{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用热<span style=\"color:red\">力学</span>相图和超声时域反射法研究了致孔剂聚乙二醇（PEG）对聚偏氟乙烯-g-聚N-异丙基丙烯酰胺（PVDF-g-PNIPAAm）<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程的影响。结果表明,在PVDF-g-PNIPAAm/DMF/H2O成膜体系中添加PEG后,促进了成膜体系的分相,体系变得更不稳定。加入PEG后,使得PVDF-g-PNIPAAm/DMF/H2O成膜体系的<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>速度加快,体系更容易发生瞬时液液分相,导致<span style=\"color:red\">膜</span>孔尺寸增加,纯水通量提高,但温度响应性能不明显。","authors":[{"authorName":"冯霞","id":"3c567bd0-dc3e-4fcf-87e2-91344b3e157b","originalAuthorName":"冯霞"},{"authorName":"郭艳芬","id":"82940ef5-22cc-44ec-a5e7-644b526f44c3","originalAuthorName":"郭艳芬"},{"authorName":"赵义平","id":"c5ed70f0-6082-4ff9-a41a-fe5e665f973d","originalAuthorName":"赵义平"},{"authorName":"李建新","id":"b50838ca-f55c-428e-8950-33d15e72d8ec","originalAuthorName":"李建新"},{"authorName":"陈熙","id":"030ba716-b051-479d-97f4-776a130212ad","originalAuthorName":"陈熙"},{"authorName":"陈莉","id":"5b0911c4-c764-4535-8eaa-ce3def9bc93d","originalAuthorName":"陈莉"}],"doi":"","fpage":"26","id":"fd9a37e2-28ee-4f61-b869-718de81c50d2","issue":"10","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"dfd33c09-8c35-4750-9f9c-b6c334a7a6c9","keyword":"聚偏氟乙烯-g-聚N-异丙基丙烯酰胺","originalKeyword":"聚偏氟乙烯-g-聚N-异丙基丙烯酰胺"},{"id":"44a73d6b-2f38-45e9-b9da-200be561cc27","keyword":"<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>热<span style=\"color:red\">力学</span>","originalKeyword":"成膜热力学"},{"id":"83474872-42f8-49d0-b283-ce61ad0365e8","keyword":"<span style=\"color:red\">成</span><span style=\"color:red\">膜</span><span style=\"color:red\">动力学</span>","originalKeyword":"成膜动力学"},{"id":"9d30dce4-1d9a-40f0-9e9c-d68f4db5dace","keyword":"超声时域反射","originalKeyword":"超声时域反射"},{"id":"e9ed23c0-e3c3-4343-b11d-d46d5ff62997","keyword":"致孔剂","originalKeyword":"致孔剂"}],"language":"zh","publisherId":"gfzclkxygc201210007","title":"致孔剂对PVDF-g-PNIPAAm温度敏感<span style=\"color:red\">膜</span><span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程及<span style=\"color:red\">膜</span>性能的影响","volume":"28","year":"2012"},{"abstractinfo":"通过测量稀土转化<span style=\"color:red\">膜</span>生长微观形貌、稀土转化<span style=\"color:red\">膜</span>生长曲线、<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>反应表观活化能、<span style=\"color:red\">成</span>膜电位时间曲线及Tafel曲线,研究电镀锌稀土转化<span style=\"color:red\">膜</span><span style=\"color:red\">成</span><span style=\"color:red\">膜</span><span style=\"color:red\">动力学</span>.结果表明:稀土转化<span style=\"color:red\">膜</span>的生长分为快速生长、缓慢生长、平稳生长3个阶段,3个阶段生长速率与单位面积转化<span style=\"color:red\">膜</span>质量均呈抛物线关系,形成具有保护性能的<span style=\"color:red\">膜</span>层;其中第一、二阶段<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>反应的活化能分别为18.17,28.93 kJ·mol-1,具有较快的反应速率,第三阶段<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>反应的活化能为42.41 kJ·n.mol-1,反应速率相对较慢.此外,<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>反应还与外因<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>温度和<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>时间有关,升高温度可缩短转化<span style=\"color:red\">膜</span><span style=\"color:red\">成</span><span style=\"color:red\">膜</span>的时间,有利于转化<span style=\"color:red\">膜</span>的形成,<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>温度在25～35℃之间,<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>时间在120～180s之间,<span style=\"color:red\">膜</span>层具有较好的耐蚀性能.","authors":[{"authorName":"章江洪","id":"a0917ec9-50f2-48ea-a1c5-5a109b33caba","originalAuthorName":"章江洪"},{"authorName":"张英杰","id":"39ec7a1b-5971-4a40-8b3e-31426c50c38a","originalAuthorName":"张英杰"}],"doi":"","fpage":"569","id":"c9b20938-5b50-4816-a85e-d6124e53c62f","issue":"5","journal":{"abbrevTitle":"ZGXTXB","coverImgSrc":"journal/img/cover/ZGXTXB.jpg","id":"86","issnPpub":"1000-4343","publisherId":"ZGXTXB","title":"中国稀土学报"},"keywords":[{"id":"270a40c6-6d34-4341-9a9d-7d4abbfc4305","keyword":"电镀锌","originalKeyword":"电镀锌"},{"id":"f8d5a8f4-4b61-4e8c-97a7-1868880c2bdd","keyword":"稀土转化<span style=\"color:red\">膜</span>","originalKeyword":"稀土转化膜"},{"id":"7d44ba90-469e-4fc1-8cbb-f8a4ca8ea892","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"}],"language":"zh","publisherId":"zgxtxb201005010","title":"电镀锌层稀土转化<span style=\"color:red\">膜</span><span style=\"color:red\">成</span><span style=\"color:red\">膜</span><span style=\"color:red\">动力学</span>研究","volume":"28","year":"2010"},{"abstractinfo":"用电化学石英晶体微天平(EQCM)研究了中性Na_2SO_4溶液中钝化型缓蚀剂NaNO_2和沉淀型缓蚀剂Na_2SiO_3在铁上的<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>行为。根据EQCM原理和条件,推导了求解真实<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>质量变化的近似公式,获得了缓蚀剂<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>的等温<span style=\"color:red\">动力学</span>曲线。发现含钝化型缓蚀剂NaNO_2体系中铁表面膜的生长呈抛物线规律,而在含沉淀型缓蚀剂Na_2SiO_3体系中则为直线规律;水溶液中金属表面<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>具有与金属高温氧化成<span style=\"color:red\">膜</span>类似的<span style=\"color:red\">动力学</span>规律。","authors":[{"authorName":"戴忠旭","id":"f6d0c277-e8f3-4c81-ba30-8d52ce022393","originalAuthorName":"戴忠旭"},{"authorName":"甘复兴","id":"0aec8ff4-8455-41b4-8f78-c2dea727dbe1","originalAuthorName":"甘复兴"},{"authorName":"汪的华","id":"8e0fb3eb-2615-4b9e-b09d-b7064a3095c0","originalAuthorName":"汪的华"},{"authorName":"姚禄安","id":"6d13d27c-a4d5-413c-9ba4-4afb60ac97ac","originalAuthorName":"姚禄安"}],"categoryName":"|","doi":"","fpage":"251","id":"d356923c-d87d-4ecb-9185-016f60438df7","issue":"4","journal":{"abbrevTitle":"ZGFSYFHXB","coverImgSrc":"journal/img/cover/中国腐蚀封面19-3期-01.jpg","id":"81","issnPpub":"1005-4537","publisherId":"ZGFSYFHXB","title":"中国腐蚀与防护学报"},"keywords":[{"id":"ea9da6bb-393b-478d-a1ef-8e4c1bb197f8","keyword":"电化学石英晶体微天平","originalKeyword":"电化学石英晶体微天平"},{"id":"238f28d0-1d78-4130-9313-bc987b2497a8","keyword":" Armco-iron","originalKeyword":" Armco-iron"},{"id":"3a660167-eb5c-4d49-8f2a-28a00743690c","keyword":" Corrosion inhibitor","originalKeyword":" Corrosion inhibitor"},{"id":"383b7905-4031-4f7d-b9af-8657e2ebf470","keyword":" Filming kinetics","originalKeyword":" Filming kinetics"}],"language":"zh","publisherId":"1005-4537_1998_4_1","title":"用EQCM研究中性介质中铁缓蚀剂的<span style=\"color:red\">成</span><span style=\"color:red\">膜</span><span style=\"color:red\">动力学</span>","volume":"18","year":"1998"},{"abstractinfo":"采用原位聚合方法,以氯金酸(HAuCl4)为氧化剂,苯胺(ANI)为还原剂,制备聚苯胺-金复合材料<span style=\"color:red\">膜</span>.用扫描电镜(SEM)表征了复合<span style=\"color:red\">膜</span>的形貌;并用石英晶体微天平(QCM)实时监测该复合材料的<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程,研究了其<span style=\"color:red\">成</span><span style=\"color:red\">膜</span><span style=\"color:red\">动力学</span>.结果表明,金粒子的平均粒径为400 nm,较均匀地分布在复合<span style=\"color:red\">膜</span>中;复合<span style=\"color:red\">膜</span>的增长速率随氯金酸浓度、苯胺浓度和反应温度的升高而增大,得到<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>反应对氧化刺为0.5级,对苯胺为1.5级,并由增长速率与温度的关系计算出<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程的活化能为(40.32±0.15)kJ/mol.","authors":[{"authorName":"仇伟","id":"39fcb40d-6e09-45b3-9916-ea629fbee9ff","originalAuthorName":"仇伟"},{"authorName":"黄欢","id":"bd50ab6a-87ec-4c2b-835b-5e95223dc876","originalAuthorName":"黄欢"},{"authorName":"刘见祥","id":"fb67649b-6841-4192-9e02-f37f3fd737de","originalAuthorName":"刘见祥"},{"authorName":"薛涛","id":"1289a325-ba84-4fcf-bd69-e00e48d89174","originalAuthorName":"薛涛"},{"authorName":"曾舒","id":"92728c3c-f023-4239-8e33-e898bbdf6df8","originalAuthorName":"曾舒"}],"doi":"","fpage":"88","id":"aaafdb36-53cd-4964-bf04-132c6e2406de","issue":"10","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"bfce72ee-c44d-4609-a6f1-d764f12fd157","keyword":"复合材料","originalKeyword":"复合材料"},{"id":"e119ba9d-a757-4b33-8135-3e011495fa94","keyword":"聚苯胺-金复合<span style=\"color:red\">膜</span>","originalKeyword":"聚苯胺-金复合膜"},{"id":"459e888c-40ef-4c23-99fe-b292690bab83","keyword":"石英晶体微天平","originalKeyword":"石英晶体微天平"},{"id":"145f9653-657d-4d80-a832-c34614a0140a","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"},{"id":"70ab111b-e6ba-42d5-8363-4c67a45cbe47","keyword":"原位聚合","originalKeyword":"原位聚合"}],"language":"zh","publisherId":"gfzclkxygc201010023","title":"聚苯胺-金复合材料的<span style=\"color:red\">成</span><span style=\"color:red\">膜</span><span style=\"color:red\">动力学</span>","volume":"26","year":"2010"},{"abstractinfo":"在扩散-反应限制凝聚模型(DRLA)的基础上,假设高分子溶液在<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程中聚合物凝聚过程可视为簇凝聚-解离可逆反应,结合扩散-反应方程提出了非溶剂致相分离(NIPS)法<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程的扩散限制-反应凝聚(DLRA)模型.将模型推导出的铸<span style=\"color:red\">膜</span>液层中聚集体浓度方程与朗伯-比尔定律相结合,对NIPS法不同体系PVDF铸模液<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程中<span style=\"color:red\">膜</span>液层吸光度倒数(1/A)随时间变化的曲线进行了拟合,拟合曲线相关系数R2大于0.97,说明DLRA模型能较准确地反映NIPS法<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>的<span style=\"color:red\">动力学</span>过程.","authors":[{"authorName":"袁国林","id":"664b7d38-373e-4cff-afb9-1f45d610128d","originalAuthorName":"袁国林"},{"authorName":"许振良","id":"7f1360a8-1cd1-434f-b87a-a8e6e4fda5c8","originalAuthorName":"许振良"},{"authorName":"姬朝青","id":"7c0e7e2c-cf98-4fe2-9ca8-a1f23159049e","originalAuthorName":"姬朝青"},{"authorName":"魏永明","id":"f119ba39-0ee0-413a-8599-4da82d7304aa","originalAuthorName":"魏永明"}],"doi":"10.3969/j.issn.1007-8924.2010.04.020","fpage":"97","id":"7c90b19d-e17b-4e43-9fd9-dc63471ad0e2","issue":"4","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"b48dedad-cbdd-41d1-a87e-2e39d788b31c","keyword":"<span style=\"color:red\">膜</span>","originalKeyword":"膜"},{"id":"4fe842f7-e065-4d1d-93ff-66034757c79c","keyword":"非溶剂致相分离","originalKeyword":"非溶剂致相分离"},{"id":"713d6196-cb1f-4b6c-984b-2e66ccad72d6","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"},{"id":"66c01150-f873-45bb-a94f-6e42535be6b0","keyword":"模型","originalKeyword":"模型"}],"language":"zh","publisherId":"mkxyjs201004020","title":"NIPS法PVDF<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程扩散限制-反应凝聚<span style=\"color:red\">动力学</span>模型的研究","volume":"30","year":"2010"},{"abstractinfo":"以杂萘联苯聚醚砜酮(PPESK)/NMP为铸<span style=\"color:red\">膜</span>液体系,进行<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程凝胶<span style=\"color:red\">动力学</span>研究.发现凝胶<span style=\"color:red\">动力学</span>曲线(X2～t)不是由单一直线组成的,而是由三段对应着不同膜结构的直线组成.考察了不同添加剂对PPESK-NMP体系凝胶速度的影响.结果表明,亲水性强的添加剂,可提高铸<span style=\"color:red\">膜</span>液体系的亲水性,从而加快溶剂、非溶剂的传质速率,凝胶速度加快,<span style=\"color:red\">膜</span>的水通量增加.使铸<span style=\"color:red\">膜</span>液黏度增加的添加剂,使非溶剂扩散系数降低,凝胶速度减慢,<span style=\"color:red\">膜</span>的水通量减少.丙二酸添加剂增大了铸<span style=\"color:red\">膜</span>液的亲水性,使铸<span style=\"color:red\">膜</span>液的凝胶速度增大.吐温添加剂既增加了铸<span style=\"color:red\">膜</span>液的亲水性又增加了铸<span style=\"color:red\">膜</span>液的黏度,凝胶速度也先变小后变大.PEG添加剂虽然增大了铸<span style=\"color:red\">膜</span>液体系的亲水性,但同时也提高了铸<span style=\"color:red\">膜</span>液的黏度,凝胶速度的变化不大.","authors":[{"authorName":"秦培勇","id":"4fd15cd3-b240-4ed5-842d-69bdccbf2422","originalAuthorName":"秦培勇"},{"authorName":"陈翠仙","id":"4298119c-50f9-4dc8-87b0-bef79fa8d1f5","originalAuthorName":"陈翠仙"},{"authorName":"黄薇","id":"03932489-e073-44dc-ac3d-1be3df498e8d","originalAuthorName":"黄薇"},{"authorName":"李继定","id":"780d56f8-e5e1-45ee-ace2-c341354c5417","originalAuthorName":"李继定"},{"authorName":"孙本惠","id":"97539c97-ae4d-48ea-8ccd-8f9e8fae3507","originalAuthorName":"孙本惠"}],"doi":"10.3969/j.issn.1007-8924.2007.01.002","fpage":"7","id":"74fb9977-6910-496c-a865-dc95e48ef016","issue":"1","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"2504c0ad-9810-46e9-b892-8c3a02f08f5e","keyword":"PPESK","originalKeyword":"PPESK"},{"id":"c5ebc93a-5b5d-4bde-9fa5-6671bdf364ad","keyword":"凝胶<span style=\"color:red\">动力学</span>","originalKeyword":"凝胶动力学"},{"id":"dfb77e19-f027-4eba-87bc-5fa4545987d1","keyword":"添加剂","originalKeyword":"添加剂"},{"id":"f587d948-e9ca-49e7-bc43-393f86d1ffb6","keyword":"相转化","originalKeyword":"相转化"}],"language":"zh","publisherId":"mkxyjs200701002","title":"杂萘联苯聚醚砜酮类材料<span style=\"color:red\">成</span><span style=\"color:red\">膜</span><span style=\"color:red\">动力学</span>研究(Ⅰ)添加剂对PPESK凝胶<span style=\"color:red\">动力学</span>的影响","volume":"27","year":"2007"},{"abstractinfo":"以杂萘联苯聚醚砜酮(PPESK)/NMP为聚<span style=\"color:red\">膜</span>液体系,进行了<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程凝胶<span style=\"color:red\">动力学</span>研究;浊点实验表明,随着醇类物质碳原子数目的增多,相图的二相区变小,凝胶过程所需的非溶剂量增多.还考察了不同凝胶浴对PPESK/NMP体系凝胶速度的影响.结果表明,使絮凝值增大的非溶剂,凝胶过程中所需的非溶剂量增多,凝胶速度降低.凝胶浴中加入溶剂使铸<span style=\"color:red\">膜</span>液和凝胶浴的化学势差降低,使非溶剂和溶剂的传质速度下降,凝胶速度减小.当NMP浓度为80%时,膜结构由指状转变为海绵状结构.","authors":[{"authorName":"秦培勇","id":"5a05662d-4b35-4111-9471-58bfd7517389","originalAuthorName":"秦培勇"},{"authorName":"陈翠仙","id":"5d95a919-65c7-4b69-9696-f6dd91094354","originalAuthorName":"陈翠仙"},{"authorName":"黄薇","id":"65b890d0-eeff-4e8f-8e1e-ef16c9511d2e","originalAuthorName":"黄薇"},{"authorName":"李继定","id":"8270b5d9-1471-49aa-a8ea-e91ea2af7021","originalAuthorName":"李继定"},{"authorName":"孙本惠","id":"db18a4ae-3933-47d2-be81-425526b7d32d","originalAuthorName":"孙本惠"}],"doi":"10.3969/j.issn.1007-8924.2007.01.003","fpage":"13","id":"b4805605-f2db-4689-96cb-b26ad3fe4967","issue":"1","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"2984a410-8daa-4712-8708-cabe7b4d4e73","keyword":"PPESK","originalKeyword":"PPESK"},{"id":"e3045ae7-5870-402a-90d3-3db21795bbcf","keyword":"凝胶<span style=\"color:red\">动力学</span>","originalKeyword":"凝胶动力学"},{"id":"aa7be4f9-4771-4031-9399-85ba6b2970f2","keyword":"凝胶浴","originalKeyword":"凝胶浴"},{"id":"06985443-fd41-47d1-a037-b433a741ace0","keyword":"相转化","originalKeyword":"相转化"}],"language":"zh","publisherId":"mkxyjs200701003","title":"杂萘联苯聚醚砜酮类材料<span style=\"color:red\">成</span><span style=\"color:red\">膜</span><span style=\"color:red\">动力学</span>研究(Ⅱ)凝胶介质对 PPESK凝胶<span style=\"color:red\">动力学</span>的影响","volume":"27","year":"2007"},{"abstractinfo":"用大冶铁矿磁铁精矿为原料,在实验室型圆盘造球机中造球,研究了水分、膨润土用量、给料量和圆盘转速对成球<span style=\"color:red\">动力学</span>的影响.研究发现,水分是影响生球成长速度的敏感因素;增加膨润土用量的效果与水分相反;在一定的充填范围内,生球平均直径与给料量无关.本文以试验为依据提出了具有一级反应形式的<span style=\"color:red\">动力学</span>模型方程,即dS/dt=-KcS,分析了速度常数Kc的影响因素.","authors":[{"authorName":"陈铁军","id":"fd2b0e08-5f59-429c-85ba-6ed33207e1ae","originalAuthorName":"陈铁军"},{"authorName":"彭志坚","id":"e373e31e-ea29-4671-aa42-4f145a6b4485","originalAuthorName":"彭志坚"},{"authorName":"肖志东","id":"01230690-1a10-4e21-ba62-8de013008249","originalAuthorName":"肖志东"},{"authorName":"胡承凡","id":"52bb3900-cb43-4bb9-bebf-40c5a4b967c8","originalAuthorName":"胡承凡"}],"doi":"10.3969/j.issn.1001-1447.2003.02.002","fpage":"5","id":"f554cb1b-15ff-4bb2-a94a-c0d0ae18dd15","issue":"2","journal":{"abbrevTitle":"GTYJ","coverImgSrc":"journal/img/cover/GTYJ.jpg","id":"29","issnPpub":"1001-1447","publisherId":"GTYJ","title":"钢铁研究"},"keywords":[{"id":"159d399a-c8ea-4adc-a22c-3d0ebb340d98","keyword":"球团","originalKeyword":"球团"},{"id":"cc09d8bf-2b26-4e7c-9557-321f9e1f238a","keyword":"磁铁精矿","originalKeyword":"磁铁精矿"},{"id":"d834afaf-c310-42dc-9662-2a3a4e5e2670","keyword":"<span style=\"color:red\">成</span>球<span style=\"color:red\">动力学</span>","originalKeyword":"成球动力学"},{"id":"b19a7b1a-c5e7-4d9b-aed7-690d47a5b817","keyword":"模型","originalKeyword":"模型"}],"language":"zh","publisherId":"gtyj200302002","title":"大冶铁精矿<span style=\"color:red\">成</span>球<span style=\"color:red\">动力学</span>试验研究","volume":"31","year":"2003"},{"abstractinfo":"利用平面接触角测量仪和紫外-可见吸收光谱法监测了聚苯乙烯磺酸钠(PSS)/聚二烯丙基二甲基胺盐酸盐(PDDA)分子沉积(MD)<span style=\"color:red\">膜</span><span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程. 通过<span style=\"color:red\">动力学</span>研究,揭示了不同聚电解质分子具有不同平衡吸附时间的微观机理. 结果表明,PSS/PDDA是以单分子层层状沉积;2种分子的<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程包括扩散控制的Langmuir 快速吸附和相对缓慢的表面重组2个阶段;第6层PSS和第7层PDDA MD<span style=\"color:red\">膜</span>润湿性稳定的时间分别为35和25 min;PSS和PDDA的吸附速率常数分别为0.604和1.231 mL/(g*s).","authors":[{"authorName":"高芒来","id":"f74ee7b2-507e-4524-a313-6818fdec77e3","originalAuthorName":"高芒来"},{"authorName":"陈刚","id":"3b57311d-fc61-4303-a687-83eb151c0e0c","originalAuthorName":"陈刚"}],"doi":"10.3969/j.issn.1000-0518.2003.10.013","fpage":"972","id":"9fb80f41-52e9-4b43-b05e-28ec4d352610","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"72b1e2c1-2022-4da7-843d-25b554e5e1f1","keyword":"聚苯乙烯磺酸钠","originalKeyword":"聚苯乙烯磺酸钠"},{"id":"a1c1982f-edc9-474f-a5bc-293239926d81","keyword":"聚二烯丙基二甲基胺盐酸盐","originalKeyword":"聚二烯丙基二甲基胺盐酸盐"},{"id":"b0c29164-04d1-4c70-bd4d-6baa4b382c37","keyword":"分子沉积<span style=\"color:red\">膜</span>","originalKeyword":"分子沉积膜"},{"id":"e45be89c-62a4-444a-ae47-3f5042956ebc","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"}],"language":"zh","publisherId":"yyhx200310013","title":"聚电解质PSS/PDDA分子沉积<span style=\"color:red\">膜</span><span style=\"color:red\">动力学</span>","volume":"20","year":"2003"},{"abstractinfo":"阳极氧化是镁合金的重要防腐表面处理技术,但目前对镁合金阳极氧化成<span style=\"color:red\">膜</span>的形成机制还不十分清楚.本工作从<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>过程、微观形貌、组分、元素的传质行为、合金相对成<span style=\"color:red\">膜</span>的影响、物理生长模型等方面综述了镁合金阳极氧化成<span style=\"color:red\">膜</span>的生长<span style=\"color:red\">动力学</span>过程,提出了镁合金阳极氧化有待深入研究的方向.这将有利于掌握镁合金阳极氧化成<span style=\"color:red\">膜</span>机制,改进其阳极氧化工艺,扩大镁合金的实际应用.","authors":[{"authorName":"刘渝萍","id":"3b9c9864-59e7-4f30-8ad7-d77d990bac7e","originalAuthorName":"刘渝萍"},{"authorName":"李婷婷","id":"bb101a0d-2670-404f-9dc6-0274c0b026e2","originalAuthorName":"李婷婷"},{"authorName":"李晶","id":"b94d6ae0-0d4a-4e8b-be5c-acb8f0057a7e","originalAuthorName":"李晶"},{"authorName":"陈昌国","id":"adef30c0-5cbf-4b95-b94e-72844345cd38","originalAuthorName":"陈昌国"},{"authorName":"张丁非","id":"731df2a2-0e35-459c-85dc-b23f3fd52313","originalAuthorName":"张丁非"}],"doi":"","fpage":"1013","id":"a44ab25c-8753-494b-9f60-769a241db4c8","issue":"4","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"1e9680dc-38ac-4a42-9436-dd291e3665bd","keyword":"镁合金","originalKeyword":"镁合金"},{"id":"670ce0c2-af28-4b35-8c41-ac713f6a3a5c","keyword":"阳极氧化","originalKeyword":"阳极氧化"},{"id":"b70f8d73-864e-4950-a78c-7ce568583806","keyword":"<span style=\"color:red\">成</span><span style=\"color:red\">膜</span>","originalKeyword":"成膜"},{"id":"86af34ad-00ba-4df8-affe-a7a6f60b0036","keyword":"<span style=\"color:red\">动力学</span>","originalKeyword":"动力学"}],"language":"zh","publisherId":"xyjsclygc201404051","title":"镁合金阳极氧化<span style=\"color:red\">膜</span>的生长<span style=\"color:red\">动力学</span>过程","volume":"43","year":"2014"}],"totalpage":5001,"totalrecord":50009}