C.Bouvy
,
B.L.Su
材料科学技术（英文）
Optoelectronic nanocomposites are a new class of materials, which exhibit very interesting and particular properties and attract a growing attention due to their potential applications in information storage and optoelectronic devices. Zinc oxide, ZnO, is one of the most interesting binary semiconductor (3.37 eV) with very important optical properties, which can be used in the fields such as short wavelength lasers, blue light emitting diodes, UV detectors, gas sensors, etc. This paper reviews the very recent progress in the preparation of silica-based ZnO nanocomposites. After an introduction reviewing the theoretical background, the article will begin with a survey of the optical properties and the quantum size effect (QSE) of ZnO/SiO2 nanocomposites prepared by the inclusion of ZnO nanoclusters inside silica mesoporous materials. The second part will focus on one of the most interesting properties of ZnO/SiO2 nanocomposites, which is the random lasing effect after one- and two-photon excitation. The final part will deal with the introduction of ZnO nanoparticles inside microporous zeolites and the observation of QSE. For comparison, the photoluminescence (PL) and QSE properties of ZnS nanoparticles occluded in mesoporous media are also described. New potential applications will be discussed since short-wavelength devices are required by industry to design, for instance, new information storage supports and biolabelling devices.
关键词:
ZnO nanoparticles
,
nanoparticles
,
microporous
,
and
,
mesopo
安栋
,
郭欣
,
郑楚光
工程热物理学报
使用分子动力学熔融-淬火法(QMD)建立微孔无定形碳原子结构模型,采用巨正则蒙特卡洛法(GCMC)研究CO2、N2在模型中的吸附行为.通过与热解聚糠醇制备的微孔无定形碳样品比较,所建模型在径向分布函数、孔径分布函数、吸附等温线等方面有很高的符合度.CO2、N2吸附计算表明:所建立的微孔无定形碳模型,对CO2、N2混合组分吸附具有很高的选择性,CO2/N2吸附比随着温度和压力的增加逐渐降低.
关键词:
微孔
,
无定形
,
分子动力学
,
吸附
陈忠元
,
居亚兰
,
张文锋
,
朱云峰
,
李李泉
材料导报
用萃取活化法制备了PVA基碱性多孔聚合物电解质,其制备过程包括3步:(1)PVA/PEG共混膜的制备;(2)通过萃取制备PVA基多孔膜;(3)用KOH溶液浸泡多孔膜.并采用交流阻抗、扫描电镜和X射线衍射法对该膜进行了分析,结果表明,制得的多孔膜具有不对称的孔状结构,当m(PVA)∶m(PEG)=7 ∶ 3时,样品经过萃取活化后吸液率与离子电导率最大,分别为94.4%和9.71×10-3S/cm;循环伏安测试表明,体系的电化学稳定窗口达到2.2V,经过50个循环后电化学稳定窗口仍保持在2.2V.这种新型碱性多孔聚合物电解质有望应用在镍氢电池中.
关键词:
碱性聚合物电解质
,
多孔
,
离子电导率
,
电化学稳定窗口
