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作为电子传送材料的新型含吡啶大环化合物合成与性质

李廷希 , 黄仁和

功能材料

合成并表征了新型含吡啶大环化合物-TMCD衍生物,包括二甲基TMCD、四甲基TMCD、二萘TMCD,研究发现这些化合物在有机电致发光器件中是有用的电子传送材料.

关键词: 含吡啶大环化合物 , TMCD衍生物 , 有机致电发光 , 电子传送材料

Organic Electrofluorescent Materials Using Pyridine-Containing Macrocyclic Compounds

Tingxi LI , Long FU , Wenwen YU , Renhe HUANG

材料科学技术(英)

Novel pyridine-containing macrocyclic compounds, such as 6,12,19,25-tetramethyl-7,11,20,24-dinitrilo-dibenzo[b,m]1,4,12,15-tetra-azacyclodoc osine (TMCD), were synthesized and used as electron transport layer in organic electroluminescent devices. Devices with a structure of glass/indium-tin oxide/arylamine derivative/tris(quinolinolato)aluminum(III) (Alq)/TMCD/LiF/Al exhibited green emission from the Alq layer with external quantum efficiency of 0.84% and luminous efficiency of 1.3 lm/W. The derivatives of TMCD were synthesized and characterized as well. These compounds were also found to be useful as the electron-transporting materials in organic electroluminescent devices.

关键词: Pyridine-containing macrocyclic compound , 有机电致发光 , 电子传输材

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