{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以偏苯三酸酐(TMA)为原料,分别与4,4'-<span style=\"color:red\">二</span>氨基<span style=\"color:red\">二</span>苯醚、4,4'-<span style=\"color:red\">二</span>氨基<span style=\"color:red\">二</span>苯甲烷、1,6-己<span style=\"color:red\">二</span>胺反应,得到三种含<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>结构的<span style=\"color:red\">二羧酸</span>产物( DIDA-a、DIDA-b、DIDA-c )。利用傅里叶红外光谱( FT-IR )、核磁共振氢谱(1 H NMR)对<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span><span style=\"color:red\">二羧酸</span>的结构进行表征。通过单因素实验,考察溶剂用量、反应时间、反应温度和反应物摩尔比对<span style=\"color:red\">二</span>酸产物收率的影响,得出DIDA-a的优化合成条件：偏酐起始浓度1.11mol/L,<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>化反应时间6h,<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>化反应温度140℃,TMA和<span style=\"color:red\">二</span>胺摩尔比2.05；DIDA-b的优化合成条件：偏酐起始浓度1.05mol/L,<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>化反应时间5.5h,<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>化反应温度145℃,TMA和<span style=\"color:red\">二</span>胺摩尔比2.02；DIDA-c的优化合成条件：偏酐起始浓度0.95mol/L,<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>化反应时间5h,<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>化反应温度135℃,TMA 和<span style=\"color:red\">二</span>胺摩尔比2.03。","authors":[{"authorName":"王玲珑","id":"532b93b0-36a3-4bde-baff-393005497737","originalAuthorName":"王玲珑"},{"authorName":"潘鹤林","id":"34569f86-349d-4dec-a0a3-000aa8c1c1c1","originalAuthorName":"潘鹤林"},{"authorName":"李盛玉","id":"4760ae35-3d25-4d80-80d0-db50dea67d1a","originalAuthorName":"李盛玉"},{"authorName":"高婷","id":"66a9ae56-d78c-4eb7-9c12-ac13d9bb613e","originalAuthorName":"高婷"},{"authorName":"曹正国","id":"9a77fec5-8955-4cd6-9553-5b3cf2d4e361","originalAuthorName":"曹正国"},{"authorName":"任伟","id":"53c2d41d-f8ec-42dc-bc3b-2153862657e2","originalAuthorName":"任伟"}],"doi":"","fpage":"22","id":"b3517c35-f293-453c-8993-5509cdd18f30","issue":"2","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"53d989b0-f654-483d-a25e-d175daa98b07","keyword":"偏苯三酸酐","originalKeyword":"偏苯三酸酐"},{"id":"5c7f9e02-2a13-458a-94cd-f3cdb546b7af","keyword":"<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span><span style=\"color:red\">二羧酸</span>","originalKeyword":"酰亚胺二羧酸"},{"id":"e63f632b-e3fa-4b2b-8ee5-908e91584f0a","keyword":"<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>化","originalKeyword":"酰亚胺化"}],"language":"zh","publisherId":"hccllhyyy201402007","title":"<span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span><span style=\"color:red\">二羧酸</span>的合成研究","volume":"","year":"2014"},{"abstractinfo":"以苝四酸酐为原料合成了1,7-<span style=\"color:red\">二</span>溴-3,4,9,10-苝四酸酐(PeryBr_2)、N,N'-<span style=\"color:red\">二</span>(十二烷基)-1,7-<span style=\"color:red\">二</span>溴-3,4,9,10-苝四<span style=\"color:red\">羧酸</span><span style=\"color:red\">二</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>(DD-PeryBr_2)和N,N'-<span style=\"color:red\">二</span>(十二烷基)-1,7-<span style=\"color:red\">二</span>对叔丁基苯氧基-3,4,9,10-苝四<span style=\"color:red\">羧酸</span><span style=\"color:red\">二</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>(DD-PeryBp_2) 3种苝四<span style=\"color:red\">羧酸</span><span style=\"color:red\">二</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>类化合物,并对其结构和性能利用紫外-可见吸收光谱、傅立叶红外光谱、核磁共振、质谱、热分析和荧光光谱测试技术进行了表征和测试. 结果表明,DD-PeryBp_2能很好的溶于甲苯、氯仿、四氢呋喃等常用有机溶剂. 紫外可见最大吸收波长和荧光最大发射波长分别为548和576 nm. DD-PeryBp_2具有很好的热稳定性,质量损失5%时的温度为433 ℃.","authors":[{"authorName":"徐业伟","id":"cbdb53cb-ee51-4fed-8a79-74f7987a1881","originalAuthorName":"徐业伟"},{"authorName":"朱方华","id":"5c4facaf-2101-4f72-a34b-e06dfc952c1b","originalAuthorName":"朱方华"},{"authorName":"张海连","id":"1ae42d1a-3ca0-4f71-a8da-f1d5d3bde152","originalAuthorName":"张海连"},{"authorName":"王鹏","id":"5b3ace54-e259-4ffd-9ca7-e2e507ce3aaf","originalAuthorName":"王鹏"},{"authorName":"张林","id":"a20a0054-bdcc-46ed-9a39-75222fcdce2d","originalAuthorName":"张林"}],"doi":"10.3969/j.issn.1000-0518.2009.11.004","fpage":"1269","id":"bc7f677a-4f50-439f-bc65-5b0ab13809fd","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"058517b1-858b-4e5b-9c61-45acd044ce1d","keyword":"苝四<span style=\"color:red\">羧酸</span><span style=\"color:red\">二</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"苝四羧酸二酰亚胺"},{"id":"c87d6c25-fb94-4334-8127-3c7bd5544f47","keyword":"溶解性","originalKeyword":"溶解性"},{"id":"828b9301-9c0b-4637-8e02-a3ef59a014e6","keyword":"热稳定性","originalKeyword":"热稳定性"},{"id":"d7749a28-4ba0-449a-b1cc-b49c91993081","keyword":"发光材料","originalKeyword":"发光材料"}],"language":"zh","publisherId":"yyhx200911004","title":"可溶性苝四<span style=\"color:red\">羧酸</span><span style=\"color:red\">二</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>发光材料的合成及表征","volume":"26","year":"2009"},{"abstractinfo":"<span style=\"color:red\">二</span>环[2.2.1]庚烷<span style=\"color:red\">二羧酸</span>盐和<span style=\"color:red\">二</span>环[2.2.2]庚烷<span style=\"color:red\">二羧酸</span>盐是重要的分散型聚丙烯成核剂,HPN-68是最优秀的商业化产品.该类成核剂最大的特点是可以提高聚丙烯的结晶温度和改性PP收缩的各向同性.详细介绍了该类成核剂的结构、制备方法和在聚丙烯中的应用.","authors":[{"authorName":"史建公","id":"955cba93-6e26-41d4-bbb6-8e7edc39e67f","originalAuthorName":"史建公"},{"authorName":"张敏宏","id":"22a50051-59da-4d84-ae50-a50baac06540","originalAuthorName":"张敏宏"},{"authorName":"赵桂良","id":"998a9b92-4959-4b2f-919d-5d56cf95d9d2","originalAuthorName":"赵桂良"},{"authorName":"刘志坚","id":"28444e33-56e5-41b9-a1d4-88edd68d8f2c","originalAuthorName":"刘志坚"},{"authorName":"石勤智","id":"3cabf8c6-209d-40b5-a355-10845b680d4c","originalAuthorName":"石勤智"},{"authorName":"赵丽梅","id":"c4c57c28-53c7-4d12-aac3-af8ddc36eb6b","originalAuthorName":"赵丽梅"},{"authorName":"杨万泰","id":"4769515d-1786-4f53-8d19-cbd196c57ccd","originalAuthorName":"杨万泰"}],"doi":"10.3969/j.issn.1671-5381.2011.04.010","fpage":"46","id":"145c363c-ccc7-4942-80b0-3083fdac69e5","issue":"4","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"8ed941eb-cbad-4ece-a0f7-c4bc8a4c3d91","keyword":"成核剂","originalKeyword":"成核剂"},{"id":"be5af6a3-28c5-4109-b168-805c2fcd7a7f","keyword":"<span style=\"color:red\">二</span>环[2.2.1]庚烷<span style=\"color:red\">二羧酸</span>盐","originalKeyword":"二环[2.2.1]庚烷二羧酸盐"},{"id":"c09d66c5-23b2-40c9-a2fc-53c7eeb72f49","keyword":"<span style=\"color:red\">二</span>环[2.2.2]庚烷<span style=\"color:red\">二羧酸</span>盐","originalKeyword":"二环[2.2.2]庚烷二羧酸盐"},{"id":"dd4b3df9-5451-4e83-8e95-9491f6462fc7","keyword":"聚丙烯","originalKeyword":"聚丙烯"}],"language":"zh","publisherId":"hccllhyyy201104010","title":"<span style=\"color:red\">二</span>环[2.2.1]/[2.2.2]庚烷<span style=\"color:red\">二羧酸</span>盐成核剂研究及应用进展","volume":"40","year":"2011"},{"abstractinfo":"应用DSC考察了降冰片烯<span style=\"color:red\">二羧酸</span>盐对等规聚丙烯结晶和熔融行为的影响.结果表明,降冰片烯<span style=\"color:red\">二羧酸</span>盐的加入提高了聚丙烯的结晶温度和熔融温度.其中钠盐(BCHE11)和钙盐(BCHE20)成核效果较为显著,添加质量分数在0.2%时可使聚丙烯的结晶峰值温度提高10.8℃和9.4℃.应用Avrami方法对降冰片烯<span style=\"color:red\">二羧酸</span>盐成核的聚丙烯等温结晶动力学进行了研究,结果表明,成核聚丙烯半结晶时间都小于空白聚丙烯,尤其是BCHEll和BCHE20.成核聚丙烯的Avrami指数n都在3左右,这表明成核聚丙烯的结晶生长方式为异相成核的三维球晶生长方式.","authors":[{"authorName":"赵世成","id":"e89eb265-f6ef-4acf-9f6f-c7fd13f73c58","originalAuthorName":"赵世成"},{"authorName":"辛忠","id":"c8c43826-3c66-45e8-bec7-58b688db2c29","originalAuthorName":"辛忠"},{"authorName":"盛波扬","id":"5b993457-6773-4f06-8c7a-f55effd856c1","originalAuthorName":"盛波扬"}],"doi":"","fpage":"46","id":"68425ded-7dac-42ed-8e9c-4d609393996d","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"1890391b-0243-4ddb-b5b3-cadd08942a03","keyword":"等规聚丙烯","originalKeyword":"等规聚丙烯"},{"id":"f6b59925-73de-4a99-bc5f-ce5fe62638c9","keyword":"烷基<span style=\"color:red\">二羧酸</span>盐","originalKeyword":"烷基二羧酸盐"},{"id":"89e2635e-4302-4270-80b2-0b3b806edfd0","keyword":"成核剂","originalKeyword":"成核剂"},{"id":"db20081c-ade1-429d-ae6e-1b99d6ddda7f","keyword":"结晶动力学","originalKeyword":"结晶动力学"}],"language":"zh","publisherId":"gfzclkxygc200903013","title":"降冰片烯<span style=\"color:red\">二羧酸</span>盐类成核剂在等规聚丙烯中的成核效应","volume":"25","year":"2009"},{"abstractinfo":"通过液相扩散法合成了一个新的配位聚合物Cu(CBA) PY2 (H2O)(CBA为4-(3('-)羧丙酰胺基)苯甲酸阴离子,Py为吡啶),并对该化合物进行了元素分析、红外、热重、粉末X射线衍射表征,其结构由X射线单晶衍射确定.该化合物属于单斜晶系,空间群P2/c,晶胞参数:C21 H21CuN3O6,a=2.15208(12) nm,b =0.57071 (3) nm,c=1.72977(9) nm,α=90°,β=94.3200(10)°,y=90°,R1=0.0296,wR2 =0.0801.在该配合物中,柔性<span style=\"color:red\">二羧酸</span>配体4-(3('-)羧丙酰胺基)苯甲酸阴离子桥联相邻的Cu(Ⅱ)离子形成一维链状结构,相邻链之间通过N-H…O和O-H…O氢键连接起来形成<span style=\"color:red\">二</span>维层状结构,层与层之间通过C-H…O氢键扩展成三维超分子结构.","authors":[{"authorName":"李庆海","id":"f23bfe3c-0cc2-4693-8755-e8e9ac65d6c5","originalAuthorName":"李庆海"},{"authorName":"江顺风","id":"80f5faf0-ebbc-4bdd-b63e-c3edd5499352","originalAuthorName":"江顺风"},{"authorName":"程鹏翔","id":"a9cdfae9-2483-4730-80f1-9e5aeb43cca6","originalAuthorName":"程鹏翔"}],"doi":"","fpage":"1875","id":"3c6f002e-48e6-4bd2-9dff-860f5a989e1d","issue":"7","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"354deeb6-5ba4-4b46-80ea-88de257afd63","keyword":"配位聚合物","originalKeyword":"配位聚合物"},{"id":"8d7abdca-090a-4f9b-a533-0bd4e460ec16","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"60f50e2f-6386-4505-b37c-b25714abecac","keyword":"柔性<span style=\"color:red\">二羧酸</span>配体","originalKeyword":"柔性二羧酸配体"}],"language":"zh","publisherId":"rgjtxb98201607029","title":"柔性<span style=\"color:red\">二羧酸</span>铜配合物的合成与晶体结构","volume":"45","year":"2016"},{"abstractinfo":"合成了3种顺-5-降冰片烯-内-2,3-<span style=\"color:red\">二羧酸</span>酯类内给电子体,考察了内给电子体空间位阻对催化剂催化1-丁烯於浆聚合的影响.实验结果表明,当外给电子体为<span style=\"color:red\">二</span>异丁基<span style=\"color:red\">二</span>甲氧基硅烷时,以顺-5-降冰片烯-内-2,3-<span style=\"color:red\">二羧酸</span><span style=\"color:red\">二</span>甲酯为内给电子体制备的催化剂催化得到的聚丁烯相对分子质量最大,为98.1×104,相对分子质量分布最宽(PDI=5.6).就提高催化剂活性而言,顺-5-降冰片烯-内-2,3-<span style=\"color:red\">二羧酸</span><span style=\"color:red\">二</span>乙酯内给电子体更有优势.此外,对比考察顺-双环[2,2,1]-庚-内-2,3-<span style=\"color:red\">二羧酸</span><span style=\"color:red\">二</span>乙酯内给电子体对催化剂催化性能影响发现,降冰片烯环上双键的还原大大降低了催化剂的活性.","authors":[{"authorName":"董小芳","id":"bdbc3048-4599-462b-b477-69edda04e9af","originalAuthorName":"董小芳"},{"authorName":"崔晓鹏","id":"63812347-ba90-463f-a3be-f162283647cd","originalAuthorName":"崔晓鹏"},{"authorName":"杨敏","id":"68e1f0dc-31b8-435b-8baf-348df3f0cc49","originalAuthorName":"杨敏"},{"authorName":"刘宾元","id":"3ab93fe3-4f5e-438d-ad5e-d9397c5b80bf","originalAuthorName":"刘宾元"}],"doi":"10.16865/j.cnki.1000-7555.2017.03.005","fpage":"25","id":"a70bc1b0-60df-4242-8144-d3c012b8b1bd","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"accc9fc8-4a7e-449d-acad-327753d5e4ad","keyword":"内给电子体","originalKeyword":"内给电子体"},{"id":"f059f1fd-fe41-49b6-8cba-890832cc0af1","keyword":"顺-5-降冰片烯-内-2,3-<span style=\"color:red\">二羧酸</span>酯","originalKeyword":"顺-5-降冰片烯-内-2,3-二羧酸酯"},{"id":"fc3f9f8f-a0bd-4c16-bf19-6c2019bbbd9d","keyword":"Ziegler-Natta催化剂","originalKeyword":"Ziegler-Natta催化剂"},{"id":"7ba6ec3b-1ebd-4635-a2ba-7f07b7c2af7a","keyword":"聚(1-丁烯)","originalKeyword":"聚(1-丁烯)"}],"language":"zh","publisherId":"gfzclkxygc201703005","title":"降冰片烯-2,3-<span style=\"color:red\">二羧酸</span>酯类内给电子体对Ziegler-Natta催化剂催化1-丁烯聚合的影响","volume":"33","year":"2017"},{"abstractinfo":"合成了几种新型的轻稀土2,5-噻吩<span style=\"color:red\">二羧酸</span>-1,10-菲咯啉的三元配合物,通过元素分析、热分析、红外光谱法确定其组成为Ln2(L)3(phen)2·nH2O(Ln=La,n=2;Ln =Sm,Eu,Gd,n =4).重点研究了铕配合物的荧光性能,并测定其荧光寿命为0.83 ms.另以Gd3+配合物为模型化合物,通过低温磷光光谱确定了2,5-噻吩<span style=\"color:red\">二羧酸</span>配体的三重态能级为18200 cm-1,并通过低温磷光寿命的测定详细讨论了有机配体之间的分子内能量传递机制和效率.","authors":[{"authorName":"张勇","id":"47afc744-2dcf-4f6f-8f6b-11aa99766026","originalAuthorName":"张勇"},{"authorName":"廖莉玲","id":"47c2b62a-16c3-4190-b864-af3c15c4db9a","originalAuthorName":"廖莉玲"},{"authorName":"邹文静","id":"08a7caed-08fb-4126-9abd-201d3f558c18","originalAuthorName":"邹文静"},{"authorName":"李存雄","id":"da329f0f-32b6-42ce-8295-5e814db2c45d","originalAuthorName":"李存雄"},{"authorName":"胡继伟","id":"50d422db-856f-43b4-8b84-7569ad42706b","originalAuthorName":"胡继伟"},{"authorName":"秦樊鑫","id":"7428fb9b-fd3b-4890-8c18-ddc705e57edd","originalAuthorName":"秦樊鑫"},{"authorName":"李秋华","id":"59ad1547-5212-4732-acf6-1e3bb5025524","originalAuthorName":"李秋华"}],"doi":"10.3969/j.issn.1004-0277.2011.04.002","fpage":"8","id":"58c7023b-9163-48ab-b776-7823471f5816","issue":"4","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"f97b0238-32a0-4d41-9dbf-3172c50c3b2a","keyword":"稀土","originalKeyword":"稀土"},{"id":"4302e8b5-996f-47a4-9cd3-a4d486406b1a","keyword":"2,5-噻吩<span style=\"color:red\">二羧酸</span>","originalKeyword":"2,5-噻吩二羧酸"},{"id":"6f1a0122-1a9c-461e-bd9e-77273b4c17ff","keyword":"1,10-菲咯啉","originalKeyword":"1,10-菲咯啉"},{"id":"4ccc95b2-003a-4364-ba80-31e92c32f828","keyword":"配合物","originalKeyword":"配合物"},{"id":"1dacd0ac-e390-4be9-9ac3-05a54900647e","keyword":"谱学性质","originalKeyword":"谱学性质"}],"language":"zh","publisherId":"xitu201104002","title":"轻稀土-2,5-噻吩<span style=\"color:red\">二羧酸</span>-1,10-菲咯啉三元配合物的合成、表征及谱学性质","volume":"32","year":"2011"},{"abstractinfo":"以稀土氯化物、1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮和2,6-吡啶<span style=\"color:red\">二羧酸</span>为原料,制备了一类新型稀土三元配合物,通过元素分析、红外光谱、紫外光谱、热重-差热分析、光电子能谱分析及X射线粉末衍射等手段对配合物进行了表征,确定了该类配合物的化学组成可能为:Na2[RE (PMBP)3 (PDA)]·nH2O(RE=Sm3,Y3+,Er3+,其中La配合物含有一分子配位水).抗菌实验结果表明,三元配合物对大肠杆菌、金黄色葡萄球菌具一定的抑制作用,Na2[Er((PMBP)3 (PDA)]·5 H2O对大肠杆菌作用较好,而Na2[Sm(PMBP)3 (PDA)]·5H2O对金黄色葡萄球菌作用较好.采用紫外光谱法和荧光光谱法初步研究了配合物与CT-DNA的作用方式,结果表明配合物是以插入模式与DNA结合的.同时配合物Na2[Sm(PMBP)3 (PDA)]·5H2O具有荧光特性,可用作荧光探针等,在生物活性上具有一定的应用前景.","authors":[{"authorName":"郁慧","id":"1ada6bd6-d472-42a8-895f-9faeb72d4644","originalAuthorName":"郁慧"},{"authorName":"程宁宁","id":"5bffaa75-01bf-4c68-a939-b82cd5dd83ef","originalAuthorName":"程宁宁"},{"authorName":"许东芳","id":"87eeeb80-df5a-4f66-8740-e3518e2345c8","originalAuthorName":"许东芳"},{"authorName":"林静容","id":"277e89c4-0bbd-4bd6-971c-462a4a8b248d","originalAuthorName":"林静容"},{"authorName":"何其庄","id":"87a2e987-9e8a-40c0-a81b-a1f6692cfb56","originalAuthorName":"何其庄"}],"doi":"10.11785/S1000-4343.20140311","fpage":"328","id":"f8ea1156-12b1-424b-9292-a29678aa554f","issue":"3","journal":{"abbrevTitle":"ZGXTXB","coverImgSrc":"journal/img/cover/ZGXTXB.jpg","id":"86","issnPpub":"1000-4343","publisherId":"ZGXTXB","title":"中国稀土学报"},"keywords":[{"id":"be97ef83-9320-4713-96bf-a8036b2bad25","keyword":"配合物","originalKeyword":"配合物"},{"id":"289eca1d-a8c0-4452-b9f2-ccbf3a1c44cd","keyword":"抗菌","originalKeyword":"抗菌"},{"id":"d806b534-1b70-49b1-b280-27f8560b4be7","keyword":"DNA","originalKeyword":"DNA"},{"id":"9d3a2aa4-d429-4904-9528-edc3aba62c26","keyword":"稀土","originalKeyword":"稀土"}],"language":"zh","publisherId":"zgxtxb201403011","title":"稀土-吡唑啉酮-2,6-吡啶<span style=\"color:red\">二羧酸</span>配合物的合成、表征及其性质研究","volume":"32","year":"2014"},{"abstractinfo":"从Cis-[Pt(NH3)2(H2O)2](NO3)2 与1,1-环丁烷<span style=\"color:red\">二羧酸</span>钠的化学反应中,分离出一种新的Pt(II)配合物,通过元素分析、红外光谱, 质谱和高效液相色谱的分析测试,初步推测结构为顺式-四氨-μ-<span style=\"color:red\">二</span>(1,1-环丁烷<span style=\"color:red\">二羧酸</span>根-O1,O2)合<span style=\"color:red\">二</span>铂的新化学结构式.","authors":[{"authorName":"李瑞丹","id":"87422494-dce4-4d93-9057-fc5a1dd8c98b","originalAuthorName":"李瑞丹"},{"authorName":"余尧","id":"61139284-1daf-41aa-9155-7cf6b6548f85","originalAuthorName":"余尧"},{"authorName":"谌喜珠","id":"f2608b89-147d-46f2-bc55-f2b79ebf0923","originalAuthorName":"谌喜珠"},{"authorName":"傅文甫","id":"b681eb9c-0250-4c1d-b709-2a09902bd787","originalAuthorName":"傅文甫"}],"doi":"10.3969/j.issn.1004-0676.2009.02.007","fpage":"33","id":"b4b6885d-6f62-4705-9822-838c8350cdec","issue":"2","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"2890cd23-b7bc-4589-8152-4329acf32002","keyword":"配位化学","originalKeyword":"配位化学"},{"id":"53d4ab64-a0f1-4992-935b-537795322b66","keyword":"铂(II)","originalKeyword":"铂(II)"},{"id":"5ac95cd2-6f87-4604-b087-b6256c2d4623","keyword":"双核配合物","originalKeyword":"双核配合物"},{"id":"60acbf96-de12-4e52-b2bd-69cfa72a96aa","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"gjs200902007","title":"Cis-[Pt(NH3)2(H2O)2](NO3)2与1,1-环丁烷<span style=\"color:red\">二羧酸</span>钠形成的一种新的Pt(Ⅱ)配合物","volume":"30","year":"2009"},{"abstractinfo":"合成了5种新型镧掺杂铕的2,5-噻吩<span style=\"color:red\">二羧酸</span>(H2L)、1,10-菲咯啉(Phen)四元异核配合物,通过元素分析、TG-DTA、红外光谱法确定其组成为(EuxLay)2L3(Phen)2·4H2O(χ:y=0.90∶0.10、0.70:0.30、0.50∶0.50、0.30∶0.70、0.10∶0.90),配体的羧基与稀土离子以螯合双齿配位.荧光光谱测试表明镧对铕的配合物有荧光浓聚效应.","authors":[{"authorName":"李存雄","id":"ae96cada-ccc1-4dfe-ba90-1c319f9d4097","originalAuthorName":"李存雄"},{"authorName":"张勇","id":"12f0425d-e397-4f86-89a1-239bd12a74e3","originalAuthorName":"张勇"},{"authorName":"廖莉玲","id":"9d3fa295-2b62-48b1-90c5-7051d208215a","originalAuthorName":"廖莉玲"},{"authorName":"邹文静","id":"a13273a9-de08-4a74-bec3-5baa1da9df14","originalAuthorName":"邹文静"},{"authorName":"吴迪","id":"6d526c09-b1a5-4a24-b2e6-1e678ef4e920","originalAuthorName":"吴迪"},{"authorName":"秦樊鑫","id":"3ce803aa-8d7d-443e-bee6-9d6a50c770ae","originalAuthorName":"秦樊鑫"}],"doi":"","fpage":"49","id":"80bce943-bde8-47e1-8eef-d2024cde3e06","issue":"4","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"f032dc7a-9697-40df-bbfe-1f6456040c11","keyword":"稀土","originalKeyword":"稀土"},{"id":"fbd6145d-6acf-4d5e-ba2c-38404676b32e","keyword":"2,5-噻吩<span style=\"color:red\">二羧酸</span>","originalKeyword":"2,5-噻吩二羧酸"},{"id":"ae160b5f-e709-4010-9d96-5cdadac366cf","keyword":"1,10-菲咯啉","originalKeyword":"1,10-菲咯啉"},{"id":"80aa887f-caf1-4488-97a5-adbdb51797d4","keyword":"异核配合物","originalKeyword":"异核配合物"},{"id":"a0f43628-b2d4-459f-bc3f-c34ec93d46b1","keyword":"谱学性质","originalKeyword":"谱学性质"}],"language":"zh","publisherId":"cldb201104013","title":"镧掺杂铕的2,5-噻吩<span style=\"color:red\">二羧酸</span>-1,10-菲咯啉四元异核配合物的合成、表征及谱学性质","volume":"25","year":"2011"}],"totalpage":3123,"totalrecord":31225}