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回火处理对Fe-Mn基合金剪切模量的影响

谭延昌 , 赵玉华 , 魏肃宁

金属学报

研究了回火温度和时间对两种成分Fe-Mn基合金剪切模量的影响。结果指出,附加Cr,Ti的合金在回火状态下ΔG G-T曲线有极小和极大两个极值,而附加Cr,Ni,W,C的合金只呈现极大值特征。这是由于Ni,W,C降低反铁磁转变点T_N造成的, 随着回火温度升高或回火时间增加,ΔG_λ效应逐渐增加。

关键词: Fe-Mn基合金 , shear modulus , tempering , null

稀土元素对Si-Mn-V钢淬火、回火过程中组织结构转变的影响

王笑天 , 姚引良 , 邵谭华

金属学报

采用透射电镜,X射线,膨胀仪等方法,对含稀土和不含稀土的4种低、中碳Si—Mn-V钢(20SiMn2V;20SiMn2VRE;40SiMn2V和40SiMn_2VRE)进行了淬火、回火过程中组织结构转变的对比试验,结果表明:稀土元素可以细化低、中碳钢的奥氏体晶粒度;降低M_s点;细化马氏体板条束和板条晶尺寸;并增加中碳钢马氏体中位错亚结构的相对比例。而对低、中碳钢淬火回火组织中残余奥氏体的体积和热稳定性影响甚微。 稀土元素明显地抑制了低碳马氏体在低温回火过程中的分解,阻碍板条晶内片状渗碳体的析出,并推迟其长大球化过程。稀土元素也明显地抑制了中碳马氏体中高温回火过程中粒状渗碳体的析出和球化过程。

关键词: 稀土元素 , tempering , transformation , SiMnV steel

马氏体冷轧-回火制备超细晶钢及其热稳定性

蓝慧芳 , W.J.Liu , 刘相华

材料研究学报

在低碳钢和低碳加铌、钒、钛微合金钢中,通过马氏体冷轧--回火的方法获得了尺寸为数百纳米的超细晶粒铁素体组织,研究了超细晶粒组的形成机制和热稳定性. 通过马氏体相变在这些钢中引入了大量高密度位错,马氏体冷轧后位错进一步增殖, 形成大量位错胞状结构;在500-600℃进行的60 min回火将上述胞状结构转变成具有清晰大角晶界的超细晶粒.在回火过程中形成的微合金元素碳化物对位错运动和晶界移动具有有效的“钉扎”作用,有助于获得超细晶组织并明显提高其热稳定性.

关键词: 金属材料 , cold rolled martensite , tempering , microalloyed steel , precipitation

2.25Cr-1Mo-0.25V钢焊缝中第二相高温回火转变

陶鹏张弛杨志刚武田裕之

金属学报

利用TEM和EDX技术, 研究了2.25Cr-1Mo-0.25V钢焊缝中第二相在700 ℃下保温一系列时间段的转变. 结果表明, 焊后空冷焊缝中的第二相为M3C, 回火过程中第二相主要组成为M3C+M7C3+M23C6. 长时间回火后M3C发生球化并消失, 初期析出的低wCr/wFe(Cr与Fe的质量比)的M7C3是亚稳相, M23C6只能在较低的回火参数范围内存在, 后期形成了wCrwFe更高的M7C3稳定的第二相. M3C多呈球状,M7C3M23C6多为长条状和块状.

关键词: 焊缝 , second phase , carbide , tempering , low alloy steel 2.25Cr--1Mo--0.25V

4335V钢中碳化物的研究

钟家湘 , 郑秀华 , 徐宗瑞 , 白德忠

金属学报

实验表明,4335V钢淬火回火后析出三种碳化物:(1)M_3C,在200至700℃回火时析出,其中溶有Cr,Mn,Mo,V,随回火温度升高,Cr含量从2.6%增至19.5%;(2)M_7C_3,在400℃以上回火时析出,其中含Cr20—30%,还溶有Mn和Mo;(3)M_4C_3,在高于500℃回火时析出,其中M为V,Mo,Cr,其原子比为V:Mo:Cr≈7:1:1。 本文还研究了碳化物的形貌和分布特征,以及与淬火亚结构的关系,初步分析了它们对钢的低温冲击韧性的影响。

关键词: 4335V钢 , carbide , tempering

ATOMIC DIFFUSION CONTROL DURING TEMPERING OF STEEL 20Cr11MoVNbNB

FU Changpu HAN Yong Shaanxi Mechanical Engineering Institute , Xi'an , China FU Changpu , associate professor , Department of Materials Engineering , Shaanxi Mechanical Engineering Institute , Xi'an 710048 , China

金属学报(英文版)

Studies were made of the effect of tempering at temperatures from 25 to 750℃ for 0.5 to 100 h on changes of hardness,precipitated phase and its alloying element content as well as activation energy of tempering for quenched steel 20Cr11MoVNbNB.Tempering of the steel at temperatures below 400℃ may be controlled by the diffusion of C atoms in α-Fe,and above 400℃,by diffusion of Cr,also Mo or V,in α-Fe.

关键词: steel 20Cr11MoVNbNB , null , null , null

EFFECTS OF RARE EARTH METALS ON MICROSTRUCTURAL TRANSFORMATION OF LOW OR MEDIUM CARBON Si-Mn-V STEELS DURING QUENCHING AND TEMPERING

WANG Xiaotian YAO Yinliang SHAO Tanhua Xi′an Jiaotong University , Xi′an , China

金属学报(英文版)

The microstruetural transformation of steels:20SiMn2V,20SiMn2VRE,40SiMn2V and 40SiMn2VRE during quenching and tempering have been examined by TEM,X-ray diffraction and dilatometer.It was shown that the addition of rare earth metals not only can refine the austenite grains of the low or medium carbon steels and packet of lath martensite and lath size,lower the M_s temperature,but can also raise the relative percentage of disloca- tion substructure of martensite in medium carbon steel,but there is little effect on volume frac- tion and thermal stability of retained austenite quenching and tempering structure of low or medium carbon steels.The rare earth metals may remarkably inhibit the decomposition of low carbon martensite during low temperature tempering,retard the precipitation of cementite plates in lath grains and delay the spheroidization of carbides.They may also restrain obvious- ly the precipitation and spheroidization of cementite in medium carbon martensite during high temperature tempering.

关键词: rare earth metals , null , null , null

EFFECTS OF TEMPERING TEMPERATURE AND TIME ON SHEAR MODULUS OF Fe-Mn BASED ALLOYS

TAN Yanchang ZHAO Yuhua WEI Shuning Northeast University of Technology , Shenyang , China

金属学报(英文版)

Effects of the tempering temperature and time on the shear modulus of Fe-Mn based alloys have been studied.The results show that(ΔG/G)-Tcurves of tempered alloys containing Cr and Ti have two extreme values—maximum and minimum,and that the curves of tem- pered alloys containing Cr,Ni,W and C only have a maximum value.This is the reason that Ni,W and C decrease the transformation point T_N of the antiferromagnetism.The ΔG_λ ef- feet increases gradually with the rise of tempering temperature or with the increase of tem- pering time.

关键词: Fe-Mn based alloys , null , null , null

TEMPERING RESPONSE OF A DEFORMED LOW CARBON DUAL PHASE STRUCTURE

JIN Man , JIANG Zhonghao , NAN Shenghui , HU Jiandong , LIAN jianshe(Jilin University of Technology , Changchun , China)(Manuscript received 8 February 1995)Correspondent:LI Geping , (Institute of Metal Research , Chinese Academy of Sciences , Shenyang 110015 , China)

金属学报(英文版)

The low carbon dual phase structure was cold de formed first,then was tempered at 200 to 600℃.The variation in strength and ductility during tempering of the steel was investigated.It was found that a fter the de formed dual phase structure was tempered at 200 to 600℃, with the increase in the tempering temperature the tensile strength decreases rapidly;the lotal elongation remains constant at 200 to 500℃ but began to rise dramatically at a critical temperature between 500 and 600℃.However,when the non-deformed dual phase structure was tempered at the same temperature range,the tensile strength decreases and the total elongation increases continuously with the increase of temperature.It was demonstrated from TEM analysis that precipitating carbides density along the boundaries ofmartensite lath and the recrystallized grains are responsible for the tempering response ofthe de formed dual phase structure.

关键词: :de formed dual phase structure , null , null

CARBIDES IN STEEL 4335 V

ZHONG Jiaxiang ZHENG Xiuhua XU Zongrui Beijing Institute of Technology , Beijing , ChinaBAI Dezhong Nei Monggol Machine Works No.2 , Nei Monggol , China Beijing Institute of Technology , Beijing 100081 , China

金属学报(英文版)

Three types of alloy carbides have been observed in tempered steel 4335V:M_3C,M_7C_3 and M_4C_3.The precipitation temperatures are 200—700,400 and 500 ℃ respectively.The com- position,morphologies and distribution patterns of the carbides as well as the relationship be- tween them and as-quenched substructures have been investigated.The influence of the car- bides on the low temperature impact toughness of the steel has also been discussed.

关键词: steel 4335V , null , null

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