制步骤。根据相图,分析了两次出现腐蚀高峰的原因。

关键词: 环烷酸 , hydrogen sulfide , diagram

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